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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 415 records · Page 23
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Midwest Regional Carbon Conversion/Utilization Procurement Grant Workshop

https://events.usea.org/events/midwest-regional-carbon-conversionutilization-procurement-grant-workshop As the U.S. economy moves toward clean energy and a lower carbon future, the U.S. Department of Energy (DOE) is seeking to partner with states, communities, and industries to support the procurement and development of carbon conversion products. These efforts have been enabled by provisions included in the Bipartisan Infrastructure Law (BIL). As part of the BIL, supporting the Administration’s goal to achieve a carbon-free power sector by 2035 and putting the United States on a path to a net-zero economy by 2050, a new initiative was established within DOE’s Office of Fossil Energy and Carbon Management through its Carbon Conversion/Utilization Program. The new initiative will establish a demonstration grant program to issue grants to eligible entities to procure commercial and industrial products derived from the conversion of anthropogenic carbon oxides and demonstrate a significant net reduction in life cycle greenhouse gas emissions compared to incumbent technologies, processes, and products. DOE-FECM will establish a demonstration grant program within the Carbon Conversion/Utilization Program to support eligible applicants that procure those commercial and industrial products derived from anthropogenic carbon oxides. Therefore, the Carbon Conversion/Utilization Program, with the assistance of the United States Energy Association (USEA), will conduct a series of workshops (both virtual and in-person) with relevant stakeholders, e.g., product manufacturers, eligible entities, or their representative national organizations (e.g., United States Conference of Mayors, etc.) to solicit input and ideas on challenges and opportunities for a potential grant program.

Larimore, Ryan↗
DOE OSTI2024

Comparing net zero pathways across the Atlantic A model inter-comparison exercise between the Energy Modeling Forum 37 and the European Climate and Energy Modeling Forum

Europe and North America account for 32 % of current carbon emissions. Due to distinct legacy systems, energy infrastructure, socioeconomic development, and energy resource endowment, both regions have different policy and technological pathways to reach net zero by the mid-century. Against this background, our paper examines the results from the net zero emission scenarios for Europe and North America that emerged from the collaboration of the European and American Energy Modeling Forums. Here, in our analysis, we perform an inter-comparison of various integrated assessments and bottom-up energy system models. A clear qualitative consensus emerges on five main points. First, Europe and the United States reach net zero targets with electrification, demand-side reductions, and carbon capture and sequestration technologies. Second, the use of carbon capture and sequestration is more predominant in the United States due to a steeper decarbonization schedule. Third, the buildings sector is the easiest to electrify in both regions. Fourth, the industrial sector is the hardest to electrify in the United States and transportation in Europe. Fifth, in both regions, the transition in the energy mix is driven by the substitution of coal and natural gas with solar and wind, but to a different extent.

100 % renewables↗
DOE OSTI2022

Which “second-best” climate policies are best? Simulating cost-effective policy mixes for passenger vehicles

In the real-world of political opposition and complex market failures, carbon pricing alone will not achieve deep GHG mitigation targets. Hence, in this study, we search for the most cost-effective “second-best” policies. Focusing on the light-duty vehicle sector in the case of Canada, we compare several policies in terms of effectiveness (regarding 2030 GHG goals) and mitigation costs, namely: (i) a carbon tax; (ii) a vehicle emission standard (or VES); (iii) a zero emissions vehicle (ZEV) mandate, and (iv) combinations of all three at various stringencies. In this effort, we apply the AUtomaker-consumer Model (AUM), which endogenously simulates consumer and automaker decisions and technological change. Comparing individual policies, the regulations are about three times more expensive than the carbon tax. Among “second-best” policies, the VES is cheaper than a ZEV mandate at lower stringencies, but at higher stringencies the two are similarly efficient (both incentivize widespread ZEV deployment). In policy mixes, cost-effectiveness is improved by a carbon tax. Specifically, inclusion of a CDN$100–150/tonne tax can achieve targets while being 30–40% less costly than a regulation alone. We suggest that policymakers implement carbon pricing as stringently as politically feasible (for efficiency), complemented by regulations as needed (for efficacy) to meet GHG targets.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2020

Impact of Backbone Rigidity on the Thermomechanical Properties of Semiconducting Polymers with Conjugation Break Spacers

