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At least 433 records · Page 24

Energy Distribution among Reaction Products. III: The Method of Measured Relaxation Applied to H + Cl2

The method of measured relaxation is described for the determination of initial vibrational energy distribution in the products of exothermic reaction. Hydrogen atoms coming from an orifice were diffused into flowing chlorine gas. Measurements were made of the resultant ir chemiluminescence at successive points along the line of flow. The concurrent processes of reaction, diffusion, flow, radiation, and deactivation were analyzed in some detail on a computer. A variety of relaxation models were used in an attempt to place limits on k(nu prime), the rate constant for reaction to form HCl in specified vibrational energy levels: H+Cl2 yields (sup K(nu prime) HCl(sub nu prime) + Cl. The set of k(?) obtained from this work is in satisfactory agreement with those obtained by another experimental method (the method of arrested relaxation described in Parts IV and V of the present series.

Pacey, P. D.↗

UV Lidar Receiver Analysis for Tropospheric Sensing of Ozone

A simulation of a ground based Ultra-Violet Differential Absorption Lidar (UV-DIAL) receiver system was performed under realistic daytime conditions to understand how range and lidar performance can be improved for a given UV pulse laser energy. Calculations were also performed for an aerosol channel transmitting at 3 W. The lidar receiver simulation studies were optimized for the purpose of tropospheric ozone measurements. The transmitted lidar UV measurements were from 285 to 295 nm and the aerosol channel was 527-nm. The calculations are based on atmospheric transmission given by the HITRAN database and the Modern Era Retrospective Analysis for Research and Applications (MERRA) meteorological data. The aerosol attenuation is estimated using both the BACKSCAT 4.0 code as well as data collected during the CALIPSO mission. The lidar performance is estimated for both diffuseirradiance free cases corresponding to nighttime operation as well as the daytime diffuse scattered radiation component based on previously reported experimental data. This analysis presets calculations of the UV-DIAL receiver ozone and aerosol measurement range as a function of sky irradiance, filter bandwidth and laser transmitted UV and 527-nm energy

Pliutau, Denis↗

Power-Law Template for Infrared Point-Source Clustering

We perform a combined fit to angular power spectra of unresolved infrared (IR) point sources from the Planck satellite (at 217, 353, 545, and 857 GHz, over angular scales 100 approx < l approx < 2200), the Balloon-borne Large-Aperture Submillimeter Telescope (BLAST; 250, 350, and 500 micron; 1000 approx < l approx < 9000), and from correlating BLAST and Atacama Cosmology Telescope (ACT; 148 and 218 GHz) maps. We find that the clustered power over the range of angular scales and frequencies considered is well fitted by a simple power law of the form C(sup clust)(sub l) varies as l (sub −n) with n = 1.25 +/- 0.06. While the IR sources are understood to lie at a range of redshifts, with a variety of dust properties, we find that the frequency dependence of the clustering power can be described by the square of a modified blackbody, ν(sup Beta)B(ν, T(sub eff) ), with a single emissivity index Beta = 2.20 +/- 0.07 and effective temperature T(sub eff) = 9.7 K. Our predictions for the clustering amplitude are consistent with existing ACT and South Pole Telescope results at around 150 and 220 GHz, as is our prediction for the effective dust spectral index, which we find to be alpha(sub 150-220) = 3.68 +/- 0.07 between 150 and 220 GHz. Our constraints on the clustering shape and frequency dependence can be used to model the IR clustering as a contaminant in cosmic microwave background anisotropy measurements. The combined Planck and BLAST data also rule out a linear bias clustering model.

cosmic background radiation↗

The Nature of the Unresolved Extragalactic Cosmic Soft X-Ray Background

In this paper we investigate the power spectrum of the unresolved 0.5-2 keV cosmic X-ray background (CXB) with deep Chandra 4-Msec (Ms) observations in the Chandra Deep Field South (CDFS). We measured a signal that, on scales >30 arcsec, is significantly higher than the shot noise and is increasing with angular scale. We interpreted this signal as the joint contribution of clustered undetected sources like active galactic nuclei (AGN), galaxies and the intergalactic medium (IGM). The power of unresolved cosmic source fluctuations accounts for approximately 12 per cent of the 0.5-2 keV extragalactic CXB. Overall, our modelling predicts that approximately 20 per cent of the unresolved CXB flux is produced by low-luminosity AGN, approximately 25 per cent by galaxies and approximately 55 per cent by the IGM. We do not find any direct evidence of the so-called 'warm hot intergalactic medium' (i.e. matter with 10(exp 5) less than T less than 10(exp 7) K and density contrast delta less than 1000), but we estimated that it could produce about 1/7 of the unresolved CXB. We placed an upper limit on the space density of postulated X-ray-emitting early black holes at z greater than 7.5 and compared it with supermassive black hole evolution models.

