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At least 415 records · Page 23

GLGM-3: A Degree-ISO Lunar Gravity Model from the Historical Tracking Data of NASA Moon Orbiters

In preparation for the radio science experiment of the Lunar Reconnaissance Orbiter (LRO) mission, we analyzed the available radio tracking data of previous NASA lunar orbiters. Our goal was to use these historical observations in combination with the new low-altitude data to be obtained by LRO. We performed Precision Orbit Determination on trajectory arcs from Lunar Orbiter 1 in 1966 to Lunar Prospector in 1998, using the GEODYN II program developed at NASA Goddard Space Flight Center. We then created a set of normal equations and solved for the coefficients of a spherical harmonics expansion of the lunar gravity potential up to degree and order 150. The GLGM-3 solution obtained with a global Kaula constraint (2.5 x 10(exp -4)/sq l) shows good agreement with model LP150Q from the Jet Propulsion Laboratory, especially over the nearside. The levels of data fit with both gravity models are very similar (Doppler RMS of approx.0.2 and approx. 1-2 mm/s in the nominal and extended phases, respectiVely). Orbit overlaps and uncertainties estimated from the covariance matrix also agree well. GLGM-3 shows better correlation with lunar topography and admittance over the nearside at high degrees of expansion (l > 100), particularly near the poles. We also present three companion solutions, obtained with the same data set but using alternate inversion strategies that modify the power law constraint and expectation of the individual spherical harmonics coefficients. We give a detailed discussion of the performance of this family of gravity field solutions in terms of observation fit, orbit quality, and geophysical consistency.

Mazarico, E.↗

Results from the July 1981 Workshop on Passive Remote Sensing of the Troposphere

Potential roles of passive remote sensors in the study of the chemistry and related dynamics of the lower atmosphere were defined by a Tropospheric Passive Remote Sensing Workshop, and technology advances required to implement these roles were identified. A promising role is in making global-scale, multilayer measurements of the more abundant trace tropospheric gaseous species (e.g., O3, CO, CH4, HNO3) and of aerosol thickness and size distribution. It includes both nadirand limb-viewing measurements. Technology advances focus on both scanning- and fixed-spectra, nadir-viewing techniques with resolutions of 0.1 kaysers or better. Balloon- and Shuttle-borne experiments should be performed to study the effects of instrument noise and background fluctuations on data inversion and to determine the utility of simultaneously obtained nadir- and limb-viewing data.

Keafer, L. S., Jr.↗

Pair Production and Annihilation in Strong Magnetic Fields

Electromagnetic phenomena occurring in the presence of strong magnetic fields are currently of great interest in high-energy astrophysics. In particular, the process of pair production by single photons in the presence of fields of order 10 to the 12th power Gauss is of importance in cascade models of pulsar gamma ray emission, and may also become significant in theories of other radiation phenomena whose sources may be neutron stars (e.g., gamma ray bursts). In addition to pair production, the inverse process of pair annihilation is greatly affected by the presence of superstrong magnetic fields. The most significant departures from annihilation processes in free space are a reduction in the total rate for annihilation into two photons, a broadening of the familiar 511-keV line for annihilation at rest, and the possibility for annihilation into a single photon (which dominates the two-photon annihilation for B ( 10 the 13th power Gauss). The physics of these pair conversion processes, which is reviewed briefly, can become quite complex in the teragauss regime, and can involve calculations which are technically difficult to incorporate into models of emission mechanisms in neutron star magnetospheres. However, theoretical work, especially the case of pair annihilation, also suggests potential techniques for more direct measurements of field strengths near the stellar surface.

