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At least 415 records · Page 23

Multiple and nonlocal cation redox in Ca–Ce–Ti–Mn oxide perovskites for solar thermochemical applications

Modeling-driven design of redox-active off-stoichiometric oxides for solar thermochemical H 2 production (STCH) seldom has resulted in empirical demonstration of competitive materials. Here, we report the theoretical prediction and experimental evidence that the perovskite Ca 2/3 Ce 1/3 Ti 1/3 Mn 2/3 O 3 is synthesizable with high phase purity, stable, and has desirable redox thermodynamics for STCH, with a predicted average neutral oxygen vacancy (VO) formation energy, E v = 3.30 eV. Flow reactor experiments suggest potentially comparable or greater H 2 production capacity than recent promising Sr–La–Mn–Al and Ba–Ce–Mn metal oxide perovskites. Utilizing quantum-based modeling of a solid solution on both A and B sub-lattices, we predict the impact of nearest-neighbor composition on E v and determine that A-site Ce 4+ reduction dominates the redox-activity of Ca 2/3 Ce 1/3 Ti 1/3 Mn 2/3 O 3 . X-ray absorption spectroscopy measurements provide evidence that supports these predictions and reversible Ce 4+ -to-Ce 3+ reduction. Our models predict that Ce 4+ reduces even when it is not nearest-neighbor to the V O , suggesting that refinement of Ce stoichiometry has the possibility of further enhancing performance.

08 HYDROGEN↗

Observations of Transient ISS Floating Potential Variations During High Voltage Solar Array Operations

The International Space Station (ISS) continues to be a world-class space research laboratory after over 15 years of operations, and it has proven to be a fantastic resource for observing spacecraft floating potential variations related to high voltage solar array operations in Low Earth Orbit (LEO). Measurements of the ionospheric electron density and temperature along the ISS orbit and variations in the ISS floating potential are obtained from the Floating Potential Measurement Unit (FPMU). In particular, rapid variations in ISS floating potential during solar array operations on time scales of tens of milliseconds can be recorded due to the 128 Hz sample rate of the Floating Potential Probe (FPP) pro- viding interesting insight into high voltage solar array interaction with the space plasma environment. Comparing the FPMU data with the ISS operations timeline and solar array data provides a means for correlating some of the more complex and interesting transient floating potential variations with mission operations. These complex variations are not reproduced by current models and require further study to understand the underlying physical processes. In this paper we present some of the floating potential transients observed over the past few years along with the relevant space environment parameters and solar array operations data.

Willis, Emily M.↗

SPHINX: An SEP Model Validation Infrastructure developed through Community Challenges and the SEP Scoreboards

Solar Energetic Particle (SEP) events are interesting from a scientific perspective as they are the product of a broad set of physical processes from the corona out through the extent of the heliosphere, and provide insight into processes of particle acceleration and transport that are widely applicable in astrophysics. From the operations perspective, SEP events pose a radiation hazard for aviation, electronics in space, and human space exploration, in particular for missions outside of the Earth’s protective magnetosphere including to the Moon and Mars (Whitman et al 2022). For these reasons, SEP modelers have developed a rich and diverse set of models with a wide variety of aims. Some models probe the basic physics at the heart of particle acceleration and transport. Others produce fast statistical forecasts or employ disruptive new techniques like Machine Learning with the goal to assist end users in making operational decisions. To enable a consistent and quantitative understanding of SEP model performance, a generalized, automated validation infrastructure, called SPHINX, is being developed at NASA SRAG in close collaboration with NASA CCMC, NASA M2M, NOAA SWPC, and BIRA-IASB. This infrastructure has been built up through a multi-year community challenge. Starting in 2018 at the SHINE workshop, an effort was launched through SHINE, ISWAT, and ESWW to encourage quantitative, comprehensive, and consistent validation of SEP models. This effort has defined a set of challenge SEP events with the aim of generating quantitative comparisons between forecasts and observations and a set of challenge “non-events” to assess false alarms. In 2023, these challenge lists have been extended to statistically significant numbers with a prescribed set of rules for producing forecasts and supported through the dedicated SEPVAL working meetings. The participation of the research community has allowed the infrastructure to validate all the types of outputs being produced by SEP models. In parallel, the SPHINX code is being applied to real time forecasts submitted to the SEP Scoreboards, ensuring that the validation infrastructure can interpret forecasts produced in an operational scenario and provide metrics meaningful for operations. Upon completion, SPHINX and its interactive user interface, SPHINX-Web, will be made available for public use.

