Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “CO2 Transport”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 433 records · Page 24
All sourcesNASA NTRSDOE OSTI
NASA NTRS2000

Numerical Simulation of a Chemically Reacting Sorbent Bed for LSS Applications

A detailed numerical model of a chemisorption bed has been developed. The model is based on the constant pressure mass transport equation for gaseous flow through a packed bed, and the equation for diffusion and reaction within a spherical particle. Because there is a wealth of data from the NASA and the Navy bodies of literature, the LiOH-H2O-CO2 system is chosen for application of the model and interpretation of results. Prior models of this system from the life support literature are limited. The current model incorporates many of the features of elaborate models developed for investigation of industrial systems or energy applications (e.g., coal, desulphurization): it distinguishes bulk convection and bed dispersion; mass transport to the particle surface, transport within the particle, and reaction. It uses the nonsteady (not pseudo-steady state) form of the equations. The chemistry is modeled as a multi-step, reversible reaction with evolving solid structure. The resulting system of equations is large. The ODEPACK family of solvers is used to integrate the system. Reaction coefficients are determined by experiment. Typical results of the model are illustrated with mission input parameters. Using the model, an explanation is offered for 1) the varied performance results found after pre-breathing (or after simulated pre-breathe conditions), 2) interrupted use and 3) low temperature use. In addition, options for a reusable canister are explored. The computational resource implications of adding energy equations are discussed briefly, as are applicability to other relevant space and undersea systems.

Luna, Bernadette↗
DOE OSTI2021

Can improved canopy light transmission ameliorate loss of photosynthetic efficiency in the shade? An investigation of natural variation in Sorghum bicolor

Abstract Previous studies have found that maximum quantum yield of CO2 assimilation (Φ CO2,max,app) declines in lower canopies of maize and miscanthus, a maladaptive response to self-shading. These observations were limited to single genotypes, leaving it unclear whether the maladaptive shade response is a general property of this C4 grass tribe, the Andropogoneae. We explored the generality of this maladaptation by testing the hypothesis that erect leaf forms (erectophiles), which allow more light into the lower canopy, suffer less of a decline in photosynthetic efficiency than drooping leaf (planophile) forms. On average, Φ CO2,max,app declined 27% in lower canopy leaves across 35 accessions, but the decline was over twice as great in planophiles than in erectophiles. The loss of photosynthetic efficiency involved a decoupling between electron transport and assimilation. This was not associated with increased bundle sheath leakage, based on 13C measurements. In both planophiles and erectophiles, shaded leaves had greater leaf absorptivity and lower activities of key C4 enzymes than sun leaves. The erectophile form is considered more productive because it allows a more effective distribution of light through the canopy to support photosynthesis. We show that in sorghum, it provides a second benefit, maintenance of higher Φ CO2,max,app to support efficient use of that light resource.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

