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At least 433 records · Page 24

O · , H · , and · OH radical etching probability of polystyrene obtained for a radio frequency driven atmospheric pressure plasma jet

Atmospheric pressure plasma jets have great potential for the surface modification of polymers. In this work, the authors report on polystyrene etching by a radio frequency driven atmospheric pressure plasma jet with a focus on the role of H · , O · , and · OH radicals in this process. The absolute flux of H · , O · , and · OH radicals reaching the surface of the polymer was determined by a COMSOL MULTIPHYSICS reacting fluid dynamics model incorporating detailed transport phenomena in the boundary layer near the substrate. The simulated results of H · and · OH densities in the jet effluent were experimentally verified by two-photon absorption laser induced fluorescence and laser induced fluorescence, respectively. The carbon atom removal flux from the polystyrene surface was taken from previously reported measurements using the same plasma source. The authors show that the boundary layer effects in the interfacial region above the substrate can have a significant impact on the calculated etching probabilities. The reaction probability (β) has a significant uncertainty although a variation of 2 orders of magnitude in β leads to uncertainties of approximately 1 order of magnitude variation in the determined etching probability. The etching probability of polystyrene by · OH radicals was confirmed to be at least an order of magnitude larger than the polystyrene etching probability by O · radicals. The authors also confirmed the weak polystyrene etching probability by H · radicals. The model suggests that the presence of a 30 ppm O 2 impurity can lead to the production of · OH radicals in the far effluent of the Ar + 1% H 2 plasma jet close to the substrate at sufficient densities to enable effective etching.

36 MATERIALS SCIENCE↗

Effect of grain-boundary θ-Al 2 Cu precipitates on tensile and compressive creep properties of cast Al–Cu–Mn–Zr alloys

Tensile and compressive creep tests were performed at 300 °C on high-temperature Al–Cu–Mn–Zr (ACMZ) alloys with 6 wt% Cu (6Cu) and 9 wt% Cu (9Cu) to evaluate the effect on creep properties of micron-size θ-Al 2 Cu intergranular precipitates. For compressive creep, the increased volume fraction of θ-precipitates at grain boundaries (from ~0.7% in 6Cu to ~ 6% in 9Cu) does not affect deformation rates across the investigated stress range of 15–110 MPa, consistent with creep being controlled by submicron θ'-Al 2 Cu precipitates within grains, whose size and fractions are the same in both alloys. In contrast, for tensile creep, 9Cu creeps faster than 6Cu at stresses above 20 MPa, and this difference increases with the stress level. Additionally, this discrepancy between tensile and compressive creep behavior is explained by cavitation during tensile creep, which is favored by higher volume fraction and larger size of intergranular θ precipitates in 9Cu. Conversely, larger precipitates impede cavity linkage resulting in improved creep ductility of 9Cu as compared to 6Cu at 300 °C.

36 MATERIALS SCIENCE↗

A simplified fourwall interference assessment procedure for airfoil data obtained in the Langley 0.3-meter transonic cryogenic tunnel

A simplified fourwall interference assessment method has been described, and a computer program developed to facilitate correction of the airfoil data obtained in the Langley 0.3-m Transonic Cryogenic Tunnel (TCT). The procedure adopted is to first apply a blockage correction due to sidewall boundary-layer effects by various methods. The sidewall boundary-layer corrected data are then used to calculate the top and bottom wall interference effects by the method of Capallier, Chevallier and Bouinol, using the measured wall pressure distribution and the model force coefficients. The interference corrections obtained by the present method have been compared with other methods and found to give good agreement for the experimental data obtained in the TCT with slotted top and bottom walls.

Murthy, A. V.↗

Effects of a rough boundary surface on polarization of the scattered field from an inhomogeneous medium

A combination of the standard Kirchhoff method for rough surface scattering with the Rayleigh phase function radiative transfer method for volume scattering is employed in the present study of the effect of surface roughness on the polarization of the scattered field. It is found that for pure surface scattering, the polarization ratio between zero and 20 deg incidence angles is sensitive to surface roughness change. When both surface and volume scattering are present, however, copolarization nulls by colatitude or degree of polarization at zero to 15 deg incidence angle, and copolarization or crosspolarization nulls by longitude at large incidence angles, are better indicators of surface roughness changes. It is noted that degree of polarization and copolarization nulls by colatitude vary monotonously with incidence angle, while in combined surface and volume scattering these have, respectively, a minimum and a maximum. This characteristic allows the separation of combined surface and volume scattering from pure surface or volume scattering.

