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At least 433 records · Page 24

Factors controlling precision and accuracy in isotope-ratio-monitoring mass spectrometry

The performance of systems in which picomole quantities of sample are mixed with a carrier gas and passed through an isotope-ratio mass spectrometer system was examined experimentally and theoretically. Two different mass spectrometers were used, both having electron-impact ion sources and Faraday cup collector systems. One had an accelerating potential of 10kV and accepted 0.2 mL of He/min, producing, under those conditions, a maximum efficiency of 1 CO2 molecular ion collected per 700 molecules introduced. Comparable figures for the second instrument were 3 kV, 0.5 mL of He/min, and 14000 molecules/ion. Signal pathways were adjusted so that response times were <200 ms. Sample-related ion currents appeared as peaks with widths of 3-30 s. Isotope ratios were determined by comparison to signals produced by standard gases. In spite of rapid variations in signals, observed levels of performance were within a factor of 2 of shot-noise limits. For the 10-kV instrument, sample requirements for standard deviations of 0.1 and 0.5% were 45 and 1.7 pmol, respectively. Comparable requirements for the 3-kV instrument were 900 and 36 pmol. Drifts in instrumental characteristics were adequately neutralized when standards were observed at 20-min intervals. For the 10-kV instrument, computed isotopic compositions were independent of sample size and signal strength over the ranges examined. Nonlinearities of <0.04%/V were observed for the 3-kV system. Procedures for observation and subtraction of background ion currents were examined experimentally and theoretically. For sample/ background ratios varying from >10 to 0.3, precision is expected and observed to decrease approximately 2-fold and to depend only weakly on the precision with which background ion currents have been measured.

NASA Discipline Exobiology↗

Knock-Limited Performance of Triptane and 28-R Fuel Blends as Affected by Changes in Compression Ratio and in Engine Operating Variables

A knock-limited performance investigation was conducted on blends of triptane and 28-P fuel with a 12-cylinder, V-type, liquid-cooled aircraft engine of 1710-cubic-inch displacement at three compression ratios: 6.65, 7.93, and 9.68. At each compression ratio, the effect of changes in temperature of the inlet air to the auxiliary-stage supercharger and in fuel-air ratio were investigated at engine speeds of 2280 and. 3000 rpm. The results show that knock-limited engine performance, as improved by the use of triptane, allowed operation at both take-off and cruising power at a compression ratio of 9.68. At an inlet-air temperature of 60 deg F, an engine speed of 3000 rpm ; and a fuel-air ratio of 0,095 (approximately take-off conditions), a knock-limited engine output of 1500 brake horsepower was possible with 100-percent 28-R fuel at a compression ratio of 6.65; 20-percent triptane was required for the same power output at a compression ratio of 7.93, and 75 percent at a compression ratio of 9.68 allowed an output of 1480 brake horsepower. Knock-limited power output was more sensitive to changes in fuel-air ratio as the engine speed was increased from 2280 to 3000 rpm, as the compression ratio is raised from 6.65 to 9.68, or as the inlet-air temperature is raised from 0 deg to 120 deg F.

Brun, Rinaldo J.↗

The global distribution of water vapor in the middle atmosphere of Venus

Near-IR measurements are presented of the mean vertical and horizontal distribution of water vapor in the Venus clouds as measured by the Pioneer Venus Orbiter IR radiometer, and comparisons are made with previous data. Six thermal channels were used to generate several hundred thousand readings for determination of the mean mixing ratio. Averaging was performed as a function of the solar zenith angle, with profiles retrieved with a relaxation method applied to radiance data at 45 microns. Consideration was given to mean cloud models and temperature profiles obtained from the five temperature sounding channels scanning from 11.5-15 microns. Laboratory tests were effected to validate the transmission functions. The results included a maximum column abundances above the cloud optical depth in the early afternoon in the equatorial regions. Mixing ratio enhancement was highest on the dayside and at high altitudes, with a mean ratio of 0.0001 at a 40% uncertainty level. Day-to-day fluctuations in the pressure level at 11.5 microns was larger than 10%, far below the factors of 2-3 determined by other investigators.

