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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 433 records · Page 24
All sourcesNASA NTRSDOE OSTI
NASA NTRS2014

Core-Mantle Partitioning of Volatile Elements and the Origin of Volatile Elements in Earth and Moon

Depletions of siderophile elements in mantles have placed constraints on the conditions on core segregation and differentiation in bodies such as Earth, Earth's Moon, Mars, and asteroid 4 Vesta. Among the siderophile elements there are a sub-set that are also volatile (volatile siderophile elements or VSE; Ga, Ge, In, As, Sb, Sn, Bi, Zn, Cu, Cd), and thus can help to constrain the origin of volatile elements in these bodies, and in particular the Earth and Moon. One of the fundamental observations of the geochemistry of the Moon is the overall depletion of volatile elements relative to the Earth, but a satisfactory explanation has remained elusive. Hypotheses for Earth include addition during accretion and core formation and mobilized into the metallic core, multiple stage origin, or addition after the core formed. Any explanation for volatile elements in the Earth's mantle must also be linked to an explanation of these elements in the lunar mantle. New metal-silicate partitioning data will be applied to the origin of volatile elements in both the Earth and Moon, and will evaluate theories for exogenous versus endogenous origin of volatile elements.

Righter, K.↗
NASA NTRS2015

REE Partitioning in Lunar Minerals

Rare earth elements (REE) are an extremely useful tool in modeling lunar magmatic processes. Here we present the first experimentally derived plagioclase/melt partition coefficients in lunar compositions covering the entire suite of REE. Positive europium anomalies are ubiquitous in the plagioclase-rich rocks of the lunar highlands, and complementary negative Eu anomalies are found in most lunar basalts. These features are taken as evidence of a large-scale differentiation event, with crystallization of a global-scale lunar magma ocean (LMO) resulting in a plagioclase flotation crust and a mafic lunar interior from which mare basalts were subsequently derived. However, the extent of the Eu anomaly in lunar rocks is variable. Fagan and Neal [1] reported highly anorthitic plagioclase grains in lunar impact melt rock 60635,19 that displayed negative Eu anomalies as well as the more usual positive anomalies. Indeed some grains in the sample are reported to display both positive and negative anomalies. Judging from cathodoluminescence images, these anomalies do not appear to be associated with crystal overgrowths or zones.

Rapp, J. F.↗
NASA NTRS2015

Friction and Wear Management Using Solvent Partitioning of Hydrophilic-Surface-Interactive Chemicals Contained in Boundary Layer-Targeted Emulsions

Lubrication additives of the current invention require formation of emulsions in base lubricants, created with an aqueous salt solution plus a single-phase compound such that partitioning within the resulting emulsion provides thermodynamically targeted compounds for boundary layer organization thus establishing anti-friction and/or anti-wear. The single-phase compound is termed "boundary layer organizer", abbreviated BLO. These emulsion-contained compounds energetically favor association with tribologic surfaces in accord with the Second Law of Thermodynamics, and will organize boundary layers on those surfaces in ways specific to the chemistry of the salt and BLO additives. In this way friction modifications may be provided by BLOs targeted to boundary layers via emulsions within lubricating fluids, wherein those lubricating fluids may be water-based or oil-based.

Richmond, Robert Chaffee↗
NASA NTRS2016

Partitioning of U, Th and K Between Metal, Sulfide and Silicate, Insights into the Volatile-Content of Mercury

During the early stages of the Solar System formation, especially during the T-Tauri phase, the Sun emitted strong solar winds, which are thought to have expelled a portion of the volatile elements from the inner solar system. It is therefore usually believed that the volatile depletion of a planet is correlated with its proximity to the Sun. This trend was supported by the K/Th and K/U ratios of Venus, the Earth, and Mars. Prior to the MESSENGER mission, it was expected that Mercury is the most volatile-depleted planet. However, the Gamma Ray Spectrometer of MESSENGER spacecraft revealed elevated K/U and K/Th ratios for the surface of Mercury, much higher than previous expectations. It is possible that the K/Th and K/U ratios on the surface are not a reliable gauge of the bulk volatile content of Mercury. Mercury is enriched in sulfur and is the most reduced of the terrestrial planets, with oxygen fugacity (fO2) between IW-6.3 and IW-2.6 log units. At these particular compositions, U, Th and K behave differently and can become more siderophile or chalcophile. If significant amounts of U and Th are sequestered in the core, the apparent K/U and K/Th ratios measured on the surface may not represent the volatile budget of the whole planet. An accurate determination of the partitioning of these elements between silicate, metal, and sulfide phases under Mercurian conditions is therefore essential to better constrain Mercury's volatile content and assess planetary formation models.

