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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS2020

Mock Catalogs for the Extragalactic X-ray Sky: Simulating AGN Surveys with ATHENA and with the AXIS Probe

We present a series of new, publicly available mock catalogs of X-ray selected active galactic nuclei (AGNs), nonactive galaxies, and clusters of galaxies. These mocks are based on up-to-date observational results on the demographic of extragalactic X-ray sources and their extrapolations. They reach fluxes below 10-20 erg cm-2 s-1 in the 0.5–2 keV band, that is, more than an order of magnitude below the predicted limits of future deep fields, and they therefore represent an important tool for simulating extragalactic X-ray surveys with both current and future telescopes. We used our mocks to perform a set of end-to-end simulations of X-ray surveys with the forthcoming ATHENA mission and with the AXIS probe, a subarcsecond resolution X-ray mission concept proposed to the Astro 2020 Decadal Survey. We find that these proposed, next generation surveys may transform our knowledge of the deep X-ray Universe. As an example, in a total observing time of 15 Ms, AXIS would detect ~225 000 AGNs and ~50 000 nonactive galaxies, reaching a flux limit of f0:5-2 ~ 5 x 10-19 erg cm-2 s-1 in the 0.5–2 keV band, with an improvement of over an order of magnitude with respect to surveys with current X-ray facilities. Consequently, 90% of these sources would be detected for the first time in the X-rays. Furthermore, we show that deep and wide X-ray surveys with instruments such as AXIS and ATHENA are expected to detect ~20 000 z > 3 AGNs and ~250 sources at redshift z > 6, thus opening a new window of knowledge on the evolution of AGNs over cosmic time and putting strong constraints on the predictions of theoretical models of black hole seed accretion in the early universe.

X-ray galaxies↗
NASA NTRS1984

The Shuttle Remote Manipulator System and its use in orbital operations

It is pointed out that the Shuttle Remote Manipulator System (RMS) is a key element in the Space Transportation System's ability to deploy, retrieve, and handle payloads in space. In addition, the RMS has the capability of performing other critical tasks such as inspection, construction, and satellite servicing. The present investigation is concerned with various end of arm tool concepts which could augment the RMS's capability enabling it to perform functions such as pushing/holding (applying pressure), prying, clamping (nonimpulse release) and shearing. Attention is also given to a tool for satellite servicing, a method for augmenting the operator's 'feel' for the job by force/moment sensing, and a possible four phase program for implementation of the tool system. A description is given of the key elements of RMS flight testing carried out to date.

Sachdev, S. S.↗
NASA NTRS2001

Planetary Accretion, Oxygen Isotopes and the Central Limit Theorem

The accumulation of presolar dust into increasingly larger aggregates (CAIs and Chondrules, Asteroids, Planets) should result in a very drastic reduction in the numerical spread in oxygen isotopic composition between bodies of similar size, in accord with the Central Limit Theorem. Observed variations in oxygen isotopic composition are many orders of magnitude larger than would be predicted by a simple, random accumulation model that begins in a well-mixed nebula - no matter which size-scale objects are used as the beginning or end points of the calculation. This discrepancy implies either that some as yet unspecified process acted on the solids in the Solar Nebula to increase the spread in oxygen isotopic composition during each and every stage of accumulation or that the nebula was heterogeneous and maintained this heterogeneity throughout most of nebular history. Large-scale nebular heterogeneity would have significant consequences for many areas of cosmochemistry, including the application of some well-known isotopic systems to the dating of nebular events or the prediction of bulk compositions of planetary bodies on the basis of a uniform cosmic abundance.

Nuth, Joseph A., III↗
NASA NTRS2018

In-Flight Operation of the Dawn Ion Propulsion System Through Completion of the Final Orbit Around Dwarf Planet Ceres

