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At least 433 records · Page 24

Thermal Analyzer for Planetary Soil (TAPS): an in Situ Instrument for Mineral and Volatile-element Measurements

Thermal Analyzer for Planetary Soil (TAPS) offers a specific implementation for the generic thermal analyzer/evolved-gas analyzer (TA/EGA) function included in the Mars Environmental Survey (MESUR) strawman payload; applications to asteroids and comets are also possible. The baseline TAPS is a single-sample differential scanning calorimeter (DSC), backed by a capacitive-polymer humidity sensor, with an integrated sampling mechanism. After placement on a planetary surface, TAPS acquires 10-50 mg of soil or sediment and heats the sample from ambient temperature to 1000-1300 K. During heating, DSC data are taken for the solid and evolved gases are swept past the water sensor. Through ground based data analysis, multicomponent DSC data are deconvolved and correlated with the water release profile to quantitatively determine the types and relative proportions of volatile-bearing minerals such as clays and other hydrates, carbonates, and nitrates. The rapid-response humidity sensors also achieve quantitative analysis of total water. After conclusion of soil-analysis operations, the humidity sensors become available for meteorology. The baseline design fits within a circular-cylindrical volume less than 1000 cm(sup 3), occupies 1.2 kg mass, and consumes about 2 Whr of power per analysis. Enhanced designs would acquire and analyze multiple samples and employ additional microchemical sensors for analysis of CO2, SO2, NO(x), and other gaseous species. Atmospheric pumps are also being considered as alternatives to pressurized purge gas.

Gooding, J. L.↗

Unsteady loads measurements in a generic high speed engine model by means of recessed transducers

Results are presented from measurements of unsteady loads during performance tests of a generic high-speed engine model, which were made using high-frequency pressure gages installed in existing calorimeter ports of the engine model and recessed into the interior wall surface in order to reduce thermal flux to the gage diaphragm. In was found that the boundary layer pressure spectra at the model wall start to deviate from their flat plate counterpart at a short distance into the model inlet, which suggests the contributions to the spectra from the shock/boundary layer interaction. It was also found that significant levels of combustion noise propagate up through the subsonic portion of the boundary layer well into the inlet region. At the condition of an unstart, the combustion noise apparently couples with the acoustic modes of the model to cause acoustic 'hot spots' well upstream of the combustor.

Parrott, Tony L.↗

Calorimetry of 25 Ah lithium/thionyl chloride cells

Heat flow measurements of 25-Ah lithium thionyl chloride cells provided a method to calculate an effective thermal potential, E(TP) of 3.907 V. The calculation is useful to determine specific heat generation of this cell chemistry and design. The E(TP) value includes heat generation by electrochemical cell reactions, competitive chemical reactions, and resistance heating at the tabs, connectors, and leads. Heat flow was measured while applying electrical loads to the cell in an isothermal calorimeter set at 0, 20, and 60 C.

Johnson, C. J.↗

Fusible heat sink materials - Evaluation of alternate candidates

Fusible heat sinks are a possible source for thermal regulation of space suited astronauts. Materials with greater thermal storage capability than water could enable both an extension of time between recharging and/or a reduction in size and/or mass. An extensive literature search identified 1,215 candidates with a solid-liquid transformation within the temperature range of -13 C to 5 C. Based on data available in the literature, several candidates with a cooling capacity significantly greater than water were identified. Measurements of the transformation temperature and enthalpy of transformation were then undertaken with a differential scanning calorimeter in order to confirm the accuracy of the literature. Laboratory measurements have thus far not been able to corroborate the extremely high values found from the literature. This paper presents the approach for materials selection utilized in this study, the experimental procedure, and the results of the measurements thus far undertaken.

