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At least 433 records · Page 24

Argon hydrochloride, Ar.HCl, bond energy by infrared spectroscopy

The infrared absorption of argon (200 to 760 torr) and hydrogen chloride (2 to 6 torr) mixtures is reexamined in the missing Q branch region (spectral region between 2860 and 3010 wavelength/cm) at temperatures ranging from 195 to 298 K. The temperature dependence of two absorption features of the argon hydrogen chloride complex, at 2887 and 2879 wavelength/cm, leads to a bond energy estimate that depends on the assumptions made about the internal degrees of freedom of the complex. It is shown that agreement with experiment can be reached for well depths near 1.2 kcal/mole. This result is relatively insensitive to the choice of the vibrational frequencies and anharmonicities, but does depend on the extent to which the energy level manifolds are truncated to avoid molecular excitation in excess of the bond energy. The bond energy is found to deviate from the commonly accepted value of 0.4 kcal/mole. Possible causes for the discrepancy are considered.

Miziolek, A. W.↗

Effects of high-energy neutrino production and interactions on stars in close X-ray binaries

Limits are discussed that may be placed on binary systems in which a compact partner is a strong source of high-energy particles that produce photons, neutrinos, and other secondary particles in the companion star. The highest energy neutrinos are absorbed deep in the companion and the associated energy deposition may be large enough to affect its structure or lead to its ultimate disruption. This neutrino heating is evaluated, starting with a detailed numerical calculation of the hadronic cascade induced in the atmosphere of the companion star. For some theoretical models, the resulting energy deposition from neutrino absorption may be so great as to disrupt the companion star over a time scale of 10,000-100,000 yr. Even if the energy deposition is smaller, it may still be high enough to alter the system substantially.

Gaisser, T. K.↗

Models of space averaged energetics of plates

The analysis of high frequency vibrations in plates is of particular interest in the study of structure borne noise in aircrafts. The current methods of analysis are either too expensive (finite element method) or may have a confidence band wider than desirable (Statistical Energy Analysis). An alternative technique to model the space and time averaged response of structural acoustics problems with enough detail to include all significant mechanisms of energy generation, transmission, and absorption is highly desirable. The focus of this paper is the development of a set of equations which govern the space and time averaged energy density in plates. To solve this equation, a new type of boundary value problem must be treated in terms of energy density variables using energy and intensity boundary conditions. A computer simulation verification study of the energy governing equation is performed. A finite element formulation of the new equations is also implemented and several test cases are analyzed and compared to analytical solutions.

Bouthier, O. M.↗

Studies of BL Lacertae objects with the Einstein Observatory - The soft X-ray spectra of OJ 287 and PKS 0735+178

Accurate, soft X-ray spectra of two BL Lac objects, OJ 287 and PKS 0735+178, are presented. The X-ray spectra are well described by a power-law model with a low-energy cutoff consistent with photoelectric absorption within the Galaxy. The best-fit values of the energy spectral index in the 0.2-4.0 keV band are 0.91 and 0.76 respectively. The X-ray flux from OJ 287 is variable by a ratio of three from low to high state; PKS 0735+178 shows no indication of X-ray variability. The X-ray emission in OJ 287 is interpreted to be due to the synchrotron process from a volume common with either a beamed radio component or a stationary optical component. In PKS 0735+178, where the X-ray emission is most likely due to the Compton process operating in one of the VLBI radio components. The synchrotron self-Compton process with modest kinematic Doppler factors predicts the measured X-ray flux from PKS 0735+178 and lower than the measured flux in OJ 287.

