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At least 415 records · Page 23

On the Importance of Producing and Characterizing Laboratory Analogs of Cosmic Grains, Planetary Atmospheric Aerosols, and Surface Materials

Carbonaceous dust and aerosols have been observed in interstellar/circumstellar and planetary environments. Dedicated laboratory experiments have been developed to produce analogs of these solid materials under different experimental conditions (molecular precursors, temperature, pressure, energy source…). These experimental studies are key to investigating the physical and chemical processes that drive the formation of solid particles from gas and solid phase molecular precursors in astrophysical and planetary environments. They also allow the characterization of the physical, optical, and chemical properties of these laboratory-generated analogs, hence providing critical information that can be used as input parameters in models for the analysis and interpretation of observational data. Here, as an example of these laboratory efforts, we will present various studies that combined (1) experiments performed with the NASA Ames COSmIC facility to produce analogs of Titan’s atmospheric aerosols and cosmic grains from gas phase molecular precursors, and (2) the characterization of these analogs with the NASA Ames Optical Constants Facility (OCF) to provide the real and imaginary parts of their refractive indices, n + ik, to the community, from the visible to the far-infrared (0.59–200 µm, 16,950–50 per cm). We will also discuss the importance of the wavelength and spectral range coverage of these optical constants, n and k, for their use in radiative transfer, atmospheric and reflectance models, and present a new effort to develop an Optical Constant database (OCdb) to provide this critical data to the scientific community.

Cosmic Grains↗

Applying Fused Silica and Other Transparent Window Materials in Aerospace Applications

A variety of transparent ceramics, such as AlONs and spinels, that were developed for military applications hold promise as spacecraft windows. Window materials in spacecraft such as the Space Shuttle must meet many requirements such as maintaining cabin pressure, sustaining thermal shock, and tolerating damage from hyper-velocity impact while providing superior optical characteristics. The workhorse transparent material for space missions from Apollo to the International Space Station has been fused silica due in part to its low density, low coefficient of expansion and optical quality. Despite its successful use, fused silica exhibits lower fracture toughness and impact resistance as compared to newer materials. Can these newer transparent ceramics lighten spacecraft window systems and might they be useful for applications such as phone screens? This presentation will compare recent optical ceramics to fused silica and demonstrate how weight can be saved.

Standards↗

Impacts of Aerosol and Cloud Variability on Satellite-Derived All-skies Direct Aerosol Radiative Effects (DARE) over the North and Southeast Atlantic

The Top-of-Atmosphere (TOA) Shortwave (SW) Direct Aerosol Radiative Effect (DARE) in all-sky conditions (i.e., aerosols in clear skies and aerosols above and below all types of clouds) is the global change in upwelling radiative flux due to aerosols. It is one of the strongest indicators of global climate change due to aerosols. SW DARE at TOA depends on the Earth’s surface albedo, cloud fraction, cloud optical properties, and aerosol optical properties, which are all challenging to accurately characterize from space. The overarching goals of our project are to provide state-of-the-art observational all-sky TOA SW DARE, along with guidance on which aerosol and/or cloud properties are the most important to measure, and at which spatio-temporal scales, for accurate DARE observations. We compute all-sky DARE based on state-of-the-art cloud and aerosol retrieval algorithms from CALIOP (Cloud–Aerosol Lidar with Orthogonal Polarization) and MODIS (Moderate Resolution Imaging spectroradiometer) satellite sensors, as well as aerosol intensive properties from MERRA-2 (Modern-Era Retrospective Analysis for Research and Applications, version 2) simulations over three specific regions of the Atlantic Ocean from 2012 to 2016. In this symposium, we present a characterization of the cloud and aerosol optical and physical properties and the observational TOA SW DARE along three individual satellite tracks in the Southeast Atlantic region -- on September 18 and 20, 2016 and August 13, 2017. We then quantify the impact of assuming homogeneous cloud or aerosol fields in space-based TOA SW DARE calculations. And, finally, the resulting space-based all-skies aerosol vertical distribution and DARE calculations are evaluated using remote sensing observations from coincident suborbital flights from the NASA ORACLES (the ObseRvations of Aerosols above CLouds and their intEractionS, ORACLES field campaign) field campaign. The NASA Atmospheric Observing System (AOS) mission addresses the NASA Aerosol, Cloud, Convection and Precipitation (ACCP) designated observables and proposes, as one of its aerosol objectives, to reduce uncertainties in estimates of global mean all-sky SW DARE at TOA. Well characterizing clouds, aerosol vertical distributions, aerosol types and associated all-skies DARE over the Atlantic Ocean will inform the AOS community on where, when, how, and how often the satellite retrievals should be performed to estimate DARE and reduce all-skies DARE uncertainties most accurately. These comprehensive characterizations will also identify the key regions and times when the AOS (or other ACCP-related) suborbital missions should be conducted to evaluate and improve the AOS space-based observations and retrievals.