Selvaduray, Guna S.↗

Calorimetric studies of the ammonia-water system with application to the outer solar system

A series of heating experiments was performed on the condensed ammonia-water system using a differential scanning calorimeter (DSC). The water-rich samples were cooled quickly to below 130 K, then heated at a variety of rates. Rather than a single peritectic melt at 176 K, expected for the equilibrium system of water ice and ammonia dihydrate, four enthalpic transitions were repeatedly seen in the temperature range 150-176 K. These transitions are generally consistent with the earlier calorimetric results of Van Kasteren (1973), who interpreted the lowest temperature exotherm as crystallization of an amorphous ammonia-water compound formed during cooling. We propose that both sets of experiments are seeing the crystallization of ammonia monohydrate, which is metastable relative to the dihydrate, followed by partial remelting and crystallization of dihydrate upon further heating. The apparent stability of the monohydrate in the dihydrate equilibrium field implies a potentially complex behavior of ammonia-water ices in satellites. Possible self-heating of the mixture by several tens of degrees up to the 170 K eutectic could make mobilization of ammonia-water liquids in icy satellite interiors energetically easier than previously thought.

Yarger, Jeffery↗

Analysis of film cooling in rocket nozzles

This report summarizes the findings on the NASA contract NAG8-212, Task No. 3. The overall project consists of three tasks, all of which have been successfully completed. In addition, some supporting supplemental work, not required by the contract, has been performed and is documented herein. Task 1 involved the modification of the wall functions in the code FDNS (Finite Difference Navier-Stokes) to use a Reynolds Analogy-based method. This task was completed in August, 1992. Task 2 involved the verification of the code against experimentally available data. The data chosen for comparison was from an experiment involving the injection of helium from a wall jet. Results obtained in completing this task also show the sensitivity of the FDNS code to unknown conditions at the injection slot. This task was completed in September, 1992. Task 3 required the computation of the flow of hot exhaust gases through the P&W 40K subscale nozzle. Computations were performed both with and without film coolant injection. This task was completed in July, 1993. The FDNS program tends to overpredict heat fluxes, but, with suitable modeling of backside cooling, may give reasonable wall temperature predictions. For film cooling in the P&W 40K calorimeter subscale nozzle, the average wall temperature is reduced from 1750R to about 1050R by the film cooling. The average wall heat flux is reduced by a factor of 3.

Woodbury, Keith A.↗

Influence of test configuration on the combustion characteristics of polymers as ignition sources

The experimental evaluation of polymers as ignition sources for metals was accomplished at the NASA White Sands Test Facility (WSTF) using a standard promoted combustion test. These tests involve the transient burning of materials in high-pressure oxygen environments. They have provided data from which design decisions can be made; data include video recordings of ignition and non-ignition for specific combinations of metals and polymers. Other tests provide the measured compositions of combustion products for polymers at select burn times and an empirical basis for estimating burn rates. With the current test configuration, the detailed analysis of test results requires modeling a three-dimensional, transient convection process involving fluid motion, thermal conduction and convection, the diffusion of chemical species, and the erosion of sample surface. At the high pressure extremes, it even requires the analysis of turbulent, transient convection where the physics of the problem are not well known and the computation requirements are not practical at this time. An alternative test configuration that can be analyzed with a relatively-simple convection model was developed during the summer period. The principal change constitutes replacing a large-diameter polymer disk at the end of the metal test rod with coaxial polymer cylinders that have a diameter nearer to that of the metal rod. The experimental objective is to assess the importance of test geometries on the promotion of metal ignition by testing with different lengths of the polymer and, with an extended effort, to analyze the surface combustion in the redesigned promoted combustion tests through analytical modeling of the process. The analysis shall use the results of cone-calorimeter tests of the polymer material to model primary chemical reactions and, with proper design of the promoted combustion test, modeling of the convection process could be conveniently limited to a quasi-steady boundary layer analysis where the economical solution of parabolic equations is involved. The products for the summer period are: (1) a conceptual-level redesign of the test apparatus, and (2) the development and use of an approximate integral boundary layer analysis to demonstrate the influence of geometry changes prior to testing. A computer code STAN5, an accurate numerical boundary layer model whose earlier versions were developed for the NASA Lewis Research Center by the Fellow, also was installed and validated on the WSTF and New Mexico State University computer systems as a starting point in the development of a more detailed fluid mechanics and combustion model.

