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At least 433 records · Page 24
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NASA NTRS1992

Ground-based infrared measurements of carbonyl sulfide total column abundances - Long-term trends and variability

Attention is given to total vertical column abundances of carbonyl sulfide (OCS) derived from time series of high-resolution IR solar absorption spectra recorded near Tucson, Arizona, and in the Swiss Alps. The analysis of both data sets is based on nonlinear least squares spectral fittings of narrow intervals centered on lines of the intense nu3 band of OCS, the P(37) transition at 2045.5788/cm, and the P(15) transition at 2055.8609/cm, with a consistent set of spectroscopic line parameters. The Arizona measurements, recorded on 20 different days between May 1977 and March 1991, show a 10-percent peak-to-peak seasonal cycle with a summer maximum and a winter minimum and a trend in the total column abundance equal to (0.1 +/-0.2) percent/yr, 2sigma. The Alpine total columns exhibit a more complex seasonal variation than noted in the Arizona data. The results from the two sites indicate that there has been no significant change in the OCS total column abundance at northern midlatitudes over the last decade.

Rinsland, C. P.↗
NASA NTRS1991

Abundance variations in solar energetic particles

Abundance variations are examined in a large number of events including smaller nonimpulsive events not previously considered. Whereas a comparison at equal energy per nucleon is appropriate for heavy ions this is not the case when including H. The best representation is either in terms of rigidity or energy per charge depending on the type of event under consideration. For the majority of large events, where particles are primarily accelerated at interplanetary shocks, if abundances relative to H are evaluated at equal energy per charge then abundance ratios are compatible with solar wind values and spectral shapes agree. Furthermore the behavior of H is then compatible with that of other high FIP elements.

Cane, H. V.↗
NASA NTRS1992

Iron abundance in the hot DA white dwarfs Feige 24 and G191 B2B

Attention is given to model calculations of the far- and extreme-UV line spectra of highly ionized Fe species (Fe IV, Fe V, and Fe VI) for hot high-gravity H-rich stars. A spectral analysis of 31 hr of exposure of the DA white dwarf Feige 24 with IUE in the echelle mode reveals the presence of Fe with an abundance relative to H by number of (5-10) x 10 exp -6 with an uncertainty dominated by the determination of stellar parameters. An analysis of IUE data from the white dwarf G191 B2B results in a similar Fe abundance if this star shares similar atmospheric parameters (Teff, g) with Feige 24. Fe is thus the second most abundant photospheric element in hot DA white dwarfs.

Vennes, Stephane↗
NASA NTRS1993

Constraints on chemical evolution models from QSOALS abundances

Models of the formation and early chemical evolution of our Galaxy are guided and constrained by our knowledge of abundances in globular cluster stars and halo field stars. The abundance patterns identified in halo and disk stars should be discernible in absorption lines of gas clouds in forming galaxies which are accidentally lying in front of background QSO's. Conversely, the ensemble of QSO absorption line systems (QSOALS) at each redshift may suggest a detailed model for the formation of our Galaxy that is testable using abundance patterns in halo stars.

Lauroesch, J. T.↗
NASA NTRS1992

CNO abundances and temperature fluctuations in the Orion Nebula

The largest UV-optical data base to date of the Orion Nebula has been assembled, and the CNO abundances their distribution at a statistically significant number of positions to the north and west of the Trapezium and out to a distance of 5 arcmin has been examined. The forbidden O III temperature increases with distance from Theta1 Ori C while the forbidden N II temperature decreases with increasing distance. The density decreases as a function of increasing distance from Theta1 Ori C. The C/H, N/H, O/H, and C/O distributions are constant across the inner 5 arcmin of the northwestern quadrant of the nebula. The empirically determined mean C/H abundance calculated from UV lines is almost a factor of two lower in the number density than earlier estimates. Photoionization model calculations are consistent with a solar abundance for N/H and O/H.