There remains a lack of fundamental understanding in theroleofbackbonerigidityonthe thermomechanical properties of conjugated polymers. Here, we provide the first holistic approach to understand the fundamental influence of backbone rigidity on an n-type naphthalene diimide-based conjugated polymer, denoted by PNDI-Cx, through insertion of a flexible conjugation break spacer (CBS). CBS lengths are varied from fully conjugated with zero alkyl spacer (PNDI-C0) to a seven- carbon alkyl spacer (PNDI-C 7 ), with the CBS engineered into each repeat unit for systematic evaluation. Solution small-angle neutron scattering and oscillatory shear rheometry were employed to provide the first quantitative evidence of CBS influence over conjugated polymer chain rigidity and entanglement molecular weight (M e ), demonstrating a reduction in the Kuhn length from 521 to 36 Å for fully conjugated PNDI-C0 and PNDI-C6, respectively, as well as a nearly consistent Me of ~15 kDa upon the addition of CBS. Thermomechanical properties, such as elastic modulus and glass-transition temperature, were shown to decrease with an increasing length of CBS. An extraordinary ductility, upwards of 400% tensile strain before fracture, was observed for high-molecular-weight PNDI-C4, which we attribute to a high number of entanglements and disruption of crystallization. Furthermore, the deformation mechanism for PNDI-Cx was studied under strain through X-ray diffraction, polarized UV-vis spectroscopy, and atomic force microscopy. Overall, this work sheds light on the important role of backbone rigidity in designing flexible and stretchable conjugated polymers.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Quantum vibronic effects on the electronic properties of solid and molecular carbon

Here, we study the effect of quantum vibronic coupling on the electronic properties of carbon allotropes, including molecules and solids, by combining path integral first principles molecular dynamics (FPMD) with a colored noise thermostat. In addition to avoiding several approximations commonly adopted in calculations of electron-phonon coupling, our approach only adds a moderate computational cost to FPMD simulations and hence it is applicable to large supercells, such as those required to describe amorphous solids. We predict the effect of electron-phonon coupling on the fundamental gap of amorphous carbon, and we show that in diamond the zero-phonon renormalization of the band gap is larger than previously reported.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on CdC2(NO)4 by Materials Project

Cd(N2)2(CO2)2 is Cyanogen Chloride-derived structured and crystallizes in the orthorhombic P2_12_12 space group. The structure is zero-dimensional and consists of two cadmium molecules, four carbon dioxide molecules, and four nitrogen molecules.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on HC2(NO2)2 by Materials Project

(N2)2(CO2)4H2 is Cyanogen Chloride-derived structured and crystallizes in the orthorhombic P2_12_12 space group. The structure is zero-dimensional and consists of four ammonia molecules, four carbon dioxide molecules, and two hydrogen molecules.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on NbC4N3O13 by Materials Project

(NbCO7)2(N2)3(CO2)4(CO)2O2 crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of twelve ammonia molecules, eight carbon dioxide molecules, four formaldehyde molecules, two hydrogen peroxide molecules, and four NbCO7 clusters. In each NbCO7 cluster, Nb5+ is bonded in a 1-coordinate geometry to six O2- atoms. There are a spread of Nb–O bond distances ranging from 1.74–2.31 Å. C4+ is bonded in a linear geometry to two O2- atoms. There is one shorter (1.17 Å) and one longer (1.18 Å) C–O bond length. There are seven inequivalent O2- sites. In the first O2- site, O2- is bonded in a 1-coordinate geometry to one Nb5+ and one O2- atom. The O–O bond length is 1.41 Å. In the second O2- site, O2- is bonded in a 1-coordinate geometry to one Nb5+ and one O2- atom. In the third O2- site, O2- is bonded in a 1-coordinate geometry to one Nb5+ and one O2- atom. The O–O bond length is 1.40 Å. In the fourth O2- site, O2- is bonded in a single-bond geometry to one C4+ atom. In the fifth O2- site, O2- is bonded in a 1-coordinate geometry to one Nb5+ and one O2- atom. In the sixth O2- site, O2- is bonded in a distorted linear geometry to one Nb5+ and one C4+ atom. In the seventh O2- site, O2- is bonded in a single-bond geometry to one Nb5+ atom.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on UC3N4O11 by Materials Project

UO2(N2)2(CO3)3 crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen ammonia molecules; twelve carbonic acid molecules; and four pitchblend, uranium(iv) oxide, uranium(iv) dioxide, uranium dioxide molecules.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on VC4N2O11 by Materials Project

(VC3O8)2(N2)2(CO2)2O2 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight ammonia molecules, four carbon dioxide molecules, four water molecules, and four VC3O8 clusters. In each VC3O8 cluster, V4+ is bonded in a 2-coordinate geometry to five O2- atoms. There are a spread of V–O bond distances ranging from 1.64–2.40 Å. There are three inequivalent C4+ sites. In the first C4+ site, C4+ is bonded in a linear geometry to two O2- atoms. There is one shorter (1.16 Å) and one longer (1.18 Å) C–O bond length. In the second C4+ site, C4+ is bonded in a linear geometry to two O2- atoms. There is one shorter (1.16 Å) and one longer (1.19 Å) C–O bond length. In the third C4+ site, C4+ is bonded in a linear geometry to two O2- atoms. There is one shorter (1.17 Å) and one longer (1.18 Å) C–O bond length. There are eight inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one V4+ atom. In the second O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one V4+ and one C4+ atom. In the third O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one V4+ and one C4+ atom. In the fourth O2- site, O2- is bonded in a single-bond geometry to one C4+ atom. In the fifth O2- site, O2- is bonded in a single-bond geometry to one C4+ atom. In the sixth O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one V4+ and one C4+ atom. In the seventh O2- site, O2- is bonded in a single-bond geometry to one C4+ atom. In the eighth O2- site, O2- is bonded in a single-bond geometry to one V4+ atom.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on CdHC2(NO)4 by Materials Project