Julien, Howard L.↗

Orbit transfer rocket engine technology program enhanced heat transfer combustor technology

In order to increase the performance of a high performance, advanced expander-cycle engine combustor, higher chamber pressures are required. In order to increase chamber pressure, more heat energy is required to be transferred to the combustor coolant circuit fluid which drives the turbomachinery. This requirement was fulfilled by increasing the area exposed to the hot-gas by using combustor ribs. A previous technology task conducted 2-d hot air and cold flow tests to determine an optimum rib height and configuration. In task C.5 a combustor calorimeter was fabricated with the optimum rib configuration, 0.040 in. high ribs, in order to determine their enhancing capability. A secondary objective was to determine the effects of mixture ratio changers on the enhancement during hot-fire testing. The program used the Rocketdyne Integrated Component Evaluator (ICE) reconfigured into a thrust chamber only mode. The test results were extrapolated to give a projected enhancement from the ribs for a 16 in. long cylindrical combustor at 15 Klb nominal thrust level. The hot-gas wall ribs resulted in a 58 percent increase in heat transfer. When projected to a full size 15K combustor, it becomes a 46 percent increase. The results of those tests, a comparison with previous 2-d results, the effects of mixture ratio and combustion gas flow on the ribs and the potential ramifications for expander cycle combustors are detailed.

Brown, William S.↗

Orbit transfer rocket engine technology program

An advanced near term (1990's) space-based Orbit Transfer Vehicle Engine (OTVE) system was designed, and the technologies applicable to its construction, maintenance, and operations were developed under Tasks A through F of the Orbit Transfer Rocket Engine Technology Program. Task A was a reporting task. In Task B, promising OTV turbomachinery technologies were explored: two stage partial admission turbines, high velocity ratio diffusing crossovers, soft wear ring seals, advanced bearing concepts, and a rotordynamic analysis. In Task C, a ribbed combustor design was developed. Possible rib and channel geometries were chosen analytically. Rib candidates were hot air tested and laser velocimeter boundary layer analyses were conducted. A channel geometry was also chosen on the basis of laser velocimeter data. To verify the predicted heat enhancement effects, a ribbed calorimeter spool was hot fire tested. Under Task D, the optimum expander cycle engine thrust, performance and envelope were established for a set of OTV missions. Optimal nozzle contours and quick disconnects for modularity were developed. Failure Modes and Effects Analyses, maintenance and reliability studies and component study results were incorporated into the engine system. Parametric trades on engine thrust, mixture ratio, and area ratio were also generated. A control system and the health monitoring and maintenance operations necessary for a space-based engine were outlined in Task E. In addition, combustor wall thickness measuring devices and a fiberoptic shaft monitor were developed. These monitoring devices were incorporated into preflight engine readiness checkout procedures. In Task F, the Integrated Component Evaluator (I.C.E.) was used to demonstrate performance and operational characteristics of an advanced expander cycle engine system and its component technologies. Sub-system checkouts and a system blowdown were performed. Short transitions were then made into main combustor ignition and main stage operation.

Gustafson, N. B.↗

Cosmic x ray physics

This final report covers the period 1 January 1985 - 31 March 1992. It is divided into the following sections: the soft x-ray background; proportional counter and filter calibrations; sounding rocket flight preparations; new sounding rocket payload: x-ray calorimeter; and theoretical studies. Staff, publications, conference proceedings, invited talks, contributed talks, colloquia and seminars, public service lectures, and Ph. D. theses are listed.

Mccammon, Dan↗

Cosmic x ray physics

The annual progress report on Cosmic X Ray Physics is presented. Topics studied include: the soft x ray background, proportional counter and filter calibrations, the new sounding rocket payload: X Ray Calorimeter, and theoretical studies.

Mccammon, Dan↗

Cosmic x ray physics

The annual progress report on Cosmic X Ray Physics for the period 1 Jan. to 31 Dec. 1990 is presented. Topics studied include: soft x ray background, new sounding rocket payload: x ray calorimeter, and theoretical studies.