space weather↗

Autonomous Inverter Controls for Resilient and Secure Grid Operation: Vector Control Design for Grid Forming

The project addresses both fundamental and practical challenges of GFM/GFL inverter control for the power grids with high inverter based resources (IBRs) penetration. A data- driven modeling technique is applied to accurately model dynamics of PWM inverters, including electromagnetic-transient (EMT). Systematic and integrative designs of grid- forming (GFM) and grid-following (GFL) primary controls are developed to guarantee system performance under either normal or abnormal operating conditions without violating constraints. This modeling and control framework provides black-start capability in case of an outage without relying on rotating generators, and its secondary control is also shown to enhance resilience against cyber-physical attacks.

14 SOLAR ENERGY↗

A 3D Convective Model for the Jovian Wind Bands

In an earlier paper, we proposed that Jupiter's alternating wind bands are a manifestation of the global interaction between rotation and convection in a shallow layer. The model, however, was obtained from linearization of the 2D equations of motions. At HKUST/Hong Kong, we are now trying to study this problem by rigorous numerical simulation. Using a three-dimensional spectral numerical code, we compute models for the outermost layer of Jupiter's convective envelope. Two cases have been studied. In one the atmospheric pressure varies from 1 to 23 bar, and in the other from 1 to 115 bar. The physical parameters (internal energy flux, rotation rate) are chosen to be close to those expected, but solar heating, chemistry, as well as dynamical influences from deeper layers are ignored. The models generate wind field patterns that contain alternating jet streams with resemblance to the Jovian bands. Instantaneous values of the mean zonal flow at the equator reach 80 m/sec. Yet the mean meridional flows are less than 1% of such value. The meridional temperature profile at the cloud top level also shows a double hump structure of a few degrees (as observed) in the subtropics. Though there is not complete quantitative agreement (caused perhaps by neglected effects like solar radiation), these models demonstrate, in principle, the feasibility of generating a Jovian type wind pattern through the interaction of fast rotation and convection in a thin shell.

Mayr, H. G.↗

The physics of solar prominences

The outstanding questions on the formation of quiescent prominences are discussed. One key issue is identified to be the formation of dips in coronal magnetic field lines. A model is presented which can account for such dipped field lines. The critical ingredients of the model are that the prominence magnetic field is a truly three dimensional structure with significant variation along the prominence length, and the magnetic field has strong shear concentrated at the photospheric neutral line. Simulations which demonstrate that these two features lead to dip formation and that the geometry of the dips are such that inverse polarity prominences can be explained are presented. Another key issue is identified to be the formation of prominence condensations on dipped field lines. It is argued that a spatially varying coronal heating rate which is maximum near the chromosphere explain these condensations.

Antiochos, Spiro K.↗

Understanding the Variability of Helium Abundance in the Solar Corona Using Three Fluid Modeling and Ultraviolet Observations

The variability of helium abundance in the solar corona and the solar wind is an important signature of solar activity, solar cycle, and solar wind sources, as well as coronal heating processes. Motivated by recently reported remote-sensing UV imaging observations by Helium Resonance Scattering in the Corona and Heliosphere payload sounding rocket of helium abundance in the inner corona on 2009 September 14 near solar minimum, we present the results of the first three-dimensional three-fluid (electrons, protons, and alpha particles) model of tilted coronal streamer belt and slow solar wind that illustrates the various processes leading to helium abundance differentiation and variability. We find good qualitative agreement between the three-fluid model and the coronal helium abundance variability deduced from UV observations of streamers, providing insight on the effects of the physical processes, such as heating, gravitational settling, and interspecies Coulomb friction in the outflowing solar wind that produce the observed features. The study impacts our understanding of the origins of the slow solar wind.

