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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 415 records · Page 23
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Rapid Accumulation of Soil Inorganics on Plastics: Implications for Plastic Degradation and Contaminant Fate

As plastics degrade in the environment, chemical oxidation of the plastic surface enables inorganics to adsorb and form inorganic coatings, likely through a combination of adsorption of minerals and in situ mineral formation. The presence of inorganic coatings on aged plastics has negative implications for plastics fate, hindering our ability to recycle weathered plastics and increasing the potential for plastics to adsorb contaminants. Here, inorganic coatings formed on terrestrially weathered polyethylene were characterized using synchrotron spectroscopy and microscopy techniques across spatial scales including optical microscopy, nano-X-ray-fluorescence mapping (nano-XRF), nano-X-ray absorption near edge structure (nano-XANES), and high-energy resolution fluorescence detected-XANES (HERFD-XANES). Results indicate a heterogeneous elemental distribution and speciation which includes inorganics common to soil terrestrial environments including iron oxides and oxyhydroxides, aluminosilicates, and carbonates.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Photocarrier Dynamics in TlGaS 2 Nanoflakes and van der Waals Heterostructures with Hexagonal Boron Nitride and WS 2 Nanoflakes: Implications for Optoelectronic Applications

We present an experimental investigation on photocarrier dynamics in a TlGaS 2 bulk crystal and its heterostructures with hexagonal BN and WS 2 . The samples were obtained by mechanical exfoliation and dry transfer techniques. The photocarrier dynamics was monitored by a transient absorption technique. We observed a direct optical transition of about 555 nm in the TlGaS 2 crystal. By utilizing transient absorption of that transition, we obtained a hot-carrier energy relaxation time of less than 1 ps and a carrier lifetime of about 300 ps in TlGaS 2 at room temperature. In the hexagonal-BN-TlGaS 2 heterostructure, the photocarrier dynamics was similar to that in TlGaS 2 , indicating the type-I band alignment of this structure with both band extremes located in TlGaS 2 . In the monolayer WS 2 -TlGaS 2 heterostructure, we observed charge transfer from TlGaS 2 to WS 2 and an extended lifetime of the transferred carriers in WS 2 . Here, these results introduce TlGaS 2 as a promising layered material for developing two-dimensional van der Waals materials that can be combined with other two-dimensional materials for various optoelectronic devices.

36 MATERIALS SCIENCE↗
DOE OSTI2025

3D nanolithography with metalens arrays and spatially adaptive illumination

The growing demand for advanced materials, miniaturized devices and integrated microsystems calls for the reliable fabrication of complex, multiscale, three-dimensional (3D) architectures, a need increasingly addressed through light-based and laser-based processes. However, owing to the field-of-view (FOV) limitations of conventional imaging optics, existing 3D laser nanofabrication techniques face fundamental challenges in throughput, proximity error and stitching defects on the path to scaling. Here, in this study, we present a scalable 3D nanofabrication platform that uses a metalens-generated focal spot array to parallelize two-photon lithography (TPL) beyond centimetre-scale write field areas. Metalenses are ideally suited for producing submicron-scale focal spots for high-throughput nanolithography, as they uniquely feature large numerical apertures (NAs), immersion media compatibility and large-scale manufacturability. We experimentally demonstrate a printing system that uses a 12-cm 2 metalens array to produce more than 120,000 cooperative focal spots, corresponding to a throughput exceeding 10 8 voxels s −1 . By programmatically patterning the focal spot array using a spatial light modulator (SLM), an adaptive parallel printing strategy is developed for precise greyscale linewidth modulation and choreographed printing of semiperiodic and fully aperiodic 3D geometries. We demonstrate parallel printing of replicated microstructures (>50 M microparticles per day), centimetre-scale 3D architectures with feature sizes down to 113 nm, and photonic and mechanical metamaterials. This work demonstrates the potential of 3D nanolithography towards wafer-scale production, showing how TPL could be used at scale for applications in microelectronics, biomedicine, quantum technology and high-energy laser targets.