Mccammon, Dan↗

Aerodynamic heating in hypersonic flows

Aerodynamic heating in hypersonic space vehicles is an important factor to be considered in their design. Therefore the designers of such vehicles need reliable heat transfer data in this respect for a successful design. Such data is usually produced by testing the models of hypersonic surfaces in wind tunnels. Most of the hypersonic test facilities at present are conventional blow-down tunnels whose run times are of the order of several seconds. The surface temperatures on such models are obtained using standard techniques such as thin-film resistance gages, thin-skin transient calorimeter gages and coaxial thermocouple or video acquisition systems such as phosphor thermography and infrared thermography. The data are usually reduced assuming that the model behaves like a semi-infinite solid (SIS) with constant properties and that heat transfer is by one-dimensional conduction only. This simplifying assumption may be valid in cases where models are thick, run-times short, and thermal diffusivities small. In many instances, however, when these conditions are not met, the assumption may lead to significant errors in the heat transfer results. The purpose of the present paper is to investigate this aspect. Specifically, the objectives are as follows: (1) to determine the limiting conditions under which a model can be considered a semi-infinite body; (2) to estimate the extent of errors involved in the reduction of the data if the models violate the assumption; and (3) to come up with correlation factors which when multiplied by the results obtained under the SIS assumption will provide the results under the actual conditions.

Reddy, C. Subba↗

Arcjet system integration development

Compatibility between an arcjet propulsion system and a communications satellite was verified by testing a Government-furnished, 1.4 kW hydrazine arcjet system with the FLTSATCOM qualification model satellite in a 9.1-meter (30-foot) diameter thermal-vacuum test chamber. Background pressure was maintained at 10(exp -5) torr during arcjet operation by cryopumping the thruster exhaust with an array of 5 K liquid helium cooled panels. Power for the arcjet system was obtained from the FLTSATCOM battery simulator. Spacecraft telemetry was monitored during each thruster firing period. No changes in telemetry data attributable to arcjet operation were detected in any of the tests. Electromagnetic compatibility data obtained included radiated emission measurements, conducted emission measurements, and cable coupling measurements. Significant noise was observed at lower frequencies. Above 500 MHz, radiated emissions were generally within limits, indicating that communication links at S-band and higher frequencies will not be affected. Other test data taken with a diagnostic array of calorimeters, radiometers, witness plates, and a residual gas analyzer evidenced compatible operation, and added to the data base for arcjet system integration. Two test series were conducted. The first series only included the arcjet and diagnostic array operating at approximately 0.1 torr background pressure. The second series added the qualification model spacecraft, a solar panel, and the helium cryopanels. Tests were conducted at 0.1 torr and 10(exp-5) torr. The arcjet thruster was canted 20 degrees relative to the solar panel axis, typical of the configuration used for stationkeeping thrusters on geosynchronous communications satellites.

Zafran, Sidney↗

FDNS code to predict wall heat fluxes or wall temperatures in rocket nozzles

This report summarizes the findings on the NASA contract NAG8-212, Task No. 3. The overall project consists of three tasks, all of which have been successfully completed. In addition, some supporting supplemental work, not required by the contract, has been performed and is documented herein. Task 1 involved the modification of the wall functions in the code FDNS to use a Reynolds Analogy-based method. Task 2 involved the verification of the code against experimentally available data. The data chosen for comparison was from an experiment involving the injection of helium from a wall jet. Results obtained in completing this task also show the sensitivity of the FDNS code to unknown conditions at the injection slot. Task 3 required computation of the flow of hot exhaust gases through the P&W 40K subscale nozzle. Computations were performed both with and without film coolant injection. The FDNS program tends to overpredict heat fluxes, but, with suitable modeling of backside cooling, may give reasonable wall temperature predictions. For film cooling in the P&W 40K calorimeter subscale nozzle, the average wall temperature is reduced from 1750 R to about 1050 R by the film cooling. The average wall heat flux is reduced by a factor of three.