The Dawn mission, part of NASA’s Discovery Program, has as its goal the scientific exploration of the two most massive main-belt objects, Vesta and Ceres. The Dawn spacecraft was launched from the Cape Canaveral Air Force Station on September 27, 2007 on a Delta-II 7925H- 9.5 (Delta-II Heavy) rocket that placed the 1218-kg spacecraft onto an Earth-escape trajectory. On-board the spacecraft is an ion propulsion system (IPS) developed at the Jet Propulsion Laboratory for the heliocentric transfer to Vesta, orbit capture at Vesta, transfer between Vesta science orbits, departure and escape from Vesta, heliocentric transfer to Ceres, orbit capture at Ceres, transfer between Ceres science orbits, and orbit maintenance maneuvers. Full-power thrusting from December 2007 through October 2008 was used to successfully target a Mars gravity assist flyby in February 2009 that provided an additional DV of 2.6 km/s. Deterministic thrusting for the heliocentric transfer to Vesta resumed in June 2009 and concluded with orbit capture at Vesta on July 16, 2011. From July 2011 through September 2012 the IPS was used to transfer to all the different science orbits at Vesta and to escape from Vesta orbit. Cruise for a rendezvous with Ceres began in August 2012 and completed in late December 2014. From December 2014 through June 2016 the IPS was used for transiting the spacecraft to all science orbits at Ceres including the final orbit for Dawn’s primary mission, called the low altitude mapping orbit (LAMO), a circular orbit at a mean altitude above Ceres of approximately 385 km. Dawn met or exceeded all pre-launch science requirements and Dawn's prime mission concluded on June 30, 2016. Dawn subsequently received NASA approval for two extended missions at Ceres, called XM1 and XM2. During XM1 IPS was used for orbit maintenance and to transit the spacecraft to several new, higher-altitude science orbits, ending in an elliptical orbit at a maximum altitude of approximately 38,000 km. In XM2, IPS operations included transiting the Dawn spacecraft to its final, highly elliptical orbit at Ceres ranging from 35 km perigee to 4,800 km apogee. Science data acquisition will continue in XM2 until the hydrazine is exhausted, which is expected to occur between August and October 2018. Dawn has successfully completed all science goals for both the primary and XM1 extended missions. To date the IPS has been operated for approximately 51,250 hours, consumed approximately 416 kg of xenon, and provided a delta-V of almost 11.5 km/s, a record for an on-board propulsion system. The IPS performance characteristics are close to the expected performance based on analysis and testing performed pre-launch. Dawn’s IPS continues to be fully operational as of June 2018. This paper provides an overview of Dawn’s mission objectives and the results of Dawn IPS mission operations for XM1, and XM2 through June 2018.

Rayman, Marc D.↗
NASA NTRS1994

Eureka! Aerogel capture of meteoroids in space

Light gas gun studies have shown that 6 km/s solid mineral and glass test particles can be successively captured in 0.05 g cm(exp -3) aerogel without severe heating or fragmentation. In spite of this work, there has been uncertainty in the performance of aerogel for hypervelocity capture of real meteoroids. Natural impacts differ from simulations in that the particles are likely to be structurally weak and they typically impact at higher velocity that can be simulated in the laboratory. We are fortunate now to have had two successful capture experiments using aerogel exposed in space. These experiments provide fundamental data for the assessment of the value of silica aerogel for capture of hypervelocity meteoroids from spacecraft. The first experiment used 0.02 g cm(exp -3) aerogel flown on the lid of a Shuttle Get Away Special canister. During its 9 day exposure, the 0.165 m(exp 2) of aerogel in this Sample Return Experiment (SRE) captured two long 'carrot-shaped' tracks and one highly fractured bowl shaped 'crater'. The second collection was with 0.04 m(exp 2) of 0.05 g cm(exp -3) aerogel exposed on ESA's Eureca freeflying spacecraft that was exposed for 11 months before recovery by the Shuttle. The Eureca aerogel exposure consisted of four 10x10 cm module trays that were part of the TiCCE meteoroid collector built by the University of Kent at Canterbury. To date we have found ten 'carrot-shaped' tracks and two 'craters' on this experiment. The longest tracks in both exposures are over 2 mm long. Two of the TiCCE modules had a 0.1 micron Al film suspended a millimeter above the aerogel. On these modules several of the projectiles fragmented during passage through the film producing fields of carrot shaped tracks from the resulting miniature 'meteor' shower. Most of the tracks in these showers have observable particles at their ends. We have extracted one of the carrot track meteoroids and mounted it in epoxy for sectioning. So far the examination of these 14 impacts suggests that low density aerogel is a magic and highly effective media for intact capture of hypervelocity particles in space.

