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At least 433 records · Page 24

Sandia National Laboratories, California Chemical Management Program Annual Report

The annual program report provides detailed information about all aspects of the Sandia National Laboratories, California (SNL/CA) Chemical Management Program. It functions as supporting documentation to the SNL/CA Environmental Management System Program Manual. This program annual report describes the activities undertaken during the calender past year, and activities planned in future years to implement the Chemical Management Program, one of six programs that supports environmental management at SNL/CA. SNL/CA is responsible for tracking chemicals (chemical and biological materials), providing Material Safety Data Sheets (MSDS) and for regulatory compliance reporting according to a variety of chemical regulations. The principal regulations for chemical tracking are the Emergency Planning Community Right-to-Know Act (EPCRA) and the California Right-to-Know regulations. The regulations, the Hazard Communication/Lab Standard of the Occupational Safety and Health Administration (OSHA) are also key to the CM Program. The CM Program is also responsible for supporting chemical safety and information requirements for a variety of Integrated Enabling Services (IMS) programs primarily the Industrial Hygiene, Waste Management, Fire Protection, Air Quality, Emergency Management, Environmental Monitoring and Pollution Prevention programs. The principal program tool is the Chemical Information System (CIS). The system contains two key elements: the MSDS library and the chemical container-tracking database that is readily accessible to all Members of the Sandia Workforce. The primary goal of the CM Program is to ensure safe and effective chemical management at Sandia/CA. This is done by efficiently collecting and managing chemical information for our customers who include Line, regulators, DOE and ES and H programs to ensure compliance with regulations and to streamline customer business processes that require chemical information.

54 ENVIRONMENTAL SCIENCES↗

Characteristics of Range Hoods in California Homes -- Data Collected from a Real Estate Web Site

Venting range hoods are important residential ventilation components that remove pollutants generated by cooking activities and natural gas cooking burners. To address the lack of data on range hood installations in California, we conducted a survey by examining photographs of homes for sale or rent listed on a popular real estate web site. The survey was conducted in November 2010 and April–May 2011. Posted photos of the homes were reviewed to determine if a hood was installed, the type of hood, and two installation details that can impact performance, namely the height above the cooktop and the degree to which the hood covers the cooktop burners. We additionally collected information about the homes, including asking price for purchase or rent, type of building (e.g. detached house, townhouse or apartment), building age, floor area, and cooktop fuel type. Listings were first sampled to focus on homes built since 2005, then randomly sampled to include varied prices and locations around the state. Data were obtained for 1002 homes built between 1865 and 2011 (median year built 1989). Homes for sale varied in asking price from $\$$16,000 to $\$$16,500,000 (median $\$$353,000) and homes for rent varied from $\$$500 to $\$$25,000 (median $\$$2125) per month. Approximately 74% of the sample had natural gas cooktops. In this sample, natural gas cooktops were more prevalent in more expensive homes than in less expensive homes. Across the entire sample, 7.4 % appeared to have no hood installed, 33% had a short hood, 13% had a deep hood and 47% had a microwave over the range. The percentage of these hoods that vent to the outdoors could not be determined. Hood type was related to coverage of the cooktop. For deep hoods, 76% appeared to cover most or all of the cooktop burners. For short hoods, 70% covered about three quarters of the cooktop. And for microwaves the vast majority (96%) covered the back burners but not the front burners. Hood type was also correlated with asking price or monthly rent, with deep hoods most common in the most expensive homes. Hood type was also correlated with home age, with microwave hoods more common in newer homes. Installation height was related to device type with microwaves installed lower (closer) to the cooktop (median 18 inches), and short hoods (median 28 inches) and deep hoods (median 30 inches) installed higher. Deep range hoods are more common with natural gas cooktops than with electric cooktops, and slightly fewer homes with natural gas cooktops lack a range hood (7%) than homes with electric cooktops (9%). This study provides limited but useful information about the characteristics of range hoods in California homes and demonstrates the potential value of non-traditional forms of data collection.