aerosol↗

Deep levels in as-grown and Si-implanted In(0.2)Ga(0.8)As-GaAs strained-layer superlattice optical guiding structures

Trap levels in about 2-micron In(0.2)Ga(0.8)As(94 A)/GaAs(25 A) strained-layer superlattices, suitable for optical waveguides, have been identified and characterized by deep-level transient spectroscopy and optical deep-level transient spectroscopy measurements. Several dominant electron and hole traps with concentrations of approximately 10 to the 14th/cu cm, and thermal ionization energies Delta-E(T) varying from 0.20 to 0.75 eV have been detected. Except for a 0.20-eV electron trap, which might be present in the In(0.2)Ga(0.8)As well regions, all the other traps have characteristics similar to those identified in molecular-beam epitaxial GaAs. Of these, a 0.42-eV hole trap is believed to originate from Cu impurities, and the others are probably related to native defects. Upon Si implantation and halogen lamp annealing, new deep centers are created. These are electron traps with Delta-E(T) = 0.81 eV and hole traps with Delta-E(T) = 0.46 eV. Traps occurring at room temperature may present limitations for optical devices.

Dhar, S.↗

Characterization of Aerosol Episodes in the Greater Mediterranean Sea Area from Satellite Observations (2000-2007)

An algorithm able to identify and characterize episodes of different aerosol types above sea surfaces of the greater Mediterranean basin (GMB), including the Black Sea and the Atlantic Ocean off the coasts of Iberia and northwest Africa, is presented in this study. Based on this algorithm, five types of intense (strong and extreme) aerosol episodes in the GMB are identified and characterized using daily aerosol optical properties from satellite measurements, namely MODIS-Terra, Earth Probe (EP)-TOMS and OMIAura. These aerosol episodes are: (i) biomass-burning/urban-industrial (BU), (ii) desert dust (DD), (iii) dust/sea-salt (DSS), (iv) mixed (MX) and (v) undetermined (UN). The identification and characterization is made with our algorithm using a variety of aerosol properties, namely aerosol optical depth (AOD), Angstrom exponent (a), fine fraction (FF), effective radius (reff) and Aerosol Index (AI). During the study period (2000e2007), the most frequent aerosol episodes are DD, observed primarily in the western and central Mediterranean Sea, and off the northern African coasts, 7 times/year for strong episodes and 4 times/year for extreme ones, on average. The DD episodes yield 40% of all types of strong aerosol episodes in the study region, while they account for 71.5% of all extreme episodes. The frequency of occurrence of strong episodes exhibits specific geographical patterns, for example the BU are mostly observed along the coasts of southern Europe and off the Atlantic coasts of Portugal, the MX episodes off the Spanish Mediterranean coast and over the Adriatic and northern Aegean Sea, while the DSS ones over the western and central Mediterranean Sea. On the other hand, the extreme episodes for all but DD aerosol display more patchy spatial patterns. The strong episodes exhibit AOD at 550 nm as high as 1.6 in the southernmost parts of central and eastern Mediterranean Sea, which rise up to 5 for the extreme, mainly DD and DSS, episodes. Although more than 90% of all aerosol episodes last 1 day, there are few cases, mainly extreme DD episodes, which last up to 4 days. Independently of their type, the Mediterranean aerosol episodes occur more frequently in spring (strong and extreme episodes) and summer (strong episodes) and most rarely during winter. A significant year by year variability of Mediterranean aerosol episodes has been identified, more in terms of their frequency than intensity. An analysis of 5-day back trajectories for the most extreme episodes provides confidence on the obtained results of the algorithm, based on the revealed origin and track of air masses causing the episodes. The 25 and 6% of all strong and extreme episodes, respectively, are MX, thus highlighting the co-existence of different aerosol types in the greater Mediterranean. The intensity of both MX and DSS episodes exhibits similar patterns to those of DD strong ones, indicating that desert dust is a determinant factor for the intensity of aerosol episodes in the Mediterranean, including DSS and MX episodes.