(Cd)2(N2)4(CO2)4H2 is Cyanogen Chloride-derived structured and crystallizes in the orthorhombic Pbcn space group. The structure is zero-dimensional and consists of four cadmium molecules, eight carbon dioxide molecules, four hydrogen molecules, and eight nitrogen molecules.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Defining Wind Energy Experience

Since 2015, the U.S. wind installed capacity has grown from 73 to over 120 gigawatts, creating jobs across many sectors and educational levels. The growth of the wind workforce will need to continue to meet the goal of 20% wind by 2030, as well as the Biden administration's goals to reduce greenhouse gas pollution by 2030, reach 100% carbon-free electricity by 2035, and achieve net-zero greenhouse gas emissions no later than 2050. Despite the needed and anticipated growth, there are challenges to meeting this demand. Research has consistently shown that it has been a challenge finding qualified applicants for open wind industry jobs. Between 2012 and 2018, the difficulty of finding qualified applicants increased from 62% to 68% according to industry respondents. In 2017, educational institutions and training programs reported that 67% of their students did not enter the wind energy industry. Research conducted in 2020 showed that 83% of interested workers had some or great difficulty finding job opportunities. In exploring reasons for this gap, the researchers found that challenges were primarily influenced by education, experience, and geography. This difficulty for wind industry employers, educational institutions, and the potential workforce is known as the "wind energy workforce gap." This report further investigates the experience aspect of this gap.

17 WIND ENERGY↗
DOE OSTI2024

Effect of Support on Iron-Based Catalyst Toward CO2-Free H2 Production From Methane Pyrolysis

The global demand for low-emission hydrogen production is increasing rapidly due to the potential for hydrogen to substitute conventional fossil fuels in energy related applications. Among all the current practical technologies – Steam Reforming of Methane (SMR), Water Electrolysis, and Methane Pyrolysis – methane pyrolysis has the potential to produce economical- and near-zero-emission hydrogen because the reaction produces a solid carbon by-product that can be monetized to offset production costs. However, this route is not without research challenges, and the selective formation of high-value carbon remains a critical issue. Supported nickel, iron, and cobalt, have been widely investigated for methane pyrolysis. Although iron-based catalysts are less active than Ni, iron catalysts offer less resistance to coke formation, are inexpensive, and have a longer lifetime. One area not sufficiently explored is the effect of support materials other than Al2O3 for the iron-based catalysts. Therefore, in this study we investigated a detailed variation of support material to study their influence on the catalytic performance. Moreover, this study offers a fair comparison because all catalytic materials were synthesized and studied under identical conditions, allowing a direct comparison of the obtained results; this is important because results reported in different publications in literature are often not comparable, due to very different reaction conditions.

Aireddy, Divakar Reddy↗
DOE OSTI2025

Climate-focused Life Cycle Assessments of Biochar Production by an ARTi Pyrolysis Reactor and an Air Burners CharBoss® Air Curtain Incinerator

This report presents a limited, dynamic, consequential life cycle assessment (LCA) to compare the climate impacts of two biochar production methods using wood as a feedstock. The two methods are a pyrolysis reactor supplied by ARTi (Des Moines, IA, https://www.arti.com/) and a T26 CharBoss® air curtain incinerator supplied by Air Burners, Inc. (Palm City, FL, https://airburners.com/). The underlying LCA methodology is described in a chapter by Singh et al. (2024) and implemented in the form of a workbook freely available as online Supplementary Material for the chapter. For the convenience of the reader, a pre-print version of the relevant portions of Singh et al. (2024) is attached as Appendix A to this report. Specific assumptions and calculations to obtain the input parameters used in this LCA for each production method are described in the Methodology section below. This implementation of the LCA considers emissions associated with biomass loading, comminution and conversion, biochar decay in soil, and the production and use of bioenergy generated during the conversion process. The LCA is “limited” in that upstream emissions associated with biomass production, harvest, transportation, and land-use change, as well as embodied emissions in equipment and facilities are not considered. Similarly, downstream emissions from biochar transport and incorporation into soil (i.e., tillage), and the impact of biochar soil amendments on soil greenhouse gas (GHG) emissions (other than CO 2 from biochar decay in soil), soil organic carbon stocks, crop response, and surface albedo are not considered. As the intent is to compare different biochar production methods in a simple unbiased manner, the primary alternative biomass pathway for the LCA is immaculate combustion, which is the hypothetical instantaneous and complete conversion of carbon in the biomass to CO 2 at time zero without generation of any other greenhouse gases or aerosols (GHGAs) or any useful bioenergy. Use of this pathway provides relative values for the production methods and, when the embodied emissions are similar and the same feedstock is used, these relative values are reasonable approximations for those attained with a full LCA.

