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At least 433 records · Page 24

Thermal environment effects on strength and impact properties of boron-aluminum composites

Thermal effects on fracture strength and impact energy were studied in 50 volume percent unidirectional composites of 143 and 203 micron boron fibers in 6061 and 1100 aluminum matrices. For 6061 matrix composites, strength was maintained to approximately 400 C in the cyclic tests and higher than 400 C in the static tests. For the 1100 matrix composites, strength degradation appeared near 260 C after cycling and higher than 260 C in static heating. This composite strength degradation is explained by a fiber degradation mechanism resulting from a boron-aluminum interface reaction. The impact energy absorption degraded significantly only above 400 C for both matrix alloys. Thus, while impact loss for the 6061 composite correlates with the fiber strength loss, other energy absorption processes appear to extend the impact resistance of the 1100 matrix composites to temperatures beyond where its strength is degraded. Interrupted impact tests on as-received and thermally cycled composites define the range of load over which the fibers break in the impact event.

Grimes, H. H.↗

Processing effects on the mechanical properties of tungsten heavy alloys

Tungsten heavy alloys exhibit significant mechanical property sensitivities to the fabrication variables. These sensitivities are illustrated in this examination of vacuum sintering and the effects of composition, sintering temperature, and sintering time on the mechanical properties of tungsten heavy alloys. Measurements were conducted to assess the density, strength, hardness, and elongation dependencies. A detrimental aspect of vacuum sintering is matrix phase evaporation, although vacuum sintering does eliminate the need for postsintering heat treatments.

Kishi, Toshihito↗

Convective Melting of Particles in Flow Under Microgravity Conditions

Study of melting of dispersed or packed solid particles in a fluid under gravity and microgravity conditions provides benchmark information for many engineering applications such as material processing, environmental assessment and protection and space fire protection. During such processes, packed or dispersed solid particles are interacting with fluid flow at above-melting temperatures. By unmasking the buoyancy effects in coupled flow, phase change and heat transport phenomena, a better understanding of melting rate in non-thermal equilibrium, convective conditions can be studied. A series of flight experiments were conducted onboard the NASA KC-135 Microgravity Research Airplane. The Particle Melting in Plow (PMF) module was designed to allow flow through the initially packed ice particles at controlled temperature and velocity. To achieve this, a close-loop flow system was designed. Video images were taken to record the visualization of the melting process, from which a time variation of packed particle thickness distribution at different times can be obtained by the image analysis method. The fluid temperature distribution within the melting zone is measured by thermocouples. An infrared camera was mounted from the top of the test section to record the ice-water thermal images at a given location. The results from thermal images yield local temperature variation between melting solid and liquid and local Stephan number. Typical results for a number of cases are presented. The mathematical model, describing mass, energy, and momentum balance equations for the liquid and solid phases, is presented. It is found that melting rate is influenced mainly by the ratio of Reynolds number (based on the initial particle diameter) to the Froud number, and Stephan number. At the absence of gravity, Froud number approaches zero, Reynolds number and Stephan number become dominant factors governing the melting rate. The numerically determined results are compared with the experimental ones. It is found that the discrepancy between the predicted and measured melting rate is largely due to the inaccuracy in the constitutive equations for effective thermal physical properties, such as effective thermal conductivity and diffusivity, and transport properties, such as particle interaction coefficient, and local heat transfer coefficient of particles.

Stewart, C.↗

Target Configuration Effect on Microstructures and Properties of Vertically Aligned Nanocomposites

Vertically aligned nanocomposites (VANs) are unique thin films with vertical nanostructures embedded in a matrix material, allowing for the integration of two distinct materials. These nanocomposites offer novel combined physical properties, such as nanocomposite-based multiferroics and strongly coupled physical properties, such as magneto-optic coupling. Much work has been conducted in exploring different two-phase combinations and various processing conditions to achieve novel tunable properties that cannot be obtained by any single-phase material alone. Here, in this work, the target configuration effects are explored for the growth of LaFeO 3 –CoNi 2 O 4 VANs. Both mixed and pie-shaped targets are utilized to compare the target configuration effects on the phase separation, morphology tuning, and their resulting physical properties, including optical and magnetic properties. This work suggests that the target configuration is another important parameter for achieving the desired VAN morphology and can be used to design different two-phase VANs with tailorable properties.