galaxies↗

An Empirical Determination of the Intergalactic Background Light Using Near-Infrared Deep Galaxy Survey Data Out to 5 Micrometers and the Gamma-Ray Opacity of the Universe

We extend our previous model-independent determination of the intergalactic background light, based purely on galaxy survey data, out to a wavelength of 5 micrometers. Our approach enables us to constrain the range of photon densities, based on the uncertainties from observationally determined luminosity densities and colors. We further determine a 68% confidence upper and lower limit on the opacity of the universe to gamma-rays up to energies of 1.6/(1 + z) terraelectron volts. A comparison of our lower limit redshift-dependent opacity curves to the opacity limits derived from the results of both ground-based air Cerenkov telescope and Fermi-LAT observations of PKS 1424+240 allows us to place a new upper limit on the redshift of this source, independent of IBL modeling.

BL Lacertae↗

Cosmic Infrared Background Fluctuations and Zodiacal Light

We performed a specific observational test to measure the effect that the zodiacal light can have on measurements of the spatial fluctuations of the near-IR (near-infrared)background. Previous estimates of possible fluctuations caused by zodiacal light have often been extrapolated from observations of the thermal emission at longer wavelengths and low angular resolution or from IRAC (Infrared Array Camera) observations of high-latitude fields where zodiacal light is faint and not strongly varying with time. The new observations analyzed here target the COSMOS (Cosmic Evolution Survey) field at low ecliptic latitude where the zodiacal light intensity varies by factors of approximately 2 over the range of solar elongations at which the field can be observed. We find that the white-noise component of the spatial power spectrum of the background is correlated with the modeled zodiacal light intensity. Roughly half of the measured white noise is correlated with the zodiacal light, but a more detailed interpretation of the white noise is hampered by systematic uncertainties that are evident in the zodiacal light model. At large angular scales (greater than or approximately equal to 100 arcseconds) where excess power above the white noise is observed, we find no correlation of the power with the modeled intensity of the zodiacal light. This test clearly indicates that the large-scale power in the infrared background is not being caused by the zodiacal light.

cosmology: observations aEuro" diffuse radiation a↗

The Chandra Deep Field-South Survey: 7 Ms Source Catalogs

We present X-ray source catalogs for the approx. 7 Ms exposure of the Chandra Deep Field-South (CDF-S), which covers a total area of 484.2 arcmin2. Utilizing WAVDETECT for initial source detection and ACIS Extract for photometric extraction and significance assessment, we create a main source catalog containing 1008 sources that are detected in up to three X-ray bands: 0.5-7.0 keV, 0.5-2.0 keV, and 2-7 keV. A supplementary source catalog is also provided, including 47 lower-significance sources that have bright (Ks < or = 23) near-infrared counterparts. We identify multiwavelength counterparts for 992 (98.4%) of the main-catalog sources, and we collect redshifts for 986 of these sources, including 653 spectroscopic redshifts and 333 photometric redshifts. Based on the X-ray and multiwavelength properties, we identify 711 active galactic nuclei (AGNs) from the main-catalog sources. Compared to the previous approx. 4 Ms CDF-S catalogs, 291 of the main-catalog sources are new detections. We have achieved unprecedented X-ray sensitivity with average flux limits over the central approx. 1 arcmin2 region of 1.9 x 10(exp -17), 6.4 x 10(exp -18), and 2.7 x 10(exp -17) erg/sq cm/s in the three X-ray bands, respectively. We provide cumulative number-count measurements observing, for the first time, that normal galaxies start to dominate the X-ray source population at the faintest 0.5-2.0 keV flux levels. The highest X-ray source density reaches approx. 50,500/sq deg, and 47% +/- 4 of these sources are AGNs (approx. 23,900/sq deg).

cosmology: observations – diffuse radiation – ↗

Charged particle diffusion and acceleration in Saturn's radiation belts

In the present paper, an attempt is made to determine, from the observed intensity profiles for protons and electrons in the region of L smaller than 4, whether population of Saturn's innermost trapped radiation zones from an external source is possible. It is found that if diffusion proceeds in an episodic rather than a steady-state manner (long periods of quiescence interrupted by brief periods of rapid diffusion), the basic features of the observed phase space density profiles are qualitatively reproduced for both the trapped protons and electrons.