Daugherty, J. K.↗

Pair production and annihilation in strong magnetic fields

Electromagnetic phenomena occurring in the presence of strong magnetic fields are currently of great interest in high-energy astrophysics. In particular, the process of pair production by single photons in the presence of fields of order 10 to the 12th power Gauss is of importance in cascade models of pulsar gamma ray emission, and may also become significant in theories of other radiation phenomena whose sources may be neutron stars (e.g., gamma ray bursts). In addition to pair production, the inverse process of pair annihilation is greatly affected by the presence of superstrong magnetic fields. The most significant departures from annihilation processes in free space are a reduction in the total rate for annihilation into two photons, a broadening of the familiar 511-keV line for annihilation at rest, and the possibility for annihilation into a single photon which dominates the two-photon annihilation for B (10 to 13th power Gauss) The physics of these pair conversion processes, which is reviewed briefly, can become quite complex in the teragauss regime, and can involve calculations which are technically difficult to incorporate into models of emission mechanisms in neutron star magnetospheres. However, theoretical work, especially the case of pair annihilation, also suggests potential techniques for more direct measurements of field strengths near the stellar surface.

Daugherty, J. K.↗

Testing of Commercial Hollow Fiber Membranes for Space Suit Water Membrane Evaporator

Three commercial-off-the-shelf (COTS) hollow fiber (HoFi) membrane evaporators, modified for low pressure, were tested in a vacuum chamber at pressures below 33 pascals as potential space suit water membrane evaporator (SWME) heat rejection technologies. Water quality was controlled in a series of 25 tests, first simulating potable water reclaimed from waste water and then changing periodically to simulate the ever concentrating make-up of the circulating coolant over that is predicted over the course of 100 EVAs. Two of the systems, comprised of non-porous tubes with hydrophilic molecular channels as the water vapor transport mechanism, were severely impacted by the increasing concentrations of cations in the water. One of the systems, based on hydrophobic porous polypropylene tubes was not affected by the degrading water quality, or the presence of microbes. The polypropylene system, called SWME 1, was selected for further testing. An inverse flow configuration was also tested with SWME 1, with vacuum exposure on the inside of the tubes, provided only 20% of the performance of the standard configuration. SWME 1 was also modified to block 50% and 90% of the central tube layers, and tested to investigate performance efficiency. Performance curves were also developed in back-pressure regulation tests, and revealed important design considerations arising from the fully closed valve. SWME 1 was shown to be insensitive to air bubbles injected into the coolant loop. Development and testing of a full-scale prototype based on this technology and these test results is in progress.

Bue, Grant C.↗

A Regional CO2 Observing System Simulation Experiment Using ASCENDS Observations and WRF-STILT Footprints

Knowledge of the spatiotemporal variations in emissions and uptake of CO2 is hampered by sparse measurements. The recent advent of satellite measurements of CO2 concentrations is increasing the density of measurements, and the future mission ASCENDS (Active Sensing of CO2 Emissions over Nights, Days and Seasons) will provide even greater coverage and precision. Lagrangian atmospheric transport models run backward in time can quantify surface influences ("footprints") of diverse measurement platforms and are particularly well suited for inverse estimation of regional surface CO2 fluxes at high resolution based on satellite observations. We utilize the STILT Lagrangian particle dispersion model, driven by WRF meteorological fields at 40-km resolution, in a Bayesian synthesis inversion approach to quantify the ability of ASCENDS column CO2 observations to constrain fluxes at high resolution. This study focuses on land-based biospheric fluxes, whose uncertainties are especially large, in a domain encompassing North America. We present results based on realistic input fields for 2007. Pseudo-observation random errors are estimated from backscatter and optical depth measured by the CALIPSO satellite. We estimate a priori flux uncertainties based on output from the CASA-GFED (v.3) biosphere model and make simple assumptions about spatial and temporal error correlations. WRF-STILT footprints are convolved with candidate vertical weighting functions for ASCENDS. We find that at a horizontal flux resolution of 1 degree x 1 degree, ASCENDS observations are potentially able to reduce average weekly flux uncertainties by 0-8% in July, and 0-0.5% in January (assuming an error of 0.5 ppm at the Railroad Valley reference site). Aggregated to coarser resolutions, e.g. 5 degrees x 5 degrees, the uncertainty reductions are larger and more similar to those estimated in previous satellite data observing system simulation experiments.