36 MATERIALS SCIENCE↗

Staggering Inflation To Stabilize Attitude of a Solar Sail

A document presents computational-simulation studies of a concept for stabilizing the attitude of a spacecraft during deployment of such structures as a solar sail or other structures supported by inflatable booms. Specifically, the solar sail considered in this paper is a square sail with inflatable booms and attitude control vanes at the corners. The sail inflates from its stowed configuration into a square sail with four segments and four vanes at the tips. Basically, the concept is one of controlling the rates of inflation of the booms to utilize in mass-distribution properties to effect changes in the system s angular momentum. More specifically, what was studied were the effects of staggering inflation of each boom by holding it at constant length for specified intervals between intervals of increasing length until full length is reached. The studies included sensitivity analyses of effects of variations in mass properties, boom lengths, rates of increase in boom length, initial rates of rotation of the spacecraft, and several asymmetries that could arise during deployment. The studies led to the conclusion that the final attitude of the spacecraft could be modified by varying the parameters of staggered inflation. Computational studies also showed that by feeding back attitude and attitude-rate measurements so that corrective action is taken during the deployment, the final attitude can be maintained very closely to the initial attitude, thus mitigating the attitude changes incurred during deployment and caused by modeling errors. Moreover, it was found that by optimizing the ratio between the holding and length-increasing intervals in deployment of a boom, one could cause deployment to track a desired deployment profile to place the entire spacecraft in a desired attitude at the end of deployment.

Quadrelli, Marco↗

Utilization of the Generalized Method of Cells to Analyze the Deformation Response of Laminated Ceramic Matrix Composites

In order to practically utilize ceramic matrix composites in aircraft engine components, robust analysis tools are required that can simulate the material response in a computationally efficient manner. The MAC/GMC software developed at NASA Glenn Research Center, based on the Generalized Method of Cells micromechanics method, has the potential to meet this need. Utilizing MAC/GMC, the effective stiffness properties, proportional limit stress and ultimate strength can be predicted based on the properties and response of the individual constituents. In this paper, the effective stiffness and strength properties for a representative laminated ceramic matrix composite with a large diameter fiber are predicted for a variety of fiber orientation angles and laminate orientations. As part of the analytical study, methods to determine the in-situ stiffness and strength properties of the constituents required to appropriately simulate the effective composite response are developed. The stiffness properties of the representative composite have been adequately predicted for all of the fiber orientations and laminate configurations examined in this study. The proportional limit stresses and strains and ultimate stresses and strains were predicted with varying levels of accuracy, depending on the laminate orientation. However, for the cases where the predictions did not have the desired level of accuracy, the specific issues related to the micromechanics theory were identified which could lead to difficulties that were encountered that could be addressed in future work.

Goldberg, Robert K.↗

Evaluating the effects of structural disorder on the magnetic properties of Nd 2 Zr 2 O 7

Motivated by the variation in reported lattice parameters of floating-zone-grown Nd 2 Zr 2 O 7 crystals, we have performed a detailed study of the relationship between synthesis environment, structural disorder, and magnetic properties. Using a combination of polycrystalline standards, electron-probe microanalysis, and scattering techniques, we show that crystals grown under atmospheric conditions have a reduced lattice parameter relative to pristine polycrystalline powders due to occupation of the Nd site by excess Zr (i.e., negative stuffing). In contrast, crystals grown under high-pressure Ar are nearly stoichiometric with an average lattice parameter approaching the polycrystalline value. While minimal disorder of the oxygen sublattices is observed on the scale of the average structure, neutron pair-distribution function analysis indicates a highly local disorder of the oxygen coordination, which is only weakly dependent on growth environment. Most importantly, our magnetization, heat capacity, and single-crystal neutron scattering data show that the magnetic properties of crystals grown under high-pressure Ar match closely with those of stoichiometric powders. Neutron scattering measurements reveal that the signature of magnetic moment fragmentation—the coexistence of all-in-all-out (AIAO) magnetic Bragg peaks and diffuse pinch-point scattering due to spin-ice correlations–persists in these nearly stoichiometric crystals. However, in addition to an increased AIAO transition temperature, the diffuse signal is seemingly stabilized and remains nearly unchanged upon warming to 800 mK. This behavior indicates that both the AIAO magnetic order and spin-ice correlations are sensitive to deviations of the Nd stoichiometry.

