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NASA NTRS1998

Ma'adim Vallis Estuarine Delta in Elysium Basin and Its Relevance as a Landing Site for Exobiology Exploration on Mars

The debouche of Ma'adim Vallis in the Elysium Basin generated a transitional transported sediment structure, which planimetric shape is controlled by the enclosing topography of a deep reentrant gulf of the Basin into the highland. We defined it as an estuarine delta. The location and the importance of this estuarine delta is supported by the theoretical model of graded profile constructed for Ma'adim Vallis, and by two approaches: (i) the reconstruction of Ma'adim Vallis downstream course from Gusev to Elysium Basin, and (ii) the survey of the sediment deposit in the alleged estuary. The longitudinal graded profile of Ma'adim Vallis finds its base-level in the Elysium Basin, at a about 1000 m elevation, which is in agreement with the observed Basin shoreline. This model is supported by observational evidence of flow between the northern rim of Gusev crater, and the Elysium Basin shoreline. This downstream course of Ma'adim Vallis can be divided into three hydrogeologic regions. into three hydrogeologic regions. (a) The first region is a flooded plain (Zephiria Mensae), consisting in chaotic terrain formed by highland rocks, and disintegrated lava of the western flank of Apollinaris. Morphologic indicators of the flood process are: (1) the sediment deposit over the Gusev crater northern rim that reflects the overspilling of the crater-lake water through a 40-km wide gap provided by an ancient impact crater, (2) the tear-drop shaped feature on the northeastern flank of Apollinaris Patera, and (3) the chaotic terrain that suggest the emergence of ground water generated by the seepage of the crater lake through high-permeable broken rampart material. This underground water circulation sustained by the hydrostatic pressure of the crater-lake has likely generated a hydrothermal system in the volcanic environment of Apollinaris Patera. The stratigraphy of the flooded area is identified as Hesperian age, with occurrences of Noachian hilly individual features, and as Amazonian flooded plain and chaotic material, (b) The second region is located on the western flank of Apollinaris Patera. It is surrounded by relics of deep valleys that suggest a former downstream course of Ma'adim Vallis. The geologic setting of this region (Lucus Planum) is interpreted to be an Amazonian formation composed by the middle and lower members of the Medusae Formation., c) The third region corresponds to the convergence of the west and east branches of Ma'adirn Vallis into a deep re-entrant wide gulf that penetrates about 100 km into the highland. This topographic depression is delineated by the 1000 in elevation contour. This gulf has formed an estuarine configuration centered at 3S/190W within the Elysium Basin. This configuration has favored the formation of a estuarine sedimentary delta, because of topographically controlled lateral migration. This estuarine structure is strongly dominated by the incoming supply of Ma'adim Vallis fluvial sediment extracted from Zephiria Mensae and Lucus Planum. The obtuse-angle geometry of the estuary increases the sedimentation rate, which is higher than in the course of the channel. The sediment deposition process is governed by the estuarine water circulation. The inflowing loaded fluvial water enters the estuary as a bottom current, and mixes with the relatively less-loaded water of the receiving basin. When they mixed. the inflowing fluvial material, and the landward basin circulating water generate an accumulation of highly-diversified estuarine deposit stratification. This accumulation of material is mostly centered in the transitional zone of the delta. The sediment trapping efficiency of the estuary is function of the energy balance between the inflowing fluvial water, and the ingoing basin current. The submergence of the delta by the rising of the water-level increases the estuary water-depth, and consequently the sediment entrapment is favored. The locus of sediment accumulation moves landward in the zone of inflowing fluvial water. This results in the rising of the channel base-level, thus in the increase of the length of the longitudinal graded-profile. The sediment deposit facies of the zone A shows a generally smooth surface. The longitudinal deposit is bordered by alluvial terraces that reflect the variations of the channel level. The waning of the Elysium Basin caused the erosion of the Basin estuarine zone by small channels, this episode being characterized by dissected tear-drop shaped mesa-like morphologies in the delta. Our estuarine delta model predicts a lithostratigraphic depositional sequence associated with the water submergence and the transgression of Elysium Basin. The thickness of the estuarine sediment corresponds to the Elysium Basin levels changes relatively to the bed floor of the estuary, The depositional sequence of Ma'adim Vallis are described: (1) a pro-current filled region (A), where fluvial are longitudinally accumulated by the inflowing water, (2) inverse current from Elysium Basin (B), where fluvial and lacustrine sediments are accumulated, and (3) zone of current equilibrium (C), where the sediments are distributed as a shoreline at the boundary of the estuarine delta. The estuary sedimentology dynamics collects and keeps the record of the geologic unit material crossed by Ma'adim Vallis, and those of the lakebed deposit of Elysium Basin. The predicted mixed stratigraphic sequence from fluvial and lacustrine sediment makes this site an exceptional environment to concentrate potential multi-origin biologic records. We envision four possible strategies to explore this sedimentologic record: (1) longitudinal surface and subsurface traverses in region A to investigate outcrop levees, (2) exploration of the mesa walls in region B, (3) deep drilling hole lodging of the sequential deposits in the zones A and B, and (4) surface and subsurface exploration of the shoreline delta. The expected results for each of these strategies are: (1) in the deepest layers of region A are predicted frequent and abundant coarse material, sandy lenses lamination grading downward from sand to cobbles. Volcanic debris from the Noachian crustal Plateau unit material, hydrothermal altered rocks, carbonates, Hesperian and possibly Amazonian volcanic material, from Apollinaris Patera, altered rocks and carbonates from Zephiria Mensae are expected. As a favorable environment for inception of life, possible biological records are expected in transported rock, (2) At the surface, and subsurface (<=100 m), large deposits sandy to silted material from Elysium paleolake basin mixed with fine-grained sediments from Ma'adim Vallis are expected mostly in the upstream part of region B, (3) on the shoreline of the estuarine delta, abundant fine material from Elysium paleolake basin (evaporites, carbonates), mostly Amazonian in age are expected. The Ma'adini estuary is a favorable landing site for all the above mentioned science aspects, and .for its location. The site lies near the equator, which is favorable for the rover solar power supply, and at 1000m elevation, which is a favorable configuration for the descent system braking. Another advantage is the extent of the area of high scientific interest (33,000 sq km), which provides a good ellipse, and potential long study traverses.