Brownlee, D. E.↗
NASA NTRS2012

Customizing NASA's Earth Science Research Products for addressing MENA Water Challenges

As projected by IPCC 2007 report, by the end of this century the Middle East North Mrica (MENA) region is projected to experience an increase of 3 C to 5 C rise in mean temperatures and a 20% decline in precipitation. This poses a serious problem for this geographic zone especially when majority of the hydrological consumption is for the agriculture sector and the remaining amount is for domestic consumption. In late 2011, the World Bank, USAID and NASA have joined hands to establishing integrated, modem, up to date NASA developed capabilities for various countries in the MENA region for addressing water resource issues and adapting to climate change impacts for improved decision making for societal benefits. The main focus of this undertaking is to address the most pressing societal issues which can be modeled and solved by utilizing NASA Earth Science remote sensing data products and hydrological models. The remote sensing data from space is one of the best ways to study such complex issues and further feed into the decision support systems. NASA's fleet of Earth Observing satellites offer a great vantage point from space to look at the globe and provide vital signs necessary to maintain healthy and sustainable ecosystem. NASA has over fifteen satellites and thirty instruments operating on these space borne platforms and generating over 2000 different science products on a daily basis. Some of these products are soil moisture, global precipitation, aerosols, cloud cover, normalized difference vegetation index, land cover/use, ocean altimetry, ocean salinity, sea surface winds, sea surface temperature, ozone and atmospheric gasses, ice and snow measurements, and many more. All of the data products, models and research results are distributed via the Internet freely through out the world. This project will utilize several NASA models such as global Land Data Assimilation System (LDAS) to generate hydrological states and fluxes in near real time. These LDAS products will then be further compared with other NASA satellite observations (MODIS, VIIRS, TRMM, etc.) and other discrete models to compare and optimize evapotranspiration, soil moisture and crop irrigation, drought assessment and water balance. The floods being a critical disaster in many of the MENA countries, NASA's global flood mapping and modeling framework (CREST) will be customized for country specific needs and delivered to the remote sensing organizations for their future use. Training is an important component under this activity and adequate level of training will be offered to build basic capacity to work with NASA provided data products, models for their future use. This paper provides a comprehensive introduction to NASA's Earth Science mission for understanding the behavior of our home Planet, projecting its health for future generations and applying research results solving societal issues.

Habib, Shahid↗
NASA NTRS1988

Macrofossil extinction patterns at Bay of Biscay Cretaceous-Tertiary boundary sections

Researchers examined several K-T boundary cores at Deep Sea Drilling Project (DSDP) core repositories to document biostratigraphic ranges of inoceramid shell fragments and prisms. As in land-based sections, prisms in the deep sea cores disappear well before the K-T boundary. Ammonites show a very different extinction pattern than do the inoceramids. A minimum of seven ammonite species have been collected from the last meter of Cretaceous strata in the Bay of Biscay basin. In three of the sections there is no marked drop in either species numbers or abundance prior to the K-T boundary Cretaceous strata; at the Zumaya section, however, both species richness and abundance drop in the last 20 m of the Cretaceous, with only a single ammonite specimen recovered to date from the uppermost 12 m of Cretaceous strata in this section. Researchers conclude that inoceramid bivalves and ammonites showed two different times and patterns of extinction, at least in the Bay of Biscay region. The inoceramids disappeared gradually during the Early Maestrichtian, and survived only into the earliest Late Maestrichtian. Ammonites, on the other hand, maintained relatively high species richness throughout the Maestrichtian, and then disappeared suddenly, either coincident with, or immediately before the microfossil extinction event marking the very end of the Cretaceous.

Ward, Peter D.↗
NASA NTRS2012

The Integration and Test Program of the James Webb Space Telescope

The James Webb Space Telescope (JWST) project has entered into a comprehensive integration and test (I&T) program that over the coming years will assemble the various elements of the observatory (the Optical Telescope Element [OTE], the Integrated Science Instrument Module [ISIM], and the Spacecraft) and verify the readiness of the integrated system for launch. The I&T program as replanned for a 2018 launch readiness date has a number of interesting features. These include a streamlined ISIM cryo-vacuum test program at Goddard Space Flight Center, a streamlined OTIS (OTE + ISIM) test program at Johnson Space Center (JSC), the addition of a second Core cryo-vacuum thermal test, the enhancement of the Pathfinder program at JSC, and enhancement of the subsystem-level testing program for the MIRI cryo-cooler. These latter activities all serve to reduce the risk heading into the end-to-end optical and thermal testing of the telescope at JSC, leading to reduced cost and schedule risk for that critical activity. We report here on the overall I&T program for JWST and on the status of the hardware and plans that support it.