Madejski, Greg M.↗

FE K EMISSION AND ABSORPTION FEATURES IN THE XMM-EPIC SPECTRUM OF THE SEYFERT GALAXY IC 4329A

We present a re-analysis of the XMM-Newton long-look of the X-ray bright Seyfert galaxy IC 4329a. The Fe K bandpass is dominated by two peaks, consistent with emission from neutral or near-neutral Fe Ka and KP. A relativistic diskline model whereby both peaks are the result of one doubly-peaked diskline profile is found to be a poor description of the data. Models using two relativistic disklines are found to describe the emission profile well. A low-inclination, moderately-relativistic dual-diskline model is possible if the contribution from narrow components, due to distant material, is small or absent. A high-inclination, moderately relativistic profile for each peak is possible if there are roughly equal contributions from both the broad and narrow components. Upper limits on Fe XXV and Fe XXVI emission and absorption at the systemic velocity of IC 4329a are obtained. We also present the results of RXTE monitoring of this source obtained so far; the combined XMM-Newton and RXTE data sets allow us to explore the time-resolved spectral behavior of this source on time scales ranging from hours to 2 years. We find no strong evidence for variability of the Fe Ka emission line on any time scale probed, likely due to the minimal level of continuum variability. We detect a narrow absorption line, at a energy of 7.68 keV in the rest frame of the source; its significance has been confirmed using Monte Carlo simulations. This feature is most likely due to absorption from Fe XXVI blueshifted to approximately 0.1c relative to the systemic velocity, making IC 4329a the lowest-redshift AGN known with a high-velocity, highly-ionized outflow component. As is often the case with similar outflows seen in high-luminosity quasars, the estimated mass outflow rate is larger than the inflow accretion rate, signaling that the outflow represents a substantial portion of the total energy budget of the AGN. The outflow could arise from a radiatively-driven disk wind, or it may be in the form of a discrete, transient blob of ejected material.

Markowitz, A.↗

Optical properties of epitaxial CoSi2 and NiSi2 films on silicon

The optical constants of epitaxial films of CoSi2 and NiSi2, grown by molecular beam epitaxy on Si(111), in the energy range of 0.9-4.0 eV have been measured. The behavior of the optical constants is characteristic of metals. It is Drude-like in low energy region and deviates from Drude behavior as interband transitions set in. Interband transitions are found to have already set in at 1 eV. The absorption varies significantly with energy, which has implications for photoresponse studies of internal photoemission in these material systems.

Jimenez, J. R.↗

An Einstein survey of the 1 keV soft X-ray background in the Galactic plane

We have analyzed 56 Einstein Observatory Imaging Proportional Counter (IPC) observations within +/- 3 deg of the Galactic plane in order to determine the low-latitude soft X-ray background flux in the 0.56-1.73 keV band. Any detected X-ray point source which fell within our regions of study was removed from the image, enabling us to present maps of the background flux as a function of Galactic latitude along 18 meridians. These maps reveal considerable structure to the background in the Galactic plane on an angular scale of approximately 1 deg. Our results are compared with those of an earlier study of the 1 keV X-ray background along l = 25 deg by Kahn & Caillault. The double-peaked structure they found is not discernible in our results, possibly because of the presence of solar backscattered flux in their data. A model which takes into account contributions to the background by extragalactic and stellar sources, the distribution of both atomic and molecular absorbing material with the Galaxy, the energy dependence of the cross section for absorption of X-rays, and the energy dependence of the detector has been constructed and fitted to these new data to derive constraints on the scale height, temperature, and volume emissivity of the unaccounted-for X-ray-emitting material. The results of this model along l = 25 deg are roughly similar to those of the model of Kahn & Caillault along the same meridian.

Stanford, John M.↗

Intergalactic Photon Spectra from the Far-IR to the UV Lyman Limit for 0 < z < 6 and the Optical Depth of the Universe to High-Energy Gamma Rays

We calculate the intergalactic photon density as a function of both energy and redshift for 0<z<6 for photon energies from.003 eV to the Lyman limit cutoff at 13.6 eV in a (Omega)CDM universe with (Omega)(Lambda)=0.7 and (Omega)m=0.3. The basic features of our backward-evolution model for galaxies were developed in earlier papers by Malkan & Stecker. With a few improvements, we find that this evolutionary model gives predictions of new deep number counts from Spitzer, as well as a calculation of the spectral energy distribution of the diffuse infrared background, which are in good agreement with the data. We then use our calculated intergalactic photon densities to extend previous work on the absorption of high-energy Gamma-rays in intergalactic space owing to interactions with low-energy photons and the 2.7 K cosmic microwave background radiation. We calculate the optical depth of the universe, Tau , for Gamma-rays having energies from 4 GeV to 100 TeV emitted by sources at redshifts from 0 to 5. We also give an analytic fit with numerical coefficients for approximating (E(Gamma), z). As an example of the application of our results, we calculate the absorbed spectrum of the blazar PKS 2155-304 at z=0.117 and compare it with the spectrum observed by the HESS air Cerenkov Gamma-ray telescope array.

