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At least 433 records · Page 24

Origins of etioporphyrins in sediments - Evidence from stable carbon isotopes

In samples of the Julia Creek and Condor oil shales (Australia, Albian, and early Tertiary, respectively) etioporphyrin III is significantly depleted in C-13 (4 per mil) relative to porphyrins derived from chlorophylls. This isotopic difference suggests a large contribution from some independent source. The haem group found in cytochromes derived from microbial sources is the most likely candidate.

Boreham, Christopher J.↗

Helium and neon isotopes in deep Pacific Ocean sediments

Helium and neon concentration measurements, along with isotope ratio determinations, have been made for particles collected in the deep Pacific with a magnetic sled, and they are believed to be of extraterrestrial origin. Analyses were made for samples consisting of composites of many extremely fine particles and for several individual particles large enough to contain sufficient gas for analysis but small enough to escape melting in their passage through the atmosphere. Step-heating was employed to extract the gas. Cosmic-ray spallation products or solar-wind helium and neon, if present, were not abundant enough to account for the isotopic compositions measured. In the case of the samples of magnetic fines, the low temperature extractions provided elemental and isotopic ratios in the general range found for the primordial gas in carbonaceous chondrites and gas-rich meteorites. The isotopic ratios found in the high temperature extractions suggest the presence of solar-flare helium and neon.

Nier, A. O.↗

Large-scale patterns of eolian sediment transport on Venus - Predictions for Magellan

The atmosphere of Venus is likely to exert a major influence on the surface. Arecibo and Venera 15/16 observations of the population of impact craters with bright halos give direct evidence of surface modification, on the scale of centimeters, to smooth the surface on time scales of 50 - 250 my. Both chemical and mechanical modifications probably occur. Diurnal winds in the planetary boundary layer can transport particles. Using boundary layer theory, including the effects of topography, surface stresses and resulting transport and deposition of sand-size particles are calculated. Regional slopes are sites of largest surface stresses. Sand will be generally transported downhill, although there is a preferential net transport from east to west, in the same direction as the atmospheric superrotation. It is predicted here that streaks may be seen in the Magellan radar images which will indicate directions of net eolian transport on the surface of Venus.

Saunders, R. S.↗

The global budget of impact-derived sediments on Venus

The sedimentary cycle of Venus is examined, with specific attention to the contribution from impact events. The observed record of impact craters on the surface of Venus can be used to calculate the contribution of fine materials generated by impact processes to the global sedimentary cycle. Ejecta volume calculations carried out on the basis of various crater population scenarios suggest that the maximum global ejecta layer thickness over the past 1 Gyr is about 1-2 mm. This would translate to a global accumulation rate of only 0.002 to 0.01 micron per year. Moreover, most of this material could never have been available for global transport; it is projected that over 90 percent of the ejecta would be deposited within 1-3 radii of the crater rim, and only 0.02-0.05 percent could be available as fine dust for global sedimentary cycle. Therefore, the global layer thickness of transportable impact-derived dust can be no more than a few mm over the past 1 Gyr.

Garvin, James B.↗

Fine structure of the late Eocene Ir anomaly in marine sediments

The Late Eocene Ir abundance profile in deep sea cores from Ocean Drilling Program Leg 113 Hole 689B on the Maude Rise off of Antarctica was studied with 410 samples continuously in 10 cm increments and measured with the Iridium Coincidence (ICS). The ICS was subsequently modified to measure 13 other elements simultaneously with the Ir. The abundance profiles of these elements were then determined in the Late Eocene Massignano section in central Italy with 250 samples (encompassing roughly 2 million years of accumulation) which were collected about every 5 cm in about 2 cm increments. These studies augmented a previous one (which included many elements) of deep sea cores from Deep Sea Drilling Project Site 592 on the Lord Howe Rise in the Tasman Sea between Australia and New Zealand. In the latter study, 50 samples (encompassing roughly 0.7 million years of accumulation) were collected continuously in 10 cm increments. The results from these studies are discussed.

Asaro, F.↗

Search for microaustralites in deep-sea sediments less than 20,000 years old

Several authors have proposed that australites fell less than 20,000 years ago. We searched for microtektites in the tops of 46 deep-sea cores and were unable to find evidence for a microtektite layer less than 20,000 years old. Either the australite fall was not accompanied by microtektites, or the strewnfield did not extend into the area searched, or the australites fell about 0.77 Ma ago as indicated by their radiometric ages.