A radioisotope - enabled reactive transport model for deep vadose zone carbon

In mountainous regions, which constitute the principle source of recharge to major rivers and regional aquifers, infiltration occurs through fractured, partially saturated, weathered bedrock that acts as a boundary layer between saturated aquifers and surface soil. Commonly this deep vadose zone (DVZ) is many meters thick, and yet its role in regulating the generation, retention and mobility of reactive solutes, including nutrients, contaminants and weathering products, is largely unknown. In particular, many of the key reactions that drive the formation of the weathered DVZ and the quality of water moving through it are redox processes, regulated by the availability of organic carbon and oxygen below the soil layer. The role of the DVZ is thus also poorly constrained in the context of carbon stocks and mobility, particularly in lithologies that are naturally high in organic carbon, such as shales. The overarching hypothesis of this study is that upland regions developed in geologic settings with abundant petrogenic carbon store and actively cycle carbon in the weathered DVZ below the soil and above the water table at rates that are significant and currently unconstrained. In order to quantify this cycling, the current study combines novel instrumentation techniques allowing new direct sampling of DVZ systems with advanced numerical reactive transport simulations of carbon transport and transformation. Critically, these simulations will explicitly treat the three isotopes of carbon (the abundant 12C, the stable rare 13C and the radioactive 14C) in a unified framework, thus clearly parsing between the contributions of modern surface derived carbon and lithologic carbon sources in integrated measurements of fluid and gas phase fluxes. This novel model capability will be applied to test the role of DVZ carbon cycling as a regulator of water quality and geological weathering in two complementary field sites both located in organic carbon rich shale lithologies. The first is the Eel River Critical Zone Observatory (ERCZO) in Mendocino County, California, and the second is the Lawrence Berkeley National Laboratory Watershed Function Scientific Focus Area (SFA) in the East River watershed, near Crested Butte, Colorado. At the ERCZO, a novel vadose zone monitoring system has been installed in a 20 m thick, partially saturated, weathered shale hillslope, and preliminary data already indicate substantial CO2 flux generated many meters below the soil surface. At the SFA field site, an instrumented hillslope transect indicates a more complex multi-dimensional fluid and solute transport regime, which will serve as a key test of the calibrated models. Collectively, this project will advance understanding of the cycling of carbon belowground and in relation to transport pathways across the poorly constrained DVZ characteristic of primary water recharge areas. The key product of this work will be enhanced isotope simulation capabilities that are robust and publicly available for application across a broad diversity of systems.

58 GEOSCIENCES↗
NASA NTRS2006

Role of Climate Change in Global Predictions of Future Tropospheric Ozone and Aerosols

A unified tropospheric chemistry-aerosol model within the Goddard Institute for Space Studies general circulation model II is applied to simulate an equilibrium CO2-forced climate in the year 2100 to examine the effects of climate change on global distributions of tropospheric ozone and sulfate, nitrate, ammonium, black carbon, primary organic carbon, secondary organic carbon, sea salt, and mineral dust aerosols. The year 2100 CO2 concentration as well as the anthropogenic emissions of ozone precursors and aerosols/aerosol precursors are based on the Intergovernmental Panel on Climate Change Special Report on Emissions Scenarios (SRES) A2. Year 2100 global O3 and aerosol burdens predicted with changes in both climate and emissions are generally 5-20% lower than those simulated with changes in emissions alone; as exceptions, the nitrate burden is 38% lower, and the secondary organic aerosol burden is 17% higher. Although the CO2-driven climate change alone is predicted to reduce the global O3 concentrations over or near populated and biomass burning areas because of slower transport, enhanced biogenic hydrocarbon emissions, decomposition of peroxyacetyl nitrate at higher temperatures, and the increase of O3 production by increased water vapor at high NOx levels. The warmer climate influences aerosol burdens by increasing aerosol wet deposition, altering climate-sensitive emissions, and shifting aerosol thermodynamic equilibrium. Climate change affects the estimates of the year 2100 direct radiative forcing as a result of the climate-induced changes in burdens and different climatological conditions; with full gas-aerosol coupling and accounting for ozone and direct radiative forcings by the O2, sulfate, nitrate, black carbon, and organic carbon are predicted to be +0.93, -0.72, -1.0, +1.26, and -0.56 W m(exp -2), respectively, using present-day climate and year 2100 emissions, while they are predicted to be +0.76, -0.72, 0.74, +0.97, and -0.58 W m(exp -2), respectively, with year 2100 climate and emissions.

Liao, Hong↗
DOE OSTI2022

Underground sources of drinking water chemistry changes in response to potential CO 2 leakage