Wang, James S.↗

The Global Methane Budget 2000–2017

Understanding and quantifying the global methane (CH4) budget is important for assessing realistic pathways to mitigate climate change. Atmospheric emissions and concentrations of CH4 continue to increase, making CH4 the second most important human-influenced greenhouse gas in terms of climate forcing, after carbon dioxide (CO2). The relative importance of CH4 compared to CO2 depends on its shorter atmospheric lifetime, stronger warming potential, and variations in atmospheric growth rate over the past decade, the causes of which are still debated. Two major challenges in reducing uncertainties in the atmospheric growth rate arise from the variety of geographically overlapping CH4 sources and from the destruction of CH4 by short-lived hydroxyl radicals (OH). To address these challenges, we have established a consortium of multidisciplinary scientists under the umbrella of the Global Carbon Project to synthesize and stimulate new research aimed at improving and regularly updating the global methane budget. Following Saunois et al. (2016), we present here the second version of the living review paper dedicated to the decadal methane budget, integrating results of top-down studies (atmospheric observations within an atmospheric inverse-modelling framework) and bottom-up estimates (including process-based models for estimating land surface emissions and atmospheric chemistry, inventories of anthropogenic emissions, and data-driven extrapolations). For the 2008–2017 decade, global methane emissions are estimated by atmospheric inversions (a top-down approach) to be 576 Tg CH4/yr (range 550–594, corresponding to the minimum and maximum estimates of the model ensemble). Of this total, 359 Tg CH4/yr or ∼ 60 % is attributed to anthropogenic sources, that is emissions caused by direct human activity (i.e. anthropogenic emissions; range 336–376 Tg CH4/yr or 50 %–65 %). The mean annual total emission for the new decade (2008–2017) is 29 Tg CH4/yr larger than our estimate for the previous decade (2000–2009), and 24 Tg CH4/yr larger than the one reported in the previous budget for 2003–2012 (Saunois et al., 2016). Since 2012, global CH4 emissions have been tracking the warmest scenarios assessed by the Intergovernmental Panel on Climate Change. Bottom-up methods suggest almost 30 % larger global emissions (737 Tg CH4/yr, range 594–881) than top-down inversion methods. Indeed, bottom-up estimates for natural sources such as natural wetlands, other inland water systems, and geological sources are higher than top-down estimates. The atmospheric constraints on the top-down budget suggest that at least some of these bottom-up emissions are overestimated. The latitudinal distribution of atmospheric observation-based emissions indicates a predominance of tropical emissions (∼ 65 % of the global budget, < 30° N) compared to mid-latitudes (∼ 30 %, 30–60° N) and high northern latitudes (∼ 4 %, 60–90° N). The most important source of uncertainty in the methane budget is attributable to natural emissions, especially those from wetlands and other inland waters. Some of our global source estimates are smaller than those in previously published budgets (Saunois et al., 2016; Kirschke et al., 2013). In particular wetland emissions are about 35 Tg CH4/yr lower due to improved partition wetlands and other inland waters. Emissions from geological sources and wild animals are also found to be smaller by 7 Tg CH4/yr by 8 Tg CH4/yr, respectively. However, the overall discrepancy between bottom-up and top-down estimates has been reduced by only 5 % compared to Saunois et al. (2016), due to a higher estimate of emissions from inland waters, highlighting the need for more detailed research on emissions factors. Priorities for improving the methane budget include (i) a global, high-resolution map of water-saturated soils and inundated areas emitting methane based on a robust classification of different types of emitting habitats; (ii) further development of process-based models for inland-water emissions; (iii) intensification of methane observations at local scales (e.g., FLUXNET-CH4 measurements) and urban-scale monitoring to constrain bottom-up land surface models, and at regional scales (surface networks and satellites) to constrain atmospheric inversions; (iv) improvements of transport models and the representation of photochemical sinks in top-down inversions; and (v) development of a 3D variational inversion system using isotopic and/or co-emitted species such as ethane to improve source partitioning.