Leon Ofman↗

An Earth Albedo Model: A Mathematical Model for the Radiant Energy Input to an Orbiting Spacecraft Due to the Diffuse Reflectance of Solar Radiation from the Earth Below

Past missions have shown that the earth's albedo can have a significant effect on the sun sensors used for spacecraft attitude control information. In response to this concern, an algorithm was developed to simulate this phenomenon, consisting of two parts, the physical model of albedo and its effect on the sun sensors. This paper contains the theoretical development of this model, practical operational notes, and its implementation in a FORTRAN subroutine.

Flatley, Thomas W.↗

Energy diffusion of pickup ions upstream of comets

A steady state model of pickup ion energization upstream of a cometary bow wave is presented in order to investigate the effects of quasi-linear energy diffusion in the turbulence there. The model assumes that the ions are immediately isotropized at pickup, and it includes the effects of adiabatic acceleration in the slowing solar wind and of continual pickup of ions as the comet is approached. By taking all physical quantities to fall off as power laws with distance from the comet, an analytical expression is obtained for the distribution function of pickup ions in the reference frame moving with the solar wind. To illustrate the application of this model, the model results are compared to the observations of pickup ions at comet Giacobini-Zinner. At present, this is the only cometary encounter for which sufficient quantitative information is available. The model does not compare well with these observations, but it is not clear whether the differences are due to artificial problems in the model or the data analysis or to the action of other energization processes at this comet. Preliminary results from the Halley encounters appear to agree more closely with this model.

Isenberg, Philip A.↗

High-spectral resolution solar microwave observations

The application of high-spectral resolution microwave observations to the study of solar activity is discussed with particular emphasis on the frequency dependence of microwave emission from solar active regions. A shell model of gyroresonance emission from active regions is described which suggest that high-spectral resolution, spatially-resolved observations can provide quantitative information about the magnetic field distribution at the base of the corona. Corresponding observations of a single sunspot with the Owens Valley frequency-agile interferometer at 56 frequencies between 1.2 and 14 Ghs are presented. The overall form of the observed size and brightness temperature spectra was consistent with expectations based on the shell model, although there were differences of potential physical significance. The merits and weaknesses of microwave spectroscopy as a technique for measuring magnetic fields in the solar corona are briefly discussed.

Hurford, G. J.↗

Io's sodium cloud - Explanation of the east-west asymmetries. II

A three- dimensional model for Io's sodium cloud incorporating the full effects of solar radiation acceleration associated with solar resonance scattering of atoms in the D-1 and D-2 lines is developed and applied to interpret two different but related east-west asymmetries exhibited in the cloud, using data obtained from ground-based telescopes. The physical changes produced in the cloud by the solar radiation acceleration as a function of satellite phase angle are documented, and how these changes explain the asymmetries is clarified. The model results suggest an east-west phase lag asymmetry of 10-15 degrees; results for the observed east-west intensity asymmetry of Bergstrahl (1977) are also presented. The east-west shape and intensity asymmetries are found to follow directly from the lack of circular symmetry about Jupiter of the forces acting on the cloud atoms.

Smyth, W. H.↗

Building Reliable Forecasts of Solar Activity

Solar ionizing radiation critically depends on the level of the Sun’s magnetic activity. For robust physics-based forecasts, we employ the procedure of data assimilation, which combines theoretical modeling and observational data such that uncertainties in both the model and the observations are taken into account. Currently we are working in two major directions: 1) development of a new long-term forecast procedure on time-scales of the 11-year solar cycle, using a 2-dimensional mean-field dynamo model and synoptic magnetograms; 2) development of 3-dimensional radiative MHD (Magnetohydrodynamic) simulations to investigate the origin and precursors of local manifestations of magnetic activity, such as the formation of magnetic structures and eruptive dynamics.

Kitiashvili, Irina↗

Detailed studies of the dynamics and energetics of coronal bullets

Coronal bullets are small ejecta of cool, dense plasma observed to accelerate through the solar atmosphere from 20 to 450 km/s. The NRL Dynamic Flux Tube Model has been used to simulate the evolving physical properties of these dynamic events. The present calculations utilize an adaptive-gridding technique to resolve the fine structure within and around the bullets. In this work, an identification was made of a component of shocked plasma which piles up ahead of the bullet and eventually dominates both the dynamics and heating of the original bullet mass. The observational consequences of this shocked component are discussed in terms of the available HRTS EUV data, and suggestions are made for optimizing future observations of this phenomenon. An investigation has also been conducted of the structure of the bullet material visible in EUV spectral lines and the observable characteristics of the EUV-emitting plasma. Finally, the most likely mechanisms for accelerating the bullets, as well as favorable sites of origin are evaluated.