The purpose of this study was to quantify changes to underground sources of drinking water (USDW) quality in response to potential CO 2 leakage from geologic CO 2 sequestration (GCS) reservoirs. Here, the developed a framework of combined laboratory experiments and reactive transport simulations and used this framework to evaluate the Ogallala aquifer overlying the Farnsworth Unit (FWU), an active GCS site, as a case study. Using chemical reaction parameters obtained from laboratory experiments and numerical simulations, site-specific mechanisms of CO 2 -water-sediment interactions at the USDW aquifer were interpreted. Long-term risks of potential CO 2 leakage were then evaluated with field-scale numerical models using the regional hydrogeological characteristics and reaction parameters obtained from our experiments and simulations. Results suggest that carbonate mineral impurity and cation exchange are key mechanisms for interactions between CO 2 and the aquifer sediment. Additionally, for a large leakage rate of 0.1 % injection from one leaky well, the leakage plume might impact an area of 300 m in diameter and significantly affect the local water quality by changing pH and cation concentrations (e.g., Zn, Ba and Sr). After leakage ceases, the zone of impacted fluids would not migrate significantly in subsequent decades due to a low regional groundwater flowrate (for this case study). The relatively small area of impact might not be detected in a monitoring well given the broader spacing in a typical field scenario. Effective early leakage detection may require additional tools, e.g., borehole CO 2 movement, four-dimensional seismicity, CO 2 soil flux, samples from deeper aquifers, etc., to ensure effective leakage detection and long-term safety of GCS projects.

58 GEOSCIENCES↗
NASA NTRS2010

Simulation and Optimization of Vacuum Swing Adsorption Units for Spacesuit Carbon Dioxide and Humidity Control

Controlling carbon dioxide (CO2) and humidity levels in a spacesuit is critical to ensuring both the safety and comfort of an astronaut during extra-vehicular activity (EVA). Traditionally, this has been accomplished utilizing non-regenerative lithium hydroxide (LiOH) or regenerative metal oxide (MetOx) canisters which pose a significant weight burden. Although such technology enables air revitalization, the volume requirements to store the waste canisters as well as the mass to transport multiple units become prohibitive as mission durations increase. Consequently, motivation exists toward developing a fully regenerative technology for environmental control. The application of solid amine materials with vacuum swing adsorption technology has shown the capacity to control CO2 and concomitantly manage humidity levels through a fully regenerative cycle eliminating mission constraints imposed with non-regenerative technologies. Experimental results for full-size and sub-scale test articles have been collected and are described herein. In order to accelerate the developmental efforts, an axially-dispersed plug ow model with an accompanying energy balance has been established and correlated with the experimental data. The experimental and simulation results display good agreement for a variety of ow rates (110-170 SLM), replicated metabolic challenges (100-590 Watts), and atmosphere pressures under consideration for the spacesuit (248 and 760 mm Hg). The relationship between swing adsorption cycles for an outlet criterion of 6.0 mm Hg of CO2 partial pressure has been established for each metabolic challenge. In addition, variable metabolic profiles were imposed on the test articles in order to assess the ability of the technology to transition to new operational constraints. The advent of the model provides the capacity to apply computer-aided engineering practices to support the ongoing efforts to optimize and mature this technology for future application to space exploration.

Swickrath, Michael J.↗
DOE OSTI2024

Towards Immobilized Proton-Coupled Electron Transfer Agents for Electrochemical Carbon Capture from Air and Seawater

Electrochemical CO 2 separation has drawn attention as a promising strategy for using renewable energy to mitigate climate change. Redox-active compounds that undergo proton-coupled electron transfer (PCET) are an impetus for pH-swing-driven CO 2 capture at low energetic costs. However, multiple barriers hinder this technology from maturing, including sensitivity to oxygen and the slow kinetics of CO 2 capture. Here, we use vapor phase chemistry to construct a textile electrode comprising an immobilized PCET agent, poly(1-aminoanthraquinone) (PAAQ), and incorporate it into redox flow cells. This design contrasts with others that use dissolved PCET agents by confining proton-storage to the surface of an electrode kept separate from an aqueous, CO 2 -capturing phase. This system facilitates carbon capture from gaseous sources (a 1% CO 2 feed and air), as well as seawater, with the latter at an energetic cost of 202 kJ/mol CO2 , and we find that quinone moieties embedded within the electrode are more stable to oxygen than dissolved counterparts. Simulations using a 1D reaction-transport model show that moderate energetic costs should be possible for air capture of CO 2 with higher loadings of polymer-bound PCET moieties. The remarkable stability of this system sets the stage for producing textile-based electrodes that facilitate pH-swing-driven carbon capture in practical situations.