Fung, A. K.↗

The Effect of Compressibility and Outer Boundaries on Incipient Viscous Fingering

The knowledge of the effects of instability and heterogeneity on displacements, primarily enhanced oil recovery, and carbon dioxide storage are well known, although they remain difficult to predict. Here, the usual recourse to modeling these effects is through numerical simulation. Simulation remains the gold standard for prediction; however, its results lack generality, being case-specific. There are also several analytic models for displacements that are usually more informative than simulation results. However, these methods apply to steady-state, incompressible flow.

02 PETROLEUM↗

Calculation of heat transfer on shuttle type configurations including the effects of variable entropy at boundary layer edge

A relatively simple method is presented for including the effect of variable entropy at the boundary-layer edge in a heat transfer method developed previously. For each inviscid surface streamline an approximate shockwave shape is calculated using a modified form of Maslen's method for inviscid axisymmetric flows. The entropy for the streamline at the edge of the boundary layer is determined by equating the mass flux through the shock wave to that inside the boundary layer. Approximations used in this technique allow the heating rates along each inviscid surface streamline to be calculated independent of the other streamlines. The shock standoff distances computed by the present method are found to compare well with those computed by Maslen's asymmetric method. Heating rates are presented for blunted circular and elliptical cones and a typical space shuttle orbiter at angles of attack. Variable entropy effects are found to increase heating rates downstream of the nose significantly higher than those computed using normal-shock entropy, and turbulent heating rates increased more than laminar rates. Effects of Reynolds number and angles of attack are also shown.

Dejarnette, F. R.↗

Surface-cooling effects on compressible boundary-layer instability

The influence of surface cooling on compressible boundary layer instability is discussed theoretically for both viscous and inviscid modes, at high Reynolds numbers. The cooling enhances the surface heat transfer and shear stress, creating a high heat transfer sublayer. This has the effect of distorting and accentuating the viscous Tollmien-Schlichting modes to such an extent that their spatial growth rates become comparable with, and can even exceed, the growth rates of inviscid modes, including those found previously. This is for moderate cooling, and it applies at any Mach number. In addition, the moderate cooling destabilizes otherwise stable viscous or inviscid modes, in particular triggering outward-traveling waves at the edge of the boundary layer in the supersonic regime. Severe cooling is also discussed as it brings compressible dynamics directly into play within the viscous sublayer. All the new cooled modes found involve the heat transfer sublayer quite actively, and they are often multi-structured in form and may be distinct from those observed in previous computational and experimental investigations. The corresponding nonlinear processes are also pointed out with regard to transition in the cooled compressible boundary layer. Finally, comparisons with Lysenko and Maslov's (1984) experiments on surface cooling are presented.

Seddougui, Sharon O.↗

Strain energy release rate distributions for double cantilever beam specimens

A 24-ply composite double cantilever-beam specimen under mode I (opening) loading has been analyzed by a 3D FEM code that calculated along a straight delamination starter for several different specimen materials. An isotropic specimen was found to have a strain-energy release rate distribution which varied along its delamination front due to the boundary-layer effect and another effect associated with the anticlastic curvature of the bent specimen arms. A 0-deg graphite-reinforced epoxy specimen had a nearly-uniform strain-energy release rate distribution which dropped only near the edge, due to the boundary-layer effect, and a +/- 45-deg graphite/epoxy specimen exhibited a pronounced strain-energy release rate variation across the specimen width.

Crews, J. H., Jr.↗

Surface-cooling effects on compressible boundary-layer instability, and on upstream influence

The influence of surface cooling on compressible boundary-layer instability is discussed theoretically for both viscous and inviscid modes, at high Reynolds numbers, with related questions on upstream influence being considered in an Appendix. The cooling enhances the surface heat transfer and velocity gradient, crating a high-heat-transfer sublayer. This has the effect of distorting and accentuating the viscous Tollmien-Schlichting modes to such an extent that their spatial growth rates becomes comparable with, and can even exceed, the growth rates of inviscid modes, including those found previously. This is for moderate cooling, and it applies at any Mach number. In addition, the moderate cooling destabilizes otherwise stable viscous or inviscid modes, in particular triggering outward-traveling waves at the edge of the boundary layer in the supersonic regime. Severe cooling is also discussed as it brings compressible dynamics directly into play within the viscous sublayer. All the new cooled modes found involve the heat-transfer sublayer quite actively, and they are often multistructured in form and may be distinct from those observed in previous computational and experimental investigations. The corresponding nonlinear processes are also pointed out with regard to transition in the cooled compressible boundary layer. Finally, comparisons with Lysenko and Maslov's (1984) experiments on surface cooling are presented.

