Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “CuI”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 433 records · Page 24

High performance Nb/TiNi nanocomposites produced by packaged accumulative roll bonding

Taking full advantage of intrinsic high strength of nano-reinforcements has been proven difficult in a composite until the concept of strain matching was experimental verified in a nanowire Nb/TiNi in-situ composite, which was obtained via solidifying eutectic Nb/TiNi and subsequent severe wire drawing. However, the volume fraction of the nano-reinforcement was dictated by eutectic reaction, which severely limited the development of high-performance composites. Here, the martensitic transformation nanocomposites were successfully acquired with increased volume fraction and changeable morphology of the nano-reinforcement through hot packaged ARB (PARB) and subsequent wire drawing. The nano-reinforcement with lamellar configuration in the composite could exhibit a large lattice strain of similar to 3.8%, which demonstrated the applicability and effectiveness of the strain matching principle in nano-lamellar composite. The obtained composites show a yield strength over 2.0 GPa and a quasi-linear elastic strain as larger as similar to 6.5% with adjustable apparent elastic modulus from 30 to 50 GPa.

42 ENGINEERING↗

In-situ high energy X-ray diffraction study of deformation behavior in Nb nanoparticle-martensitic NiTi composite wire

Here, this study investigated the deformation behavior in Nb nanoparticle-martensitic NiTi composite wire during tensile loading by means of in-situ high-energy X-ray diffraction. Compared to Nb nanowires, the dispersedly distributed Nb nanoparticles have little effect on the transformation and deformation behaviors of NiTi matrix, causing the absence of R phase transformation and the occurrence of deformation twinning in NiTi matrix. Meanwhile, the occurrence of deformation twinning in NiTi matrix can reduce the shape strain to be coordinated by the unfavorable orientated martensite variants, and thus decreases the internal stress among NiTi martensite variants generated during martensite reorientation process. In addition, TEM result proved that Nb nanoparticles can achieve exceptionally large elastic strain in B19'-NiTi matrix (~4%), just as Nb nanowires. However, this large elastic strain (stress) will be released with the occurrence of NiTi deformation twinning.

36 MATERIALS SCIENCE↗

Hot corrosion behavior of 304 & P91 graded composite transition joint under molten sulfate salts

A novel graded composite transition joint (GCTJ) between AISI 304 stainless steel and ASTM A335 P91 steel, has been demonstrated remarkablely superior creep performance compared to the conventional dissimilar metal weldment (DMW) under equivalent conditions. However, this advance is challenged by hot corrosion under salt deposition at elevated temperatures. Here, this study investigates the hot corrosion behavior of 304&P91 GCTJ exposed to sulfate salts at 700°C. Compared to the 304 steel, corrosion attacks initiate in the P91 triangle, where the dual-phase microstructure of ferrite and tempered martensite significantly influences pitting initiation. Anodic dissolution mainly occurs within the tempered martensite due to more vulnerable sites within the tempered martensite. With prolonged exposure, corrosion propagates across both phases, and the corrosion depth within the P91 triangle is related to the exposed surface area ratio between 304 and P91. Electrochemical analysis reveals the occurrence of galvanic corrosion between the 304 and P91, with a positive linear relationship between anodic dissolution current density (I a ) and the exposed surface area ratio between 304 and P91 in molten salts, further emphasizing the critical impact of this ratio on the corrosion severity in the P91 triangle. These findings underscore the importance of transition zone design optimization in mitigating localized corrosion.

Galvanic corrosion↗

Methane liquefaction with an active magnetic regenerative refrigerator

This manuscript reports liquefaction of methane using an active magnetic regenerative refrigerator (AMRR). The AMRR used to cool from 285 K to 135 K has two identical regenerators fabricated with adjacent layers of four ferromagnetic refrigerants, each with sequentially lower Curie temperatures and lesser masses from hot to cold temperatures. The dual multilayer regenerators were assembled in opposition with a single cold region between them. For this set of experiments equal mass of helium gas was pumped through all layers of the regenerators during the two flow steps of the four-step AMR cycle. After successfully reaching 135 K, a compact condensing coil-fin tube heat exchanger (HEX) with a small storage vessel was mounted in the cold region of the dual regenerator assembly to be cooled during the hot-to-cold helium flow from alternatively demagnetized regenerators. The cold HEX was used to cool and liquefy a process stream of methane gas supplied at 295 K and different pressures in different runs. Further, by measuring time to liquefy a known volume of methane at three different pressures, cooling powers of the AMRR as a function of temperature were determined. The resultant data were compared to those predicted by the AMRR performance model. Conclusions from these experiments and suggestions for future work are presented.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Stochastic gravitational wave background from global cosmic strings

Global cosmic strings are generically predicted in particle physics beyond the Standard Model, e.g., a post-inflationary global U(1) symmetry breaking which may associate with axion-like dark matter. Here, we demonstrate that although subdominant to Goldstone emission, gravitational waves (GWs) radiated from global strings can be observable with current/future GW detectors. The frequency spectrum of such GWs is also shown to be a powerful tool to probe the Hubble expansion rate of the Universe at times prior to the Big Bang nucleosynthesis where the standard cosmology has yet to be tested.

