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At least 433 records · Page 24

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NASA NTRS1994

Effects of silver ions (Ag+) on contractile ring function and microtubule dynamics during first cleavage in Ilyanassa obsoleta

The terminal phase of cell division involves tight constriction of the cleavage furrow contractile ring, stabilization/elongation of the intercellular bridge, and final separation of the daughter cells. At first cleavage, the fertilized eggs of the mollusk, Ilyanassa obsoleta, form two contractile rings at right angles to each other in the same cytoplasm that constrict to tight necks and partition the egg into a trefoil shape. The cleavage furrow contractile ring (CF) normally constricts around many midbody microtubules (MTs) and results in cleavage; the polar lobe constriction contractile ring (PLC) normally constricts around very few MTs and subsequently relaxes without cleavage. In the presence of Ag+ ions, the PLC 1) begins MT-dependent rapid constriction sooner than controls, 2) encircles more MTs than control egg PLCs, 3) elongates much more than control PLCs, and 4) remains tightly constricted and effectively cleaves the polar lobe from the egg. If Ag(+)-incubated eggs are returned to normal seawater at trefoil, tubulin fluorescence disappears from the PLC neck and the neck relaxes. If nocodazole, a drug that depolymerizes MTs, is added to Ag(+)-incubated eggs during early PLC constriction, the PLC is not stabilized and eventually relaxes. However, if nocodazole is added to Ag(+)-incubated eggs at trefoil, tubulin fluorescence disappears from the PLC neck but the neck remains constricted. These results suggest that Ag+ accelerates and gradually stabilizes the PLC constriction by a mechanism that is initially MT-dependent, but that progressively becomes MT-independent.

Non-NASA Center↗

NASA NTRS1966

Highly sensitive solids mass spectrometer uses inert-gas ion source

Mass spectrometer provides a recorded analysis of solid material surfaces and bulk. A beam of high-energy inert-gas ions bombards the surface atoms of a sample and converts a percentage into an ionized vapor. The mass spectrum analyzer separates the vapor ionic constituents by mass-to-charge ratio.

Source record↗

NASA NTRS1985

Plasma and magnetospheric research

Several programs and variations have been developed to determine statistical means of different plasma parameters when binned in different variables. These parameters include temperature, densities and spacecraft potentials for any of the ion species, as well as ratios of these variables for any other ion species to the corresponding variable for H(+). The variables for binning include L, radial distance, and geomagnetic latitude; and separate statistics are automatically run for local morning and local evening data. These programs all run from output files from the plasma parameter thin sheath analysis program. A variant program also bins for magnetic activity, using either Kp or Dst, which requires an additional magnetic activity input file. These programs can be run either interactively or in batch mode, using file listings generated by a DIRECTORY command. In addition to printed output, these programs generate output files which can be used to plot the results. Programs to plot these averaged data are under development.

Comfort, R. H.↗

NASA NTRS1988

Geomagnetic activity during the passage of the earth through Halley's tail in 1910

The magnetic disturbance expected when the earth passed through the center of Comet Halley's tail in 1910 apparently occurred 12 hr too early. A detailed study of the records reveals that the discrepancy is due to a change in the convention for determining the start of the day. The magnetic disturbance did in fact arrive at the expected time and no unusual aberration of the solar wind need be invoked to explain the timing. The disturbance consisted of two troughs in the horizontal component of the earth's magnetic field, separated by about 14 hr, presumably associated with wakes in the solar wind momentum flux on either side of the ion tail. The disturbance was independent of latitude, indicating that the responsible current system flowed far above the earth's surface. After the comet's passage the magnetosphere was left in a mildly disturbed condition, with a weak ring current present.