Walter, Donald K.↗
NASA NTRS1992

Light-element abundances in Population II dwarfs

This paper reviews the abundances of the light elements lithium, beryllium, and boron in main-sequence and subgiant, Population II stars. Li is important to cosmology because it is synthesized in the Big Bang, but is also used to study stellar structure. Beryllium is useful for studying galactic chemical evolution because its formation in the interstellar medium involves different physics to stellar nucleosynthesis, and it thus provides independent data on the evolution of the halo. Some (though not all) inhomogeneous Big Bang nucleosynthesis codes predict a significant primordial component to this element, so its observed abundance may constrain such models. Boron, observations of which became feasible with the operation of the Hubble Space Telescope, provides complementary data to Be, helping check the element ratios predicted by calculations of spallation reactions in the interstellar medium, and will indicate whether the observed Be abundance has an excess over the expected spallation component, indicating a possible primordial component.

Ryan, Sean G.↗
NASA NTRS1992

Water vapor column abundance retrievals during FIFE

A variation of the modified Langley plot algorithm is reported here and applied to the retrieval of atmospheric water column abundance from a filtered sunphotometer. In this new methodology an absorption data base (LOWTRAN 7) is used to compute a water abundance versus transmittance curve of growth, rather than the square-root dependence previously assumed. Validation of the technique is provided from an uncertainty analysis, and plans to further validate using Fourier transform spectrometers are detailed. The new sunphotometer technique is used to report local column water vapor during the First ISLSCP Field Experiment (FIFE), and comparisons are made with abundances retrieved via FIFE radiosonde observations. The sunphotometer data can best be utilized, however, to in turn validate data from airborne or in-orbit measurements of water vapor. With these flight sensors, horizontal and topographic variability within the scene can be viewed. An example of the airborne data set is given using an image from the airborne visible infrared imaging spectrometer, as acquired on August 31, 1990.

Bruegge, Carol J.↗
NASA NTRS1993

Diffusion effects on the helium abundance of the solar transition region and corona

The diffusion of helium in the solar transition region is studied by solving the mass and momentum conservation equations for a hydrogen-helium plasma given a representative temperature profile. Steady state solutions show that two distinct atmospheres may result. In cases where the thermal force on alpha-particles is balanced by the partial pressure gradient force, helium is the dominant coronal species. On the other hand, if it is the frictional force between protons and alpha-particles which balances the thermal force on alpha-particles then hydrogen is the major coronal component. In order to explore which of these solutions are attainable within reasonable time scales, the time-dependent equations are solved, starting from an initial state with a uniform helium abundance of 10 percent. The atmosphere as a whole is close to hydrostatic equilibrium, but due the thermal forces the individual elements are not. This force inbalance leads to a differential flow between species. It is found that this differential flow leads to a significant enhancement of the coronal helium abundance. Even for the relatively shallow temperature gradient used the helium abundance in the lower corona increases to 30 percent over a 24 hr period.

Hansteen, Viggo H.↗
NASA NTRS1993

The abundances of hydrogen, helium, oxygen, and iron accelerated in large solar particle events

Energy spectra measured in 10 large flares with the University of Maryland/Max-Planck-Institut sensors on ISEE I and Goddard Space Flight Center sensors on IMP 8 allowed us to determine the average H, He, O, and Fe abundances as functions of energy in the range of about 0.3-80 MeV/nucleon. Model fits to the spectra of individual events using the predictions of a steady state stochastic acceleration model with rigidity-dependent diffusion provided a means of interpolating small portions of the energy spectra not measured with the instrumentation. Particles with larger mass-to-charge ratios were relatively less abundant at higher energies in the flare-averaged composition. The Fe/O enhancement at low SEP energies was less than the Fe/O ratios observed in He-3-rich flares. Unlike the SEP composition averaged above 5 MeV/nucleon, the average SEP abundances above 0.3 MeV/nucleon were similar to the average solar wind.

Mazur, J. E.↗
NASA NTRS1993

Elemental abundances of flaring solar plasma - Enhanced neon and sulfur

Elemental abundances of two flares observed with the SMM Flat Crystal Spectrometer are compared and contrasted. The first had a gradual rise and a slow decay, while the second was much more impulsive. Simultaneous spectra of seven bright soft X-ray resonance lines provide information over a broad temperature range and are available throughout both flares, making these events unique in the SMM data base. For the first flare, the plasma seemed to be characterized by coronal abundances but, for the second, the plasma composition could not be coronal, photospheric, or a linear combination of both. A good differential emission measure fit required enhanced neon such that Ne/O = 0.32 +/- 0.02, a value which is inconsistent with the current models of coronal abundances based on the elemental first-ionization potential. Similar values of enhanced neon are found for flaring plasma observed by the SMM gamma-ray spectrometer, in (He-3)-rich solar energetic particle events, and in the decay phase of several long duration soft X-ray events. Sulfur is also enhanced in the impulsive flare, but not as dramatically as neon. These events are compared with two models which attempt to explain the enhanced values of neon and sulfur.