36 MATERIALS SCIENCE↗

Hot environment effects on alloy mechanical properties

Prolonged high temperature performance of structural alloys requires joint attention to both corrosion and mechanical properties, and to their possible interactions. In this interpretive review paper, we provide a systematic compaction of theories and key observations on corrosion-mechanical properties interactions, from early single crystal work in the 1930s to recent studies on superalloys in nonoxidizing, oxidizing and hot corrosive environments. Particular attention is paid to environmental effects on creep, stress rupture and fatigue properties.

Davidson, J. M.↗

Pretreatment effects on the morphology and properties of aluminum oxide thermally grown on NiCoCrAlY

The effect of pretreatments on the morphology and properties of aluminum oxide thermally grown from NiCoCrAlY was investigated. The goal was to optimize process steps to produce a highly adherent, continuous, and insulating aluminum oxide. Two pretreatments were carried out, one in vacuum (about 0.0001 Torr) at 1350 K for 5 h, and the other consisting of deposition of a 1-micron thick Al2O3 film by activated reactive evaporation. Samples were subsequently oxidized thermally at 1000 C for 50 h at 0.5 Torr oxygen pressure. The two pretreatments were carried out on electron-beam evaporation NiCoCrAlY, about 120 microns thick, deposited on a superalloy turbine blade substrate. The results showed that the thermally grown oxide was significantly different in microstructure, surface topography and in its adherence to the NiCoCrAlY for the two pretreatments. Optimum results were obtained by combining the two pretreatments to produce an adherent, continuous, and insulating oxide film on the NiCoCrAlY-coated superalloy substrate.

Prakash, S.↗

Local-Field Effects in Linear Response Properties within a Polarizable Frozen Density Embedding Method

In this work, we present a polarizable frozen density embedding (FDE) method for calculating polarizabilities of coupled subsystems. The method (FDE-pol) combines a FDE method with an explicit polarization model such that the expensive freeze/thaw cycles can be bypassed, and approximate nonadditive kinetic potentials are avoided by enforcing external orthogonality between the subsystems. To describe the polarization of the frozen environment, we introduce a Hirshfeld partition-based density-dependent method for calculating the atomic polarizabilities of atoms in molecules, which alleviates the need to fit the atomic parameters to a specific system of interest or to a larger general set of molecules. Further, we show that the Hirshfeld partition-based method predicts molecular polarizabilities close to the basis set limit, and thus, a single basis set-dependent scaling parameter can be introduced to improve the agreement against the reference polarizability data. To test the model, we characterized the uncoupled and coupled response of small interacting molecular complexes. Here, the coupled response properties include the perturbation of the frozen system due to the external perturbation which is ignored in the uncoupled response. We show that FDE-pol can accurately reproduce both the exact uncoupled polarizability and the coupled polarizabilities of the supermolecular systems. Using damped response theory, we also demonstrate that the coupled frequency-dependent polarizability can be described by including local field effects. The results emphasize the necessity of including local-field effects for describing the response properties of coupled subsystems, as well as the importance of accurate atomic polarizability models.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Effect of measured material properties on the finite element analysis of an OH-58 composite tail boom

A static and dynamic finite element analysis is conducted on a U.S. Army OH-58 composite tail boom and compared with test data. The tail boom is a filament-wound graphite/epoxy monocoque structure. The structural design of the composite tail boom skin is based on 50-percent graphite fiber volume. However, material tests on representative samples of the tail boom skin reveal that the graphite fiber-volume fraction varied from 44.6 to 49.3 percent. To determine the effect of using measured material properties, static and dynamic finite element analyses are conducted for three fiber-volume conditions of 45, 48, and 50 percent. The static and dynamic model with the 45-percent fiber-volume graphite skins gives the closest agreement with test data.