54 ENVIRONMENTAL SCIENCES↗

Analysis of Concentrating Solar Power with Thermal Energy Storage in a California 33% Renewable Scenario

This analysis evaluates CSP with TES in a scenario where California derives 33% of its electricity from renewable energy sources. It uses a commercial grid simulation tool to examine the avoided operational and capacity costs associated with CSP and compares this value to PV and a baseload generation with constant output. Overall, the analysis demonstrates several properties of dispatchable CSP, including the flexibility to generate during periods of high value and avoid generation during periods of lower value. Of note in this analysis is the fact that significant amount of operational value is derived from the provision of reserves in the case where CSP is allowed to provide these services. This analysis also indicates that the 'optimal' configuration of CSP could vary as a function of renewable penetration, and each configuration will need to be evaluated in terms of its ability to provide dispatchable energy, reserves, and firm capacity. The model can be used to investigate additional scenarios involving alternative technology options and generation mixes, applying these scenarios within California or in other regions of interest.

14 SOLAR ENERGY↗

Data Measured on Water Collected from Fall River Springs, California

In October 1997 field collection of water emerging from large volume springs located at the headwater of Fall River in northeastern California resulted in the measurement of stable isotope, radiocarbon, tritium, and dissolved noble gases. This work was follow-on to previous studies on similar spring systems in Hat Creek Valley and surrounding Mt. Shasta in northern California (Rose and Davisson, 1996; Rose et al., 1996; Davisson and Rose, 1997). The data for Fall River springs was never formally published and is therefore tabulated in Table 1 in order to be recorded in public record. These studies, along with many parallel and subsequent ones using isotopes and elemental concentrations, are all related to the general research area of tracing sources and quantifying transport times of natural and man-made materials in the environment. This type of research has direct relevance in characterizing environmental contamination, understanding resource development and protection, designing early detection in WMD related terrorism, and application in forensics analysis.

07 ISOTOPE AND RADIATION SOURCES↗

California GAMA Special Study: Stable Isotopic Composition of Boron in Groundwater - San Diego County Domestic Well Data

The Groundwater Ambient Monitoring and Assessment (GAMA) Program is a comprehensive groundwater quality monitoring program for the state of California. Managed by the California State Water Resources Control Board (SWRCB), the goals of the Program are twofold: to improve statewide groundwater monitoring, and to increase the availability of groundwater quality information to the public. The Domestic Well Project has sampled 137 wells in San Diego County in an effort to assess the quality of these unregulated domestic use water sources. Lawrence Livermore National Laboratory (LLNL) performed isotopic analyses of domestic well water samples for the SWRCB; this study summarizes the results of measurements of the isotopic composition of dissolved boron in groundwater in 56 wells, and provides some interpretations regarding the significance of these findings. These data, in conjunction with water and nitrate isotopic composition data (Singleton et al., 2010), are useful for determining the source(s) of nitrate in potentially-contaminated San Diego County groundwater reservoirs. The isotopic composition of dissolved boron (δ 11 B) in sampled San Diego County groundwaters varies from -0.8 to +64.4 ‰. Most sampled groundwaters (44 of 56) have δ 11 B values between +20 and +50 ‰, within the isotopic composition range characteristic of animal manure. These samples tend to have high nitrate concentrations (>50 mg/L as NO 3 ) These results are consistent with isotopic composition of nitrogen in nitrate (δ 15 N) data from Singleton et al. (2010), indicating that animal manure is a primary source of nitrate in most groundwaters measured in this study. Seven samples have δ 11 B values less than +20 ‰, outside of the animal manure δ 11 B range. These groundwaters tend to have low nitrate concentrations(<10 mg/L as NO 3 ), although two have nitrate concentrations greater than 10 mg/L, suggesting that wastewater may partially contribute to their nitrate budget. No samples measured in this study have boron or nitrate isotopic compositions consistent with a mineral fertilizer nitrate source. Five sampled groundwaters have δ 11 B values greater than +50 ‰, significantly higher than any known anthropogenic boron source. More work is needed to assess the source of nitrate and boron in the greater than +50 ‰ groundwaters.