Russell, C. T.↗

NASA NTRS2002

Retinoid quantification by HPLC/MS(n)

Retinoic acid (RA) mediates most of the biological effects of vitamin A that are essential for vertebrate survival. It acts through binding to receptors that belong to the nuclear receptor transcription factor superfamily (Mangelsdorf et al. 1994). It is also a highly potent vertebrate teratogen. To determine the function and effects of endogenous and exogenous RA, it is important to have a highly specific, sensitive, accurate, and precise analytical procedure. Current analyses of RA and other retinoids are labor intensive, of poor sensitivity, have limited specificity, or require compatibility with RA reporter cell lines (Chen et al. 1995. BIOCHEM: Pharmacol. 50: 1257-1264; Creech Kraft et al. 1994. BIOCHEM: J. 301: 111-119; Lanvers et al. 1996. J. Chromatogr. B Biomed. Appl. 685: 233-240; Maden et al. 1998. DEVELOPMENT: 125: 4133-4144; Wagner et al. 1992. DEVELOPMENT: 116: 55-66). This paper describes an HPLC/mass spectrometry/mass spectrometry product ion scan (HPLC/MS(n)) procedure for the analysis of retinoids that employs atmospheric pressure chemical ionization MS. The retinoids are separated by normal-phase column chromatography with a linear hexane-isopropanol-dioxane gradient. Each retinoid is detected by a unique series of MS(n) functions set at optimal collision-induced dissociation energy (30% to 32%) for all MS(n) steps. The scan events are divided into three segments, based on HPLC elution order, to maximize the mass spectrometer duty cycle. The all-trans, 9-cis, and 13-cis RA isomers are separated, if desired, by an isocratic hexane-dioxane-isopropanol mobile phase. This paper describes an HPLC/MS(n) procedure possessing high sensitivity and specificity for retinoids.

NASA Discipline Developmental Biology↗

NASA NTRS1980

Raw liquid waste treatment process

A raw sewage treatment process is disclosed in which substantially all the non-dissolved matter, which is suspended in the sewage water is first separated from the water, in which at least organic matter is dissolved. The non-dissolved material is pyrolyzed to form an activated carbon and ash material without the addition of any conditioning agents. The activated carbon and ash material is added to the water from which the non-dissolved matter was removed. The activated carbon and ash material absorbs organic matter and heavy metal ions, it is believed, are dissolved in the water and is thereafter supplied in a counter current flow direction and combined with the incoming raw sewage to facilitate the separation of the non-dissolved settleable materials from the sewage water. The used carbon and ash material together with the non-dissolved matter which was separated from the sewage water are pyrolyzed to form the activated carbon and ash material.

Humphrey, Marshall F.↗

NASA NTRS1976

Phase separation of metallic hydrogen-helium alloys

Calculations are presented for the thermodynamic functions and phase separation boundaries of solid metallic hydrogen helium alloys at temperatures between 0 K and 19,000 K and at pressures between 15 and 90 megabars. Expressions for the band structure energy of a randomly disordered alloy (including third order in the electron ion interaction) are derived and evaluated. Short and long range order are included by the quasi-chemical method, and lattice dynamics in the virtual crystal harmonic approximation. We conclude that at temperatures below 4,000 K there is complete phase separation of hydrogen helium alloys, and that a miscibility gap remains at the highest temperatures and pressures considered. The relevance of these results to models of the deep interior of Jupiter is briefly discussed.

Straus, D. M.↗

NASA NTRS2009

Low-Pressure, Field-Ionizing Mass Spectrometer

A small mass spectrometer utilizing a miniature field ionization source is now undergoing development. It is designed for use in a variety of applications in which there are requirements for a lightweight, low-power-consumption instrument that can analyze the masses of a wide variety of molecules and ions. The device can operate without need for a high-vacuum, carrier-gas feed radioactive ionizing source, or thermal ionizer. This mass spectrometer can operate either in the natural vacuum of outer space or on Earth at any ambient pressure below 50 torr (below about 6.7 kPa) - a partial vacuum that can easily be reached by use of a small sampling pump. This mass spectrometer also has a large dynamic range - from singly charged small gas ions to deoxyribonucleic acid (DNA) fragments larger than 104 atomic mass units - with sensitivity adequate for detecting some molecules and ions at relative abundances of less than one part per billion. This instrument (see figure) includes a field ionizer integrated with a rotating-field mass spectrometer (RFMS). The field ionizer effects ionization of a type characterized as "soft" in the art because it does not fragment molecules or initiate avalanche arcing. What makes the "soft" ionization mode possible is that the distance between the ionizing electrodes is less than mean free path for ions at the maximum anticipated operating pressure, so that the ionizer always operates on the non-breakdown side of the applicable Paschen curve (a standard plot of breakdown potential on the ordinate and pressure electrode separation on the abscissa). The field ionizer in this instrument is fabricated by micromachining a submicron-thick membrane out of an electrically nonconductive substrate, coating the membrane on both sides to form electrodes, then micromachining small holes through the electrodes and membrane. Because of the submicron electrode separation, even a potential of only 1 V applied between the electrodes gives rise to an electric field with a strength of in excess of a megavolt per meter strong enough to ionize any gas molecules passing through the holes. An accelerator grid and an electrostatic deflector focus the ions from the field ionizer into the rotating-field cell of the RFMS. The potentials applied to the electrodes of the cell to generate the rotating electric field typically range from 1 to 13 V. The ions travel in well-defined helices within this cell, after which they are collected in a Faraday cup. The mass of most of the molecules reaching the Faraday cup decreases with increasing frequency of rotation of the electric field in the cell. Therefore, the frequency of rotation of the electric field is made to vary in order to scan through a desired range of ion masses: For example, lightweight gas molecules are scanned at frequencies in the megahertz range, while DNA and other large organic molecules are scanned at kilohertz frequencies.