Materials science↗
DOE OSTI2022

Exploring leakage in dielectric films via automated experiments in scanning probe microscopy

Here electronic conduction pathways in dielectric thin films are explored using automated experiments in scanning probe microscopy (SPM). In this study, we use large field of view scanning to identify the position of localized conductive spots and develop an SPM workflow to probe their dynamic behavior at higher spatial resolution as a function of time, voltage, and scanning process in an automated fashion. Using this approach, we observe the variable behaviors of the conductive spots in a 20-nm-thick ferroelectric Hf 0.54 Zr 0.48 O 2 film, where conductive spots disappear and reappear during continuous scanning. There are also fresh conductive spots that develop during scanning. The automated workflow is universal and can be integrated into a wide range of microscopy techniques, including SPM, electron microscopy, optical microscopy, and chemical imaging.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Measurement bias in self-heating x-ray free electron laser experiments from diffraction studies of phase transformation in titanium

X-ray self-heating is a common by-product of X-ray Free Electron Laser (XFEL) techniques that can affect targets, optics, and other irradiated materials. Diagnosis of heating and induced changes in samples may be performed using the x-ray beam itself as a probe. However, the relationship between conditions created by and inferred from x-ray irradiation is unclear and may be highly dependent on the material system under consideration. Here, we report on a simple case study of a titanium foil irradiated, heated, and probed by a MHz XFEL pulse train at 18.1 keV delivered by the European XFEL using measured x-ray diffraction to determine temperature and finite element analysis to interpret the experimental data. We find a complex relationship between apparent temperatures and sample temperature distributions that must be accounted for to adequately interpret the data, including beam averaging effects, multivalued temperatures due to sample phase transitions, and jumps and gaps in the observable temperature near phase transformations. The results have implications for studies employing x-ray probing of systems with large temperature gradients, particularly where these gradients are produced by the beam itself. Finally, this study shows the potential complexity of studying nonlinear sample behavior, such as phase transformations, where biasing effects of temperature gradients can become paramount, precluding clear observation of true transformation conditions.

Crystallography↗
DOE OSTI2023

Improved Productivity with Multilaser Rotary Powder Bed Fusion Additive Manufacturing

Laser powder bed fusion (LPBF) enables the fabrication of intricate, geometrically complex structures with a sufficiently fine surface finish for many engineering applications with a diversity of available feedstock metals. However, the production rate of LPBF systems is not well suited for mass production in comparison to traditional manufacturing methods. LPBF systems measure their deposition rates in 100's of grams per hour, while other processes measure in kilograms per hour or even in the case of processes such as forming, stamping, and casting, 100's of kilograms per hour. To be widely adopted in industry for mass production, LPBF requires a new scalable architecture that enables many orders of magnitude improvement in deposition rate, while maintaining the geometry freedom of additive manufacturing. This article explores concepts that could achieve as much as four orders of magnitude increase in the production rate through the application of (1) rotary table kinematic arrangements; (2) a dramatic number of simultaneously operating lasers; (3) reductions of laser optic size; (4) improved scanning techniques; and (5) an optimization of toroidal build plate size. To theoretically demonstrate the possibilities of production improvements, a productivity analysis is proposed for synchronous reluctance motors with relevance to the electric vehicle industry, given the recent increase in the diversity of printable soft magnetic alloys. The analysis provides insights into the impact of the architecture and process parameters necessary to optimize rotary powder bed fusion for mass production.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Determination of nuclear charge radius by extreme-ultraviolet spectroscopy of Na-like ions

We report on a method for determining the absolute nuclear charge radius of high-𝑍 elements using extreme-ultraviolet spectroscopy of highly charged Na-like ions in tandem with highly accurate atomic structure calculations of transition energy differences. The application of this method has reduced the nuclear charge radius uncertainty of 191 Ir by a factor of 8 from the currently accepted literature value, with a recently reported charge radius of 5.435(12) fm. The result reduces the charge radius uncertainty along the full Ir isotopic chain when combined with prior optical isotope shift measurements. The technique utilizes only a few million ions stored in an ion trap, which should apply to measurements with small quantities of radioactive nuclei.

Atom & ion trapping & guiding↗
DOE OSTI2025

Deep Neural Network Assisted Distributed Strain and Temperature Fiber Sensor System for Natural Gas Pipeline Monitoring