Schofield, J. T.↗

A DEEPER LOOK AT FAINT Hα EMISSION IN NEARBY DWARF GALAXIES

We present deep Hα imaging of three nearby dwarf galaxies, carefully selected to optimize observations with the Maryland-Magellan Tunable Filter (MMTF) on the Magellan 6.5 m telescope. An effective bandpass of ∼13 Å is used, and the images reach 3σ flux limits of ∼8 × 10{sup −18} erg s{sup −1} cm{sup −2}, which is about an order of magnitude lower than standard narrowband observations obtained by the most recent generation of local Hα galaxy surveys. The observations were originally motivated by the finding that the Hα/FUV flux ratio of galaxies systematically declines as global galactic properties such as the star formation rate (SFR) and stellar mass decrease. The three dwarf galaxies selected for study have SFRs that, when calculated from their Hα luminosities using standard conversion recipes, are ∼50% of those based on the FUV. Follow-up studies of many of the potential causes for the trends in the Hα/FUV flux ratio have been performed, but the possibility that previous observations have missed a non-negligible fraction of faint ionized emission in dwarf galaxies has not been investigated. The MMTF observations reveal both diffuse and structured Hα emission (filaments, shells, possible single-star H ii regions) spanning extents up to 2.5 times larger relative to previous observations. However, only up to an additional ∼5% of Hα flux is captured, which does not account for the trends in the Hα/FUV ratio. Beyond investigation of the Hα/FUV ratio, the impact of the newly detected extended flux on our understanding of star formation, the properties of H ii regions, and the propagation of ionizing photons warrant further investigation.

79 ASTRONOMY AND ASTROPHYSICS↗

Non-thyroid cancer incidence in Belarusian residents exposed to Chernobyl fallout in childhood and adolescence: Standardized Incidence Ratio analysis, 1997–2011

Background: While an increased risk of thyroid cancer from post-Chernobyl exposure to Iodine-131 (I-131) in children and adolescents has been well-documented, risks of other cancers or leukemia as a result of residence in radioactively contaminated areas remain uncertain. Methods: We studied non-thyroid cancer incidence in a cohort of about 12,000 individuals from Belarus exposed under age of 18 years to Chernobyl fallout (median age at the time of Chernobyl accident of 7.9 years). During 15 years of follow-up from1997 through 2011, 54 incident cancers excluding thyroid were identified in the study cohort with 142,968 person-years at risk. We performed Standardized Incidence Ratio (SIR) analysis of all solid cancers excluding thyroid (n=42), of leukemia (n=6) and of lymphoma (n=6). Results: We found no significant increase in the incidence of non-thyroid solid cancer (SIR=0.83, 95% Confidence Interval [CI]: 0.61; 1.11), lymphoma (SIR=0.66, 95% CI: 0.26; 1.33) or leukemia (SIR=1.78, 95% CI: 0.71; 3.61) in the study cohort as compared with the sex-, age- and calendar-time-specific national rates. These findings may in part reflect the relatively young age of study subjects (median attained age of 33.4 years), and long latency for some radiation-related solid cancers. Conclusions: We found no evidence of statistically significant increases in solid cancer, lymphoma and leukemia incidence 25 years after childhood exposure in the study cohort; however, it is important to continue follow-up non-thyroid cancers in individuals exposed to low-level radiation at radiosensitive ages. - Highlights: • We monitor cancers in a Belarusian cohort of exposed as children due to Chernobyl. • No increase in solid cancer rates was found as compared to the national rates. • An elevation of leukemia rates was detected, although statistically insignificant. • Results are consistent with those in a cohort of exposed as children in Ukraine. • Further monitoring of cancer situation in this cohort is warranted.

54 ENVIRONMENTAL SCIENCES↗

Low aspect ratio wing code validation experiment

An experiment was performed on a low-aspect ratio wing to define the limits of the validity of codes which are used to predict the flow over modern fighter configurations. The focus of the experiment is to provide data at or near the true operating conditions of transonic aircraft. The Reynolds numbers reached in this experiment reproduce those experienced by an aircraft with a 5-m root chord, flying at 14 to 16 km, from Mach 0.6 to 0.8. The angle-of-attack range of the experiment extends into the regime of leading-edge separation.

Olsen, Michael E.↗

Powdered aluminum and oxygen rocket propellants: Subscale combustion experiments

Aluminum combined with oxygen has been proposed as a potential lunar in situ propellant for ascent/descent and return missions for future lunar exploration. Engine concepts proposed to use this propellant have not previously been demonstrated, and the impact on performance from combustion and two-phase flow losses could only be estimated. Therefore, combustion tests were performed for aluminum and aluminum/magnesium alloy powders with oxygen in subscale heat-sink rocket engine hardware. The metal powder was pneumatically injected, with a small amount of nitrogen, through the center orifice of a single element O-F-O triplet injector. Gaseous oxygen impinged on the fuel stream. Hot-fire tests of aluminum/oxygen were performed over a mixture ratio range of 0.5 to 3.0, and at a chamber pressure of approximately 480 kPa (70 psia). The theoretical performance of the propellants was analyzed over a mixture ratio range of 0.5 to 5.0. In the theoretical predictions the ideal one-dimensional equilibrium rocket performance was reduced by loss mechanisms including finite rate kinetics, two-dimensional divergence losses, and boundary layer losses. Lower than predicted characteristic velocity and specific impulse performance efficiencies were achieved in the hot-fire tests, and this was attributed to poor mixing of the propellants and two-phase flow effects. Several tests with aluminum/9.8 percent magnesium alloy powder did not indicate any advantage over the pure aluminum fuel.