Hartley, Frank↗

NASA NTRS1999

Rocket/Radar Sporadic-E Experiment Conducted during the El Coqui 2 Campaign

In order to investigate the complex electrodynamics and neutral-plasma coupling inherent to sporadic-E layers in the earth's mid-latitude ionosphere, a series of rocket/radar experiments were planned as part of the NASA El Coqui H Campaign from Tortuguero Launch Range, Puerto Rico, in March-April, 1998. The rocket experiments consisted of two pairs of "mother-daughter" payloads with limited apogees so that the payloads "hovered" in the sporadic-E region (95-125 km). Each payload pair included vector DC and AC electric field detectors, a highly accurate flux-gate DC magnetometer, an ion mass spectrometer, an ionization gauge, and spaced-electric field receivers to measure the wavelength and phase velocity of the unstable plasma waves. Separate rockets were included to simultaneously carry aloft TMA trails to measure the neutral wind and its velocity shear, believed responsible for the sporadic-E layer formation. In addition to the rocket experiments, incoherent scatter radar measurements of plasma density and drift velocity were gathered almost every night during the 3 week campaign. Continuous VHF backscatter radar operations were carried out from a site near Salinas, Puerto Rico, where 3-m backscatter echoes were observed associated with sporadic-E and other types of low altitude ionospheric layers. Other radars that operated during the campaign included an HF backscatter system near Ponce, Puerto Rico, and a second VHF backscatter radar set up near Aguadila Puerto Rico. On 24 March 1998, one of the instrumented rockets was launched, attaining an apogee of 129 km. The payloads successfully pierced an intense sporadic-E layer observed by both the Arecibo radar and the in-situ density and ion mass spectrometer probes. In-situ DC electric fields revealed very low (about 1-2 mV/m) ambient fields with small amplitude structures of the same order. No high frequency (short scale) waves were observed, consistent with the VHF backscatter observations at the time of the launch. An overview of the observations will be presented.

Pfaff, R.F.↗

NASA NTRS1983

High voltage v-groove solar cell

A high voltage multijunction solar cell comprises a number of discrete voltage generating regions, or unit cells, which are formed in a single semiconductor wafer and are connected together so that the voltages of the individual cells are additive. The unit cells comprise doped regions of opposite conductivity types separated by a gap. The method includes forming V-shaped grooves in the wafer and orienting the wafer so that ions of one conductivity type can be implanted in one face of the groove while the other face is shielded. A metallization layer is applied and selectively etched away to provide connections between the unit cells.

Evans, J. C., Jr.↗

NASA NTRS1993

The nightside ionosphere of Venus under varying levels of solar EUV flux

Solar activity varied widely over the 14 year lifetime of the Pioneer Venus Orbiter (PVO), and these variations directly affected the properties of the nightside ionosphere. At solar maximum, when solar EUV was largest, the Venus ionosphere was found to extend to highest altitudes and nightward ion transport was the main source of the nightside ionosphere. At solar minimum, nightward ion transport was reduced, and electron precipitation was thought to be the main source. In this study, we have attempted a separation of spatial variations from temporal variations by examining the altitude profiles of the magnetic field, and electron density and temperature for three different solar EUV flux ranges. In the upper ionosphere and near-planet magnetotail (h greater than 1800 km), the solar EUV flux effects are significant. The electron density decreases about an order of magnitude from high to low EUV flux, while the electron temperature at least doubles. The magnetic field also increases 2 - 3 nT. In the lower ionosphere (200 - 600 km), lower EUV fluxes are associated with slightly reduced density, and higher temperature. These results are in accord with recent entry phase observations, where the electron density measured above the ionospheric density peak is lower than that observed at solar maximum during the early Pioneer Venus mission.