Kimble, Randy↗
NASA NTRS2012

Avoiding Human Error in Mission Operations: Cassini Flight Experience

Operating spacecraft is a never-ending challenge and the risk of human error is ever- present. Many missions have been significantly affected by human error on the part of ground controllers. The Cassini mission at Saturn has not been immune to human error, but Cassini operations engineers use tools and follow processes that find and correct most human errors before they reach the spacecraft. What is needed are skilled engineers with good technical knowledge, good interpersonal communications, quality ground software, regular peer reviews, up-to-date procedures, as well as careful attention to detail and the discipline to test and verify all commands that will be sent to the spacecraft. Two areas of special concern are changes to flight software and response to in-flight anomalies. The Cassini team has a lot of practical experience in all these areas and they have found that well-trained engineers with good tools who follow clear procedures can catch most errors before they get into command sequences to be sent to the spacecraft. Finally, having a robust and fault-tolerant spacecraft that allows ground controllers excellent visibility of its condition is the most important way to ensure human error does not compromise the mission.

guidance and control↗
DOE OSTI2021

Wyoming CarbonSAFE: Advancing Commercialization of Low-Carbon Energy Technologies in Fossil-Rich Wyoming

Wyoming’s Powder River Basin (PRB) is the most prolific coal producer and exporter in the United States and the State of Wyoming’s largest oil-producing basin. In addition to being a leading energy producer, the PRB is the site of research programs whose aim is to develop and integrate low-carbon technologies into existing fossil fuel energy industries. Much of the PRB’s low-carbon research is focused around Dry Fork Station (DFS), which is the newest coal-fired power station in the western US. Currently, DFS hosts five carbon capture projects, including pilot-scale capture projects that utilize different capture technologies and a full front-end engineering and design (FEED) study, a commercial CO 2 pipeline for nearby CO 2 -enhanced oil recovery industry, and is also co-located with the Wyoming Integrated Test Center, which is a host facility for unconventional carbon utilization research (i.e. flue gas carbon-to-products innovations). DFS is also the host site for the Wyoming CarbonSAFE project. Wyoming CarbonSAFE, funded by the Department of Energy/National Energy Technology Laboratory, is a multi-phased program (currently in Phase II) whose core objective is developing and validating storage sites within a complex capable of storing 50 million metric tonnes of CO 2 over a 30 year project period using carbon capture, utilization and storage (CCUS). This paper will provide an overview of the project to-date, showing that CarbonSAFE goals are achievable with respect to geologic, environmental, regulatory, CO 2 source and economic conditions, and why the State of Wyoming offers one of the more favorable environments to advance the commercialization studies. In 2019, the project team designed and completed a ~10,000 foot stratigraphic test well just south of DFS. From this well, the team collected over 600 feet of core, fluid samples from target injection zones, and a full petrophysical log suite. In addition, legacy 2D seismic lines were acquired and a 3D seismic survey was acquired in the fall of 2020. The objective of these field activities has been to identify and characterize target storage reservoirs and associated caprock. This complex has several reservoirs that could meet commercial injection goals, and over 4000 feet of associated caprock. Simulations of site performance suggest that stacked injection provides the most effective storage strategy, and would necessitate several sites within the greater complex to meet final project injection goals. Other work within this project includes the development of a business-case around proximal fields with CO 2 -enhanced oil recovery potential and existing tax credits, assessment of regulatory conditions, including pore space ownership and Class VI injection well permitting requirements, implementation of a robust public outreach Electronic copy available at: https://ssrn.com/abstract=3821220 GHGT-15 McLaughlin 2 program, and surface site characterization activities that have focused on environmental factors. In the PRB and at DFS, the State of Wyoming and other entities have made carbon management a priority of its future energy industry by providing a regulatory and business framework that is favorable to advancing these technologies. These endeavors will become more realistic with the successful implementation of Wyoming CarbonSAFE, and its ability to secure and validate commercial-scale CCUS at the center of Wyoming’s premier low-carbon research efforts.