Meyer, Mike L.↗

Deep active learning for classifying cancer pathology reports

Abstract Background Automated text classification has many important applications in the clinical setting; however, obtaining labelled data for training machine learning and deep learning models is often difficult and expensive. Active learning techniques may mitigate this challenge by reducing the amount of labelled data required to effectively train a model. In this study, we analyze the effectiveness of 11 active learning algorithms on classifying subsite and histology from cancer pathology reports using a Convolutional Neural Network as the text classification model. Results We compare the performance of each active learning strategy using two differently sized datasets and two different classification tasks. Our results show that on all tasks and dataset sizes, all active learning strategies except diversity-sampling strategies outperformed random sampling, i.e., no active learning. On our large dataset (15K initial labelled samples, adding 15K additional labelled samples each iteration of active learning), there was no clear winner between the different active learning strategies. On our small dataset (1K initial labelled samples, adding 1K additional labelled samples each iteration of active learning), marginal and ratio uncertainty sampling performed better than all other active learning techniques. We found that compared to random sampling, active learning strongly helps performance on rare classes by focusing on underrepresented classes. Conclusions Active learning can save annotation cost by helping human annotators efficiently and intelligently select which samples to label. Our results show that a dataset constructed using effective active learning techniques requires less than half the amount of labelled data to achieve the same performance as a dataset constructed using random sampling.

59 BASIC BIOLOGICAL SCIENCES↗

Technical and economic feasibility of solar flat-plate collector thermal energy systems for small and medium manufacturers

Manufacturing industries require process heating for a wide variety of operations, such as drying, cooking, washing, and sterilizing. Studies of industrial energy consumption have shown that more than 50% of industrial heating demand is in the low (<60 °C), medium (60-150 °C), and medium-high (<250 °C) temperature ranges. A significant fraction of this low temperature thermal energy could be generated by commercially available solar flat-plate collector thermal energy systems, which would reduce the use of fossil fuels, energy cost volatility, and carbon emissions. However, manufacturing industries have not been able to take advantage of solar flat-plate collector systems for two main reasons: First, information is not readily available about when and what flat-plate collector system sizes can be economically applied and, second, manufacturers often do not have appropriate personnel or analysis tools to make decisions about installation of solar flat-plate collector systems. The goal of this research is to provide design decision support to small- and medium-sized manufacturers in conducting feasibility analysis for the application of solar flat-plate collector systems in their operations. The $\bar{φ}, f$-chart method and modified $\bar{φ}, f$-chart design method are used to predict the amount of energy collected by solar flat-plate collectors. A simplified model is proposed to assess the cost of solar flat-plate collector energy systems. To demonstrate the presented feasibility analysis methodology, a decision support software application is developed. What-if scenarios are presented for several geographic locations of varying climates. A sensitivity analysis of savings-to-investment ratio (SIR) was performed by changing selected input parameters by ±30% from the base case. It was found that SIR is sensitive to natural gas price, followed by collector area dependent cost, discount rate, cost of the auxiliary gas heater, and cost of the preheating system.

14 SOLAR ENERGY↗

Analytical evaluation of effect of equivalence ratio inlet-air temperature and combustion pressure on performance of several possible ram-jet fuels

The results of an analytical investigation of the theoretical air specific impulse performance and adiabatic combustion temperatures of several possible ram-jet fuels over a range of equivalence ratios, inlet-air temperatures, and combustion pressures, is presented herein. The fuels include octane-1, 50-percent-magnesium slurry, boron, pentaborane, diborane, hydrogen, carbon, and aluminum. Thermal effects from high combustion temperatures were found to effect considerably the combustion performance of all the fuels. An increase in combustion pressure was beneficial to air specific impulse at high combustion temperatures. The use of these theoretical data in engine operation and in the evaluation of experimental data is described.