Karpen, J. T.↗

Studies of Planet Formation Using a Hybrid N-Body + Planetesimal Code

The goal of our proposal was to use a hybrid multi-annulus planetesimal/n-body code to examine the planetesimal theory, one of the two main theories of planet formation. We developed this code to follow the evolution of numerous 1 m to 1 km planetesimals as they collide, merge, and grow into full-fledged planets. Our goal was to apply the code to several well-posed, topical problems in planet formation and to derive observational consequences of the models. We planned to construct detailed models to address two fundamental issues: (1) icy planets: models for icy planet formation will demonstrate how the physical properties of debris disks - including the Kuiper Belt in our solar system - depend on initial conditions and input physics; and (2) terrestrial planets: calculations following the evolution of 1-10 km planetesimals into Earth-mass planets and rings of dust will provide a better understanding of how terrestrial planets form and interact with their environment.

Kenyon, Scott J.↗

Studies of Planet Formation using a Hybrid N-body + Planetesimal Code

The goal of our proposal was to use a hybrid multi-annulus planetesimal/n-body code to examine the planetesimal theory, one of the two main theories of planet formation. We developed this code to follow the evolution of numerous 1 m to 1 km planetesimals as they collide, merge, and grow into full-fledged planets. Our goal was to apply the code to several well-posed, topical problems in planet formation and to derive observational consequences of the models. We planned to construct detailed models to address two fundamental issues: 1) icy planets - models for icy planet formation will demonstrate how the physical properties of debris disks, including the Kuiper Belt in our solar system, depend on initial conditions and input physics; and 2) terrestrial planets - calculations following the evolution of 1-10 km planetesimals into Earth-mass planets and rings of dust will provide a better understanding of how terrestrial planets form and interact with their environment. During the past year, we made progress on each issue. Papers published in 2004 are summarized. Summaries of work to be completed during the first half of 2005 and work planned for the second half of 2005 are included.

Kenyon, Scott J.↗

Community Coordinated Modeling Center Support of Science Needs for Integrated Data Environment

Space science models are essential component of integrated data environment. Space science models are indispensable tools to facilitate effective use of wide variety of distributed scientific sources and to place multi-point local measurements into global context. The Community Coordinated Modeling Center (CCMC) hosts a set of state-of-the- art space science models ranging from the solar atmosphere to the Earth's upper atmosphere. The majority of models residing at CCMC are comprehensive computationally intensive physics-based models. To allow the models to be driven by data relevant to particular events, the CCMC developed an online data file generation tool that automatically downloads data from data providers and transforms them to required format. CCMC provides a tailored web-based visualization interface for the model output, as well as the capability to download simulations output in portable standard format with comprehensive metadata and user-friendly model output analysis library of routines that can be called from any C supporting language. CCMC is developing data interpolation tools that enable to present model output in the same format as observations. CCMC invite community comments and suggestions to better address science needs for the integrated data environment.

Kuznetsova, M. M.↗

GSFC Heliophysics Science Division 2008 Science Highlights

This report is intended to record and communicate to our colleagues, stakeholders, and the public at large about heliophysics scientific and flight program achievements and milestones for 2008, for which NASA Goddard Space Flight Center's Heliophysics Science Division (HSD) made important contributions. HSD comprises approximately 261 scientists, technologists, and administrative personnel dedicated to the goal of advancing our knowledge and understanding of the Sun and the wide variety of domains that its variability influences. Our activities include Lead science investigations involving flight hardware, theory, and data analysis and modeling that will answer the strategic questions posed in the Heliophysics Roadmap; Lead the development of new solar and space physics mission concepts and support their implementation as Project Scientists; Provide access to measurements from the Heliophysics Great Observatory through our Science Information Systems, and Communicate science results to the public and inspire the next generation of scientists and explorers.

Gilbert, Holly R.↗