McLaughlin, Fred↗
DOE OSTI2020

Employing Molecular Phylodynamic Methods to Identify and Forecast HIV Transmission Clusters in Public Health Settings: A Qualitative Study

Molecular HIV surveillance is a promising public health strategy for curbing the HIV epidemic. Clustering technologies used by health departments to date are limited in their ability to infer/forecast cluster growth trajectories. Resolution of the spatiotemporal dynamics of clusters, through phylodynamic and phylogeographic modelling, is one potential strategy to develop a forecasting tool; however, the projected utility of this approach needs assessment. Prior to incorporating novel phylodynamic-based molecular surveillance tools, we sought to identify possible issues related to their feasibility, acceptability, interpretation, and utility. Qualitative data were collected via focus groups among field experts (n = 17, 52.9% female) using semi-structured, open-ended questions. Data were coded using an iterative process, first through the development of provisional themes and subthemes, followed by independent line-by-line coding by two coders. Most participants routinely used molecular methods for HIV surveillance. All agreed that linking molecular sequences to epidemiological data is important for improving HIV surveillance. We found that, in addition to methodological challenges, a variety of implementation barriers are expected in relation to the uptake of phylodynamic methods for HIV surveillance. The participants identified several opportunities to enhance current methods, as well as increase the usability and utility of promising works-in-progress.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1991

Guideline requirements for serviceable spacecraft grasping/berthing/docking interfaces based on simulations and flight experience (survey paper)

As space vehicles and structures become larger and more complex, the development of systems to assist humans in assembling, operating, maintaining, and performing space rescue or retrieval of these vehicles and structures becomes increasingly important. With the diversity of international spacecraft, both manned and unmanned, planned to be in orbit in the future, a set of guidelines for berthing and docking subsystems is mandatory if servicing, resupply, and retrieval is to become practical on an international level. Successful interaction between these space systems and ground and/or space-based humans requires standardized and effective operational interface designs, particularly with respect to space grasping/berthing/docking interface mechanisms. This paper defines the spacecraft mechanical interfaces necessary to create a standard dynamic envelope for joining two free-flying spacecraft in a 'hard' berth or dock with each other in space. A review was made of past space flights and dynamics simulations dating back to 1962 to obtain necessary parameters and their values for successful manually controlled and autonomous spacecraft docking/berthing. The various spacecraft docking/berthing mechanisms and concepts are illustrated along with their dynamic capture and impact tolerances including maximum contact velocity along the approach axis and in the y-z plane; capture linear misalignment tolerances; and maximum capture roll, pitch, and yaw angles. From this data sets of recommended guidelines parameters were developed for autonomous and manual impact docking tolerances, non-impact grasping/berthing tolerances (end effectors), berthing contact conditions, and alignment tolerances after rigidizing. Also, detailed requirements were developed for mechanical design interface features, as well as latching, unlatching, and separation tolerances. This data was drafted in the form of a proposed ANSI Standard guideline, reviewed, and added to by members of the committee representing several spacecraft manufacturers, NASA, and the USAF, and a consensus was reached.

Thompson, Allen B.↗
DOE OSTI2021

A Circular Economy for Lithium-Ion Batteries Used in Mobile and Stationary Energy Storage: Drivers, Barriers, Enablers, and U.S. Policy Considerations

As large-format battery energy storage (BES) capacity increases in the United States, so will the volume of spent lithium-ion batteries (LiBs) (Bade 2019). Estimates based on a 10-year lifetime assumption found that the volume of LiBs that have reached the end of their utility for electric vehicle (EV) applications could total two million units (four million metric tons) annually by 2040 in the United States (Richa et al. 2014; Ai and Borucki 2018). Although there is currently no publicly available decommissioning or end-of-life (EoL) projection for stationary BES systems, the U.S. energy storage market is expected to grow from an annual deployment of 523 megawatts in 2013 to 7.3 gigawatts in 2025 (Wood MacKenzie and ESA 2020; Wesoff 2020). Despite potential secondary market opportunities and the potential benefits associated with the reuse/recovery of LiB material, anecdotal evidence suggests that in the United States most decommissioned LiBs from EVs are landfilled or otherwise disposed of (Steward et al. 2019; Salim et al. 2019; CPUC 2019; DTSC 2019d; NREL 2019b; Jacoby 2019; DOE 2019). The reuse of large-format LiBs is not at commercial scale and to date consists of only a handful of U.S.-led pilot projects. Similarly, less than 5% of LiBs from EVs are sent to recycling facilities in the United States (Steward et al. 2019; Jacoby 2019; America Made 2019; Patel 2017). As awareness of current practices grows, and the demand for critical LiB materials increases, U.S. industry stakeholders, regulators, and policymakers are starting to (1) consider solutions to drive and enable environmentally sustainable materials management decisions and behaviors and (2) identify barriers to a circular economy for LiBs (Figure 1). Circular economy principles (Figure 1) attempt to transition from a “take-make-consume-dispose” linear economic system to a circular system that allows for the long life, high performance, and the reuse/recovery of products and materials (Ellen MacArthur Foundation 2016). We begin this report by summarizing drivers, barriers, and enablers to a circular economy for LiBs used in mobile and stationary BES systems in the United States. We then report on our analysis of federal and state regulatory considerations that may impact the reuse/recovery and disposal of LiBs, and potential civil and criminal liabilities associated with noncompliance. We conclude by highlighting state policies and initiatives in the United States that expressly address reuse/recovery and disposal of large-format LiBs. Our results are based on legal and literature-based research and interviews with mobile and stationary BES industry stakeholders, regulators, and policymakers. While this report addresses stationary BES, as well as mobile BES, much of the information and experience with LiB decommissioning and EoL material management is derived from the increasing management of spent EV LiBs in the United States.