07 ISOTOPE AND RADIATION SOURCES↗

Analysis of Open Automated Demand Response Deployments in California and Guidelines to Transition to Industry Standards

This report reviews the Open Automated Demand Response (OpenADR) deployments within the territories serviced by California's investor-owned utilities (IOUs) and the transition from the OpenADR 1.0 specification to the formal standard?OpenADR 2.0. As demand response service providers and customers start adopting OpenADR 2.0, it is necessary to ensure that the existing Automated Demand Response (AutoDR) infrastructure investment continues to be useful and takes advantage of the formal standard and its many benefits. This study focused on OpenADR deployments and systems used by the California IOUs and included a summary of the OpenADR deployment from the U.S. Department of Energy-funded demonstration conducted by the Sacramento Municipal Utility District (SMUD). Lawrence Berkeley National Laboratory collected and analyzed data about OpenADR 1.0 deployments, categorized architectures, developed a data model mapping to understand the technical compatibility of each version, and compared the capabilities and features of the two specifications. The findings, for the first time, provided evidence of the total enabled load shed and average first cost for system enablement in the IOU and SMUD service territories. The OpenADR 2.0a profile specification semantically supports AutoDR system architectures and data propagation with a testing and certification program that promotes interoperability, scaled deployments by multiple vendors, and provides additional features that support future services.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Site environmental report for 2013. Sandia National Laboratories, California.

Sandia National Laboratories (SNL) is one of three national laboratories supporting the United States Department of Energy (DOE) statutory responsibilities for nuclear weapon research and design, development of energy technologies, and basic scientific research. SNL facilities are located in New Mexico, California, Nevada, and Hawaii. Sandia National Laboratories, California (SNL/CA) is a multi-program engineering and science laboratory supporting the nuclear weapons stockpile program, energy and environment research, homeland security, micro- and nano-technologies, and basic science and engineering research.

Larsen, Barbara L.↗

Pollutant Exposures from Natural Gas Cooking Burners: A Simulation-Based Assessment for Southern California

Residential natural gas cooking burners (NGCBs) can emit substantial quantities of pollutants and they are typically used without venting. The objective of this study is to quantify pollutant concentrations and occupant exposures resulting from NGCB use in California homes. A mass balance model was applied to estimate time-dependent pollutant concentrations throughout homes and the "exposure concentrations" experienced by individual occupants. The model was applied to estimate nitrogen dioxide (NO{sub 2}), carbon monoxide (CO), and formaldehyde (HCHO) concentrations for one week each in summer and winter for a representative sample of Southern California homes. The model simulated pollutant emissions from NGCBs, NO{sub 2} and CO entry from outdoors, dilution throughout the home, and removal by ventilation and deposition. Residence characteristics and outdoor concentrations of CO and NO{sub 2} were obtained from available databases. Ventilation rates, occupancy patterns, and burner use were inferred from household characteristics. Proximity to the burner(s) and the benefits of using venting range hoods were also explored. Replicate model executions using independently generated sets of stochastic variable values yielded estimated pollutant concentration distributions with geometric means varying less than 10%. The simulation model estimates that in homes using NGCBs without coincident use of venting range hoods, 62%, 9%, and 53% of occupants are routinely exposed to NO{sub 2}, CO, and HCHO levels that exceed acute health-based standards and guidelines. NGCB use increased the sample median of the highest simulated 1-hr indoor concentrations by 100, 3000, and 20 ppb for NO{sub 2}, CO, and HCHO, respectively. Reducing pollutant exposures from NGCBs should be a public health priority. Simulation results suggest that regular use of even moderately effective venting range hoods would dramatically reduce the percentage of homes in which concentrations exceed health-based standards.