Glass, B. P.↗

Martian aeolian processes, sediments, and features

In this review of the aeolian regime on Mars, consideration is given to the sources and characteristics of the particles that are involved in aeolian processes and the winds that are required to set grains into motion. Dust storms are reviewed and previous observations and the mechanisms of dust-storm generation are assessed. Various aeolian features, including dunes and albedo features, as well as windblown mantle deposits are discussed. In planning for future missions to Mars, aeolian processes must be taken into account. Surface modifications by the wind and windblown deposits can influence remote-sensing observations, affect sampling strategies, and have detrimental effects on manned and unmanned spacecraft on the surface.

Greeley, Ronald↗

Atmospheric tides on Venus. IV - Topographic winds and sediment transport

A novel theory is presented for the Venus boundary layer which encompasses the effects of topography and uses the mixing-length hypothesis to preclude the unknown eddy viscosity. The maps of mass-flux and erosion/deposition rate presented are based on Pioneer Venus orbiter relief measurements. The typically 19 cm/sec friction speeds associated with the present theory are several times greater than those estimated on the basis of Venera 9 and 10 anemometry, and mean aeolian transport is generally away from the equator, contrary to Magellan orbiter windstreak directions.

Dobrovolskis, Anthony R.↗

Sulfur transformations in the sediments of a New Hampshire salt marsh

Summer sulfate reduction and sulfide and iron chemistry were monitored in marsh soils along a gradient from a creekside Spartina alterniflora region to an inland area dominated by S. patens. Sulfate reduction rates measured using S-35 increased from 0.4 in June to as much as 4.5 micro-mole/ml(sup -1)d(sup -1) in July in S. alterniflora soils with most rapid rates occurring in the upper few cm. Rates in S. patens soils were approximately equal to 5-8 fold slower with the most rapid rates occurring generally in soils deeper than 10 cm. The recovery percentage of reduced S-35 sulfur varied with depths at both locations; dissolved and acid-volatile sulfides dominating S. alterniflora regions while chromium-reducible solid phases were abundant in S. patens soils. Dissolved sulfide in S. alterniflora soils increased throughout the summer to approximately equal to 2.8 mM while sulfide in S. patens soils was abundant only in soils deeper than 15 cm. Dissolved sulfide covaried inversely with iron. Diel studies demonstrated that sulfide and iron varied approximately equal to two-fold in response to a semi-diurnal tide. Dissolved sulfide turnover was most rapid during periods of active plant growth.

Hines, Mark E.↗

Sedimentation, volcanism, and ancestral lakes in the Valles Marineris: Clues from topography

Compilation of a simplified geologic/geomorphic map onto a digital terrain model of Valles Marineris has permitted quantitative evaluations of topographic parameters. The study showed that, if their interior layered deposits are lacustrine, the ancestral Valles Marineris must have consisted of isolated basins. If, on the other hand, the troughs were interconnected as they are today, the deposits are most likely to volcanic origin, and the mesas in the peripheral troughs may be table mountains. The material eroded from the trough walls was probably not sufficient to form all of the interior layered deposits, but it may have contributed significantly to their formation.

Lucchitta, B. K.↗

Carbon Isotope Biogeochemistry of Methane from Anoxic Sediments

The isotopic composition of naturally occurring methane was used to constrain the tropospheric budget of that radiatively active gas. Numerous studies have shown that the isotopic composition is not constant, even for a specific source, and may vary temporally and spatially. The objective was to develop a process-level model that reproduced the seasonal variations in the C-13/C-12 composition of methane observed at the coastal site, Cape Lookout Bight, NC. Details of the mass balance are provided. Experiments and models designed to determine what factors incluence C-13/C-12 ratio of dissolved CO2 are reported. All the factors described were combined in a model that faithfully reproduces the seasonal C-13/C-12 variations observed at Cape Lookout. The model is described.

