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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 433 records · Page 24
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Ab initio dynamics and photoionization mass spectrometry reveal ion–molecule pathways from ionized acetylene clusters to benzene cation

Significance The formation of benzene and its cation constitutes a likely gateway to polycyclic aromatic hydrocarbons, which are the bridge to larger carbonaceous material such as soot in combustion processes and interstellar dust. Our paper reports computational and experimental results that address the long-standing puzzle of how ion–molecule reactions involving small unsaturated organics, such as acetylene, which is widespread in the interstellar medium, can lead to benzene cation. We present insights into the facile way in which C 6 H 6 + products, including benzene cation, can be accessed after ionization of cold isolated neutral clusters, and show that there is a catalytic role for what are nominally spectator acetylene molecules.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2012

ACTIVE GALACTIC NUCLEUS OBSCURATION FROM WINDS: FROM DUSTY INFRARED-DRIVEN TO WARM AND X-RAY PHOTOIONIZED

We present calculations of active galactic nucleus winds at {approx}parsec scales along with the associated obscuration. We take into account the pressure of infrared radiation on dust grains and the interaction of X-rays from a central black hole with hot and cold plasma. Infrared radiation (IR) is incorporated in radiation-hydrodynamic simulations adopting the flux-limited diffusion approximation. We find that in the range of X-ray luminosities L = 0.05-0.6 L{sub Edd}, the Compton-thick part of the flow (aka torus) has an opening angle of approximately 72 Degree-Sign -75 Degree-Sign regardless of the luminosity. At L {approx}> 0.1, the outflowing dusty wind provides the obscuration with IR pressure playing a major role. The global flow consists of two phases: the cold flow at inclinations {theta} {approx}> 70 Degree-Sign and a hot, ionized wind of lower density at lower inclinations. The dynamical pressure of the hot wind is important in shaping the denser IR-supported flow. At luminosities {<=}0.1 L{sub Edd} episodes of outflow are followed by extended periods when the wind switches to slow accretion.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

EVIDENCE OF HOT HIGH VELOCITY PHOTOIONIZED PLASMA FALLING ON ACTIVELY ACCRETING T TAURI STARS

The He II (1640 Å) line and the resonance doublet of N V (UV1) provide a good diagnostic tool to constrain the excitation mechanism of hot (T{sub e} > 40,000 K) atmospheric/magnetospheric plasmas in T Tauri stars (TTSs). Making use of the data available in the Hubble Space Telescope archive, this work shows that there are at least two distinct physical components contributing to the radiation in these tracers: the accretion flow sliding on the magnetosphere and the atmosphere. The N V profiles in most sources are symmetric and at rest with respect to the star. The velocity dispersion of the profile increases from non-accreting (σ = 40 km s{sup –1}) to accreting (σ = 120 km s{sup –1}) TTSs, suggesting that the macroturbulence field in the line formation region decreases as the stars approach the main sequence. Evidence of the N V line being formed in a hot solar-like wind has been found in RW Aur, HN Tau, and AA Tau. The He II profile has a strong narrow component that dominates the line flux; the dispersion of this component ranges from 20 to 60 km s{sup –1}. Current data suggest that both accretion shocks and atmospheric emission might contribute to the line flux. In some sources, the He II line shows a broad and redward-shifted emission component often accompanied by semiforbidden O III] emission that has a critical electron density of ∼3.4 × 10{sup 10} cm{sup 3}. In spite of their different origins (inferred from the kinematics of the line formation region), N V and He II fluxes are strongly correlated, with only the possible exception of some of the heaviest accretors.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

EVIDENCE FOR PHOTOIONIZATION-DRIVEN BROAD ABSORPTION LINE VARIABILITY

We present a qualitative analysis of the variability of quasar broad absorption lines using the large multi-epoch spectroscopic data set of the Sloan Digital Sky Survey Data Release 10. We confirm that variations of absorption lines are highly coordinated among different components of the same ion or the same absorption component of different ions for C iv, Si iv, and N v. Furthermore, we show that the equivalent widths (EWs) of the lines decrease or increase statistically when the continuum brightens or dims. This is further supported by the synchronized variations of emission and absorption-line EWs when the well-established intrinsic Baldwin effect for emission lines is taken into account. We find that the emergence of an absorption component is usually accompanied by the dimming of the continuum while the disappearance of an absorption-line component is accompanied by the brightening of the continuum. This suggests that the emergence or disappearance of a C iv absorption component is only the extreme case, when the ionic column density is very sensitive to continuum variations or the continuum variability the amplitude is larger. These results support the idea that absorption-line variability is driven mainly by changes in the gas ionization in response to continuum variations, that the line-absorbing gas is highly ionized, and in some extreme cases, too highly ionized to be detected in UV absorption lines. Due to uncertainties in the spectroscopic flux calibration, we cannot quantify the fraction of quasars with asynchronized continuum and absorption-line variations.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2026