Stecker, F. W.↗

Determining the composition of olivine on asteroidal surfaces

Olivine was remotely identified as a major component on many S- and A-type asteroids based on qualitative analyses of broad absorption features near 1.0 micron in their telescopic reflectance spectra. Laboratory studies showed that this diagnostic olivine absorption feature is composed of three individual absorption bands resulting from electronic transitions of Fe(+2) in distorted M1 and M2 sites. Both the overall absorption feature and each of the individual absorption bands are also known to vary systematically as a function of olivine composition. Thus, it should be possible to remotely determine the composition of olivine present on the surfaces of the various olivine-rich asteroids. However, extrapolation of laboratory studies to compositional interpretation of asteroid spectra is complicated by several factors: observational noise; lower spectral resolution; compositional heterogeneities (including the presence of other phases such as pyroxenes and/or metal); and the effects of alteration processes. In order to address such complex problems, a quantitative approach to spectral analysis, the modified Gaussian model (MGM) was developed by Sunshine et al., which deconvolves spectra into their constituent absorption bands. The MGM, a refinement of the Gaussian model, more accurately adheres to the physical processes involved in electronic transition absorptions. Under the MGM, each spectrum is modeled in log reflectance and energy as a sum of absorption bands superimposed onto a baseline or continuum. Each absorption band is described by three model parameters (center, width, and strength) which can be interpreted and used to infer composition. One of the strengths of the MGM is that it allows compositional information to be extracted directly from measured spectra and is therefore complementary to other approaches to modeling asteroid spectra which require the use of meteorites and/or terrestrial samples as spectral analogs. A quantitative understanding of the properties of olivine absorptions was established by using the MGM to analyze a laboratory suite of spectra spanning a full range of olivine compositions.

Sunshine, Jessica M.↗

A unified theory of stable auroral red arc formation at the plasmapause

A theory is proposed that SAR-arcs are generated at the plasmapause as a consequence of the turbulent dissipation of ring current energy. During the recovery phase of a geomagnetic storm, the plasmapause expands outward into the symmetric ring current. When the cold plasma densities reach about 100/cu cm, ring current protons become unstable and generate intense ion cyclotron wave turbulence in a narrow region 1/2 earth radius wide (just inside the plasmapause). Approximately one-half of the ring current energy is dissipated into wave turbulence which in turn is absorbed through a Landau resonant interaction with plasma spheric electrons. The combined thermal heat flux to the ionosphere due to Landau absorption of the wave energy and proton-electron Coulomb dissipation is sufficient to drive SAR-arcs at the observed intensities. It is predicted that the arcs should be localized to a narrow latitudinal range just within the stormtime plasmapause. They should occur at all local times and persist for the 10 to 20 hour duration of the plasma-pause expansion.

Cornwall, J. M.↗

The ultimate efficiency of photosensitive systems

These systems have in common two important but not independent features: they can produce a storable fuel, and they are sensitive only to radiant energy with a characteristic absorption spectrum. General analyses of the conversion efficiencies were made using the operational characteristics of each particular system. An efficiency analysis of a generalized system consisting of a blackbody source, a radiant energy converter having a threshold energy and operating temperature, and a reservoir is reported. This analysis is based upon the first and second laws of thermodynamics, and leads to a determination of the limiting or ultimate efficiency for an energy conversion system having a characteristic threshold.