Mckibben, R. B.↗

Cosmological considerations on the diffuse gamma-ray isotropic background

Bignami et al (1979) have recently studied the problem of the origin of the diffuse gamma-ray isotropic radiation. They have concluded that within standard cosmology with Lambda = 0 and p = 0, BL Lacertae objects and Seyfert galaxies can account for most of the diffuse radiation if they have not evolved in time. For QSOs, an evolutionary factor is allowed by the data. From the study of radio data, however, it is known that strong evolutionary effects are expected. The discrepancy cannot be explained by changing the geometry of the universe. Contrary to the case of standard cosmology, it is found that in order to fit the diffuse gamma-ray background, the evolutionary function required is almost identical to the one previously determined from the study of the log N-log S relation.

Canuto, V. M.↗

Theoretical analysis of infrared radiation shields of spacecraft

For a system of N diffuse, gray body radiation shields which view only adjacent surfaces and space, the net radiation method for enclosures has been used to formulate a system of linear, nonhomogeneous equations in terms of the temperatures to the fourth power of each surface in the coupled system of enclosures. The coefficients of the unknown temperatures in the system of equations are expressed in terms of configuration factors between adjacent surfaces and the emissivities. As an application, a system of four conical radiation shields for a spin stabilized STARPROBE spacecraft has been designed and analyzed with respect to variations of the cone half angles, the intershield spacings, and emissivities.

Shealy, D. L.↗

Aerosol scattering of ultraviolet sunlight in the tropical maritime atmosphere

The effects of atmospheric aerosol scattering on the vertical profile of solar ultraviolet radiation are investigated. Measurements of diffuse and total ultraviolet radiation were made using a rocketborne optical sonde in the marine atmosphere of Antigua. During observations, the sun was at zenith. Vertical profiles of directly transmitted solar radiation were calculated by subtraction of the diffuse component from the total radiance. Using these values of direct downward solar UV-flux, the optical thickness of the atmosphere was derived as a function of altitude. Absorption by ozone was also considered. In the troposphere the values of observed optical thickness were in general equal to or lower than those expected theoretically from Rayleigh scattering alone. The measured radiation profiles were compared with those computed for a multiple scattering model atmosphere. Some computations regarding the interaction of UV-sunlight with maritime aerosols are presented.

Ghazi, A.↗

Status and future of high energy diffuse gamma-ray astronomy

There are two distinctly different high energy diffuse gamma-ray components, one well correlated with broad galactic features and the other apparently isotropic and presumably extragalactic. The observed diffuse galactic high energy gamma radiation is generally thought to be produced in interactions between the cosmic rays and the interstellar matter and photons. It should then ultimately be possible to obtain from the diffuse galactic emission a detailed picture of the galactic cosmic-ray distribution, a high contrast view of the general structure of the galaxy, and further insight into molecular clouds. Two of the candidates for the explanation of the extragalactic diffuse radiation are the sum of emission from active galaxies and matter-antimatter annihilation. A major advancement in the study of the properties of both galactic and extragalactic gamma radiation should occur over the next decade.

Fichtel, C. E.↗

Radial diffusion models of energetic electrons and Jupiter's synchrotron radiation. 2: Time variability

We used a radial diffusion code for energetic electrons in Jupiter's magnetosphere to investigate variations in Jupiter's radio emission due to changes in the electron phase space density at L shells between 6 and 50, and due to changes in the radial diffusion parameters. We suggest that the observed variations in Jupiter's radio emission are likely caused by changes in the electron phase space density at some boundary L(sub 1) is greater than 6, if the primary mode of transport of energetic electrons is radial diffusion driven by fluctuating electric and/or magnetic fields induced by upper atmospheric turbulence. We noticed an excellent empirical correlation, both in phase and relative amplitude, between changes in the solar wind ram pressure and Jupiter's synchrotron radiation if the electron phase space density at the boundary L(sub 1) (L(sub 1) is approximately equal to 20-50) varies linearly with the square root of the solar wind ram pressure, f is approximately (N(sub s)nu(exp 2 sub s))(exp 1/2). The calculations were carried out with a diffusion coefficient D(sub LL) = D(sub n)L(exp n) with n = 3. The diffusion coefficient which best fit the observed variations in Jupiter's synchrotron radiation D(sub 3) = 1.3 +/- 0.2 x 10(exp -9)/s is approximately 0.041/yr, which corresponds to a lagtime of approximately 2 years. We further show that the observed short term (days-weeks) variations in Jupiter's radio emission cannot be explained adequately when radial diffusion is taken into account.