methane budget↗

Geophysical Interpretation of Venus Gravity Data

The subsurface distribution of Venus was investigated through the analysis of the data from Pioneer Venus Orbiter (PVO). In particular, the Doppler tracking data were used to map the gravitational potential. These were compared to the topographic data from the PVO radar (ORAD). In order to obtain an unbiased comparison, the topography data obtained from the PVO-ORAD were filtered to introduce distortions which are the same as those of the gravity models. Both the gravity and filtered topography maps are derived by two stage processes with a common second stage. In the first stage, the topography was used to calculate a corresponding spacecraft acceleration under the assumptions that the topography has a uniform given density and no compensation. In the second stage, the acceleration measures found in the first stage were passed through a linear inverter to yield maps of gravity and topography. Because these maps are the result of the same inversion process, they contain the same distortion; a comparison between them is unbiased to first order.

Reasenberg, R. D.↗

Characterization of Transport Errors in Chemical Forecasts from a Global Tropospheric Chemical Transport Model

We propose a new methodology to characterize errors in the representation of transport processes in chemical transport models. We constrain the evaluation of a global three-dimensional chemical transport model (GEOS-CHEM) with an extended dataset of carbon monoxide (CO) concentrations obtained during the Transport and Chemical Evolution over the Pacific (TRACE-P) aircraft campaign. The TRACEP mission took place over the western Pacific, a region frequently impacted by continental outflow associated with different synoptic-scale weather systems (such as cold fronts) and deep convection, and thus provides a valuable dataset. for our analysis. Model simulations using both forecast and assimilated meteorology are examined. Background CO concentrations are computed as a function of latitude and altitude and subsequently subtracted from both the observed and the model datasets to focus on the ability of the model to simulate variability on a synoptic scale. Different sampling strategies (i.e., spatial displacement and smoothing) are applied along the flight tracks to search for systematic model biases. Statistical quantities such as correlation coefficient and centered root-mean-square difference are computed between the simulated and the observed fields and are further inter-compared using Taylor diagrams. We find no systematic bias in the model for the TRACE-P region when we consider the entire dataset (i.e., from the surface to 12 km ). This result indicates that the transport error in our model is globally unbiased, which has important implications for using the model to conduct inverse modeling studies. Using the First-Look assimilated meteorology only provides little improvement of the correlation, in comparison with the forecast meteorology. These general statements can be refined when the entire dataset is divided into different vertical domains, i.e., the lower troposphere (less than 2 km), the middle troposphere (2-6 km), and the upper troposphere (greater than 6 km). The best agreement between the observations and the model is found in the lower and middle troposphere. Downward displacements in the lower troposphere provide a better fit with the observed value, which could indicate a problem in the representation of boundary layer height in the model. Significant improvement is also found for downward and southward displacements in the upper troposphere. There are several potential sources of errors in our simulation of the continental outflow in the upper troposphere which could lead to such biases, including the location and/or the strength of deep convective cells as well as that of wildfires in Southeast Asia.

Bey, I.↗

Evaluation of a trajectory command concept for manual control of carrier approaches and landings

A novel trajectory control system concept was implemented to provide manual control of a conventional jet aircraft. This concept, called Total Aircraft Flight Control System (TAFCOS), utilizes an inverse model of the aerodynamic and propulsion characteristics and employs feedforward control to provide the required acceleration command. The concept requires on-board digital computations which can easily be handled by a modern airborne computer. The system was studied in a piloted simulation of the carrier approach and landing task with primarily visual flight and guidance cues. The principal modes of vertical flight-path control investigated were vertical velocity command and vertical acceleration command. The study included manual carrier approaches with and without moderate ship motion and associated air disturbances, and tests of the effects of discrete gusts. Manual control of flight path through this new concept was shown to be feasible as an addition to an automatic control system and to have potential as an improved mode of control over conventional control for the carrier approach task.