Buoncristiani, A. M.↗

Eta Carinae and the 2003.5 Minimum: Ultraviolet Changes of the Central Source and the Very Nearby Ejecta

We utilized the high spatial and high spectral resolution of the HST/STIS MAMA echelle modes in the ultraviolet (0.025 sec spatial resolution and 30,000 to 120,000 spectral resolving power) to view changes in and around Eta Carinae before and after the X-Ray drop which occurred on June 29, 2003. Major changes in the spectra of the Central Source and nearby nebulosities occurred between June 22 and July 5. Visibility of the Central Source dropped, especially between 1175 and 1350 A, but not uniformly through the UV. This fading is likely due to multiple line absorptions both in the source and in the intervening ejecta. Nebular emission of Si III and Fe III, located 0.09 sec to the west, disappeared. By July 29, a bright feature extending up to 0.07 sec east of the Central Source became prominent in broad emission lines near 2500 A, but was not noticeable longward of 2900 A. ACS/HRC imagery and STIS CCD spectra taken concurrently are being examined for larger scale changes. Numerous narrow velocity components between -146 and -585 km/s were identified in spectra before the minimum. New components appeared primarily in Fe II absorption lines with velocities between -170 and -380 km/s. While the lines of the -513 km/s component did not change, most lines of the -146 km/s component changed considerably. Lines originating from high energy levels diminished or disappeared, while lines originating from lower energy levels strengthened. Strong absorption lines of Ti II, not present before the X-Ray drop, appeared within seven days, but disappeared by July 29. Further analysis of these unprecedented data will provide significant new information about the structure of Eta Carinae and its periodic variations.

Gull, T. R.↗

Near-infrared absorption spectra of (O-16)3 and (O-18)3 - Adiabatic energy of the 1A2 state?

The band positions and isotope shifts for the weak vibronic bands of O3 near 1 micron are determined experimentally using a low-resolution dual-beam absorption spectrometer with a 0.2-m holographic-grating monochromator and identical absorption chambers of volume about 600 cu cm and optical path length 46 cm. The experimental setup and procedures and the signal-processing methods applied are described, and the results are presented in tables and graphs. It is found that the adiabatic energy of the 1A2 state lies 9990 + or - 70/cm (1.24 + or - 0.01 eV) above the electronic ground state, close to the O + O2 dissociation limit. The applicability of the present results to studies of O3 in the upper atmosphere is indicated.

Anderson, S. M.↗

Ultraviolet Changes of the Central Source and the Very Nearby Ejecta

We utilized the high spatial and high spectral resolution of the HST/STIS MAMA echelle modes in the ultraviolet (0.025 inch spatial resolution and 30,000 to 120,000 spectral resolving power) to view changes in and around Eta Carinae before and after the X-Ray drop which occurred on June 29, 2003 (M. Corcoran, IAUC 8160). Major changes in the spectra of the Central Source and nearby nebulosities occurred between June 22 and July 5. Visibility of the Central Source dropped, especially between 1175 and 1350 Angstroms, but not uniformly throughout the ultraviolet. This fading is likely due to multiple line absorptions both in the source and in the intervening ejecta. Nebular emission of Si III] and Fe III, located 0.09 sec. to the west, disappeared. By July 29, a bright feature extending up to 0.071 sec. east of the Central Source became prominent in broad emission lines near 2500 Angstroms, but was not noticeable longward of 2900 Angstroms. ACS/HRC imagery and STIS CCD spectra taken concurrently are being examined for larger scale changes. Numerous narrow velocity components between -146 and -585 kilometers per second were identified in spectra before the minimum. New components appeared primarily in Fe II absorption lines with velocities between -170 and -380 kilometers per second. While the lines of the -513 kilometers per second component did not change, most lines of the -146 kilometers per second component changed considerably. Lines originating from high energy levels diminished or disappeared, while lines originating from lower energy levels strengthened. Strong absorption lines of Ti II, not present before the X-Ray drop, appeared within seven days, but disappeared by July 29. Further analysis of these unprecedented data will provide significant new information about the structure of Eta Carinae and its periodic variations.

Gull, Theodore R.↗