Bowman, L. M.↗

Effect of Al substitution on the magnetocaloric properties of Ni-Co-Mn-Sn multifunctional alloys

Ni-Mn-based metamagnetic shape memory alloys have been extensively studied due to their multifunctional properties including magnetocaloric effect (MCE), magnetoresistance effect, and magnetic-field-induced strain. However, the large intrinsic thermal hysteresis of these alloys sets a limit on further development for practical applications. Here, with a few atomic percent Al substitution, we greatly reduced the thermal hysteresis and transformation temperature interval while maintaining the large magnetization difference (ΔM) between austenite and martensite. The simultaneous achievement of a large ΔM and low thermal hysteresis leads to a remarkable enhancement in MCE upon Al substitution, and a maximum magnetic entropy change of 31.6 J/kg K is achieved under a field of 5 T in Ni 39 Co 11 Mn 40 Sn 8 Al 2 . Furthermore, our in situ high-energy X-ray diffraction experiments show that the Ni 39 Co 11 Mn 40 Sn 8 Al 2 has good geometric compatibility between austenite and martensite, which accounts for the reduced thermal hysteresis in this alloy. This study is instructive for the development of high-performance magnetocaloric materials in the metamagnetic shape memory alloys.

36 MATERIALS SCIENCE↗

Interfacial Effects on the Dielectric Properties of Elastomer Composites and Nanocomposites

Elastomer-based composites and nanocomposites are discussed, with the emphasis on the filler and interfacial effects on their dynamics, and the resulting manifestation in their macroscopic dielectric or mechanical response. Specifically, selected polydimethylsiloxane (PDMS)/barium-titanate and styrene-butadiene rubber (SBR)/graphene oxide nanocomposites are discussed, as examples where controlled spatial distribution of filler (structured composites) gives rise to significantly different dielectric and thermomechanical behaviors. Also, ethylene–propylene–diene (EPDM)/carbon black (CB) composites are presented, as examples of systems that exhibit an abnormal temperature dependence of dielectric relaxation; and this response is discussed in the context of CB cluster polarization and quantified through a simple scaling model of the same. Finally, multi-filler EPDM/CB/ceramic elastomer nanocomposites are discussed, as examples of systems with antagonistic interfacial effects between conductive and dielectric fillers, as well as with strong interphase responses that can overwhelm the dielectric contributions from the fillers; in these systems, interphasial responses result in counter-intuitive dielectric behaviors and in strong deviations from standard design principles typically employed in the design of dielectric composite systems.

Li, Bo↗

Transport Coefficients in Rotating Weakly Compressible Turbulence

Analytical studies of compressible turbulence have found that compressible velocity fluctuations create both effective fluid transport properties and an effective equation of state. This paper investigates the effects of rotation on compressible turbulence. It is shown that rotation modifies the transport properties of compressible turbulence by replacing the turbulence time scale by a rotational time scale, much as rotation modifies the transport properties of incompressible turbulence. But thermal equilibrium properties are modified in a more complex manner. Two regimes are possible: one dominated by incompressible fluctuations, in which the sound speed is modified as it is in non-rotating turbulence, and a rotation dominated regime in which the sound speed enhancement is rotation dependent. The dimensionless parameter which discriminates between regimes is identified. In general, rotation is found to suppress the effects of compressibility. A novel feature of the present analysis is the use of a non-Kolmogorov steady state as the reference state of turbulence. introduction of such steady states expands the power and utility of analytical turbulence closures to a wider range of problems.

Rubinstein, Robert↗

Ageing of PBF‐Grade Poly(Phenylene Sulfide) Powder and its Effect on Critical Printability Properties

Abstract Poly(phenylene sulfide) (PPS) is a high‐performance polymer suiting the needs of powder bed fusion (PBF) early‐adopter industries. Although there are many benefits to PBF's powder bed‐based, one drawback is thermal ageing of the powder not incorporated into printed parts. Ideally, unfused powder can be reused in future builds; however, it is unlikely that critical printability properties of the thermally aged powder will remain unchanged. Changes in properties lead to either limited reuse through a practice of mixing used and new powder, or elimination of all powder after each build. In this paper, the authors report effects of thermal ageing in simulated printing conditions on properties of PPS critical to PBF processing. PBF‐grade PPS powder is exposed to process‐mimicking conditions. Properties relevant to the three PBF manufacturing process sub‐functions are assessed for the aged powders. Single‐layer prints are made using aged powder to observe polymer‐PBF interactions ad machina. Significant and systematic deviations from the as‐received state of the powder are observed for thermal and coalescence related properties with increasing exposure time and temperature. These changes are interpreted both in terms of physical and chemical changes in PPS and in terms of how these changes may impact the PBF printing process.

Chatham, Camden A.↗