Mcneill, W. E.↗

Idaho Wildfires II: Assessing the Relationship Between Drought Indicators and Wildfire Risk to Enhance Hazard Modeling and Inform Mitigation Planning

The western United States has experienced twenty years of increased and prolonged drought which have exacerbated wildfire hazards. These jeopardize population centers through increased risks to ecosystem services, local economies, and livelihoods. The Idaho Office of Emergency Management, Water Resources, and Department of Lands are seeking methods to dynamically monitor these conditions and update models that inform hazard mitigation planning and resource allocation. Towards this, these agencies partnered with NASA DEVELOP to produce drought-enhanced wildfire hazard models. Part of a two-term project, the two teams revised the state’s static wildfire hazard model with refined data layers and remotely-sensed data to reflect dynamic ecosystem responses to drought conditions and wildfire potential. Our team distinguished between rangeland and forestland ecosystems, and investigated relationships between drought metrics and vegetation condition using TerrSet Earth Trends Modeler. This analysis determined that total precipitation at a 5-month lag interval (r 2 = 0.72) along with the Evaporative Stress Index (r 2 = 0.69); and precipitation at a 5-month interval (r 2 = 0.42) were important drivers in rangeland and forestland, respectively. These driver variables were incorporated into a temporally dynamic wildfire hazard map. Our team used linear regression to correlate hazard ratings with wildfire frequency. For the year 2020, neither the enhanced hazard model (p < 0.10, r 2 = 0.01) nor the state’s static model (p < 0.05, r 2 = 0.03) were strongly correlated with actual wildfire frequency as they expressed an inverse relationship between wildfire hazard and frequency. This suggests wildfire occurrence is complex and not necessarily driven by the variables used.

Wildfire↗

Turbulent Transport in the Gray Zone: A Large Eddy Model Intercomparison Study of the CONSTRAIN Cold Air Outbreak Case

To quantify the turbulent transport at gray zone length scales between 1 and 10 km the Lagrangian evolution of the CONSTRAIN cold air outbreak (CAO) case was simulated with seven large eddy models. The case is characterized by rather large latent and sensible heat fluxes, and a rapid deepening rate of the boundary layer. In some models the entrainment velocity exceeds 4 cm/s. A significant fraction of this growth is attributed to a strong longwave radiative cooling of the inversion layer. The evolution and the timing of the breakup of the stratocumulus cloud deck differ significantly among the models. Sensitivity experiments demonstrate that a decrease in the prescribed cloud droplet number concentration, and the inclusion of ice microphysics, both act to speed up the thinning of the stratocumulus by enhancing the production of precipitation. In all models the formation of mesoscale fluctuations is clearly evident in the cloud fields but also in the horizontal wind velocity. Resolved vertical fluxes remain important for scales up to 10 km. The simulation results show that the resolved vertical velocity variance gradually diminishes with a coarsening of the horizontal mesh, but the total vertical fluxes of heat, moisture, and momentum are only weakly affected. This is a promising result as it demonstrates the potential use of a mesh size dependent turbulent length scale for convective boundary layers at gray zone model resolutions.

gray zone↗

Line shape parameters of PH3 transitions: Theoretical studies of self-broadened widths and line mixing effects

Line mixing effects have been calculated in various parallel and perpendicular bands of self-broadened PH3 lines and compared with recent experimental data. The theoretical approach is an extension to symmetric tops with high inversion barrier of the formalism previously developed for NH3 [Q. Ma and C. Boulet, J. Chem. Phys. 144, 224303 (2016)]. The model takes into account the non-diagonality of the scattering operator within the line space as well as, in a correct way, the double degeneracy of the j, k levels when k ≠ 0. Transitions between such levels should be considered as doublets whose components may be coupled by the line mixing process. It has been shown that, at low pressure, the inversion of the experimental data will strongly depend on the splitting between the two components of a doublet. When it is significant, one can measure independently both the width of one component and the intra-doublet coupling matrix element. Otherwise, one can only measure the sum of these two elements. Comparisons with measurements show that the present formalism leads to accurate predictions of the experimental line shapes.