09 BIOMASS FUELS↗
DOE OSTI2023

A Review of CCUS in the Context of Foams, Regulatory Frameworks and Monitoring

Greenhouse gas emission into the atmosphere is considered the main reason for the rise in Earth’s mean surface temperature. According to the Paris Agreement, to prevent the rise of the global average surface temperature beyond two degrees Celsius, global CO2 emissions must be cut substantially. While a transition to a net-zero emission scenario is envisioned by mid-century, carbon capture, utilization, and storage (CCUS) will play a crucial role in mitigating ongoing greenhouse gas emissions. Injection of CO2 into geological formations is a major pathway to enable large-scale storage. Despite significant recent technological advancements, mass deployment of these technologies still faces several technical and non-technical difficulties. This paper provides an overview of technical milestones reached thus far in CO2 capture, utilization, geological storage, monitoring technologies, and non-technical aspects such as regulatory frameworks and related policies in the US and the rest of the world. This paper describes different injection methods to store CO2 in various subsurface formations, the use of foams and the resulting potential gains in CO2 storage capacity, the role of nanoparticles for foam stabilization, and ensuring long-term storage safety. This work also addresses several safety-related aspects of geological storage and subsurface monitoring technologies that may mitigate risks associated with long-term storage.

42 ENGINEERING↗
DOE OSTI2023

AI-Based Optimal Design and Controls Can Greatly Reduce Carbon Emissions and Enhance Resilience in Residential Communities in Cold Climates

Net-zero energy residential communities are crucial for achieving decarbonization goals, but the high-penetration photovoltaic (PV) in those communities is posing challenges to the distribution grid. Traditional design and operation of net-zero communities rely on rule-of-thumb methods and may not work in complex scenarios. Artificial intelligence and machine learning methods can optimally size PV for net-zero energy, identify user preferences and usage patterns, and fully unlock the potential of distributed energy resources to address distribution grid issues.

artificial intelligence↗
DOE OSTI2021

Imidazole-graphyne: a new 2D carbon nitride with a direct bandgap and strong IR refraction

Six-membered rings are common building blocks of many carbon structures. Recent studies have shown that penta-graphene composed of five-membered carbon rings have properties very different from that of graphene. This has motivated the search for new carbon structures. Among this is cp-graphyne, composed of carbon pentagons and bridged by acetylenic linkers. However, the bandgap of cp-graphyne, like that of graphene, is zero, making it unsuitable for applications in electronics. Herein, we show that a new two-dimensional (2D) carbon nitride structure formed by assembling the five-membered imidazole molecules with acetylenic linker can overcome this limitation. Named ID-GY, this new material not only has a direct band gap of 1.10 eV, but it is dynamically and mechanically stable and can withstand temperatures up to 1200 K. In addition, due to its porous and anisotropic geometry, the Young's modulus of ID-GY along the diagonal direction is lower than that of most 2D materials reported previously. Equally important, ID-GY exhibits strong refraction near infrared (IR) and has potential for applications in nanoelectronics and optical devices. These results, based on density functional theory, can stimulate experimental studies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Achieving American Leadership in the Nuclear Energy Supply Chain Factsheet

The United States is committed to achieving a 50 to 52 percent reduction from 2005 levels in economy-wide net greenhouse gas pollution by 2030, creating a carbon pollution-free power sector by 2035, and achieving net zero emissions economy-wide by no later than 2050. Nuclear energy is essential to meeting those goals. That includes the existing fleet and advanced reactors that are moving forward for deployment and under development. Nuclear power plants produce 20 percent of the total electricity supply in the United States today and are the largest source of carbon-free energy. However, we have an opportunity to expand significantly nuclear energy’s percentage of electricity generated in the United States. The U.S. Department of Energy (DOE) Office of Nuclear Energy (NE) report - developed in response to President Biden’s Executive Order “America’s Supply Chains” signed in 2021 - describes the nuclear supply chain and investigates challenges for continued operation of today’s 93 reactors and construction of advanced reactors. The supply chain is critical for successfully enabling the continued operation of the existing domestic fleet of light-water reactors as well as supporting deployment of advanced nuclear technologies.

Source record↗