Schmelz, J. T.↗
NASA NTRS1993

Estimating modal abundances from the spectra of natural and laboratory pyroxene mixtures using the modified Gaussian model

The modified Gaussian model (MGM) is used to explore spectra of samples containing multiple pyroxene components as a function of modal abundance. The MGM allows spectra to be analyzed directly, without the use of actual or assumed end-member spectra and therefore holds great promise for remote applications. A series of mass fraction mixtures created from several different particle size fractions are analyzed with the MGM to quantify the properties of pyroxene mixtures as a function of both modal abundance and grain size. Band centers, band widths, and relative band strengths of absorptions from individual pyroxenes in mixture spectra are found to be largely independent of particle size. Spectral properties of both zoned and exsolved pyroxene components are resolved in exsolved samples using the MGM, and modal abundances are accurately estimated to within 5-10 percent without predetermined knowledge of the end-member spectra.

Sunshine, Jessica M.↗
NASA NTRS1993

Abundance inhomogeneities and atmospheric structure in CN-bimodal globular cluster giants

It has been suggested by several authors that the sodium and aluminum abundance variations correlating with CN-band strength, frequently observed in CN-bimodal globular cluster giants, could be spurious manifestations of different temperature structures in the 'CN-strong' and 'CN-weak' stars, caused by different molecular line blanketing related to the C, N, and O trio. For stellar parameters generally appropriate to giants in the intermediate metallicity CN-bimodal cluster M4, we demonstrate through new model atmosphere calculations, employing opacity sampling and spherical geometry, that the observed abundance anomalies cannot be the result of atmospheric temperature structure. Our results using spherical geometry are compared to identical calculations performed with plane-parallel geometry: the effects of atmospheric extension on derived abundances for all lines considered amount to less than 0.1 dex.

Drake, Jeremy J.↗
NASA NTRS1993

The abundance of sulfur dioxide below the clouds of Venus

We present a new method for determining the abundance of sulfur dioxide below the clouds of Venus. Absorption by the 3nu3 band of SO2 near 2.45 microns has been detected in high-resolution spectra of the night side of Venus recorded at the Canada-France Hawaii telescope in 1989 and 1991. The inferred SO2 abundance is 130 +/- 40 ppm at all observed locations and pertains to the 35-45 km region. These values are comparable to those measured by the Pioneer Venus and Venera 11/12 entry probes in 1978. This stability stands in contrast to the apparent massive decrease in SO2 observed at the cloud tops since these space missions. These results are consistent with laboratory and modeling studies of the SO2 destruction rates in the lower atmosphere of Venus. The new spectroscopic technique presented here allows a remote monitoring of the SO2 abundance below the clouds, a likely tracer of Venusian volcanism.

Bezard, Bruno↗
NASA NTRS1993

Evidence for a dispersion in the lithium abundances of extreme halo stars

Evidence is presented to the effect that there exists a small dispersion in the lithium abundances of extreme halo dwarfs. This dispersion cannot be accounted for by standard stellar models alone, particularly toward the turnoff, and would thus require early differential Galactic Li enrichment, perhaps independent of metallicity. The magnitude of the dispersion is also consistent with the predictions of evolutionary models of halo stars with rotation, which do not require, but do not rule out either, early Galactic enrichment. These rotational models also predict a significant depletion in the lithium abundance during the stars' lifetime. The rotational models predict that stars which formed with very low initial angular momentum will have lithium abundances measurably above the plateau.