Ali, Fawaz↗
NASA NTRS1974

Photoballistics of volcanic jet activity at Stromboli, Italy

Two night eruptions of the volcano Stromboli were studied through 70-mm photography. Single-camera techniques were used. Particle sphericity, constant velocity in the frame, and radial symmetry were assumed. Properties of the particulate phase found through analysis include: particle size, velocity, total number of particles ejected, angular dispersion and distribution in the jet, time variation of particle size and apparent velocity distribution, averaged volume flux, and kinetic energy carried by the condensed phase. The frequency distributions of particle size and apparent velocities are found to be approximately log normal. The properties of the gas phase were inferred from the fact that it was the transporting medium for the condensed phase. Gas velocity and time variation, volume flux of gas, dynamic pressure, mass erupted, and density were estimated. A CO2-H2O mixture is possible for the observed eruptions. The flow was subsonic. Velocity variations may be explained by an organ pipe resonance. Particle collimation may be produced by a Magnus effect.

Chouet, B.↗
NASA NTRS1985

The Martian hydrologic cycle - Effects of CO2 mass flux on global water distribution

The Martian CO2 cycle, which includes the seasonal condensation and subsequent sublimation of up to 30 percent of the planet's atmosphere, produces meridional winds due to the consequent mass flux of CO2. These winds currently display strong seasonal and hemispheric asymmetries due to the large asymmetries in the distribution of insolation on Mars. It is proposed that asymmetric meridional advection of water vapor on the planet due to these CO2 condensation winds is capable of explaining the observed dessication of Mars' south polar region at the current time. A simple model for water vapor transport is used to verify this hypothesis and to speculate on the effects of changes in orbital parameters on the seasonal water cycle.

James, P. B.↗
NASA NTRS1992

Midlatitude weather systems on Mars: Is there a hemispheric asymmetry?

The Viking Lander meteorology observations confirmed that midlatitude weather systems are present in the Northern Hemisphere of Mars during the autumn, winter, and early spring. These systems have properties consistent with a development through baroclinic instability of the wintertime zonal-mean circulation. It is known that the weather systems must be of importance for the zonal-mean circulation by virtue of their heat and momentum transports. Observations show that they are associated with dust raising, and they must be involved in the transport of dust; the weather systems almost certainly must act to produce significant water transports as well. Recent simulations with the ARC Mars General Circulation Model (GCM) show that the heat transports by the weather system (and by the zonal-mean circulation) during northern winter can be very substantial: large enough to significantly reduce the CO2 condensation at polar latitudes. This could be largely responsible for the observed early spring halt in the north polar cap recession and for the presence of westerly winds near the cap edge during this season.

Barnes, J. R.↗
NASA NTRS2011

Simulation and Optimization of Vacuum Swing Adsorption Units for Spacesuit Carbon Dioxide and Humidity Control

Controlling carbon dioxide (CO2) and humidity levels in a spacesuit is critical to ensuring both the safety and comfort of an astronaut during extra-vehicular activity (EVA). Traditionally, this has been accomplished utilizing either non-regenerative lithium hydroxide (LiOH) or regenerative but heavy metal oxide (MetOx) canisters which pose a significant weight burden. Although such technology enables air revitalization, the volume requirements to store the waste canisters as well as the mass to transport multiple units become prohibitive as mission durations increase. Consequently, motivation exists toward developing a fully regenerative technology for spacesuit environmental control. The application of solid amine materials with vacuum swing adsorption technology has shown the capacity to control CO2 while concomitantly managing humidity levels through a fully regenerative cycle eliminating constraints imposed with the traditional technologies. Prototype air revitalization units employing this technology have been fabricated in both a rectangular and cylindrical geometry. Experimental results for these test articles have been collected and are described herein. In order to accelerate the developmental efforts, an axially-dispersed plug flow model with an accompanying energy balance has been established and correlated with the experimental data. The experimental and simulation results display good agreement for a variety of flow rates (110-170 ALM), replicated metabolic challenges (100-590 Watts), and atmosphere pressures under consideration for the spacesuit (248 and 760 mm Hg). The testing and model results lend insight into the operational capabilities of these devices as well as the influence the geometry of the device has on performance. In addition, variable metabolic profiles were imposed on the test articles in order to assess the ability of the technology to transition to new metabolic conditions. The advent of the model provides the capacity to apply computer-aided engineering practices to support the ongoing efforts to optimize and mature this technology for future application to space exploration.