Habermann, M.↗
NASA NTRS2017

A Synthesis of Experimental Data Describing the Partitioning of Moderately Volatile Elements in Major Rock Forming Minerals: Implications for the Moon

Highly volatile elements [condensation temperatures below about 700 K] and water are highly informative about lunar bulk composition (hence origin), differentiation and magmatic evolution, and the role of impacts in delivering volatiles to the Moon. Fractionation of volatile elements compared to moderately volatile and refractory elements are informative about high-temperature conditions that operated in the proto-lunar disk. Existing data show clearly that the Moon is depleted in volatile elements compared to the bulk silicate Earth. For example, K/Th is ~400-700 in the Moon compared to 2800-3000 in Earth. A complicating factor is that the abundances of the highly volatile elements in major lunar lithologies vary by approximately two orders of magnitude. Perhaps most interesting, H2O is not correlated with the concentration of volatile elements, indicating a decoupling of highly volatile elements from the even more volatile H2O. We contend that this decoupling could be a significant tracer of processes operating during lunar formation, differentiation, and bombardment, and the combination of analyzing both volatile elements and water is likely to provide significant insight into lunar geochemical history. This variation and lack of correlation raises the question: what were the relative contributions of crystallization in the magma ocean, subsequent mantle overturn, production of secondary magmas, and addition of volatiles by large impacts in producing this apparently large range in volatile abundances? This current study will produce new partitioning data relevant to the role and distribution of the volatile and non-volatile, yet geochemically significant elements (Co, Ni, Zn, Se, Rb, Sr, Mo, Ag, Cd, In, Sb, Ce, Yb, Tl, Pb, Bi) during the thermal and magmatic evolution of the Moon.

Vander Kaaden, Kathleen E.↗
NASA NTRS2017

Chirp-Partition Based Pre-Distortion for Reduced Carrier Leakage in Circulator-Based Wide-Band FMCW Radar Systems

This paper presents a digital pre-distortion scheme to reduce carrier-leakage in wideband FMCW radars that use a circulator to provide isolation between the transmitter and receiver. The proposed digital pre-distortion technique first power combines the leakage signal with a second pre-distorting signal prior to entering the radar receiver. The Phase & amplitude of this pre-distorting signal are adjusted for partitions of the FMCW chirp to provide cancellation. Transitions between sections are pulse shaped to eliminate broadband frequency content.

Tang, A↗
NASA NTRS2021

The 2019-2020 Australian drought and bushfires altered the partitioning of hydrological fluxes

Though coarse in spatial resolution, the nearly all weather measurements from passive microwave sensors can help in improving the spatiotemporal coverage of optical and thermal infrared sensors for monitoring vegetation changes on the land surface. This study demonstrates the use of vegetation optical depth retrievals from the Soil Moisture Active Passive mission for capturing the vegetation alterations from the recent 2019-2020 Australian bushfires and drought. The impact of vegetation disturbance s on terrestrial water budget is examined by assimilating the vegetation optical depth retrievals into a dynamic phenology model. The results demonstrate that assimilating vegetation optical depth observations lead to improved simulation of evapotranspiration, runoff, and soil moisture states. The study also demonstrates that the vegetation changes from the 2019-2020 Australian drought and fires led to significant modifications in the partitioning of evaporative and runoff fluxes, resulting in increased bare soil evaporation, reduced transpiration, and higher runoff.

data assimilation↗
NASA NTRS2022

Optimizing Lunar Map Partitioning for Multipath Fade Loss Analyses

A methodology is presented pertaining to the run-time optimization of quasi-optical ray-tracing simulations. These shooting-and-bouncing ray methods are used for assessing multipath fade loss in cislunar communication links. Our approach employs partitioning lunar terrain maps in shapes that approximate two-dimensional projections of Fresnel zone cross-sections. This technique drastically reduces computational run-time without causing significant loss of simulation accuracy.