Atmospheric Chemistry↗

Research studies on advanced optical module/head designs for optical devices

A summary is presented of research in optical data storage materials and of research at the center. The first section contains summary reports under the general headings of: (1) Magnetooptic media: modeling, design, fabrication, characterization, and testing; (2) Optical heads: holographic optical elements; and (3) Optical heads: integrated optics. The second section consist of a proposal entitled, Signal Processing Techniques for Optical Data Storage. And section three presents various publications prepared by the center.

Burke, James J.↗

A symmetrical laser Doppler velocity meter and its application to turbulence characterization

A symmetrical method of optical heterodyning of the Doppler shifted scattered laser radiation developed for velocity measurements with a minimal instrumental spectral broadening and a high signal-to-noise ratio. The method employs two laser beams incident on the moving scatterer and does not use any reference beam for heterodyning. The Doppler signal frequency is independent of the scattering angle and the signal possesses no receiving aperture broadening. Optical alignment is simple. Typical values of the instrumental spectral broadening were approximately 0.8 percent of the center frequency of the Doppler signal, and the signal-to-noise ratio was approximately 25 dB, obtained from an air flow system using submicron dioctylphthalate scattering aerosol. Experimental and theoretical studies were made on the characteristics of the Doppler signal and the effect of system parameters in turbulent flow measurement. The optimization process involved in the beam optics and in the use of a spatial filter is described. For localized flow measurement in any direction of the three-dimensional orthogonal coordinates, the system, using uncorrected optical components, had a sensing volume which can be described by a sensitive length of 600 microns and a diameter of 100 microns.

Mazumder, M. K.↗

The X-ray properties of high-redshift quasi-stellar objects

Sensitive X-ray information is presented for about 90 previously uncataloged high-redshift, optically selected QSOs. Two high-redshift subsets of this larger data base are emphasized: (1) a 'complete' sample of 37 objects with z = 1.8 - 3.0, and B of 19.5 or less and (2) a sample of 78 QSOs that span a narrow range in redshift and optical luminosity. From the complete sample, it is inferred that such QSOs contribute less than 3 percent to the diffuse X-ray background (XRB), and that the contribution of all QSOs with B of 19.5 or less to the XRB is 21 + or - 8 percent. For the narrow sample, it is found that the mean X-ray to optical luminosity ratio is characterized by alpha(eff)ox = 1.50 + or - 0.03. A variety of new, model-independent, empirical evidence is presented that the primary dependence of alpha(ox) is on optical luminosity rather than redshift. It is concluded that QSOs can supply as much as 70 percent of the XRB, with the typical contributor a moderate redshift QSO with B of roughly 19-21.

Anderson, Scott F.↗

Sub-visual Cirrus detection and characterization

Analysis of archived cold optics (COR) radiometer data is yielding useful information on the diurnal, geographic, seasonal and altitude variability of atmospheric background radiance levels in the 11 micron window region. This database is a compilation of Kuiper Infrared Technology Experiment (KITE) and Atmospheric Radiance Study (ARS) observations under a wide variety of conditions. Correlating the measurements from these two studies with the LOWTRAN model code has revealed several important results. First, the 11 micron window appears to be filled-in, i.e., the troughs on either side of the nitric acid peak are shallower than expected. Second, the amplitude of the background radiances measured exceeds the model predictions by a factor of 2 to 3 or more. This is thought to be due to the existence of thin, high altitude cirrus clouds (sub-visual cirrus) above the sensor platform. These high background levels are observed under quiescent conditions in the South Pacific (Marshall Islands), as well as over the continental United States (the West Coast). In the tropics, there appears to be little diurnal variability, a plausible seasonal variation and a linear dependence between 7.2 and 11.4 micron band data, indicating possible multi-spectral approaches to detection of sub-visual cirrus clouds. Theoretical analysis of the magnitude of the effects of a sub-visual cirrus cloud on atmospheric background radiances measured by a near-horizontal sensor is in progress.

Schmidt, E.↗

A scanning defect mapping system for semiconductor characterization

We have developed an optical scanning system that generates maps of the spatial distributions of defects in single and polycrystalline silicon wafers. This instrument, called Scanning Defect Mapping System, utilizes differences in the scattering characteristics of dislocation etch pits and grain boundaries from a defect-etched sample to identify and count them. This system simultaneously operates in the dislocation mode and the grain boundary (GB) mode. In the 'dislocation mode,' the optical scattering from the etch pits is used to statistically count dislocations, while ignoring the GB's. Likewise, in the 'grain boundary mode' the system only recognizes the local scattering from the GB's to generate grain boundary distributions. The information generated by this instrument is valuable for material quality control, identifying mechanisms of defect generation and the nature of thermal stresses during the crystal growth, and the solar cell process design.