Karr, Gerald R.↗

Thermochemistry of dense hydrous magnesium silicates

Recent experimental investigations under mantle conditions have identified a suite of dense hydrous magnesium silicate (DHMS) phases that could be conduits to transport water to at least the 660 km discontinuity via mature, relatively cold, subducting slabs. Water released from successive dehydration of these phases during subduction could be responsible for deep focus earthquakes, mantle metasomatism and a host of other physico-chemical processes central to our understanding of the earth's deep interior. In order to construct a thermodynamic data base that can delineate and predict the stability ranges for DHMS phases, reliable thermochemical and thermophysical data are required. One of the major obstacles in calorimetric studies of phases synthesized under high pressure conditions has been limitation due to the small (less than 5 mg) sample mass. Our refinement of calorimeter techniques now allow precise determination of enthalpies of solution of less than 5 mg samples of hydrous magnesium silicates. For example, high temperature solution calorimetry of natural talc (Mg(0.99) Fe(0.01)Si4O10(OH)2), periclase (MgO) and quartz (SiO2) yield enthalpies of drop solution at 1044 K to be 592.2 (2.2), 52.01 (0.12) and 45.76 (0.4) kJ/mol respectively. The corresponding enthalpy of formation from oxides at 298 K for talc is minus 5908.2 kJ/mol agreeing within 0.1 percent to literature values.

Bose, Kunal↗

Postburst nebular emission of soft gamma-ray repeaters

The soft gamma ray repeater SGR 1806-20 has been shown to be unambiguously associated with the central region of the radio nebula G10.0-0.3. The nebula surrounding SGR 1806-20 is probably a supernova remnant and has a nonthermal radio spectrum typical of a 'plerion,' circumstellar gas energized by a relativistic particle outflow from a central source. The association of soft gamma ray repeaters (SGRs) with supernova remnants is supported by the likely association of another repeater, SGR 0525-66, with the nebula N49 in the Large Magellanic Cloud. Gas nebulae surrounding SGRs provide ideal calorimeters to tap both the impulsive and steady state energy released from these bursting sources. We discuss in this Letter a simple model of high-energy emission produced by impulsive release of relativistic particles in nebulae surrounding SGRs following bursting episodes. This nebular X-ray and gamma ray emission can be detected and monitored by ROSAT, ASCA, and the Compton Gamma Ray Observatory.

Tavani, Marco↗

Metallized Gelled Propellants: Oxygen/RP-1/Aluminum Rocket Heat Transfer and Combustion Measurements

A series of rocket engine heat transfer experiments using metallized gelled liquid propellants was conducted. These experiments used a small 20- to 40-lb/f thrust engine composed of a modular injector, igniter, chamber and nozzle. The fuels used were traditional liquid RP-1 and gelled RP-1 with 0-, 5-, and 55-percentage by weight loadings of aluminum particles. Gaseous oxygen was used as the oxidizer. Three different injectors were used during the testing: one for the baseline O(2)/RP-1 tests and two for the gelled and metallized gelled fuel firings. Heat transfer measurements were made with a rocket engine calorimeter chamber and nozzle with a total of 31 cooling channels. Each chamber used a water flow to carry heat away from the chamber and the attached thermocouples and flow meters allowed heat flux estimates at each of the 31 stations. The rocket engine Cstar efficiency for the RP-1 fuel was in the 65-69 percent range, while the gelled 0 percent by weight RP-1 and the 5-percent by weight RP-1 exhibited a Cstar efficiency range of 60 to 62% and 65 to 67%, respectively. The 55-percent by weight RP-1 fuel delivered a 42-47% Cstar efficiency. Comparisons of the heat flux and temperature profiles of the RP-1 and the metallized gelled RP-1/A1 fuels show that the peak nozzle heat fluxes with the metallized gelled O2/RP-1/A1 propellants are substantially higher than the baseline O2/RP-1: up to double the flux for the 55 percent by weight RP-1/A1 over the RP-1 fuel. Analyses showed that the heat transfer to the wall was significantly different for the RP-1/A1 at 55-percent by weight versus the RP-1 fuel. Also, a gellant and an aluminum combustion delay was inferred in the 0 percent and 5-percent by weight RP-1/A1 cases from the decrease in heat flux in the first part of the chamber. A large decrease in heat flux in the last half of the chamber was caused by fuel deposition in the chamber and nozzle. The engine combustion occurred well downstream of the injector face based on the heat flux estimates from the temperature measurements.

Palaszewski, Bryan↗