Deliyannis, Constantine P.↗
NASA NTRS1993

Trace-element abundances in several new ureilites

Four new ureilites are analyzed for trace-element abundances. Frontier Mountain (FRO) 90054 is an augite-rich ureilite and has high rare earth element (REE) abundances with a pattern expected of augite. FRO 90036 and Acfer 277 have REE patterns similar to the V-shape pattern of other ureilites. Nuevo Mercurio (b) has very high REE abundances, but they look like they are due to terrestrial alteration. The siderophile-element pattern of these ureilites are similar to those of known ureilites.

Boynton, William V.↗
NASA NTRS1993

Carbon abundances, major element chemistry, and mineralogy of hydrated interplanetary dust particles

Hydrated interplanetary dust particles (IDP's) comprise a major fraction of the interplanetary dust particles collected in the stratosphere. While much is known about the mineralogy and chemistry of hydrated IDP's, little is known about the C abundance in this class of IDP's, the nature of the C-bearing phases, and how the C abundance is related to other physical properties of hydrated IDP's. Bulk compositional data (including C and O) for 11 hydrated IDP's that were subsequently examined by the transition electron microscopy (TEM) to determine their mineralogy and mineral chemistry are reported. Our analysis indicates that these hydrated IDP's are strongly enriched in C relative to the most C-rich meteorites. The average abundance of C in these hydrated IDP's is 4X CI chondrite values. The bulk compositions (including C and O) of 11 hydrated IDP's were determined by thin-window, energy-dispersive x ray (EDX) spectroscopy of the uncoated IDP's on Be substrates in the scanning electron microscopy (SEM). As a check on our C measurements, one of the IDP's (L2006H5) was embedded in glassy S, and microtome thin sections were prepared and placed onto Be substrates. Thin-film EDX analyses of multiple thin sections of L2006H5 show good agreement with the bulk value determined in the SEM. Following EDX analysis, the mineralogy and mineral chemistry of each IDP was determined by analyzing ultramicrotome thin sections in a TEM equipped with an EDX spectrometer.

Keller, L. P.↗
NASA NTRS1994

Abundance determination in solar active region

An improved method has been developed to evaluate element abundances from emission line intensities of thin plasmas, depending on the differential emission measure (DEM) of the source. Observations made by the Solar EUV Rocket Telescope and Spectrograph (SERTS) Rocket EUV Spectrograph are used to perform a detailed analysis of the DEM distribution for temperatures larger than 10(exp 5) K in a solar active region. Comparison of the DEM distributions obtained by means of lines from different elements allows the verification of relative abundances for the most common elements of the solar corona, and gives an abundance estimates for the minor components, such as Na, Al, Ar, Cr, Mn and Zn.

Monsignori Fossi, B. C.↗
NASA NTRS1994

Energetic-particle abundances in impulsive solar flare events

We report on the abundances of energetic particles from impulsive solar flares, including those from a survey of 228 He-3 rich events, with He-3/He-4 is greater than 0.1, observed by the International Sun Earth Explorer (ISEE) 3 spacecraft from 1978 August through 1991 April. The rate of occurrence of these events corresponds to approximately 1000 events/yr on the solar disk at solar maximum. Thus the resonant plasma processes that enhance He-3 and heavy elements are a common occurrence in impulsive solar flares. To supply the observed fluence of He-3 in large events, the acceleration must be highly efficient and the source region must be relatively deep in the atmosphere at a density of more than 10(exp 10) atoms/cu cm. He-3/He-4 may decrease in very large impulsive events because of depletion of He-3 in the source region. The event-to-event variations in He-3/He-4, H/He-4, e/p, and Fe/C are uncorrelated in our event sample. Abundances of the elements show a pattern in which, relative to coronal composition, He-4, C, N, and O have normal abundance ratios, while Ne, Mg, and Si are enhanced by a factor approximately 2.5 and Fe by a factor approximately 7. This pattern suggests that elements are accelerated from a region of the corona with an electron temperature of approximately 3-5 MK, where elements in the first group are fully ionized (Q/A = 0.5), those in the second group have two orbital electrons (Q/A approximately 0.43), and Fe has Q/A approximately 0.28. Ions with the same gyrofrequency absorb waves of that frequency and are similarly accelerated and enhanced. Further stripping may occur after acceleration as the ions begin to interact with the streaming electrons that generated the plasma waves.

Reames, D. V.↗