25 ENERGY STORAGE↗
DOE OSTI2024

Real-time breath analysis towards a healthy human breath profile

Abstract The direct analysis of molecules contained within human breath has had significant implications for clinical and diagnostic applications in recent decades. However, attempts to compare one study to another or to reproduce previous work are hampered by: variability between sampling methodologies, human phenotypic variability, complex interactions between compounds within breath, and confounding signals from comorbidities. Towards this end, we have endeavored to create an averaged healthy human ‘profile’ against which follow-on studies might be compared. Through the use of direct secondary electrospray ionization combined with a high-resolution mass spectrometry and in-house bioinformatics pipeline, we seek to curate an average healthy human profile for breath and use this model to distinguish differences inter- and intra-day for human volunteers. Breath samples were significantly different in PERMANOVA analysis and ANOSIM analysis based on Time of Day, Participant ID, Date of Sample, Sex of Participant, and Age of Participant ( p < 0.001). Optimal binning analysis identify strong associations between specific features and variables. These include 227 breath features identified as unique identifiers for 28 of the 31 participants. Four signals were identified to be strongly associated with female participants and one with male participants. A total of 37 signals were identified to be strongly associated with the time-of-day samples were taken. Threshold indicator taxa analysis indicated a shift in significant breath features across the age gradient of participants with peak disruption of breath metabolites occurring at around age 32. Forty-eight features were identified after filtering from which a healthy human breath profile for all participants was created.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2022

π-Extension and chlorination of non-fullerene acceptors enable more readily processable and sustainable high-performance organic solar cells

Organic solar cells (OSCs) processed without halogenated solvents and complex treatments are essential for future commercialization. Herein, we report three novel small molecule acceptors (NFAs) consisting of a Y6-like core but with π-extended naphthalene with progressively more chlorinated end-capping groups and a longer branched chain on the Nitrogen atom. These NFAs exhibit good solubilities in non-chlorinated organic solvents, broad optical absorptions, close π-π stacking distances (3.63–3.84 Å), and high electron mobilities (~10 -3 cm 2 V -1 s -1 ). Further, the o-xylene processed and as-cast binary devices using PM6 as the donor polymer exhibit a PCE increasing upon progressive chlorination of the naphthalene end-capping group from 8.93% for YN to 14.38% for YN-Cl to 15.00% for YN-2Cl. Furthermore similarly processed ternary OSCs were fabricated by employing YN-Cl and YN-2Cl as the third component of PM6:CH1007 blends (PCE = 15.75%). Compared to all binary devices, the ternary PM6:CH1007:YN-Cl (1:1:0.2) and PM6:CH1007:YN-2Cl (1:1:0.2) cells exhibit significantly improved PCEs of 16.49% and 15.88%, respectively, which are among the highest values reported to date for non-halogenated solvent processed OSCs without using any additives and blend post-deposition treatments.

