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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 433 records · Page 24
All sourcesNASA NTRSDOE OSTI
NASA NTRS1980

The settling of helium and the ages of globular clusters

Model low-mass globular-cluster stars were evolved with their helium allowed to diffuse under the influence of gravity, thermal diffusion, and concentration gradient. The evolution tended to speed up. Also, the turnoff point moved toward lower luminosity and slightly lower surface temperature. If the luminosity at turnoff is used as the sole criterion for determining the age of a globular cluster, the inferred ages of such clusters are reduced by about 22% from starting values in the vicinity of 15 billion years.

Noerdlinger, P. D.↗
NASA NTRS1981

Vertical transport and photochemistry in the terrestrial mesosphere and lower thermosphere /50-120 km/

A study is conducted of the coupled effects of kinetics, solar cycle flux variations, and vertical transport on the distribution of long-lived hydrogen-carbon-oxygen compounds in the terrestrial mesosphere and lower thermosphere, using a one-dimensional aeronomy model. The calculations account for the important chemical reactions and use rocket measurements of the solar flux at solar minimum and maximum. Photodissociation rates appropriate for the mesosphere are determined with a spherical shell atmosphere formalism. Detailed corrections for the O2 Schumann-Runge bands and the temperature dependence of the CO2 cross sections are used. An eddy diffusion profile is derived which is in agreement with the Aladdin 74 mass spectral measurements of atomic O, O2, CO2, and Ar in the lower thermosphere and observations of the O3 minimum at about 80 km.

Allen, M.↗
NASA NTRS1983

Models of the formation of the solar nebula

Protostellar cloud collapse and solar nebula formation models indicate that the size of the nebula produced will be larger in terms of both gas centrifugal balance R(CF) and collapse time diffusion length R(V). From this, it can be deduced that low mass nebulas are produced if (R(V)/R(CF))-squared is much greater than unity, while nebulas result for values lower than approximately unity. The total angular momentum value distinguishes most current models of the solar nebula. Analytic expressions for the surface density, nebular mass flux and photospheric temperature distributions during the formation stage are presented for simple modes illustrating and general properties of growing protostellar disks.

Cassen, P.↗
NASA NTRS1985

Modelling of Laser-Enhanced Chemical Vapor Deposition

Research is directed at development of a detailed model of mass and heat transfer and chemical reaction in the pyrolysis of silane for the growth of thin amorphous silicon substrates incorporating laser heating of the gas phase above the film. The model will be the basis for evaluation of the relative importances of the decomposition of SiH4 in the vapor phase, mass transfer of the intermediate species, e.g., SiH2, and the evolution of hydrogen gas. Plans are also underway for developing a model for homogeneous nucleation of Si in the vapor phase to model the rate limitations observed at high gas-phase temperatures and high partial pressures of silane. Work was concentrated on an almost one-dimensional model for the coupling of the CO2 laser beam for heat transfer of the vapor phase with simple kinetic models for SiH4 decomposition and subsequent absorption of Si vapor on the substrate. Mass transfer in the vapor phase is assumed to be solely by diffusion. The role of convection in the vapor phase caused by the large changes in density in and around the center of the laser beam will be analyzed to evaluate the potential of microgravity experiments for increasing the uniformity of the film and the deposition rate.

Brown, R. A.↗
NASA NTRS1985

The O2(+) vibrational distribution in the Venusian ionosphere

The vibrational distribution of O2(+) in the ionosphere of Venus was calculated for a model atmosphere (similar to one discribed by Fox, 1982), based on data from the Pioneer Venus neutral mass spectrometer. The calculation of the ion densities includes both chemistry and diffusion. At 100 km, quenching precludes survival of vibrationally excited 02(+). At the exobase, near 200 km, more than half of O2(+) molecules are vibrationally excited. The effects of vibrationally excited O2(+) on the hot oxygen coronas and the airglow are discussed.

