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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 433 records · Page 24
All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

An oxide dispersion strengthened alloy for gas turbine blades

The strength of the newly developed alloy MA-6000E is derived from a nickel alloy base, an enlongated grain structure, naturally occurring precipitates of gamma prime, and an artificial distribution of extremely fine, stable oxide particles. Its composition is Ni-15% Cr-2% Mo-2% Ta-4% W-4.5% Al-2.5% Ti-0.15% Zr-0.05% C-0.01% B-1.1% Y2O3. It exhibits strength of a conventional nickel-base alloy at 1400 F, but is quite superior at 2000 F. Its shear strength is relatively low, necessitating consideration of special joining procedures. Its high-cycle, low-cycle, and thermal fatigue properties are excellent. The relationship between alloy micro-structure and properties is discussed.

Glasgow, T. K.↗
NASA NTRS1979

Kinetics of the phase transformation in a Ti-15Mo-5Zr-3Al alloy as studied by X-ray diffraction

The purpose of the study is to make the T-T-T diagram available and to describe the X-ray diffraction techniques used to determine the fraction of transformed phase in the Ti-15Mo-5Zr-3Al metastable beta-alloy which decomposes into the hexagonal alpha-phase and the bcc beta-phase of a higher Mo concentration. The sheet material studied for this study is not ideal for an X-ray examination because of both a rolling and annealing texture as well as grain size problems. These difficulties are overcome using special X-ray techniques. Equations are given that indicate the approximations to be accepted if pole figure data are disregarded. Lattice parameter data from the beta phase enables one to obtain an approximate phase diagram.

Rao, V. B.↗
NASA NTRS1979

Adherence of sputtered titanium carbides

The study searches for interface treatment that would increase the adhesion of TiC coating to nickel- and titanium-base alloys. Rene 41 (19 wt percent Cr, 11 wt percent Mo, 3 wt percent Ti, balance Ni) and Ti-6Al-4V (6 wt percent Al, 4 wt percent V, balance Ti) are considered. Adhesion of the coatings is evaluated in pin-and disk friction tests. The coatings and interface regions are examined by X-ray photoelectron spectroscopy. Results suggest that sputtered refractory compound coatings adhere best when a mixed compound of coating and substrate metals is formed in the interfacial region. The most effective type of refractory compound interface appears to depend on both substrate and coating material. A combination of metallic interlayer deposition and mixed compound interface formation may be more effective for some substrate coating combinations than either alone.

Brainard, W. A.↗
NASA NTRS1978

Characterization of the effects of metallic impurities on silicon solar cell performance

The effects of controlled concentrations of secondary impurities (Al, C, Ca, Cr, Cu, Fe, Mg, Mn, Mo, Ta, Ti, V, Zn, and Zr), incorporated alone or in combinations into Czochralski and float zone crystals, on the performance of silicon solar cells were investigated. Impurity concentrations ranged from 10 to the 11th to 10 to the 17th/cu cm. Solar cells were fabricated by a conventional diffusion process and characterized by computer reduction of current-voltage data. The data suggest that performance loss primarily results from reduction of the base diffusion length. On the basis of this assumption, a first order analytic model which predicts cell performance as a function of impurity concentrations is developed. Calculated performance parameters are in good agreement with observation, except for some impurities, such as Fe, Cu and Ni, which degrade cells via recombination and defects in the junction space-charge region. N-base devices are less affected by impurities, although degradation mechanisms appear to be the same as in p-devices. There seems to be very limited interaction between impurities in multiply-doped cells.

Davis, J. R.↗
NASA NTRS1979

Mechanical properties and oxidation and corrosion resistance of reduced-chromium 304 stainless steel alloys

An experimental program was undertaken to identify effective substitutes for part of the Cr in 304 stainless steel as a method of conserving the strategic element Cr. Although special emphasis was placed on tensile properties, oxidation and corrosion resistance were also examined. Results indicate that over the temperature range of -196 C to 540 C the yield stress of experimental austenitic alloys with only 12 percent Cr compare favorably with the 18 percent Cr in 304 stainless steel. Oxidation resistance and in most cases corrosion resistance for the experimental alloys were comparable to the commercial alloy. Effective substitutes for Cr included Al, Mo, Si, Ti, and V, while Ni and Mn contents were increased to maintain an austenitic structure.

Stephens, J. R.↗
NASA NTRS1979

A new method of metallization for silicon solar cells

The new metallization process based on Mo-Sn system was studied. The reaction mechanism of MoO3 and its mixture with Sn was examined. The basic ink composition was modified in order to obtain a low ohmic contact to the cell. The electrical characteristics of the cells were comparable with the existing metallization processes. However, in comparison with the standard processes using silver as the contacting metal, the saving obtained by the use of the new process was substantial.