97 MATHEMATICS AND COMPUTING↗

Enhancing carbon storage through proactively managing fire-prone coniferous mountain forests

Mountain ecosystems typically serve as carbon (C) sinks. However, studies also suggest that they could be C sources due to climate warming, drought and insect-related mortality, wildfires, and management actions. We applied the Lund-Potsdam-Jena General Ecosystem Simulator (LPJ-GUESS), a process-based dynamic vegetation-ecosystem model, to investigate the role of ecosystem management in C storage under Mediterranean climate over the 21 st century. We modified LPJ-GUESS to include implementing mechanical thinning by vegetation size classes, components, and types along with a new mechanistic fire-occurrence model that accounts for wind speed and lightning ignition. Simulations show that mechanical thinning or prescribed fire performed 5-20 years in advance of a high-severity wildfire reduced direct wildfire C emissions by 38-66 %. Our results also show that long-term management actions repeated every 5-20 years, including thinning relatively small trees (diameters up to 7 inches or ∼178 mm), can maintain stable C levels in the forest and lower dead-fuel amounts. We found that, although prescribed fire mitigated wildfire severity, ecosystem C storage from reduced wildfire emissions can be outweighed by the added emissions from the prescribed fire themselves. Thinning plus removing and sequestering the thinned biomass can ensure that forests act as net C sinks through the end of the 21 st century. However, addition of prescribed fire is needed to reduce understory and lower the projected extent of high-severity wildfire. Achieving the competing goals of reducing wildfire and making the Sierra Nevada long-term C sink can be advanced through carefully coordinated thinning, sequestration of thinned biomass, and prescribed fire.

Climate solutions↗

Quantifying the reductions in mortality from air-pollution by cancelling new coal power plants

Deep decarbonization paths to the 1.5°C or 2°C temperature stabilization futures require a rapid reduction in conventional coal-fired power plants, but countries are currently building 223 GW of new coal power capacity and plan to build 377 GW more in the next decade. Coal-fired plants are also a major contributor to air pollution related health impacts. Here, we couple an integrated human-earth system model (GCAM) with an air quality model (TM5-FASST) to examine regional health co-benefits from cancelling new coal-fired plants worldwide. Additionally, we find that cancelling all new proposed projects would decrease air pollution related premature mortality between 101,388 - 213,205 deaths (2-5%) in 2030, and 213,414 - 373,054 (5-8%) in 2050, globally, but heavily concentrated in developing Asia. Furthermore, we estimate that strengthening the climate target from 2°C to 1.5°C would avoid 326,351 additional mortalities in 2030, of which 251,011 (75%) are attributable to the incremental coal plant shutdown.

63 RADIATION, THERMAL, AND OTHER ENVIRON. POLLUTAN↗

State-by-state energy-water-land-health impacts of the US net-zero emissions goal

As decisionmakers at various scales begin to design strategies to implement the US net-zero goal, a holistic understanding of its broader economic and sustainability implications at subnational scales is important to shape public support and facilitate implementation. Here, we use an integrated assessment model to explore four different pathways toward the US net-zero goal and investigate their energy-water-land-health implications at the state level. In this study, we show that achieving the net-zero goal implies significant capital turnover (170–200 billion USD/year capital investment and 16–29 billion USD/year stranded assets in the power sector), reduced water withdrawal (120–210 km 3 /year), avoided air pollution damages (220–300 billion USD/year), and expanded forests (300–500 thousand km 2 ). However, the economic and sustainability implications of achieving the net-zero goal at the state-level may not be correlated to a state's contribution to national emission reductions. Our study lays the foundations for a deeper understanding of the broader implications of the US net-zero goal to facilitate cost-effective and environmentally sustainable transitions toward that goal.

54 ENVIRONMENTAL SCIENCES↗

From PROTAC to inhibitor: Structure-guided discovery of potent and orally bioavailable BET inhibitors

An X-ray structure of a CLICK chemistry-based BET PROTAC bound to BRD2(BD2) inspired synthesis of JQ1 derived heterocyclic amides. This effort led to the discovery of potent BET inhibitors displaying overall improved profiles when compared to JQ1 and birabresib. A thiadiazole derived 1q (SJ1461) displayed excellent BRD4 and BRD2 affinity and high potency in the panel of acute leukaemia and medulloblastoma cell lines. A structure of 1q co-crystalised with BRD4-BD1 revealed polar interactions with the AZ/BC loops, in particular with Asn140 and Tyr139, rationalising the observed affinity improvements. In addition, exploration of pharmacokinetic properties of this class of compounds suggest that the heterocyclic amide moiety improves drug-like features. Finally, our study led to the discovery of potent and orally bioavailable BET inhibitor 1q (SJ1461) as a promising candidate for further development.

60 APPLIED LIFE SCIENCES↗