Remote sensing↗

Demonstration of Aerosol Property Profiling by Multi-wavelength Lidar Under Varying Relative Humidity Conditions

The feasibility of using a multi-wavelength Mie-Raman lidar based on a tripled Nd:YAG laser for profiling aerosol physical parameters in the planetary boundary layer (PBL) under varying conditions of relative humidity (RH) is studied. The lidar quantifies three aerosol backscattering and two extinction coefficients and from these optical data the particle parameters such as concentration, size and complex refractive index are retrieved through inversion with regularization. The column-integrated, lidar-derived parameters are compared with results from the AERONET sun photometer. The lidar and sun photometer agree well in the characterization of the fine mode parameters, however the lidar shows less sensitivity to coarse mode. The lidar results reveal a strong dependence of particle properties on RH. The height regions with enhanced RH are characterized by an increase of backscattering and extinction coefficient and a decrease in the Angstrom exponent coinciding with an increase in the particle size. We present data selection techniques useful for selecting cases that can support the calculation of hygroscopic growth parameters using lidar. Hygroscopic growth factors calculated using these techniques agree with expectations despite the lack of co-located radiosonde data. Despite this limitation, the results demonstrate the potential of multi-wavelength Raman lidar technique for study of aerosol humidification process.

Whiteman, D.N.↗

The Prospect for Remote Sensing of Cirrus Clouds with a Submillimeter-Wave Spectrometer

Given the substantial radiative effects of cirrus clouds and the need to validate cirrus cloud mass in climate models, it is important to measure the global distribution of cirrus properties with satellite remote sensing. Existing cirrus remote sensing techniques, such as solar reflectance methods, measure cirrus ice water path (IWP) rather indirectly and with limited accuracy. Submillimeter/wave radiometry is an independent method of cirrus remote sensing based on ice particles scattering the upwelling radiance emitted by the lower atmosphere. A new aircraft instrument, the Far Infrared Sensor for Cirrus (FIRSC), is described. The FIRSC employs a Fourier Transform Spectrometer (FTS). which measures the upwelling radiance across the whole submillimeter region (0.1 1.0-mm wavelength). This wide spectral coverage gives high sensitivity to most cirrus particle sizes and allows accurate determination of the characteristic particle size. Radiative transfer modeling is performed to analyze the capabilities of the submillimeter FTS technique. A linear inversion analysis is done to show that cirrus IWP, particle size, and upper-tropospheric temperature and water vapor may be accurately measured, A nonlinear statistical algorithm is developed using a database of 20000 spectra simulated by randomly varying most relevant cirrus and atmospheric parameters. An empirical orthogonal function analysis reduces the 500-point spectrum (20 - 70/cm) to 15 "pseudo-channels" that are then input to a neural network to retrieve cirrus IWP and median particle diameter. A Monte Carlo accuracy study is performed with simulated spectra having realistic noise. The retrieval errors are low for IWP (rms less than a factor of 1.5) and for particle sizes (rins less than 30%) for IWP greater than 5 g/sq m and a wide range of median particle sizes. This detailed modeling indicates that there is good potential to accurately measure cirrus properties with a submillimeter FTS.

