Averaging by relaxation and the dynamic Jahn-Teller effect
Strontium chloride lanthanum ion system with dynamic Jahn-Teller effect, indicating isotropic EPM spectrum resulting from averaging by relaxation
Boatner, L. A.↗
SEARCH · Engineering Papers
Results for “STRONTIUM”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Inorganic photochromic and cathodochromic recording materials
Inorganic photochromic and cathodochromic recording materials, examining transition metal doped strontium titanates, rare earth doped calcium fluorides and Fe or S doped sodalite
Duncan, R. C., Jr.↗
Electron-paramagnetic-resonance investigation of the dynamic Jahn-Teller effect in SrC12-La/2 plus/
Electron paramagnetic resonance spectral investigation of dynamic Jahn-Teller effect in La doped strontium chloride, discussing structural variations as function of temperature
Boatner, L. A.↗
Hair radioactivity as a measure of exposure to radioisotopes
Since many radioisotopes accumulate in hair, this tropism was investigated by comparing the radioactivity of shaved with plucked hair collected from rats at various time intervals up to 24 hrs after intravenous injection of the ecologically important radioisotopes, iodine-131, manganese-54, strontium-85, and zinc-65. The plucked hair includes the hair follicles where biochemical transformations are taking place. The data indicate a slight surge of each radioisotpe into the hair immediately after injection, a variation of content of each radionuclide in the hair, and a greater accumulation of radioactivity in plucked than in shaved hair. These results have application not only to hair as a measure of exposure to radioisotopes, but also to tissue damage and repair at the hair follicle.
Strain, W. H.↗
Engineering experimental program on the effects of near-space radiation on lithium doped solar cells
The results of an experimental evaluation of the real-time degradation characteristics of lithium-diffused silicon solar cells are reported. A strontium-90 radioisotope was used for simulation of a typical earth-orbital electron environment. The experiment was performed in an ion pump vacuum chamber with samples maintained at -50, +20, +50, and +80 C. Samples were illuminated during the 6-month exposure run with solar cell 1-5 characteristics measured periodically in situ. This 6-month exposure corresponded to a 1 MeV equivalent fluence of approximately 10 to the 14th power electrons/sq cm. Several types of lithium cells were irradiatied and compared directly with conventional N/P cells. The best lithium cells compared favorably with N/P cells, particularly at the higher test temperatures. With a slight improvement of initial performance characteristics, lithium cells appear feasible for 5 to 10 year missions at synchronous altitude. Based on the reported results and those of other irradiation experiments, lithium cells would appear to be superior to N/P cells in proton-dominated earth-orbital environments. Another important conclusion of the effort was that illuminated/loaded cells degrade more rapidly than do dark/unloaded cells. The irradiation experiment provided data of high quality with a high degree of confidence because of the experimental and statistical analysis techniques utilized.
Source record↗
Upper Cenozoic basalts with high Sr-87/Sr-86 and Sr/Rb ratios, southern Great Basin, western United States.
The initial strontium isotopic composition of 15 mafic volcanic rocks from the southern Great Basin has been determined. Results indicate that the basalts must have been derived from unusual mantle material in which an originally high Rb/Sr ratio was markedly lowered during an earlier phase of magmatic activity.
Hedge, C. E.↗
Partitioning of Eu and Sr between coexisting plagioclase and K-feldspar.
Minerals were separated by an EM approach and with the aid of liquids of great density. An analysis of K, Rb, Ca, Sr, Ha, and rare earth elements was conducted by means of a mass spectrometer isotope dilution technique. The behavior of the divalent europium ions during the partition process was found to be very similar to that of divalent strontium ions, taking into consideration data of the partition coefficients between coexisting feldspars in acidic rocks.
Nagasawa, H.↗
Photogeology. Part A: Relative ages of some near-side and far-side terra plains based on Apollo 16 metric photography
Relative age measurements were made for 14 light plains areas, using 30X enlargements of Apollo 16 metric camera photography. Results indicate that: (1) Crater morphology and frequency studies consistently indicate that the Fra Mauro Formation has received 2.5 to 3 times as much impact flux as the Cayley Formation. (2) Crater counts and relative age dating indicate that the Cayley Formation is only slightly older than the oldest mare units. (3) Assuming the rubidium-strontium ages of Apollo 14 basalt breccias give minimum age for Fra Mauro Formation, the Cayley Formation must have been generated throughout a period of less than 100 million years, approximately 3.8 to 3.9 billion years ago. (4) The Cayley Formation ages obtained on the near side and far side are the same, indicating a synchrony throughout the moon in these units. (5) The linear relationship as predicted by the small impact erosion model between net accumulated flux and the maximum diameter of a crater that could be eroded below recognition is confirmed.
Soderblom, L. A.↗
The origin of the moon and solar system.
The Rb-87/Sr-87 ages of many of the lunar rocks suggest that the fundamental differentiation took place 4.5 b.y. ago and that remelting occurred without exchange of the rubidium and strontium with the surroundings. The Apollo A rocks are an exception to this. They appear to have acquired rubidium without all of the Sr-87 produced during the first aeon. Also in the remelting about half of the radiogenic leads were lost to the surroundings by a vaporization process. We interpret these results to mean that remelting occured in a system that was nearly closed to the surroundings and that the high early concentrations of radioactive elements in highly insulating surroundings made this possible.
Urey, H. C.↗
Results of a real-time irradiation of lithium P/N and conventional N/P silicon solar cells.
Eight types of lithium-diffused P/N and three types of conventional 10 ohm-cm N/P silicon solar cells were irradiated at four different temperatures with a strontium-90 radioisotope at a rate typical of that expected in earth orbit. The six-month irradiation confirmed earlier accelerator results, showed that certain cell types outperform others at the various temperatures, and, in general, verified the recent improvements and potential usefulness of lithium solar cells. The experimental approach and statistical methods and analyses employed yielded increased confidence in the validity of the results. Injection level effects were observed to be significant.