Swickrath, Michael J.↗
NASA NTRS2007

Quantifying the Impact of the North American Monsoon and Deep Midlatitude Convection on the Subtropical Lowermost Stratosphere using in Situ Measurements

The chemical composition of the lowermost stratosphere exhibits both spatial and temporal variability depending upon the relative strength of (1) isentropic transport from the tropical tropopause layer (TTL), (2) diabatic descent from the midlatitude and northern midlatitude stratosphere followed by equatorward isentropic transport, and (3) diabatic ascent from the troposphere through convection. In situ measurements made in the lowermost stratosphere over Florida illustrate the additional impact of equatorward flow around the monsoon anticyclone. This flow carries, along with older stratospheric air, the distinct signature of deep midlatitude convection. We use simultaneous in situ measurements of water vapor (H2O), ozone (O3), total odd nitrogen (NOy), carbon dioxide (CO2), and carbon monoxide (CO) in the framework of a simple box model to quantify the composition of the air sampled in the lowermost stratosphere during the mission on the basis of tracer mixing ratios ascribed to the source regions for these transport pathways. The results show that in the summer, convection has a significant impact on the composition of air in the lowermost stratosphere, being the dominant source of water vapor up to the 380 K isentrope. The implications of these results extend from the potential for heterogeneous ozone loss resulting from the increased frequency and lifetime of cirrus near the local tropopause, to air with increased water vapor that as part of the equatorward flow associated with the North American monsoon can become part of the general circulation.

Weinstock, E. M.↗
NASA NTRS2020

Causes of slowing‐down seasonal CO2 amplitude at Mauna Loa

Changing amplitude of the seasonal cycle of atmospheric CO2 (SCA) in the northern hemisphere is an emerging carbon cycle property. Mauna Loa (MLO) station (20°N, 156°W), which has the longest continuous northern hemisphere CO2 record, shows an increasing SCA before the 1980s (p < .01), followed by no significant change thereafter. We analyzed the potential driving factors of SCA slowing‐down, with an ensemble of dynamic global vegetation models (DGVMs) coupled with an atmospheric transport model. We found that slowing‐down of SCA at MLO is primarily explained by response of net biome productivity (NBP) to climate change, and by changes in atmospheric circulations. Through NBP, climate change increases SCA at MLO before the 1980s and decreases it afterwards. The effect of climate change on the slowing‐down of SCA at MLO is mainly exerted by intensified drought stress acting to offset the acceleration driven by CO2 fertilization. This challenges the view that CO2 fertilization is the dominant cause of emergent SCA trends at northern sites south of 40°N. The contribution of agricultural intensification on the deceleration of SCA at MLO was elusive according to land–atmosphere CO2 flux estimated by DGVMs and atmospheric inversions. Our results also show the necessity to adequately account for changing circulation patterns in understanding carbon cycle dynamics observed from atmospheric observations and in using these observations to benchmark DGVMs.