COMBUSTION - TURBINE ENGINES↗

Numerical study of implosion instability mitigation in magnetically driven solid liner dynamic screw pinches

Magnetized liner inertial fusion experiments on the Z accelerator suffer from magneto-Rayleigh–Taylor instabilities (MRTI) that compromise integrity of the imploding cylindrical liner, limiting achievable fusion fuel conditions and ultimately reducing magneto-inertial fusion target performance. Dynamic screw pinches (DSP) provide a method to reduce MRTI in-flight via application of magnetic field line tension to the imploding liner outer surface. In contrast with z-pinches that drive implosions with an azimuthal magnetic field, dynamic screw pinches enforce an additional axial drive magnetic field component, making the overall drive magnetic field helical. As the liner implodes, cumulative MRTI development is reduced by dynamically shifting the orientation of the fastest growing instability modes. Three-dimensional magnetohydrodynamic simulations show that the DSP mechanism effectively stabilizes initially solid cylindrical liner implosions driven by Z-scale current pulses, indicating that MRTI mitigation increases with the ratio of axial to azimuthal drive magnetic field components (i.e., the drive field ratio). We also performed a spectral analysis of the simulated imploding density distributions, extracting wavelength and pitch angle of the simulated MRTI structures to study their dynamics during the implosion. Simulations of liners initially perturbed with drive-field-aligned sinusoidal structures indicate that MRTI mitigation in DSP implosions decreases with perturbation wavelength, once again suggestive of magnetic field line tension effects.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Performance of an i -SANEX System Based on a Water-Soluble BTP under Continuous Irradiation in a γ-Radiolysis Test Loop

Here, the i -SANEX solvent formulation consisting of nominally 0.2 M TODGA/5% 1-octanol/dodecane was γ-irradiated under realistic conditions in the Idaho National Laboratory radiolysis test loop, in contact with both extraction and stripping aqueous phases. The extraction aqueous phase was 4.5 M HNO 3 , and the stripping aqueous phase was 0.018 M SO 3 –Ph–BTP/0.35 M HNO 3 . When irradiated in contact with only the 4.5 M HNO 3 phase, the TODGA solvent maintained excellent extraction performance for americium, cerium, europium, and neodymium to a maximum absorbed dose of nearly 0.9 MGy. The results for preliminary static, batch irradiations were consistent with test loop findings. When the aqueous phase was changed to that containing the aqueous soluble BTP, the irradiated aqueous phase showed a dramatic color change, but this does not appear to have had adverse effect on solvent extraction performance. The distribution ratios for both the lanthanides and actinides were invariant with absorbed dose, and the separation factors were essentially unchanged to a maximum absorbed dose of 174 kGy. The results of inductively coupled plasma mass spectrometry analysis of the aqueous and organic phases showed that ruthenium and strontium were not extracted in the presence of the irradiated BTP-aqueous phase. Molybdenum was extracted under both conditions. Further, the buildup of corrosion products of stainless steel in the presence of the BTP was not dramatically greater than in the nitric acid-only system. Phase separation times were not adversely affected by irradiation for either system. The results presented here indicate that the performance of the TODGA/SO 3 –Ph–BTP, i -SANEX process under test loop radiolysis is much better than expected based on a literature report using single-phase batch irradiation experiments, and better than might be predicted based on diglycolamide radiolysis studies alone.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Experimental investigation of aerodynamic performance of cooled turbine vanes at gas- to collant-temperature ratios up to 2.75

The results of an experimental investigation of the aerodynamic performance of two geometrically similar turbine vanes with different cooling designs are presented. The test vanes were a convection-film-cooled vanes and a transpiration-cooled vane. A solid uncooled vane with the same aerodynamic profile as the cooled vane was also tested. Four vanes of each type were tested in an annular sector cascade. The cooled vanes were tested at primary to coolant temperature ratios of 1.0, 1.75, and 2.75 and a coolant to primary pressure ratios of 1.0, 1.2, and 1.5. This resulted in coolant flows up to about 10 percent of the primary flow. The principal measurements were surveys of vane exit total pressure, total temperature, and static pressure. The report includes a brief description of the test facility and the design of the test vanes. The test results presented include weight flow and efficiency data for the uncooled vanes and coolant flow, primary flow, and efficiency data as functions of the cooling variables for the cooled vanes.

Stabe, R. G.↗

Satellite Hyperspectral Imaging Simulation

Simulation of generic pushbroom satellite hyperspectral sensors have been performed to evaluate the potential performance and validation techniques for satellite systems such as COIS(NEMO), Warfighter-1(OrbView-4) and Hyperion(EO-1). The simulations start with a generation of synthetic scenes from material maps of studied terrain. Scene-reflected radiance is corrected for atmospheric effects and convolved with sensor spectral response using MODTRAN 4 radiance and transmissions calculations. Scene images are further convolved with point spread functions derived from Optical Transfer Functions (OTF's) of the sensor system. Photon noise and etectorr/electronics noise are added to the simulated images, which are also finally quantized to the sensor bit resolution. Studied scenes include bridges and straight roads used for evaluation of sensor spatial resolution, as well as fields of minerals, vegetation and manmade materials used for evaluation of sensor radiometric response and sensitivity. The scenes are simulated with various seasons and weather conditions. Signal-to-noise ratios and expected performance are estimated for typical satellite system specifications and are discussed for all the scenes.