Digital elevation models↗
NASA NTRS2022

Electron Energization and Thermal to Non-Thermal Energy Partition During Earth's Magnetotail Reconnection

Electrons in earth's magnetotail are energized significantly both in the form of heating and in the form of acceleration to non-thermal energies. While magnetic reconnection is considered to play an important role in this energization, it still remains unclear how electrons are energized and how energy is partitioned between thermal and non-thermal components. Here, we show, based on in situ observations by NASA's magnetospheric multiscale mission combined with multi-component spectral fitting methods, that the average electron energy ε¯(or equivalently temperature) is substantially higher when the locally averaged electric field magnitude |𝐸| is also higher. While this result is consistent with the classification of “plasma-sheet” and “tail-lobe” reconnection during which reconnection is considered to occur on closed and open magnetic field lines, respectively, it further suggests that a stochastic Fermi acceleration in 3D, reconnection-driven turbulence is essential for the production and confinement of energetic electrons in the reconnection region. The puzzle is that the non-thermal power-law component can be quite small even when the electric field is large and the bulk population is significantly heated. The fraction of non-thermal electron energies varies from sample to sample between ∼20% and ∼60%, regardless of the electric field magnitude. Interestingly, these values of non-thermal fractions are similar to those obtained for the above-the-looptop hard x-ray coronal sources for solar flares.

M Oka↗
NASA NTRS2022

Microgreens Root Zone/Shoot Zone Partitioned Planting Box

To enable sustainable food production in future human exploration missions, plant growth is being studied by the Space Crop Production Team at KSC. Microgreens are good candidates for food supplements and contain specific nutrients that are lacking in the prepackaged diet, including vitamin C and vitamin K. Because they are densely sown, typical growth methods do not allow the ability to distinguish between the levels of evaporation from the rooting substrate and transpiration from the leaves. With larger plants, the root and shoot zone can be separated to distinguish these fluxes and accurate transpiration measurements of plant canopies are feasible. Furthermore, separation of the root and shoot zone may also be beneficial when harvesting microgreens in microgravity as it may reduce microbial contamination of the edible biomass by the roots, which have high microbial loads. Using a root and shoot separator box when harvesting may help with microbial contamination, but these tiny plants are challenging to handle in microgravity, so harvest management remains an open question. The innovation proposed here is a microgreen root/shoot partitioned planting box, which offers a solution to these challenges with accurate gas exchange measurements and a safe microgreen harvest in low gravity environments. Being able to measure transpiration of a microgreen canopy will be important for modeling plant growth in reduced gravity environments, so the first objective was to develop a planting unit with a seal between the root zone and the shoot zone. With an unsuitable harvesting technique, freshly harvested microgreens may add debris to the cabin, so the second objective was to test different harvesting techniques and management approaches associated with this innovation. These two objectives were pursued in parallel since many goals were the same: develop a planting unit that 1) separates the shoots from the roots, 2) allows acceptable germination rate, and 3) allows for seedlings to emerge and develop. What differed was the need to have a seal, which was only applicable for our gas exchange goal, and the need to have an embedded harvesting mechanism and bagging method which only applied to our harvesting goal. Testing of the various harvesting mechanisms and bagging methods was performed during a series of parabolic flights. All parabolic flight procedures took place inside a rented secondary containment chamber (e.g., glovebox) that was developed by the University of Louisville specifically for experiments involving fluids and other materials that may become airborne during reduced gravity flight. Three different harvesting methods and two different bagging collection methods were tested for microgreens. A third bagging method was initially tested but found to be unsuitable. Human factors were also taken into consideration, to identify which harvest and bagging collection methods would be easiest to use with favorable results in microgravity. Three parabolic flight tests were performed in total, one in November 2021 and two in December 2021.

Gioia Massa↗
NASA NTRS1999

Measurements of Chlorine Partitioning in the Winter Arctic Stratosphere

Under the extremely cold conditions in the polar winter stratosphere, heterogeneous reactions involving HCl and CIONO(sub 2) on the surfaces of polar stratospheric cloud particles can release large amounts of reactive chlorine from these reservoirs leading to rapid chemical loss of ozone in the Arctic lower stratosphere during late winter and early spring.

chlorine partitioning stratosphere polar processes↗
NASA NTRS1998

The Partitioning of NO(sub y) Species in the Summer Arctic Stratosphere

Volume mixing ratio profiles of the quantitatively significant NOy species NO, NO2, HNO3, HNO4, CINO3 and N2O5 were measured remotely form 8 to 38 km by the JPL MkIV FTIR solar absorption spectrometer during balloon flights from Fairbanks, Alaska on May 8 and July 8, 1997.

stratospheric chemistry atmospheric remote sensing↗