Seddougui, S. O.↗

The Effects of Rotation on Boundary Layers in Turbomachine Rotors

The boundary layers in turbomachine rotors are subject to Coriolis forces which can (1) contribute directly to the development of secondary flows and (2) indirectly influence the behavior of boundary layers by augmentation and/or suppression of turbulence production in the boundary layers on blades. Both these rotation-induced phenomena are particularly important in the development of understanding of flow and loss mechanisms in centrifugal and mixed flow machines. The primary objective of this paper is to review the information available on these effects.

Johnston, J. P.↗

Effects of Forward- and Backward-Facing Steps on the Crossflow Receptivity and Stability in Supersonic Boundary Layers

The effects of forward- and backward-facing steps on the receptivity and stability of three-dimensional supersonic boundary layers over a swept wing with a blunt leading edge are numerically investigated for a freestream Mach number of 3 and a sweep angle of 30 degrees. The flow fields are obtained by solving the full Navier-Stokes equations. The evolution of instability waves generated by surface roughness is simulated with and without the forward- and backward-facing steps. The separation bubble lengths are about 5-10 step heights for the forward-facing step and are about 10 for the backward-facing step. The linear stability calculations show very strong instability in the separated region with a large frequency domain. The simulation results show that the presence of backward-facing steps decreases the amplitude of the stationary crossflow vortices with longer spanwise wavelengths by about fifty percent and the presence of forward-facing steps does not modify the amplitudes noticeably across the steps. The waves with the shorter wavelengths grow substantially downstream of the step in agreement with the linear stability prediction.

Balakumar, P.↗

Experimental Determination of Jet Boundary Corrections for Airfoil Tests in Four Open Wind Tunnel Jets of Different Shapes

This experimental investigation was conducted primarily for the purpose of obtaining a method of correcting to free air conditions the results of airfoil force tests in four open wind tunnel jets of different shapes. Tests were also made to determine whether the jet boundaries had any appreciable effect on the pitching moments of a complete airplane model. Satisfactory corrections for the effect of the boundaries of the various jets were obtained for all the airfoils tested, the span of the largest being 0.75 of the jet width. The corrections for angle of attack were, in general, larger than those for drag. The boundaries had no appreciable effect on the pitching moments of either the airfoils or the complete airplane model. Increasing turbulence appeared to increase the minimum drag and maximum lift and to decrease the pitching moment.

Knight, Montgomery↗

Investigation of Longitudinal and Lateral Stability Characteristics of a Six-Propeller Deflected-Slipstream VTOL Model with Boundary-Layer Control Including Effects of Ground Proximity

An investigation of the longitudinal and lateral stability and control and Performance characteristics of a six-propeller deflected- slipstream vertical-take-off-and-landing (VTOL) model in the transition speed range was conducted in the 17-foot test section of the Langley 300-MPH 7- by 10-foot tunnel. A complete analysis of the data was not conducted. A modest amount of blowing boundary-layer control was necessary to achieve transition without wing stall.

Grunwald, Kalman J.↗

Grain boundary structure search by using an evolutionary algorithm with effective mutation methods

Grain boundaries (GBs) accommodate the misorientation between adjacent grains in a polycrystalline material. GBs are geometrically described by the macroscopic and microscopic degrees of freedom. Besides, at the atomistic level, GBs exhibit complicated behaviors under varying thermodynamic conditions. The complexity of atomistic GB structures demands stochastic searching for possible states. The effectiveness of stochastic search methods relies on techniques to recreate and select atomistic structures. In this work, we developed a new mutation operator that can induce direct and collective atomistic structure changes to boost the search efficiency of exploring GB structures with evolutionary algorithms (EA). We implemented the mutation methods along with innovative selection, crossover, boundary condition preprocessing methods to form an EA-based package to explore GB structures in grand canonical ensembles with atomistic simulations. We used this package to study the [001] symmetric tilt grain boundaries (STGBs) in FCC copper (Cu), the [110] STGBs in BCC tungsten (W), and the $[1\bar{2}10]$ STGBs in HCP magnesium (Mg). The results show that our design and implementation based on new mutation procedures, selection, and boundary conditions provide a high-quality search of atomistic GB structures in the grand canonical ensemble for different crystal lattices.

36 MATERIALS SCIENCE↗