Natural gas pipeline integrity monitoring is crucial to detect potential leaks, find structural issues, and prevent environmental damage. This article presents a system of natural gas pipeline monitoring that uses a specialized double Brillouin peak sensing fiber along with the Brillouin optical time domain analysis (BOTDAs) technique. The calibrated sensing fiber coefficients for strain and temperature are 41.8 kHz/ με and 0.9 MHz/°C for peak 1; and 47.2 kHz/ με , and 1.11 MHz/°C for peak 2, respectively. Initially, lab tests were performed by installing a short section of double Brillouin peak fiber (DBPF) on a 1-in steel pipe under pressure up to 1000 per square inch (psi) at elevated temperatures. Simultaneous distributed measurements of temperature and pressure-induced hoop strain were successfully measured. Considering the long processing speed to extract Brillouin frequency shift (BFS), we employ a novel probabilistic deep neural network (PDNN) framework for rapid BFS prediction. Additionally, using the Finite Element Method, the effects of the pipeline pressure on hoop strain were modeled and compared to the experimental hoop strain under the same set of pipeline conditions. Finally, an actual 4-in outer diameter steel natural gas pipeline was used for pilot-scale tests, where hoop strain was measured at various pressure levels. Leaks were simulated to demonstrate accurate pipeline integrity monitoring. At an internal pipe pressure of 1000 psi, hoop strain of approximately 300 με was observed, and the sensitivity was calculated as 0.28 με /psi. The results of this pilot-scale study demonstrated that the system is capable of performing distributed monitoring sufficient to detect pipeline pressure and the presence of leaks to ensure the safe operation of gas pipelines in the field.

03 NATURAL GAS↗
DOE OSTI2020

Spatial and Temporal Characterization of Polarization Entanglement

We describe the full temporal and spatial characterization of polarization-entangled photons produced by Spontaneous Parametric Down Conversions using an intensified high-speed optical camera, Tpx3Cam. This novel technique allows for precise determination of Bell inequality parameters and for new characterization methods for the spatial distribution of entangled quantum information. We also discuss a technique to synchronize multiple cameras separated by vast distances, which will be required for a distributed quantum network.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2023

Towards quantum telescopes: demonstration of a two-photon interferometer for precision astrometry

Classical optical interferometry requires maintaining live, phase-stable links between telescope stations. This requirement greatly adds to the cost of extending to long baseline separations and limits on baselines will in turn limit the achievable angular resolution. Here we describe a novel type of two-photon interferometer for astrometry, which uses photons from two separate sky sources and does not require an optical link between stations. Such techniques may make large increases in interferometric baselines practical, even by orders of magnitude, with a corresponding improvement in astrometric precision benefiting numerous fields in astrophysics. We tested a benchtop analogue version of the two-source interferometer and unambiguously observe correlated behavior in detections of photon pairs from two thermal light sources, in agreement with theoretical predictions. This work opens new possibilities in future astronomical measurements.

47 OTHER INSTRUMENTATION↗
DOE OSTI2021

Using femtosecond pump-probe spectroscopy to shed new light on complex materials

We know a lot about events that have occurred during the earth’s history, on timescales of millions of years. We are much less familiar with events that occur on “ultra”-short timescales of less than a billionth of a second. Unlike in geology, we can actually do experiments at ultrashort timescales, so we should be able to understand the “ultrafast” world much better! Ultrafast optical spectroscopy is the only technique capable of measuring processes at the fundamental time scales of electron, lattice and nuclear motion.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Semiconductor Nanostructures by Scientific Design (Final Technical Report)

We developed and used quantum simulation techniques to predict structural, electronic, optical and thermal properties affecting the scientific design of semiconductor nanostructures. We focused on the study of surfaces and interfaces at the nanoscale, in particular embedding and solvation of semiconductor nanoparticles, and provided a microscopic description of nanostructured materials in realistic environments, directly comparable with experimental conditions. We addressed three major problems: (i) the design of realistic structural models of integrated nanostructures, e.g. quantum dots embedded in solid matrices and nanostructures immersed in fluids; (ii) the development of efficient and accurate calculations to describe the excited state properties of nanostructures, beyond standard Density Functional Theory, so as to understand and predict electronic properties involved in renewable energy applications, for example solar conversion devices. In particular we developed and used methods based on a many body perturbation theory. (iii) the development of calculations of heat transport properties of nanostructured materials, for thermoelectric applications, including predictive calculations of thermal and electrical conductivity and of Seebeck coefficients. Specifically, we developed and used methods based on the Boltzmann transport equation and molecular dynamics.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2024

Distributed Temperature Profiles of Silicon Carbide Catalyst Bed in a Microwave Reactor using Fiber-optic Sensor

Microwave heating is of great interest for reducing greenhouse gas emissions of catalytic chemical conversion processes because it can heat up the reactants rapidly and efficiently and accelerate reaction rates. In microwave-assisted catalytic thermochemical conversion processes, accurate internal temperature measurement would help facilitate effective process control. Metallic thermocouples interfere and spark in the microwave heating environment, so they are not an option. Infrared pyrometers typically provide a single temperature value by averaging over a finite surface area of the catalyst bed. In this work, we use fiber-optic sensors passing through the catalyst bed to provide more accurate temperatures along the height of the catalyst bed. The fiber optic sensors are immune to the electromagnetic microwave radiation and provide temperature profiles along their length. Here, custom fiber-optic sensors were coupled to the optical distributed temperature sensing devices to measure the temperature profiles along the height of the catalyst bed at high temperatures with ~1 mm spatial resolution. The sensing devices use optical frequency domain reflectometry (OFDR) technique for distributed temperature measurement. This work shows the temperature profiles along the height of the silicon carbide powder catalyst bed in the variable and fixed frequency microwave reactors.