Macha, M.↗
NASA NTRS1980

Primordial refractory metal particles in the Allende meteorite

Refractory metal particles containing Os, Re, W, Mo, Ir, and Ru were observed in a Ca-Al-rich inclusion in the Allende meteorite. These particles are the closest to unaltered primordial metal condensates from a nebula yet reported, and appear to have been isolated from the nebula before the condensation of refractories was complete. Computer calculations of condensation indicate that the temperature of isolation appears to be close to the calculated temperature of first formation of oxides (about 1620 K at 0.0001 atm) indicating that isolation may have been effected by coating of the particles by oxides.

Blander, M.↗
NASA NTRS1979

Xenon from intermediate zones of supernovae

The paper examines the photodisintegration and neutron capture in massive stars which show that the bulk of the p-isotopes of Xe is formed during the gamma-process of Woosley and Howard (1978) by stripping of the Xe + Be seeds. The environments in which the chondrites can be formed were determined by the neutron-capture calculations; they show that the Xe-124-rich gas must be associated at the sources with anomalously large overabundances of Nd-142, Sm-144, and possibly Ba-130, and with anomalously small overabundances of the p-isotopes of Se, Kr, Sr, and Mo.

Heymann, D.↗
NASA NTRS1980

Structure and optical properties of evaporated films of the Cr- and V-group metals

Thin films of Cr, Mo, and W rapidly evaporated in high vacuum (5 x 10 to the -7th torr) onto room-temperature substrates show anomalously low reflectance (compared to bulk samples). From electron and X-ray diffraction and electron microscopy, the normal bcc crystal structure is found, but with very fine grains. Columnar grains about 100 A in diameter were separated by a less dense grain-boundary network about 10-A wide. The measured optical conductivity agrees with an inhomogeneous-medium model that assumes the normal crystalline conductivity for the grain interiors, with model parameters that correlate to the observed columnar grain size. In contrast, V and Nb films rapidly evaporated onto room-temperature substrates have the reflectance of bulk crystalline material. On liquid-nitrogen temperature substrates, however, V and Nb have normal bcc crystal structure but with small flat-plate grains, and the same model, with appropriate parameters, accounts for the optical conductivity. The difference between these two groups apparently depends on residual gases segregated at the grain boundaries in the Cr-group films.

Nestell, J. E., Jr.↗
NASA NTRS1981

Silicon materials task of the low-cost solar array project. Phase 4: Effects of impurities and processing on silicon solar cells

The results of the study form a basis for silicon producers, wafer manufacturers, and cell fabricators to develop appropriate cost-benefit relationships for the use of less pure, less costly solar grade silicon. Cr is highly mobile in silicon even at temperatures as low as 600 C. Contrasting with earlier data for Mo, Ti, and V, Cr concentrations vary from place to place in polycrystalline silicon wafers and the electrically-active Cr concentration in the polysilicon is more than an order of magnitude smaller than would be projected from single crystal impurity data. We hypothesize that Cr diffuses during ingot cooldown after growth, preferentially segregates to grain and becomes electrically deactivated. Accelerated aging data from Ni-contaminated silicon imply that no significant impurity-induced cell performance reduction should be expected over a twenty year device lifetime.

Hopkins, R. H.↗
NASA NTRS1980

The influence of isothermal annealing on the molybdenum fibers of a directed solid gamma/gamma prime - alpha alloy

The mechanical characteristics of the directed solid eutectic Ni-Al-Mo (gamma/gamma prime)-alpha alloy at high temperatures make it useful in the blades of gas turbines. Structural changes are observed for the alloy under isothermal annealing, particularly the formation of molybdenum plates at the grain boundary and an increase of the gamma phase in relation to the gamma prime phase. Molybdenum lamellas appear at the grain boundary above 1100 C which can have a negative influence on the mechanical properties. The change in the structure near the grain boundary with the increase in temperature is illustrated through a sequence of pictures.

Whittenberger, J. D.↗
NASA NTRS1981

The effect of thermal cycling to 1100 C on the alpha /Mo/ phase in directionally solidified gamma/gamma-prime-alpha alloys

Specimens of gamma/gamma-prime-alpha (Mo) eutectic alloy were thermally cycled or isothermally exposed at temperatures of 1075 to 1100 C. Transmission electron microscopy examination of cycled specimens indicated that even an exposure of 10 minutes effected noticeable changes in the shape of the alpha phase, and that the changes were cumulative as more cycles were added. The cross sections of fine, smooth fibers changed from rectangles to octagons, while lamellae and irregular shapes spheroidized. These effects are attributed to the differences in thermal expansion coefficients between the alpha phase and the gamma/gamma-prime matrix, and to the higher diffusion rates prevailing at elevated temperatures. Where the configuration of the alpha phase is a simple shape, such as a fiber, increasing the temperature eventually brings about a stress free interface between the alpha phase and the matrix by differential thermal expansion. Where the shape of the alpha phase is more complex, a stressed interface persists to higher temperatures where diffusion produces the more drastic morphological changes.