Blair, Neal E.↗

The carbon isotope biogeochemistry of (epsilon)CO2 production in a methanogenic marine sediment

To investigate the relationship between sigma(CO2) delta(C-13) values and rates of the dominant remineralization processes at the organic-rich field site of Cape Lookout Bight, NC, the isotopic composition of porewater sigma(CO2) was measured on a seasonal basis. The sigma(CO2) delta(C-13) values varies seasonally in response to changes in rates of sulfate reduction and methanogenesis, the dominant remineralization processes at this site. A tube incubation experiment was also performed to determine the isotopic signature of the sigma(CO2) produced by sulfate reduction and methanogenesis. The delta(C-13) of the sigma(CO2) produced in the sulfate reduction zone determined from the tube incubation was -14.3 plus or minus 1.9, a value enriched in C-13 relative to the labile organic fraction. The C-13-enrichment may be caused by low rates of methanogenesis occurring in the sulfate reduction zone. The delta(C-13) of the sigma(CO2) produced in the methanogenic zone was estimated to be +44 per mil, whereas the co-produced methane was -65 per mil. The fractionation factor for CO2 reduction was calculated to be 1.055, a value in agreement with previous estimates at this site. The measured concentration and delta(C-13) of the sigma(CO2) at Cape Lookout was closely reproduced by a diagenetic model using the measured rates of sulfate reduction and sigma(CO2) production, and the isotopic signature of the sigma(CO2) production in the two biogeochemical zones.

Boehme, Susan E.↗

Near-Surface Geologic Units Exposed Along Ares Vallis and in Adjacent Areas: A Potential Source of Sediment at the Mars Pathfinder Landing Site

A sequence of layers, bright and dark, is exposed on the walls of canyons, impact craters and mesas throughout the Ares Vallis region, Chryse Planitia, and Xanthe Terra, Mars. Four layers can be seen: two pairs of alternating dark and bright albedo. The upper dark layer forms the top surface of many walls and mesas. The upper dark-bright pair was stripped as a unit from many streamlined mesas and from the walls of Ares Valles, leaving a bench at the top of the lower dark layer, approximately 250 m below the highland surface on streamlined islands and on the walls of Ares Vallis itself. Along Ares Vallis, the scarp between the highlands surface and this bench is commonly angular in plan view (not smoothly curving), suggesting that erosion of the upper dark-bright pair of layers controlled by planes of weakness, like fractures or joints. These near-surface layers in the Ares Vallis area have similar thicknesses, colors, and resistances to erosion to layers exposed near the tops of walls in Valles Marineris (Treiman et al.) and may represent the same pedogenic hardpan units. From this correlation, and from analogies with hardpans on Earth, the light-color layers may be cemented by calcite or gypsum. The dark layers are likely cemented by an iron-bearing mineral. Mars Pathfinder instruments should permit recognition and useful analyses of hardpan fragments, provided that clean uncoated surfaces are accessible. Even in hardpan-cemented materials, it should be possible to determine the broad types of lithologies in the Martian highlands. However, detailed geochemical modeling of highland rocks and soils may be compromised by the presence of hardpan cement minerals.

Treiman, Allan H.↗

Accessing Martian Fluvial and Lacustrine Sediments by Landing in Holden Crater, Margaritifer Sinus

Rover missions to the surface of Mars after MER 2003, are likely to be centered around focused geologic field mapping. One objective with high priority in selecting landing sites for these missions will be to characterize the nature, spatial distribution, internal structure, composition, and depositional history of exposed sedimentary layered deposits by visiting a number of distributed outcrops identified previously (and with a high degree of certainty) from orbit. These deposits may contain prebiotic material, even fossil organisms, but their primary value will be to enable an assessment of the planet's climate at the time they were emplaced. High resolution imaging from a mobile rover will enable the detailed study of these deposits over a wide area, their internal structure and mineralogy at distributed localities, and could resolve biologically-derived structures (such as stromatolite-like textures) if they are present. With the addition of a spectrometer, it should be possible to ascertain the presence of carbonates, sulfates, organics, water (liquid, frost, and bound water), as well as a variety of silicate minerals in the context of the collected imagery. Such a mission approach is directly relevant to future exploration of Mars, because it provides the geologic context comparable to what a field geologist visiting a site for the first time would acquire. Rover missions after MER will likely have much better targeting and hazard avoidance landing systems, enabling access to planimetrically-challenged sites of high scientific interest. These vehicles will also likely have greater mobility than MER, capable of driving greater distances in a shorter amount of time. Many scientists and mission planners have realized the need to design a rover whose mobility can be comparable to the dimensions of its 3-sigma landing error ellipse.

Parker, T. J.↗