Reynard, D. L.↗
Measurement of radiation exposure of astronauts by radiochemical techniques
A cosmic radiation dose to the Apollo 17 crew of 1.3 R was calculated from the specific activities of Na-24 in their postflight urine specimens. The specific activities of K-42, Cr-51, Co60, and Sb-124, introduced by injection into the astronauts, are extremely high in these specimens. The Fe-59 and Cs-137 levels are also reported and appear to be normal. The concentrations of Na, K, Rb, Cs, Ca, Sr, Ba, Cr, Fe, Co, Ag, Au, Zn, Cd, Hg, Sn, As, Sb, Se, Br, Sc, La, Sm, Eu, Tb, Hf, Ta, and Th were measured in urine specimens from the Apollo 17 astronauts by neutron activation analysis. Strontium, barium, gold, cadmium, lanthanum, samarium, europium, terbium, thorium, and tin are reported for the first time. The concentrations or excretion rates of bromine and the alkali metals exhibit singificantly reduced postflight levels and are generally lower than values observed for previous missions. Chromium concentrations reflect radiochromium injections.
Brodzinski, R. L.↗
Metallic oxide switches using thick film technology
Metallic oxide thick film switches were processed on alumina substrates using thick film technology. Vanadium pentoxide in powder form was mixed with other oxides e.g., barium, strontium copper and glass frit, ground to a fine powder. Pastes and screen printable inks were made using commercial conductive vehicles and appropriate thinners. Some switching devices were processed by conventional screen printing and firing of the inks and commercial cermet conductor terminals on 96% alumina substrates while others were made by applying small beads or dots of the pastes between platinum wires. Static, and dynamic volt-ampere, and pulse tests indicate that the switching and self-oscillatory characteristics of these devices could make them useful in memory element, oscillator, and automatic control applications.
Patel, D. N.↗
The distribution of Sr and REE between diopside and silicate liquid
Experimental determination of the distribution coefficients in diopside-liquid pairs for strontium and nine rare-earth elements in the system CaMgSi2O6-NaAlSi3O8-CaAl2Si2O8. In experiments in air at 1265 C it is found that most of the Sr(2+), Eu(2+), and RE(3+) ions substitute for Ca(2+) and, in addition, a coupled substitution of Al(3+) for Si(4+) occurs. All of the trace ions considered are found to be excluded from the diopside lattice relative to the liquid. In the case of the trivalent ions the exclusion is much more pronounced for La and Ce, which have ionic radii larger than that of Ca(2+) in 8-fold oxygen coordination. Divalent Sr and Eu with even larger radii are also strongly excluded.
Grutzeck, M.↗
Experiments on the origins of optical activity
An investigation was conducted concerning the asymmetric adsorption of phenylalanine enantiomers by kaolin. No preferential adsorption of either phenylalanine enantiomer could be detected and there was no resolution of the racemic phenylalanine by kaolin. The attempted asymmetric polymerization of aspartic acid by kaolin is also discussed along with a strontium-90 bremsstrahlung radiolysis of leucine.
Bonner, W. A.↗
The alkaline earth intercalates of molybdenum disulfide
Molybdenum disulfide has been intercalated with calcium and strontium by means of the liquid ammonia technique. Chemical, X-ray, and superconductivity data are presented. The X-ray data reveal a lowering of crystal symmetry and increase of complexity of the structure upon intercalation with the alkaline earth metals. The Ca and Sr intercalates start to superconduct at 4 and 5.6 K, respectively, and show considerable anisotropy regarding the critical magnetic field.
Somoano, R. B.↗
Thermospheric wind measurements in the polar region
In order to study the coupling of neutral atmospheric motions with solar wind induced effects, the neutral wind and ion flow velocities were simultaneously measured at an altitude of 225 km in the polar cap F-region by releasing barium and strontium tracers from sounding rockets launched on 22 and 24 August 1971, and 10 December 1972. Ion and neutral cloud trajectories for 22 and 24 August experiments were plotted, and in both cases an anti-solar flow was deduced from the ion tracks. During the December experiment a southern and northern cloud were observed, and the magnitude of the pressure force deduced from the southern cloud motion was found in agreement with OGO-6 measurements. This confirmed that a local temperature maximum is located in the winter polar thermosphere.
Kelley, M. C.↗
Process for growing thin polished silicon sheets
Single-crystal sheets pulled from polten silicon floating on refractory melt require no slicing or polishing. Possible materials are chlorides and fluorides of barium, calcium, and strontium. Refractory melt may be able to absorb impurities from silicon and thus obviate postgrowth purification.
Radics, C. C.↗
Rare earth and trace element geochemistry of a fragment of Jurassic seafloor, Point Sal, California
Rocks from an ophiolite suite once on the seafloor were analyzed for rare earth elements (REE), Sc, Co, Na2O, Cr, Zn and FeO. Strontium isotope exchange noted in some of the lavas is attributed to basalt-seawater interaction; the Ce abundance in smectite- and zeolite-bearing lavas may also be due to prolonged exposure to seawater. The higher grades of metamorphic rock, however, show no variation from the usual flat or slightly light REE depleted profiles. Plutonic igneous rock, all light REE depleted, have total REE abundances varying by a factor of 100 between the dunites and diorites. In order of decreasing REE abundance are hornblende, clinopyroxene, plagioclase, orthopyroxene and olivine. Calculations of REE contents of liquids in equilibrium with early cumulative clinopyroxenes suggest that the parent to the stratiform sequence was more depleted in light REE than the parent to the lava pile.
Menzies, M.↗