Ho, C. M.↗

NASA NTRS1993

The Nightside Ionosphere of Venus Under Varying Levels of Solar EUV Flux

Solar activity varied widely over the 14 year lifetime of the Pioneer Venus Orbiter, and these variations directly affected the properties of the nightside ionosphere. At solar maximum, when solar EUV was largest, the Venus ionosphere was found to extend to highest altitudes and nightward ion transport was the main source of the nightside ionosphere. At solar minimum, nightward ion transport was reduced, and electron precipitation was thought to be the main source. In this study, we have attempted a separation of spatial variations from temporal variations by examining the altitude profiles of the magnetic field, and electron density and temperature for three different solar EUV flux ranges. In the upper ionosphere and near-planet magnetotail (h greater than 1800 km), the solar EUV effects are significant. The electron density decreases about an order of magnitude from high to low EUV flux, while the electron temperature at least doubles. The magnetic field also increases 2 - 3 nT. In the lower ionosphere (200 - 600 km), lower EUV fluxes are associated with slightly reduced density, and higher temperature. These results are in accord with recent entry phase observations, where the electron density measured above the ionospheric density peak is lower than that observed at solar maximum during the early Pioneer Venus mission.

Ho, C. M.↗

NASA NTRS2003

Genesis Solar-Wind Sample Return Mission: The Materials

The Genesis spacecraft has two primary instruments which passively collect solar wind. The first is the collector arrays , a set of panels, each of which can deploy separately to sample the different kinds of solar wind (regimes). The second is the concentrator, an electrostatic mirror which will concentrate ions of mass 4 through mass 25 by about a factor of 20 by focusing them onto a 6 cm diameter target. When not deployed, these instruments fit into a compact canister. After a two year exposure time, the deployed instruments can be folded up, sealed into the canister, and returned to earth for laboratory analysis. Both the collector arrays and the concentrator will contain suites of ultra-high purity target materials, each of which is tailored to enable the analysis of a different family of elements. This abstract is meant to give a brief overview of the Genesis mission, insight into what materials were chosen for flight and why, as well as head s up information as to what will be available to planetary scientist for analysis when the solar-wind samples return to Earth in 2003. Earth. The elemental and isotopic abundances of the solar wind will be analyzed in state-of-the-art laboratories, and a portion of the sample will be archived for the use of future generations of planetary scientists. Technical information about the mission can be found at www.gps.caltech.edu/genesis.

Jurewicz, A. J. G.↗

NASA NTRS2010

Comparing Solar-Flare Acceleration of >-20 MeV Protons and Electrons Above Various Energies

A large fraction (up to tens of percent) of the energy released in solar flares goes into accelerated ions and electrons, and studies indicate that these two populations have comparable energy content. RHESSI observations have shown a striking close linear correlation between the 2.223 MeV neutron-capture gamma-ray line and electron bremsstrahlung emission >300 keV, indicating that the flare acceleration of >^20 MeV protons and >300 keV electrons is roughly proportional over >3 orders of magnitude in fluence. We show that the correlations of neutron-capture line fluence with GOES class or with bremsstrahlung emission at lower energies show deviations from proportionality, primarily for flares with lower fluences. From analyzing thirteen flares, we demonstrate that there appear to be two classes of flares with high-energy acceleration: flares that exhibit only proportional acceleration of ions and electrons down to 50 keV and flares that have an additional soft, low-energy bremsstrahlung component, suggesting two separate populations of accelerated electrons. We use RHESSI spectroscopy and imaging to investigate a number of these flares in detail.