De Pater, Imke↗

Approximate Solution Methods for Spectral Radiative Transfer in High Refractive Index Layers

Some ceramic materials for high temperature applications are partially transparent for radiative transfer. The refractive indices of these materials can be substantially greater than one which influences internal radiative emission and reflections. Heat transfer behavior of single and laminated layers has been obtained in the literature by numerical solutions of the radiative transfer equations coupled with heat conduction and heating at the boundaries by convection and radiation. Two-flux and diffusion methods are investigated here to obtain approximate solutions using a simpler formulation than required for exact numerical solutions. Isotropic scattering is included. The two-flux method for a single layer yields excellent results for gray and two band spectral calculations. The diffusion method yields a good approximation for spectral behavior in laminated multiple layers if the overall optical thickness is larger than about ten. A hybrid spectral model is developed using the two-flux method in the optically thin bands, and radiative diffusion in bands that are optically thick.

Siegel, R.↗

Moving beyond the Aerosol Climatology of WRF-Solar: A Case Study over the North China Plain

Numerical weather prediction (NWP), when accessible, is a crucial input to short-term solar power forecasting. WRF-Solar, the first NWP model specifically designed for solar energy applications, has shown promising predictive capability. Nevertheless, few attempts have been made to investigate its performance under high aerosol loading, which attenuates incoming radiation significantly. The North China Plain is a polluted region due to industrialization, which constitutes a proper testbed for such investigation. Here, in this paper, aerosol direct radiative effect (DRE) on three surface shortwave radiation components (i.e., global, beam, and diffuse) during five heavy pollution episodes is studied within the WRF-Solar framework. Results show that WRF-Solar overestimates instantaneous beam radiation up to 795.3 W m -2 when the aerosol DRE is not considered. Although such overestimation can be partially offset by an underestimation of the diffuse radiation of about 194.5 W m -2 , the overestimation of the global radiation still reaches 160.2 W m -2 . This undesirable bias can be reduced when WRF-Solar is powered by Copernicus Atmosphere Monitoring Service (CAMS) aerosol forecasts, which then translates to accuracy improvements in photovoltaic (PV) power forecasts. This work also compares the forecast performance of the CAMS-powered WRF-Solar with that of the European Centre for Medium-Range Weather Forecasts model. Under high aerosol loading conditions, the irradiance forecast accuracy generated by WRF-Solar increased by 53.2% and the PV power forecast accuracy increased by 6.8%.

54 ENVIRONMENTAL SCIENCES↗

Positrons from supernovae

Positrons are produced in the ejecta of supernovae by the decay of nucleosynthetic Co-56, Ti-44, and Al-26. We calculate the probability that these positrons can survive without annihilating in the supernova ejecta, and we show that enough of these positrons should escape into the interstellar medium to account for the observed diffuse Galactic annihilation radiation. The surviving positrons are carried by the expanding ejecta into the interstellar medium where their annihilation lifetime of 10 exp 5 - 10 exp 6 yr is much longer than the average supernovae occurrence time of about 100 yr. Thus, annihilating positrons from thousands of supernovae throughout the Galaxy produce a steady diffuse flux of annihilation radiation. We further show that combining the calculated positron survival fractions and nucleosynthetic yields for current supernova models with the estimated supernova rates and the observed flux of diffuse Galactic annihilation radiation suggests that the present Galactic rate of Fe-56 nucleosynthesis is about 0.8 +/- 0.6 solar mass per 100 yr.

Chan, Kai-Wing↗

Cosine-corrected optical diffuser

In solar energy utilization studies, correct measurements of flux arriving at other angles to optical axis must be given. Developed device (Cosine diffuser) significantly reduces measurement errors. In combination of radiation transmitter and diffuser co-operating with collimated optical instrument, relative aperture of instrument is filled.

Estey, R. S.↗