03 NATURAL GAS↗

Encouraging Combined Heat and Power in California Buildings

Governor Brown’s research priorities include an additional 6.5 GW of combined heat and power (CHP) by 2030. As of 2009, roughly 0.25 GW of small natural gas and biogas fired CHP is documented by the Self-Generation Incentive Program (SGIP) database. The SGIP is set to expire, and the anticipated grid de-carbonization based on the development of 20 GW of renewable energy will influence the CHP adoption. Thus, an integrated optimization approach for this analysis was chosen that allows optimizing the adoption of distributed energy resources (DER) such as photovoltaics (PV), CHP, storage technologies, etc. in the California commercial sector from the building owners’ perspective. To solve this DER adoption problem the Distributed Energy Resources Customer Adoption Model (DER-CAM), developed by the Lawrence Berkeley National Laboratory and used extensively to address the problem of optimally investing and scheduling DER under multiple settings, has been used. The application of CHP at large industrial sites is well known, and much of its potential is already being realized. Conversely, commercial sector CHP, especially those above 50 to 100 kW peak electricity load, is widely overlooked. In order to analyze the role of DER in CO 2 reduction, 147 representative sites in different climate zones were selected from the California Commercial End Use Survey (CEUS). About 8000 individual optimization runs, with different assumptions for the electric tariffs, natural gas costs, marginal grid CO 2 emissions, and nitrogen oxide treatment costs, SGIP, fuel cell lifetime, fuel cell efficiency, PV installation costs, and payback periods for investments have been performed. The most optimistic CHP potential contribution in this sector in 2020 will be 2.7 GW. However, this result requires a SGIP in 2020, 46% average electric efficiency for fuel cells, a payback period for investments of 10 years, and a CO 2 focused approach of the building owners. In 2030 it will be only 2.5 GW due to the anticipated grid decarbonization. The 2030 result requires a 60% electric efficiency and 20 year life time for fuel cells, a payback period of 10 years, and a CO 2 minimization strategy of building owners. Finally, the possible CHP potential in 2030 shows a significant variance between 0.2 GW and 2.5 GW, demonstrating the complex interactions between technologies, policies, and customer objectives.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Clustering Method and Representative Feeder Selection for the California Solar Initiative

The screening process for DG interconnection procedures needs to be improved in order to increase the PV deployment level on the distribution grid. A significant improvement in the current screening process could be achieved by finding a method to classify the feeders in a utility service territory and determine the sensitivity of particular groups of distribution feeders to the impacts of high PV deployment levels. This report describes the utility distribution feeder characteristics in California for a large dataset of 8,163 feeders and summarizes the California feeder population including the range of characteristics identified and most important to hosting capacity. The report describes the set of feeders that are identified for modeling and analysis as well as feeders identified for the control group. The report presents a method for separating a utility's distribution feeders into unique clusters using the k-means clustering algorithm. An approach for determining the feeder variables of interest for use in a clustering algorithm is also described. The report presents an approach for choosing the feeder variables to be utilized in the clustering process and a method is identified for determining the optimal number of representative clusters.

14 SOLAR ENERGY↗

System Dynamics of the Competition of Municipal Solid Waste to Landfill, Electricity, and Liquid Fuel in California

A quantitative system dynamics model was created to evaluate the economic and environmental tradeoffs between biomass to electricity and to liquid fuel using MSW biomass in the state of California as a case study. From an environmental perspective, landfilling represents the worst use of MSW over time, generating more greenhouse gas (GHG) emissions compared to converting MSW to liquid fuel or to electricity. MSW to ethanol results in the greatest displacement of GHG emissions per dollar spent compared to MSW to electricity. MSW to ethanol could save the state of California approximately $60 billion in energy costs by 2050 compared to landfilling, while also reducing GHG emissions state-wide by approximately 140 million metric tons during that timeframe. MSW conversion to electricity creates a significant cost within the state's electricity sector, although some conversion technologies are cost competitive with existing renewable generation.

09 BIOMASS FUELS↗

Balancing energy conservation and occupant needs in ventilation rate standards for Big Box stores and other commercial buildings in California. Issues related to the ASHRAE 62.1 Indoor Air Quality Procedure