Evans, K. Franklin↗

TPSAS-NF1676L-34010-DND

We invert global black carbon (BC), organic carbon (OC) and desert dust (DD) aerosol emissions from POLDER/PARASOL spectral aerosol optical depth (AOD) and aerosol absorption optical depth (AAOD) using the GEOSChem inverse modelling framework. Our inverse modeling framework uses standard a priori emissions to provide a posteriori emissions that are constrained by POLDER/PARASOL AODs and AAODs. Our satellite-derived global aerosol emission database indicates an increase of BC and OC, while a decrease of DD with respect to the a priori emission inventories used in standard GEOS-Chem runs. The model simulations using a posteriori emissions (i.e. retrieved emissions) provide new estimate of global aerosol extinction and absorption constrained by observations. Additionally, the a posteriori model simulation of AOD, AAOD, single scattering albedo, Angstrom exponent, and absorption Angstrom exponent show better agreement with independent AERONET, MODIS, and OMI measurements than the a priori simulation. Thus, this study suggests that using satellite-constrained global aerosol emissions in aerosol transport models can improve the accuracy of simulated global aerosol properties and have potential to better understanding global aerosol effects on climate and human health.

Cheng Chen↗

Aerodynamic shape optimization using control theory

Aerodynamic shape design has long persisted as a difficult scientific challenge due its highly nonlinear flow physics and daunting geometric complexity. However, with the emergence of Computational Fluid Dynamics (CFD) it has become possible to make accurate predictions of flows which are not dominated by viscous effects. It is thus worthwhile to explore the extension of CFD methods for flow analysis to the treatment of aerodynamic shape design. Two new aerodynamic shape design methods are developed which combine existing CFD technology, optimal control theory, and numerical optimization techniques. Flow analysis methods for the potential flow equation and the Euler equations form the basis of the two respective design methods. In each case, optimal control theory is used to derive the adjoint differential equations, the solution of which provides the necessary gradient information to a numerical optimization method much more efficiently then by conventional finite differencing. Each technique uses a quasi-Newton numerical optimization algorithm to drive an aerodynamic objective function toward a minimum. An analytic grid perturbation method is developed to modify body fitted meshes to accommodate shape changes during the design process. Both Hicks-Henne perturbation functions and B-spline control points are explored as suitable design variables. The new methods prove to be computationally efficient and robust, and can be used for practical airfoil design including geometric and aerodynamic constraints. Objective functions are chosen to allow both inverse design to a target pressure distribution and wave drag minimization. Several design cases are presented for each method illustrating its practicality and efficiency. These include non-lifting and lifting airfoils operating at both subsonic and transonic conditions.

Reuther, James↗

Carbon Nanotubes/Nanofibers by Plasma Enhanced Chemical Vapour Deposition

Plasma enhanced chemical vapour deposition (PECVD) has been recently used for the production of vertically aligned carbon nanotubedfibers (CN) directly on substrates. These structures are potentially important technologically as electron field emitters (e.g. microguns, microwave amplifiers, displays), nanoelectrodes for sensors, filter media, superhydrophobic surfaces and thermal interface materials for microelectronics. A parametric study on the growth of CN grown by glow discharge dc-PECVD is presented. In this technique, a substrate containing thin film Ni catalyst is exposed to C2H2 and NH3 gases at 700 C. Without plasma, this process is essentially thermal CVD which produces curly spaghetti-like CN as seen in Fig. 1 (a). With the plasma generated by biasing the substrate at -6OOV, we observed that the CN align vertically during growth as shown in Fig. l(b), and that the magnitude of the applied substrate bias affects the degree of alignment. The thickness of the thin film Ni catalyst was found to determine the average diameter and inversely the length of the CN. The yield and density of the CN were controlled by the use of different diffusion barrier materials under the Ni catalyst. Patterned CN growth [Fig. l(c)], with la variation in CN diameter of 4.1% and 6.3% respectively, is achieved by lithographically defining the Ni thin film prior to growth. The shape of the structures could be varied from very straight nanotube-like to conical tip-like nanofibers by increasing the ratio of C2H2 in the gas flow. Due to the plasma decomposition of C2H2, amorphous carbon (a-C) is an undesirable byproduct which could coat the substrate during CN growth. Using a combination of depth profiled Auger electron spectroscopy to study the substrate and in-situ mass spectroscopy to examine gas phase neutrals and ions, the optimal conditions for a-C free growth of CN is determined.

Teo, K. B. K.↗