Nonadiabatic strong-field photoionization revisited: Detailed analysis

We develop a theoretical framework to interpret “bump-like” enhancements in the energy distribution of electrons emitted from cesium atoms subjected to intense infrared laser fields, as observed in a recent experiment. These emissions, detected at energies approaching twice the ponderomotive energy (2⁢𝑈 p ), indicate a mechanism where electrons are nonadiabatically ejected with substantial inward velocity following ionization. The bump-like features arise from returning trajectories that scatter off the residual ion. We interpret these experimental results classically using a periodically driven version of the Bohr model and quantum mechanically through Keldysh's adiabaticity parameter (𝛾 K ) and Reiss's continuum-state intensity parameter 𝒵 in a Coulomb-corrected version of the strong-field approximation (SFA) that incorporates “complex” electronic trajectories. Notably, our theoretical analysis shows that these emissions are independent of the specific short-range form of the atomic potential.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2023

Attosecond time delay in atomic photoionization: Angular-dependent transition from dipole to quadrupole and spin-flip dynamics

The angular distribution of attosecond Wigner time delay has been investigated including both quadrupole and relativistic effects using the relativistic-random-phase approximation that is based on the Dirac equation and includes significant aspects of many-body correlations. Here the results show a dramatic evolution of the time delay from (essentially nonrelativistic) dipole to quadrupole and spin-flip dynamics as a function of angle, thereby providing a venue for studying these interactions at the attosecond level.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2016

High-frequency conductivity of photoionized plasma

The tensor of the high-frequency conductivity of a plasma created via tunnel ionization of atoms in the field of linearly or circularly polarized radiation is derived. It is shown that the real part of the conductivity tensor is highly anisotropic. In the case of a toroidal velocity distribution of photoelectrons, the possibility of amplification of a weak high-frequency field polarized at a sufficiently large angle to the anisotropy axis of the initial nonequilibrium distribution is revealed.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2016

Terahertz absorption and emission upon the photoionization of acceptors in uniaxially stressed silicon

Experimental data on the spontaneous emission and absorption modulation in boron-doped silicon under CO{sub 2} laser excitation depending on the uniaxial stress applied along the [001] and [011] crystallographic directions are presented. Room-temperature radiation is used as the probe radiation. Low stress (less than 0.5 kbar) is shown to reduce losses in the terahertz region by 20%. The main contribution to absorption modulation at zero and low stress is made by A{sup +} centers. Intersubband free hole transitions additionally contribute to terahertz absorption at higher stress. These contributions can be minimized by compensation.

36 MATERIALS SCIENCE↗
DOE OSTI2016

EG ANDROMEDAE: A NEW ORBIT AND ADDITIONAL EVIDENCE FOR A PHOTOIONIZED WIND

We analyze a roughly 20 yr set of spectroscopic observations for the symbiotic binary EG And. Radial velocities derived from echelle spectra are best fit with a circular orbit having an orbital period of P = 483.3 ± 1.6 days and semi-amplitude K = 7.34 ± 0.07 km s{sup −1}. Combined with previous data, these observations rule out an elliptical orbit at the 10 σ level. Equivalent widths of H i Balmer emission lines and various absorption features vary in phase with the orbital period. Relative to the radius of the red giant primary, the apparent size of the H ii region is consistent with a model where a hot secondary star with effective temperature T{sub h} ≈ 75,000 K ionizes the wind from the red giant.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

Photoionization Models for the Inner Gaseous Disks of Herbig Be Stars: Evidence against Magnetospheric Accretion?

We investigate the physical properties of the inner gaseous disks of three hot Herbig B2e stars, HD 76534, HD 114981, and HD 216629, by modeling CFHT-ESPaDOns spectra using non-LTE radiative transfer codes. We assume that the emission lines are produced in a circumstellar disk heated solely by photospheric radiation from the central star in order to test whether the optical and near-infrared emission lines can be reproduced without invoking magnetospheric accretion. The inner gaseous disk density was assumed to follow a simple power-law in the equatorial plane, and we searched for models that could reproduce observed lines of H i (H α and H β ), He i, Ca ii, and Fe ii. For the three stars, good matches were found for all emission line profiles individually; however, no density model based on a single power-law was able to reproduce all of the observed emission lines. Among the single power-law models, the one with the gas density varying as ∼10{sup −10}( R {sub *}/ R ){sup 3} g cm{sup −3} in the equatorial plane of a 25 R {sub *} (0.78 au) disk did the best overall job of representing the optical emission lines of the three stars. This model implies a mass for the H α -emitting portion of the inner gaseous disk of ∼10{sup −9} M {sub *}. We conclude that the optical emission line spectra of these HBe stars can be qualitatively reproduced by a ≈1 au, geometrically thin, circumstellar disk of negligible mass compared to the central star in Keplerian rotation and radiative equilibrium.

79 ASTRONOMY AND ASTROPHYSICS↗