Zanoni, Vicki↗

Solution phase high repetition rate laser pump x-ray probe picosecond hard x-ray spectroscopy at the Stanford Synchrotron Radiation Lightsource

We present a dedicated end-station for solution phase high repetition rate (MHz) picosecond hard x-ray spectroscopy at beamline 15-2 of the Stanford Synchrotron Radiation Lightsource. A high-power ultrafast ytterbium-doped fiber laser is used to photoexcite the samples at a repetition rate of 640 kHz, while the data acquisition operates at the 1.28 MHz repetition rate of the storage ring recording data in an alternating on-off mode. The time-resolved x-ray measurements are enabled via gating the x-ray detectors with the 20 mA/70 ps camshaft bunch of SPEAR3, a mode available during the routine operations of the Stanford Synchrotron Radiation Lightsource. As a benchmark study, aiming to demonstrate the advantageous capabilities of this end-station, we have conducted picosecond Fe K-edge x-ray absorption spectroscopy on aqueous [FeII(phen)3]2+, a prototypical spin crossover complex that undergoes light-induced excited spin state trapping forming an electronic excited state with a 0.6–0.7 ns lifetime. In addition, we report transient Fe Kβ main line and valence-to-core x-ray emission spectra, showing a unique detection sensitivity and an excellent agreement with model spectra and density functional theory calculations, respectively. Notably, the achieved signal-to-noise ratio, the overall performance, and the routine availability of the developed end-station have enabled a systematic time-resolved science program using the monochromatic beam at the Stanford Synchrotron Radiation Lightsource.

47 OTHER INSTRUMENTATION↗

Internal performance characteristics of thrust-vectored axisymmetric ejector nozzles

A series of thrust-vectored axisymmetric ejector nozzles were designed and experimentally tested for internal performance and pumping characteristics at the Langley research center. This study indicated that discontinuities in the performance occurred at low primary nozzle pressure ratios and that these discontinuities were mitigated by decreasing expansion area ratio. The addition of secondary flow increased the performance of the nozzles. The mid-to-high range of secondary flow provided the most overall improvements, and the greatest improvements were seen for the largest ejector area ratio. Thrust vectoring the ejector nozzles caused a reduction in performance and discharge coefficient. With or without secondary flow, the vectored ejector nozzles produced thrust vector angles that were equivalent to or greater than the geometric turning angle. With or without secondary flow, spacing ratio (ejector passage symmetry) had little effect on performance (gross thrust ratio), discharge coefficient, or thrust vector angle. For the unvectored ejectors, a small amount of secondary flow was sufficient to reduce the pressure levels on the shroud to provide cooling, but for the vectored ejector nozzles, a larger amount of secondary air was required to reduce the pressure levels to provide cooling.

Lamb, Milton↗

Transient Three-Dimensional Analysis of Nozzle Side Load in Regeneratively Cooled Engines

Three-dimensional numerical investigations on the start-up side load physics for a regeneratively cooled, high-aspect-ratio nozzle were performed. The objectives of this study are to identify the three-dimensional side load physics and to compute the associated aerodynamic side load using an anchored computational methodology. The computational methodology is based on an unstructured-grid, pressure-based computational fluid dynamics formulation, and a transient inlet condition based on an engine system simulation. Computations were performed for both the adiabatic and cooled walls in order to understand the effect of boundary conditions. Finite-rate chemistry was used throughout the study so that combustion effect is always included. The results show that three types of shock evolution are responsible for side loads: generation of combustion wave; transitions among free-shock separation, restricted-shock separation, and simultaneous free-shock and restricted shock separations; along with oscillation of shocks across the lip. Wall boundary conditions drastically affect the computed side load physics: the adiabatic nozzle prefers free-shock separation while the cooled nozzle favors restricted-shock separation, resulting in higher peak side load for the cooled nozzle than that of the adiabatic nozzle. By comparing the computed physics with those of test observations, it is concluded that cooled wall is a more realistic boundary condition, and the oscillation of the restricted-shock separation flow pattern across the lip along with its associated tangential shock motion are the dominant side load physics for a regeneratively cooled, high aspect-ratio rocket engine.

Wang, Ten-See↗