This report considers the question of whether the California Energy Commission should incorporate the ASHRAE 62.1 ventilation standard into the Title 24 ventilation rate (VR) standards, thus allowing buildings to follow the Indoor Air Quality Procedure. This, in contrast to the current prescriptive standard, allows the option of using ventilation rate as one of several strategies, which might include source reduction and air cleaning, to meet specified targets of indoor air concentrations and occupant acceptability. The research findings reviewed in this report suggest that a revised approach to a ventilation standard for commercial buildings is necessary, because the current prescriptive ASHRAE 62.1 Ventilation Rate Procedure (VRP) apparently does not provide occupants with either sufficiently acceptable or sufficiently healthprotective air quality. One possible solution would be a dramatic increase in the minimum ventilation rates (VRs) prescribed by a VRP. This solution, however, is not feasible for at least three reasons: the current need to reduce energy use rather than increase it further, the problem of polluted outdoor air in many cities, and the apparent limited ability of increasing VRs to reduce all indoor airborne contaminants of concern (per Hodgson (2003)). Any feasible solution is thus likely to include methods of pollutant reduction other than increased outdoor air ventilation; e.g., source reduction or air cleaning. The alternative 62.1 Indoor Air Quality Procedure (IAQP) offers multiple possible benefits in this direction over the VRP, but seems too limited by insufficient specifications and inadequate available data to provide adequate protection for occupants. Ventilation system designers rarely choose to use it, finding it too arbitrary and requiring use of much non-engineering judgment and information that is not readily available. This report suggests strategies to revise the current ASHRAE IAQP to reduce its current limitations. These strategies, however, would make it more complex and more prescriptive, and would require substantial research. One practical intermediate strategy to save energy would be an alternate VRP, allowing VRs lower than currently prescribed, as long as indoor VOC concentrations were no higher than with VRs prescribed under the current VRP. This kind of hybrid, with source reduction and use of air cleaning optional but permitted, could eventually evolve, as data, materials, and air-cleaning technology allowed gradual lowering of allowable concentrations, into a fully developed IAQP. Ultimately, it seems that VR standards must evolve to resemble the IAQP, especially in California, where buildings must achieve zero net energy use within 20 years.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Opportunities for Automated Demand Response in California’s Dairy Processing Industry

During periods of peak electrical demand on the energy grid or when there is a shortage of supply, the stability of the grid may be compromised or the cost of supplying electricity may rise dramatically, respectively. Demand response programs are designed to mitigate the severity of these problems and improve reliability by reducing the demand on the grid during such critical times. In 2010, the Demand Response Research Center convened a group of industry experts to suggest potential industries that would be good demand response program candidates for further review. The dairy industry was suggested due to the perception that the industry had suitable flexibility and automatic controls in place. The purpose of this report is to provide an initial description of the industry with regard to demand response potential, specifically automated demand response. This report qualitatively describes the potential for participation in demand response and automated demand response by dairy processing facilities in California, as well as barriers to widespread participation. The report first describes the magnitude, timing, location, purpose, and manner of energy use. Typical process equipment and controls are discussed, as well as common impediments to participation in demand response and automated demand response programs. Two case studies of demand response at dairy facilities in California and across the country are reviewed. Finally, recommendations are made for future research that can enhance the understanding of demand response potential in this industry.

25 ENERGY STORAGE↗

University of California, San Diego (UCSD) Sky Imager Cloud Position Study Field Campaign Report

During the University of California, San Diego (UCSD) Sky Imager Cloud Position Study, two University of California, San Diego Sky Imagers (USI) (Figure 1) were deployed the U.S. Department of Energy(DOE)’s Atmospheric Radiation Measurement (ARM) Climate Research Facility Southern Great Plains SGP) research facility. The UCSD Sky Imagers were placed 1.7 km apart to allow for stereographic determination of the cloud height for clouds over approximately 1.5 km. Images with a 180-degree field of view were captured from both systems during daylight hours every 30 seconds beginning on March 11, 2013 and ending on November 4, 2013. The spatial resolution of the images was 1,748 × 1,748, and the intensity resolution was 16 bits using a high-dynamic-range capture process. The cameras use a fisheye lens, so the images are distorted following an equisolid angle projection.