Fox, J. L.↗
NASA NTRS1985

Refractory amorphous metallic (W/0.6/ Re/0.4/)76B24 coatings on steel substrates

Refractory metallic coatings of (W/0.6/ Re/0.4/)76B24 (WReB) have been deposited onto glass, quartz, and heat-treated AISI 52100 bearing steel substrates by dc magnetron sputtering. As-deposited WReB films are amorphous, as shown by their diffuse X-ray diffraction patterns; chemically homogeneous, according to secondary ion mass spectrometry (SIMS) analysis; and they exhibit a very high (approximately 1000 C) crystallization temperature. Adhesion strength of these coatings on heat-treated AISI 52100 steel is in excess of approximately 20,000 psi and they possess high microhardness (approximately 2400 HV50). Unlubricated wear resistance of such hard and adherent amorphous metallic coatings on AISI 52100 steel is studied using the pin-on-disc method under various loading conditions. Amorphous metallic WReB coatings, about 4 microns thick, exhibit an improvement of more than two and a half orders of magnitude in the unlubricated wear resistance over that of the uncoated AISI 52100 steel.

Thakoor, A. P.↗
NASA NTRS1988

The evolution of molecular clouds

The problem of the structure and evolution of molecular clouds is reviewed, with particular emphasis given to the relationship with star formation. The basic hypothesis is that magnetic fields are the primary agents for supporting molecular clouds, although damped Alfven waves may play an important role in the direction parallel to the field lines. This picture naturally leads to a conception of 'bimodal star formation'. It is proposed that high-mass stars form from the overall gravitational collapse of a supercritical cloud, whereas low-mass stars form from small individual cores that slowly condense by ambipolar diffusion from a more extended envelope until they pass the brink of graviational instability and begin to collapse dynamically from 'inside-out'. The evidence that the infall stage of protostellar evolution is terminated by the development of a powerful stellar wind is reviewed.

Shu, Frank H.↗
NASA NTRS1989

Advances and directions of ion nitriding/carburizing

Ion nitriding and carburizing are plasma activated thermodynamic processes for the production of case hardened surface layers not only for ferrous materials, but also for an increasing number of nonferrous metals. When the treatment variables are properly controlled, the use of nitrogenous or carbonaceous glow discharge medium offers great flexibility in tailoring surface/near-surface properties independently of the bulk properties. The ion nitriding process has reached a high level of maturity and has gained wide industrial acceptance, while the more recently introduced ion carburizing process is rapidly gaining industrial acceptance. The current status of plasma mass transfer mechanisms into the surface regarding the formation of compound and diffusion layers in ion nitriding and carbon build-up ion carburizing is reviewed. In addition, the recent developments in design and construction of advanced equipment for obtaining optimized and controlled case/core properties is summarized. Also, new developments and trends such as duplex plasma treatments and alternatives to dc diode nitriding are highlighted.

Spalvins, Talivaldis↗
NASA NTRS1989

Infrared spectra of crystalline and glassy silicates and application to interstellar dust

The infrared spectra of crystalline minerals predicted in theoretical condensation sequences do not match the astronomical observations. Since the astronomical spectra are a closer match to glassy silicates, the authors undertook a study to measure the infrared spectra of glassy silicates that have compositions similar to silicate minerals predicted in theoretical condensation sequences. The data should support observations aimed at elucidating condensation chemistry in dust forming regions. The authors measured the mass absorption coefficients, from 2.5 to 25 microns, of ground samples of olivine, diopside, and serpentine and also smoke samples that were prepared from these minerals. The smoke samples prepared in this way are predominantly glassy with nearly the same composition as the parent minerals. The crystalline samples consisted of pure olivine ((Fe(0.1)Mg(0.9))(2)SiO(4)), serpentine, diopside. Sample purity was confirmed by x ray diffraction. Each mineral was ground for 10 hours and a measured mass of the powder was mixed with KBr powder for absorption measurements using the method of Borghesi et a. (1985). The smoke samples were prepared from the same samples used for grinding by vaporizing the minerals using pulsed laser radiation in air. The smoke samples formed by condensation of the resulting vapor. The smoke settled onto infrared transparent KRS-5 substrates and onto a quartz crystal microbalance used to obtain mass measurements. A description of the preparation method is given in Stephens (1980). The glassy diopside showed only diffuse electron diffraction peaks and hence was nearly amorphous, while the serpentine smoke showed a weak diffraction pattern corresponding to MgO. The smoke from olivine showed a weak diffraction pattern corresponding to Fe2O3 and/or Fe3O4. The mass absorption coefficients, from 2.5 to 25 microns, of crystalline diopside, olivine, and serpentine and their corresponding smoke samples are shown in figures.