Sopori, Bushnan L.↗

WFIRST Grism Characterization

We had presented the optical design and early test result of WFIRST grism spectrometer in previous SPIE conferences. This paper reports the follow-on activity of the spectral and radiometric calibrations, including the calibration methods, experiment designs, and test equipment calibration, such as the light source and detectors used in the test. The real grism calibration includes the throughput versus wavelength, which is largely determined by the diffraction efficiency of the two diffractive surfaces. It also includes spectral resolution, point spread function, and encircle energy measurements. The measured data are presented. The comparisons between the test data and the simulation from theory or optical model are also presented.

Optics↗

A high-resolution radar and CCD imaging study of crater rays in Mare Serenitatis and Mare Nectaris

Radar and spectral image processing techniques are reviewed and their application to the rays in Mare Serenitatis and Mare Nectaris is discussed. Analysis of data for Mare Serenitatis shows that the ray that passes west of the Bessel Crater is characterized by up to 40 percent highland ejecta. Radar data show that optically bright ray deposits are characterized by enhanced 1-50 cm scale roughness within the upper meter of the regolith, but not by enhanced 1-10 m blockiness. Stokes vector analysis of the 3.0 cm radar echoes shows that the western portion of the Bessel ejecta blanket is characterized by an anomalously high nondiffuse depolarized return. The ray analyzed in Mare Nectaris passes close to Rosse Crater and is characterized by a cluster of bright secondary craters within a radar-rough halo downrange of Tycho. This downrange deposit is attributed to excavation of local fragmental material by a secondary debris surge.

Campbell, Bruce A.↗

Orbital Debris Shape Effect Investigations for Mitigating Risk

NASA’s Orbital Debris Program Office (ODPO) and Hypervelocity Impact Technology (HVIT) team have coordinated to better understand the risks to upper stages and spacecraft from non-spherical orbital debris. It is well understood that fragmentation (collision or explosion) events in orbit produce fragments of various materials, sizes, and shapes. To further characterize these parameters, the ODPO is developing the next-generation Orbital Debris Engineering Model (ORDEM) version 4.0 to include orbital debris shape distributions. Ground-based assets, such as radar and optical sensors, can provide size estimates and some insight into material based on radar return or optical filter photometry/spectroscopy, respectively. Characterizing an object’s shape requires more laboratory analyses to infer how shape affects these measurements. More importantly, in addition to size and material/density, the shape of fragments in orbit will alter the ballistic limit equations used in orbital debris risk assessments with NASA’s Bumper Code. The ODPO plans to release ORDEM 4.0 in the coming years. Performing ground-based laboratory impact tests on high-fidelity spacecraft mockups provides the means to directly measure size, mass, material/density, and shape of fragments, all key parameters needed to characterize real-world break up events. The DebriSat test, the results of which are provided, showcases the details of this type of experiment. The goal of this collaborative research between the ODPO and the HVIT team is to include a shape parameter in the environmental and breakup models used to assess risk for various space structures. This paper examines ground-based laboratory impact tests and the associated fragment shape categories. Provided these defined shapes, the approach is simplified by assuming a right circular cylinder (RCC) approximation with varying length-to-diameter ratios. Highlights of impact tests conducted by the HVIT team using non-spherical projectiles based on the RCC approximation are presented. Hydrocode simulations have also been performed to expand on the complexity of variations with non-spherical projectiles. Lastly, ray-tracing simulations of various RCCs of known material are provided to support the ongoing research on optical reflectance distributions with known shapes and to highlight how this may modify the current optical size estimation model. The status and plan forward are outlined for NASA's orbital debris shape effect investigation using a multidisciplinary approach by the ODPO and the HVIT team.