14 SOLAR ENERGY↗
DOE OSTI2020

Patchy particle model of hydrated amorphous silica

Glasses corroded in static aqueous conditions typically reach a slow, residual rate of dissolution as a result of the complex interplay between multiple processes. While intrinsically suited to address this problem, Monte Carlo (MC) models developed to date have relied on lattices to describe the amorphous structure of glass and are thus unable to reproduce the residual rate of glass corrosion. A recently developed MC approach based on amorphous structures derived from molecular dynamics simulations offers a solution [Kerisit and Du J. Non-Cryst. Solids 522 (2019) 119601], but it requires a simple model that can rapidly relax the glass-water interface upon each dissolution/condensation event to retain the ability of MC simulations to reach large spatial and temporal scales. To this end, a patchy particle model of hydrated amorphous silica was developed and evaluated against atomistic simulations in this work. Models of water and amorphous silica were first developed separately, and cross terms were then defined to enable simulations of hydrated amorphous silica structures with varying water content. While the nature of its interaction potential prevents the patchy particle model from reproducing simultaneously the structure and dynamics of the systems of interest with a single set of parameters, it described well the connectivity of hydrated amorphous silica structures and the local coordination geometry of individual species. Therefore, this model opens the door to MC simulations of the residual rate of glass corrosion and offers an alternative to atomistic models to investigate the evolution of silica gels over large spatial and temporal scales.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS2020

Model Design and Pre-Test CFD Analysis for a Supersonic Retropropulsion Wind Tunnel Test

Future Mars human lander missions will require using powered descent beginning at supersonic conditions, something which has never been done before at Mars. Significant aerosciences challenges exist due to interactions between the retrorocket exhaust plumes and the freestream flow that alter the aerodynamic behavior of the powered descent vehicle. Historically, wind tunnel tests have been used to study supersonic retropropulsion with inert gas exhaust simulants. Also, SpaceX has successfully decelerated the Falcon 9 first stage numerous times by using powered flight at supersonic conditions. On the computational side, Reynolds-Averaged Navier-Stokes flowfield simulations are regularly completed at full-scale conditions. However, the available ground and flight data do not provide a basis for calibrating the computational uncertainties for aerodynamic interference forces and moments on proposed Mars descent vehicles, either because of insufficient data or dissimilar vehicles geometries and/or conditions. Thus, additional ground testing is needed to continue addressing the aerosciences risks for large-scale human Mars landers. To that end, a retropropulsion wind tunnel test will be conducted in the NASA Langley Unitary Plan Wind Tunnel in 2020. The test is designed to improve upon similar past tests, both in terms of model design and measured data. The test campaign will use subscale model geometries derived from the two current NASA powered descent reference vehicles: a blunt low lift-to-drag vehicle and a more slender geometry. This paper covers the reference vehicles, test objectives, model design, scaling parameters, test matrix, and computational analysis to date.

Karl T Edquist↗
NASA NTRS2023

Closed Environment Air Revitalization System Based on Metal Organic Framework Adsorbents

This project utilized a systems engineering methodology to develop a vacuum swing adsorption system with full Labview automated control. The project was successful and provided students with an introduction to systems engineering and air revitalization. Specifically, two stainless steel adsorption beds were custom designed and manufactured and a sequence of computer controlled valves were used to deliver CO 2 laden, humid air, to the adsorbent where the CO 2 was removed from the air stream. Runs were completed using 13X zeolite and bed timing and switching was controlled by the computer based on the data output of a CO 2 detector. Adsorption runs using the MOF have not been completed upon the writing of this report; however, the MOF material is currently being synthesized and the runs will be completed upon receipt of the material. A follow up meeting with NASA has been tentatively planned to discuss the output of these experiments. Consistent with systems engineering practice, an end of project assessment of the class was conducted with the students and several items were realized. Specifically, the short period of performance of this grant makes it necessary to maintain a narrowly focused scope on the project such that multiple experiments after systems development (T&E) need to be limited to ensure timely completion of the proposed tasks. Also, procurement of parts may need to be moved forward in time to allow for delivery delays, and it may be necessary to request SDR, PDR, and CDR dates from NASA that are ahead of the NASA anticipated schedule. These types of lessons provided valuable to both the PI and the students and ultimately illustrate the necessity of proper systems engineering schedule risk assessment. The class met the objectives of the project and provided an introduction to systems engineering to undergraduate students. As a metric of that success, the lead engineer of the undergraduate design team acquired a job with an aerospace defense contractor, which he attributed to his knowledge of systems engineering concepts that were acquired via the X-Hab class.

T. Grant Glover↗