Stephens, John R.↗
NASA NTRS1996

Kinetics of Diffusional Droplet Growth in a Liquid/Liquid Two-Phase System

We address the problem of diffusional interactions in a finite sized cluster of spherical particles for volume fractions, V(sub v) in the range 0-0.01. We determined the quasi-static monopole diffusion solution for n particles distributed at random in a continuous matrix. A global mass conservation condition is employed, obviating the need for any external boundary condition. The numerical results provide the instantaneous (snapshot) growth or shrinkage rate of each particle, precluding the need for extensive time-dependent computations. The close connection between these snapshot results and the coarsegrained kinetic constants are discussed. A square-root dependence of the deviations of the rate constants from their zero volume fraction value is found for the higher V(sub v) investigated. This behavior is consistent with predictions from diffusion Debye-Huckel screening theory. By contrast, a cube-root dependence, reported in earlier numerical studies, is found for the lower V(sub v) investigated. The roll-over region of the volume fraction where the two asymptotics merge depends on the number of particles, n, alone. A theoretical estimate for the roll-over point predicts that the corresponding V(sub v) varies as n(sup -2), in good agreement with the numerical results.

Glicksman, M. E.↗
NASA NTRS2023

Passive Rocket Diffuser Testing: Performance Similitude Via Nozzle Contour Modification

Subscale rocket testing offers a chance to examine exhaust plume behavior and prove out auxiliary systems early in a development cycle, when the cost of design iteration remains low. Despite the utility of experimentation, perfect similitude between a rocket engine and a scaled model is unobtainable; choices must be made to prioritize the reproduction of certain parameters at the expense of others. The experimentalist’s toolkit contains a variety of techniques to achieve this selective similarity. Determination of the appropriate tool is dependent on a test series’ specific objectives, facility limitations, and financial considerations. Preservation of full nozzle geometry is crucial if its internal flow is of interest. However, subscale thrusters often serve as a simple plume source in the evaluation of adjacent phenomena: vehicle base pressures, retropropulsive flows, supersonic diffuser performance, refractory erosion, deflector cooling, impingement shock structures, etc. In such cases, it may be permissible to rework the nozzle geometry to compensate for discrepancies in subscale propellant pressure, temperature, or chemical composition. Thrust, pressure, Mach number, heat flux, and myriad other parameters can be used to ground the altered designs. Subscale diffuser testing at the full chamber pressure of flight hardware is occasionally infeasible. It is hypothesized that, absent a means of backpressure reduction, comparable performance may be obtained for a prescribed motive fluid by maintaining scaled engine mass flow and nozzle exit geometry at the expense of throat geometry, exit pressure, and Mach number. The present work offers discrete empirical support for this mass-flow-based approach to contour modification.