Harf, F. H.↗
NASA NTRS1981

Effects of alloying on aging and hardening processes of steel with 20% nickel

Measurements of hardness, thermal emf, and electrical resistance were used to study the effects of Co, Mo, Ti and Al contents on aging and hardening processes in Fe 20%Ni steel. It is shown that the effects of these alloying elements differ substantially. Anomalies which arise in the temperature dependence of physical properties due to the presence of cobalt and molybdenum are reduced by the inclusion of titanium and aluminum (and vice versa).

Bogachev, I. N.↗
NASA NTRS1981

Preparation and evaluation of advanced electrocatalysts for phosphoric acid fuel cells

A number of electrocatalyst combinations were prepared and characterized. These electrocatalysts were formulated to contain platinum combined with transition metal carbide forming elements (W, Mo, V) for cathodes and platinum combined with palladium for anodes. High resolution electron microscopy was used to determine the crystallite size and dispersion of platinum-palladium alloy electrocatalysts in order to provide analytical support for the electrochemical determinations of the particle dispersions. An equation was derived which correlates palladium crystallite size with electrochemical hydrogen adsorption. Based on comparisons of electrocatalyst performances in the presence of pure hydrogen and hydrogen containing carbon monoxide, it was shown that the apparent poisoning of the electrocatalyst by carbon monoxide is influenced by the electrode structure.

Stonehart, P.↗
NASA NTRS1981

AlGaAs/GaAs transverse junction stripe lasers with distributed feedback

Transverse junction stripe (TJS) lasers with periodic feedback were fabricated in two geometries. An interferometric and wet chemical etching technique was used to create a feedback grating across the entire pumping region for the distributed feedback (DFB) TJS laser and to create the separate distributed Bragg reflectors/DBR) for the TJS/DBR laser. The TJS/DFB laser was a double heterostructure device grown by liquid phase epitaxy (LPE) and had a third order grating etched in the top ALO.2GaO.8As layer. The grating was buried by growing an ALO.35GaO.65As layer on the grating by metal organic chemical vapor deposition (MO-CVD). The TJS/DBR laser was also fabricated in an LPE double heterostructure. The top AlGaAs layer was thinned to 0.1 micron over more than half of the laser so that the grating would be close to the GaAs active layer and optical field. Single mode operation in both configurations was obtained. The thermal shift of the laser wavelength in both cases was less than 1 Angstrom/deg K, compared to the 3 Angstrom/deg K shift of the spontaneous emission peak.

Hafich, M. J.↗
NASA NTRS1981

Long term behavior of silicon germanium thermoelectric generators

Results of tests of the long term performance of SiGe radioisotope thermoelectric generators (RTG) are presented. Three modules were monitored for 17,000-32,300 hr at hot junction temperatures of 1,085, 1,055, and 1,000 C; coating the unicouples with a 12,000 A thick layer of Si3N4 protected the modules from Si sublimation. Output degraded less than 0.3-0.4%/1,000 hr over the testing period. Life tests on a multihundredwatt (MHW) SiGe generator with 312 couples at a hot shoe temperature of 1,040 C dealt with power of 150 W at 30 V, with 0.5%/1,000 hr performance degradation. Si deposition on the insulation was found to enhance electrical conductance until a saturation point was reached. Disassembly of a test module after 16,750 hr revealed a Mo build-up, SiN4 coating deterioration, and Ti diffustion from the hot shoe to cooler regions of the junction. The presence of an Al2O3 insulator was recognized as preventing coating loss. Performance records from the Voyager and Les-8 satellites' RTG's are compared and show similar, 0.25%/1,000 hr degradation rates; RTG storage is judged to be feasible and the tests lead to projections of a 600,000 hr lifetime for a SiGe RTG.

Shields, V.↗
NASA NTRS1980

Refractory metal particles in refractory inclusions in the Allende meteorite

SEM and X-ray analysis were used to study refractory metal particles in five calcium-aluminum-rich inclusions in the Allende meteorite, and a complex variety of compositions and large departures from equilibrium were found. It is suggested that these particles could have been primordial condensates which were isolated from the nebula and from each other at different times by cocondensing oxides. Selective diffusion and/or oxidation of the more oxidizable metals (Mo, W, Fe, and Ni), phase segregations into different alloy phases (fcc, bcc, hcp, and, possibly, ordered phases), and the formation of metastable condensates could have been involved in the genesis of these materials

Fuchs, L. H.↗
NASA NTRS1982

Otoconial complexes as ion reservoirs in endolymph

Scintillation spectrometry was employed to examine the Ca-45(2+) uptake and exchange by otoconial complexes in the sensory region endolymph medium, and a comparison was made with bone mineral deposition. CaCl was injected intraperitoneally into 222 rats and blood samples were collected at set intervals during the subsequent 15 min-l mo life durations of the animals. The animals were eventually sacrificed and saccular and utricular otoconial complexes were microdissected while bone chips from the otic bone and femur were gathered by scraping. Ca-45 was present in the saccular otoconial complexes within 15 min of injection, an uptake similar to the bone deposition, while slower rates were observed with the utricular complexes. Utricular uptake, however, accelerated 5-6 hr postinjection, and total otoconial content was always lower than proportional bone absorption.

Ross, M. D.↗