58 GEOSCIENCES↗

Measured performance of filtration and ventilation systems for fine and ultrafine particles and ozone in an unoccupied modern California house

This study evaluated nine ventilation and filtration systems in an unoccupied 2006 house located 250m downwind of the I-80 freeway in Sacramento, California. Systems were evaluated for reducing indoor concentrations of outdoor particles in summer and fall/winter, ozone in summer, and particles from stir-fry cooking. Air exchange rate was measured continuously. Energy use was estimated for year-round operation in California. Exhaust ventilation without enhanced filtration produced indoor PM 2.5 that was 70% lower than outdoors. Supply ventilation with MERV13 filtration provided slightly less protection whereas supply MERV16 filtration reduced PM 2.5 5 by 97-98% relative to outdoors. Supply filtration systems used little energy but provided no benefits for indoor-generated particles. Systems with MERV13-16 filters in the recirculating heating and cooling unit (FAU) operating continuously or 20 min/h reduced PM 2.5 by 93-98%. Across all systems, removal percentages were higher for ultrafine particles and lower for black carbon, relative to PM 2.5 . Indoor ozone was 3-4% of outdoors for all systems except an electronic air cleaner that produced ozone. Filtration via the FAU or portable filtration units lowered PM 2.5 by 25-75% when operated over the hour following cooking. The energy for year-round operation of FAU filtration with an efficient blower motor was estimated at 600 kWh/year.

54 ENVIRONMENTAL SCIENCES↗

Comparative Evaluation of Financing Programs: Insights From California’s Experience

Berkeley Lab examines criteria for a comparative assessment of multiple financing programs for energy efficiency, developed through a statewide public process in California. The state legislature directed the California Alternative Energy and Advanced Transportation Financing Authority (CAEATFA) to develop these criteria. CAEATFA's report to the legislature, an invaluable reference for other jurisdictions considering these topics, discusses the proposed criteria and the rationales behind them in detail. Berkeley Lab's brief focuses on several salient issues that emerged during the criteria development and discussion process. Many of these issues are likely to arise in other states that plan to evaluate the impacts of energy efficiency financing programs, whether for a single program or multiple programs. Issues discussed in the brief include: -The stakeholder process to develop the proposed assessment criteria -Attribution of outcomes - such as energy savings - to financing programs vs. other drivers -Choosing the outcome metric of primary interest: program take-up levels vs. savings -The use of net benefits vs. benefit-cost ratios for cost-effectiveness evaluation -Non-energy factors -Consumer protection factors -Market transformation impacts -Accommodating varying program goals in a multi-program evaluation -Accounting for costs and risks borne by various parties, including taxpayers and utility customers, in cost-effectiveness analysis -How to account for potential synergies among programs in a multi-program evaluation

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

The Potential for Energy Storage to Provide Peaking Capacity in California Under Increased Penetration of Solar Photovoltaics

In this report, we examine the potential for replacing conventional peaking capacity in California with energy storage, including analysis of the changing technical potential with increased storage deployment and the effect of PV deployment. We examine nine years of historic load data, a range of storage durations (2-8 hours), and a range of PV penetration levels (0%-30%). We demonstrate how PV increases the ability of storage to reduce peak net demand. In the scenarios analyzed, the expected penetration of PV in California in 2020 could more than double the potential for 4-hour energy storage to provide capacity services.

14 SOLAR ENERGY↗

California Plug-In Electric Vehicle Infrastructure Projections: 2017-2025 - Future Infrastructure Needs for Reaching the State's Zero Emission-Vehicle Deployment Goals

This report analyzes plug-in electric vehicle (PEV) infrastructure needs in California from 2017 to 2025 in a scenario where the State's zero-emission vehicle (ZEV) deployment goals are achieved by household vehicles. The statewide infrastructure needs are evaluated by using the Electric Vehicle Infrastructure Projection tool, which incorporates representative statewide travel data from the 2012 California Household Travel Survey. The infrastructure solution presented in this assessment addresses two primary objectives: (1) enabling travel for battery electric vehicles and (2) maximizing the electric vehicle-miles traveled for plug-in hybrid electric vehicles. The analysis is performed at the county-level for each year between 2017 and 2025 while considering potential technology improvements. The results from this study present an infrastructure solution that can facilitate market growth for PEVs to reach the State's ZEV goals by 2025. The overall results show a need for 99k-130k destination chargers, including workplaces and public locations, and 9k-25k fast chargers. The results also show a need for dedicated or shared residential charging solutions at multi-family dwellings, which are expected to host about 120k PEVs by 2025. An improvement to the scientific literature, this analysis presents the significance of infrastructure reliability and accessibility on the quantification of charger demand.

33 ADVANCED PROPULSION SYSTEMS↗