subscale↗
NASA NTRS1998

Burner Emissions Associated with Lobed and Non-Lobed Fuel Injectors

The present experimental study examines NO(sub x), and CO emissions associated with three alternative fuel-injector geometries. These injectors mix fuel and air and strain their interfaces to differing extents and thus create different local equivalence ratios within flow regions upstream of flame ignition and stabilization. Two of the devices studied are lobed fuel injectors, in which molecular mixing of reactants is associated with streamwise vorticity generation, while the third one is a non-lobed fuel injector. Results show that rapid mixing allowed both lobed injector geometries to produce very lean premixed flame structures, with a lower achievable turn-down or fuel/air mass flux ratio than for the analogous non-lobed injector, which largely, produced distinct diffusion flames. All three injectors exhibited some level of sooting near walls and in the far-field region, with the non-lobed injector sooting to the greatest extent. At low fuel flow rates, in which the lobed injectors created locally very lean premixed conditions, there resulted lower NO(sub x) emissions as compared with non-lobed injector emissions. Yet at higher fuel-air mass flux ratios, NO(sub x) emissions from the lobed injectors were actually higher than for the nonlobed injector, likely due to reduced sooting and hence reduced radiative heat losses associated with enhanced mixing. For both lobed injector geometries examined here, CO emissions became high for low values of the fuel/air mass flux ratio, again consistent with locally premixed combustion behavior, despite the fact that fuel was injected separately from air directly into the burner test section. The present study demonstrates that, for fuel-air mixing enhancement devices, control of the local equivalence ratio is critical in order to optimize burner emissions.

Mitchell, M. G.↗
NASA NTRS2001

Optimized suspension culture: the rotating-wall vessel

Suspension culture remains a popular modality, which manipulates mechanical culture conditions to maintain the specialized features of cultured cells. The rotating-wall vessel is a suspension culture vessel optimized to produce laminar flow and minimize the mechanical stresses on cell aggregates in culture. This review summarizes the engineering principles, which allow optimal suspension culture conditions to be established, and the boundary conditions, which limit this process. We suggest that to minimize mechanical damage and optimize differentiation of cultured cells, suspension culture should be performed in a solid-body rotation Couette-flow, zero-headspace culture vessel such as the rotating-wall vessel. This provides fluid dynamic operating principles characterized by 1) solid body rotation about a horizontal axis, characterized by colocalization of cells and aggregates of different sedimentation rates, optimally reduced fluid shear and turbulence, and three-dimensional spatial freedom; and 2) oxygenation by diffusion. Optimization of suspension culture is achieved by applying three tradeoffs. First, terminal velocity should be minimized by choosing microcarrier beads and culture media as close in density as possible. Next, rotation in the rotating-wall vessel induces both Coriolis and centrifugal forces, directly dependent on terminal velocity and minimized as terminal velocity is minimized. Last, mass transport of nutrients to a cell in suspension culture depends on both terminal velocity and diffusion of nutrients. In the transduction of mechanical culture conditions into cellular effects, several lines of evidence support a role for multiple molecular mechanisms. These include effects of shear stress, changes in cell cycle and cell death pathways, and upstream regulation of secondary messengers such as protein kinase C. The discipline of suspension culture needs a systematic analysis of the relationship between mechanical culture conditions and biological effects, emphasizing cellular processes important for the industrial production of biological pharmaceuticals and devices.

Non-NASA Center↗
NASA NTRS1989

Stochastic histories of dust grains in the interstellar medium

The purpose is to study an evolving system of refractory dust grains within the Interstellar Medium (ISM). This is done via a combination of Monte Carlo processes and a system of partial differential equations, where refractory dust grains formed within supernova remnants and ejecta from high mass loss stars are subjected to the processes of sputtering and collisional fragmentation in the diffuse media and accretion within the cold molecular clouds. In order to record chemical detail, the authors take each new particle to consist of a superrefractory core plus a more massive refractory mantle. The particles are allowed to transfer to and fro between the different phases of the interstellar medium (ISM) - on a time scale of 10(exp 8) years - until either the particles are destroyed or the program finishes at a Galaxy time of 6x10(exp 9) years. The resulting chemical and size spectrum(s) are then applied to various astrophysical problems with the following results. For an ISM which has no collisional fragmentation of the dust grains, roughly 10 percent by mass of the most refractory material survives the rigors of the ISM intact, which leaves open the possibility that fossilized isotopically anomalous material may have been present within the primordial solar nebula. Stuctured or layered refractory dust grains within the model cannot explain the observed interstellar depletions of refractory material. Fragmentation due to grain-grain collisions in the diffuse phase plus the accretion of material in the molecular cloud phase can under certain circumstances cause a bimodal distribution in grain size.