Heather Cowardin↗

Orbital Debris Shape Effect Investigations for Mitigating Risk

NASA’s Orbital Debris Program Office (ODPO) and Hypervelocity Impact Technology (HVIT) team have coordinated to better understand the risks to upper stages and spacecraft from non-spherical orbital debris. It is well understood that fragmentation (collision or explosion) events in orbit produce fragments of various materials, sizes, and shapes. To further characterize these parameters, the ODPO is developing the next-generation Orbital Debris Engineering Model (ORDEM) version 4.0 to include orbital debris shape distributions. Ground-based assets, such as radar and optical sensors, can provide size estimates and some insight into material based on radar return or optical filter photometry/spectroscopy, respectively. Characterizing an object’s shape requires more laboratory analyses to infer how shape affects these measurements. More importantly, in addition to size and material/density, the shape of fragments in orbit will alter the ballistic limit equations used in orbital debris risk assessments with NASA’s Bumper Code. The ODPO plans to release ORDEM 4.0 in the coming years. Performing ground-based laboratory impact tests on high-fidelity spacecraft mockups provides the means to directly measure size, mass, material/density, and shape of fragments, all key parameters needed to characterize real-world break up events. The DebriSat test, the results of which are provided, showcases the details of this type of experiment. The goal of this collaborative research between the ODPO and the HVIT team is to include a shape parameter in the environmental and breakup models used to assess risk for various space structures. This paper examines ground-based laboratory impact tests and the associated fragment shape categories. Provided these defined shapes, the approach is simplified by assuming a right circular cylinder (RCC) approximation with varying length-to-diameter ratios. Highlights of impact tests conducted by the HVIT team using non-spherical projectiles based on the RCC approximation are presented. Hydrocode simulations have also been performed to expand on the complexity of variations with non-spherical projectiles. Lastly, ray-tracing simulations of various RCCs of known material are provided to support the ongoing research on optical reflectance distributions with known shapes and to highlight how this may modify the current optical size estimation model. The status and plan forward are outlined for NASA's orbital debris shape effect investigation using a multidisciplinary approach by the ODPO and the HVIT team.

Heather Cowardin↗

Highly Non-Linear Optical (NLO) organic crystals

This research project involves the synthesis and characterization of organic materials having powerful nonlinear optical (NLO) properties and the growth of highly ordered crystals and monomolecular films of these materials. Research in four areas is discussed: theoretical design of new materials, characterization of NLO materials, synthesis of new materials and development of coupling procedures for forming layered films, and improvement of the techniques for vapor phase and solution phase growth of high quality organic crystals. Knowledge gained from these experiments will form the basis for experiments in the growth of these crystals.

Harris, J. Milton↗

Validation of Satellite Aerosol Retrievals from AERONET Ground-Based Measurements

Accurate and comprehensive assessment of the parameters that control key atmospheric and biospheric processes including assessment of anthropogenic effects on climate change is a fundamental measurement objective of NASA's EOS program (King and Greenstone, 1999). Satellite assessment programs and associated global climate models require validation and additional parameterization with frequent reliable ground-based observations. A critical and highly uncertain element of the measurement program is characterization of tropospheric aerosols requiring basic observations of aerosols optical and microphysical properties. Unfortunately as yet we do not know the aerosol burden man is contributing to the atmosphere and thus we will have no definitive measure of change for the future. This lack of aerosol assessment is the impetus for some of the EOS measurement activities (Kaufman et al., 1997; King et al., 1999) and the formation of the AERONET program (Holben et al., 1998). The goals of the AERONET program are to develop long term monitoring at globally distributed sites providing critical data for multiannual trend changes in aerosol loading and optical properties with the specific goal of providing a data base for validation of satellite derived aerosol optical properties. The AERONET program has evolved into an international federated network of approximately 100 ground-based remote sensing monitoring stations to characterize the optical and microphysical properties of aerosols.

Holben, Brent↗

Fabrication and Atomic Force Microscopy Characterization of Molecular Composites of Fullerenes in Aerogel Matrix for Optical Limiting

An optical limiter is a device which exhibits a decrease in the transmittance in a material with an increase in intensity of light. Sol-gel techniques offer many advantages in the fabrication of materials. These materials possess many desirable properties for nonlinear optical (NLO) device applications which include transparency, high thermal and chemical stabilities, very low refractive index and dielectric constants. C60 shows a higher excited state absorption cross section than the ground state absorption cross section over the complete visible spectrum, and the spectrum of the excited state absorption of C60 has the same general shape as the ground state absorption. This fact suggests that fullerenes are ideal optical limiting materials. Aerogels are fabricated by sol-gel processing. One of the key issues is the dispersion of fullerenes into small and uniform pores of silica aerogel host matrices. The aerogel network was characterized by Raman spectroscopy. Atomic force microscopy is a technique with many advantages to characterize the aerogel materials. The morphology of the cleaved surface for a C60/aerogel sample shows that there are long paralleled shaped stripes with 20-30 nm in width and about 500 nm in length on the cleaved surface. The cleaved surface also was etched by 5% HF solution for one minutes, and it became smoother after HF etching. The main feature in on the surface is the spherical particles with the size of few nanometers, and no aggregated fullerenes appear. The fullerenes are well dispersed in the aerogel matrices.

Lu, W. J .↗