Shih, Albert Y.↗

NASA NTRS1994

Early time evolution of negative ion clouds and electron density depletions produced during electron attachment chemical release experiments

Two-dimensional electrostatic particle-in-cell simulations are used to study the early time evolution of electron depletions and negative ion clouds produced during electron attachment chemical releases in the ionosphere. The simulation model considers the evolution in the plane perpendicular to the magnetic field and a three-species plasma that contains electrons, positive ions, and also heavy negative ions that result as a by-product of the electron attachment reaction. The early time evolution (less than the negative ion cyclotron period) of the system shows that a negative charge surplus initially develops outside of the depletion boundary as the heavy negative ions move across the boundary. The electrons are initially restricted from moving into the depletion due to the magnetic field. An inhomogenous electric field develops across the boundary layer due to this charge separation. A highly sheared electron flow velocity develops in the depletion boundary due to E x B and Delta-N x B drifts that result from electron density gradients and this inhomogenous electric field. Structure eventually develops in the depletion boundary layer due to low-frequency electrostatic waves that have growth times shorter than the negative ion cyclotron period. It is proposed that these waves are most likely produced by the electron-ion hybrid instability that results from sufficiently large shears in the electron flow velocity.

Scales, W. A.↗

NASA NTRS2002

Miniaturized GC/MS instrumentation for in situ measurements: micro gas chromatography coupled with miniature quadrupole array and paul ion trap mass spectrometers

Miniaturized chemical instrumentation is needed for in situ measurements in planetary exploration and other spaceflight applications where factors such as reduction in payload requirements and enhanced robustness are important. In response to this need, we are 'continuing to develop miniaturized GC/MS instrumentation which combines chemical separations by gas chromatography (GC) with mass spectrometry (MS) to provide positive identification of chemical compounds in complex mixtures of gases, such as those found in the International Space Station's cabin atmosphere. Our design approach utilizes micro gas chromatography components coupled with either a miniature quadrupole mass spectrometer array (QMSA) or compact, high-resolution Paul ion trap.

GC/MC miniature mass spectrometry MEMS↗

NASA NTRS2002

Micro-machined planar field asymmetric ion mobility spectrometer as a gas chromatographic detector

A planar high field asymmetric waveform ion mobility spectrometer (PFAIMS) with a micro-machined drift tube was characterized as a detector for capillary gas chromatography. The performance of the PFAIMS was compared directly to that of a flame ionization detector (FID) for the separation of a ketone mixture from butanone to decanone. Effluent from the column was continuously sampled by the detector and mobility scans could be obtained throughout the chromatographic analysis providing chemical inforrmation in mobility scans orthogonal to retention time. Limits of detection were approximately I ng for measurement of positive ions and were comparable or slightly better than those for the FID. Direct comparison of calibration curves for the FAIMS and the FID was possible over four orders of magnitude with a semi-log plot. The concentration dependence of the PFAIMS mobility scans showed the dependence between ion intensity and ion clustering, evident in other mobility spectrometers and atmospheric pressure ionization technologies. Ions were identified using mass spectrometry as the protonated monomer and the proton bound dimer of the ketones. Residence time for column effluent in the PFAIMS was calculated as approximately 1 ms and a 36% increase in extra-column broadening versus the FID occurred with the PFAIMS.

NASA Discipline Life Sciences Technologies↗

NASA NTRS1990

Spacecraft observations of the interaction of active comets with the solar wind

Six spacecraft encountered two comets during 1985 and 1986, obtaining a wealth of data relative to the plasma processes at work in the interaction of an active comet with the solar wind. A review of what space plasma scientists have learned from these data and of their interpretations is presented. The interaction process begins millions of kilometers from the nucleus where the solar wind first picks up cometary ions that slow down the wind and causes the interplanetary magnetic field to pile up and drape around the comet's ionosphere. Thus the geometry of a comet's plasma tail is defined by this draped field. At Halley the Giotto spacecraft noted a well-defined boundary separating the mixture of solar wind and cometary plasmas and the interplanetary magnetic field from the free-field, almost pure cometary plasma in the inner coma. Additional unexpected features in the inner coma were a flux of fast 'granddaughter' ions and high densities of negative ions. Further details covering pickup ions and plasma waves, mass loading, bow shock, energetic particles, the cometosheath, the ionopause, the plasma tail, and the field-free region are provided.

Neugebauer, M.↗