Liffman, Kurt↗
NASA NTRS2003

Convective Effects During Diffusivity Measurements in Liquids with An Applied Magnetic Field

Convective contamination of self-diffusion experiments with an applied magnetic field is considered using a two-dimensional axisymmetric model. Constant, uniform, and an additional non-uniform heat fluxes are imposed along the sidewall of the cylinder while constant heat loss occurs through the top and bottom. In this model, due to a very small thermal Peclet number, convective heat transfer is neglected, and the flow is steady and inertialess. Time-dependent concentration is solved for various values of the mass Peclet number, Pe(sub m), (the ratio between the convective transport rate and the diffusive transport rate) and different magnetic field strengths represented by the Hartmann number Ha. Normalized values of these diffusivities vs. effective Pe(sub m) are presented for different imposed temperature profiles. In all cases, the diffusivity value obtained through the simulated measurement increases as the effective Pe(sub m) increases. The numerical results suggest that an additional periodic flux, or hot and cold spots, can significantly decrease the convective contamination in our geometry.

Khine, Yu Yu↗
NASA NTRS1989

Ballistic transport in planetary ring systems due to particle erosion mechanisms. I - Theory, numerical methods, and illustrative examples

Ballistic transport, defined as the net radial transport of mass and angular momentum due to exchanges of meteoroid hypersonic-impact ejecta by neighboring planetary ring regions on time-scales orders-of-magnitude shorter than the age of the solar system, is presently considered as a problem in mathematical physics. The preliminary results of a numerical scheme for following the combined effects of ballistic transport and viscous diffusion demonstrate that ballistic transport generates structure near sharp edges already present in the ring-mass distribution; the entire ring system ultimately develops an undulatory structure whose length scale is typically of the order of the radial excursion of the impact ejecta.

Durisen, Richard H.↗
NASA NTRS1993

A carbon isotope mass balance for an anoxic marine sediment: Isotopic signatures of diagenesis

A carbon isotope mass balance was determined for the sediments of Cape Lookout Bight, NC to constrain the carbon budgets published previously. The diffusive, ebullitive and burial fluxes of sigma CO2 and CH4, as well as the carbon isotope signatures of these fluxes, were measured. The flux-weighted isotopic signature of the remineralized carbon (-18.9 plus or minus 2.7 per mil) agreed with the isotopic composition of the remineralized organic carbon determined from the particulate organic carbon (POC) delta(C-13) profiles (-19.2 plus or minus 0.2), verifying the flux and isotopic signature estimates. The measured delta(C-13) values of the sigma CO2 and CH4 diffusive fluxes were significantly different from those calculated from porewater gradients. The differences appear to be influenced by methane oxidation at the sediment-water interface, although other potential processes cannot be excluded. The isotope mass balance provides important information concerning the locations of potential diagenetic isotope effects. Specifically, the absence of downcore change in the delta(C-13) value of the POC fraction and the identical isotopic composition of the POC and the products of remineralization indicate that no isotopic fractionation is expressed during the initial breakdown of the POC, despite its isotopically heterogeneous composition.

Boehme, Susan E.↗
NASA NTRS1986

Thermophoretically augmented mass transfer rates to solid walls across laminar boundary layers

Predictions of mass transfer (heavy vapor and small particle deposition) rates to solid walls, including the effects of thermal (Soret) diffusion ('thermophoresis' for small particles), are made by numerically solving the two-dimensional self-similar forced convection laminar boundary-layer equations with variable properties, covering the particle size range from vapor molecules up to the size threshold for inertial (dynamical nonequilibrium) effects. The effect of thermophoresis is predicted to be particularly important for submicron particle deposition on highly cooled solid surfaces, with corresponding enhancement factors at atmospheric conditions being over a thousand-fold at T(w)/T(e) equal to about 0.6. As a consequence of this mass transfer mechanism, the particle size dependence of the mass transfer coefficient to a cooled wall will be much weaker than for the corresponding case of isothermal capture by Brownian-convective diffusion.

Gokoglu, S. A.↗