Thapa, Juddha↗
DOE OSTI2022

Toward a More Complete Optical Census of Active Galactic Nuclei via Spatially Resolved Spectroscopy

While emission line flux ratio diagnostics are the most common technique for identifying active galactic nuclei (AGNs) in optical spectra, applying this approach to single-fiber spectra of galaxies can omit entire subpopulations of AGNs. Here, we use spatially resolved spectroscopy from the Mapping Nearby Galaxies at Apache Point Observatory (MaNGA) survey to construct a sample of 10 galaxies where Baldwin–Philips–Terlevich line flux ratio diagnostics classify each galaxy’s central 3" spectrum as LINER or star-forming, while >10% of the spaxels in the galaxy’s MaNGA footprint are classified as Seyfert. We obtain Chandra observations of these 10 galaxies with off-nuclear Seyfert regions to determine whether AGNs are actually present in them. Our main result is that 7–10 (depending on strictness of criteria) of the galaxies host one or more X-ray AGNs, even though none of them were classified as AGNs based on their single-fiber optical spectra. We find that these AGNs were not identified in the single-fiber spectra because they are AGNs in the nuclei of companion galaxies, low-luminosity AGNs, dust-obscured AGNs, and/or flickering AGNs. In summary, we find that off-nuclear AGN signatures may increase the number of known AGNs by a factor of two over what conventional single nuclear fiber spectra identify. Our results show that spatially resolved spectroscopy can be leveraged to reveal a more complete census of AGNs that are traditionally missed by single-fiber spectra.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Optical reflectance imaging reveals interlayer coupling in mechanically stacked MoS 2 and WS 2 bilayers

Optical reflectance imaging is a popular technique for characterizing 2D materials, thanks to its simplicity and speed of data acquisition. The use of this method for studying interlayer phenomena in stacked 2D layers has, however, remained limited. Here we demonstrate that optical imaging can reveal the nature of interlayer coupling in stacked MoS 2 and WS 2 bilayers through their observed reflectance contrast versus the substrate. Successful determination of interlayer coupling requires co-optimization of the illumination wavelength and the thickness of an underlying SiO 2 film. Our observations are supported by multilayer optical calculations together with an analysis of the effect of any interlayer gap. This approach promises quick characterization of constructed 2D material systems.

Nguyen, Vu↗
DOE OSTI2024

Exploring Interferometry Diagnostics for Optical Stochastic Cooling at FAST/IOTA

Optical Stochastic Cooling (OSC) is an advanced beam-cooling technique that will precede the traditional stochastic cooling. This method leverages optical radiation and high-precision feedback to cool the particles more efficiently than traditional stochastic methods by more than three orders of magnitude. As such, it is an enabler for the development of next generation discovery science machines at the frontiers of energy and intensity. This paper focuses on the development of the second phase of OSC and improving extreme beam cooling technique in accelerators. Along with the assembly and use of an interferometer to provide diagnostics and optimization to OSC systems. The interferometer can allow for the observation and analysis of fringe patterns from a recreated simpler version in the laser room. By leveraging interferometric techniques, OSC can achieve higher efficiency, verification, stability and performance.

Teriba, Folashade↗
DOE OSTI2024

EXPLORING INTERFEROMETRY DIAGNOSTICS FOR OPTICAL STOCHASTIC COOLING AT FAST/IOTA

Optical Stochastic Cooling (OSC) is an advanced beam-cooling technique that will advance the traditional stochastic cooling. This method leverages optical radiation and high-precision feedback to cool the particles more efficiently than traditional stochastic methods by more than three orders of magnitude. As such, it is an enabler for the development of next generation discovery science machines at the frontiers of energy and intensity. This paper focuses on the development of the second phase of OSC and improving extreme beam cooling techniques in accelerators. The goal was to build and characterize a Mach-Zehnder Interferometer (MZI) in the FAST laser lab using known glass plates thickness which will allow future measurements of unknown phase change due to nonlinear amplification processes.

Teriba, Folashade↗