Mauna Loa↗
NASA NTRS1979

The effect of energetically produced O2/+/ on the ion temperatures of the Martian thermosphere

The heating rates and ion temperatures of the Martian thermosphere resulting from the thermalization of the energetic O2(+) ions produced by the reactions of the solar ionization products CO2(+) and O(+) with neutral particles are calculated and the effects of small magnetic fields on the ion thermal balance are investigated. The energy transfer and transport of energetic ions is modelled by solving the continuity equation for the ions over a series of finite energy cells yielding the equilibrium densities as a function of energy and altitude. Particles which are able to proceed upwards without collisions are dealt with separately from the continuity equation. It is shown that the thermalization of the energetic O2(+) ions can greatly increase ion temperatures above 200 km compared to those calculated for only ambient electron heating. Current solar wind interaction models predict that small horizontal magnetic fields act to restrict the ion thermal conductivity and to increase upper altitude ion temperatures. The combined effects of these processes provide a partial agreement with measurements made by Viking 1.

Rohrbaugh, R. P.↗
NASA NTRS1989

Conceptual design study for Infrared Limb Experiment (IRLE)

The phase A engineering design study for the Infrared Limb Experiment (IRLE) instrument, the infrared portion of the Mesosphere-Lower Thermosphere Explorer (MELTER) satellite payload is given. The IRLE instrument is a satellite instrument, based on the heritage of the Limb Infrared Monitor of the Stratosphere (LIMS) program, that will make global measurements of O3, CO2, NO, NO2, H2O, and OH from earth limb emissions. These measurements will be used to provide improved understanding of the photochemistry, radiation, dynamics, energetics, and transport phenomena in the lower thermosphere, mesosphere, and stratosphere. The IRLE instrument is the infrared portion of the MELTER satellite payload. MELTER is being proposed to NASA Goddard by a consortium consisting of the University of Michigan, University of Colorado and NASA Langley. It is proposed that the Space Dynamics Laboratory at Utah State University (SDL/USU) build the IRLE instrument for NASA Langley. MELTER is scheduled for launch in November 1994 into a sun-synchronous, 650-km circular orbit with an inclination angle of 97.8 deg and an ascending node at 3:00 p.m. local time.

Baker, Doran J.↗
NASA NTRS1993

The Mars water cycle at other epochs - Recent history of the polar caps and layered terrain

A numerical model is presented of the integrated role of seasonal water cycle on the evolution of polar deposits on Mars over the last 10 million years. From the model, it is concluded that the only major difference between the polar caps which affects their long-term behavior is ultimately the difference in their elevations. Because of that difference, there is a preference for CO2 frost to stay longer on the northern polar cap. The average difference in sublimation at the caps results in a net south-to-north transport of water ice over long time scales. Superimposed on any long-term behavior is a transfer of water ice between the caps on the 10 exp 5 - 10 exp 6 yr time scales. The amount of water exchanged is small compared to the total ice content of the polar deposits.

Jakosky, Bruce M.↗
NASA NTRS1993

Requirements for the early atmosphere of Mars from nitrogen isotope ratios

The N escape models of Fox and Dalgarno and Fox required the presence of a dense, early CO2 atmosphere to inhibit fractionation of the N isotopes N-15 and N-14. The computed photochemical escape fluxes are so large at the present that the isotope ratio measured by Viking (about 1.62x terrestrial) can be produced in about 1.5 b.y. This model was refined in several ways. It was updated to incorporate the variation of the escape fluxes with increases in the solar fluxes at earlier times according to the model of Zahnle and Walker. As expected, this exacerbates the problem with overfractionation, but not greatly. Most of the escape and fractionation of the N occurs in the last 1.5 b.y., when the solar flux was only slightly different from the present. The dense early atmosphere must persist only a bit longer in order to reproduce the measured isotope ratio. The model was also modified to take into account changes in the O mixing ratio with time in the past, assuming that the O abundance is proportional to the square root of the solar flux. Although the production rate of O from photodissociation of CO2 scales as the solar flux, the strength of the winds and other mixing processes also increases with the solar flux, resulting in possibly more effective transport of O to the lower atmosphere where it is destroyed by catalytic and three-body recombination mechanisms.

Fox, J. L.↗