Grin, E. A.↗

NASA NTRS2001

MHD Energy Bypass Scramjet Engine

Revolutionary rather than evolutionary changes in propulsion systems are most likely to decrease cost of space transportation and to provide a global range capability. Hypersonic air-breathing propulsion is a revolutionary propulsion system. The performance of scramjet engines can be improved by the AJAX energy management concept. A magneto-hydro-dynamics (MHD) generator controls the flow and extracts flow energy in the engine inlet and a MHD accelerator downstream of the combustor accelerates the nozzle flow. A progress report toward developing the MHD technology is presented herein. Recent theoretical efforts are reviewed and ongoing experimental efforts are discussed. The latter efforts also include an ongoing collaboration between NASA, the US Air Force Research Laboratory, US industry, and Russian scientific organizations. Two of the critical technologies, the ionization of the air and the MHD accelerator, are briefly discussed. Examples of limiting the combustor entrance Mach number to a low supersonic value with a MHD energy bypass scheme are presented, demonstrating an improvement in scramjet performance. The results for a simplified design of an aerospace plane show that the specific impulse of the MHD-bypass system is better than the non-MHD system and typical rocket over a narrow region of flight speeds and design parameters. Equilibrium ionization and non-equilibrium ionization are discussed. The thermodynamic condition of air at the entrance of the engine inlet determines the method of ionization. The required external power for non-equilibrium ionization is computed. There have been many experiments in which electrical power generation has successfully been achieved by magneto-hydrodynamic (MHD) means. However, relatively few experiments have been made to date for the reverse case of achieving gas acceleration by the MHD means. An experiment in a shock tunnel is described in which MHD acceleration is investigated experimentally. MHD has several potential aerospace applications. The first is to improve the performance of hypersonic air-breathing engines for space launch and cruise vehicles. The second is to improve the performance of a high enthalpy wind tunnel. The third is to control a hypersonic vehicle. With such applications in mind, theoretical and experiments are being conducted at the NASA Ames Research Center to develop the MHD technology.

Mehta, Unmeel B.↗

NASA NTRS2021

Chapter 1: Self-organization only possible far from equilibrium--machines making machines

At the suggestion of NASA’s Physical Science Research Program in the Space Life and Physical Science Research and Application Division, Paul Chaikin, Noel Clark, and Sidney Nagel organized a focus session and workshop for the 2020 American Physical Society (APS) March meeting under the auspices of the Division of Soft Matter. Three overarching themes emerged from the workshop and are presented with additional details: • Machines made out of machines • Scalable self-sustaining ecosystems • Active materials and metamaterials This report lays out only some of the potential directions for soft matter dynamics over the next two decades. It also lays out the role that gravity plays in the organization of the basic building blocks of matter. Not only will research on soft matter have tremendous application towards understanding its behavior in our terrestrial environment, but also potentially in other NASA programs such as planetary science, exploration, robotics, etc. Attached is a White Paper for the Decadal Survey that consists of an extended Title along with the previous Introduction and Chapter 2.1 from NASA/CP-20205010493.

soft matter↗

NASA NTRS1977

Relative effects on atmospheric ozone of latitude and altitude of supersonic flight

Three calculations are reported of the potential depletion of ozone by supersonic aircraft. These calculations utilized a two-dimensional model and a three-dimensional photochemical-dynamical model of the atmosphere in which ozone and the dynamical variables of the atmosphere were derived simultaneously. All calculations were based on a continuous atmospheric injection of 1.8 million tons/yr of NO2. Injections of 45 deg N and 20 km, at equilibrium, resulted in a 36% increase in total odd nitrogen between 8 and 38 km and in global ozone depletion of approximately 12%. Injection at 45 deg N and 17 km produced a 27% increase in odd nitrogen, but, because much of this increase occurred below 20 km, the ozone depletion amounted to only 6%. Injection at 10 deg N and 29 km resulted in a 55% increase of odd nitrogen; however, although there was more depletion above 20 km altitude, there was less below that altitude, and the ozone depletion was only 12.5%. In all three calculations, at least half as much ozone depletion occurred in the Southern Hemisphere as in the Northern Hemisphere.

Cunnold, D. M.↗

NASA NTRS1990

Collision integrals and high temperature transport properties for N-N, O-O, and N-O

Accurate collision integrals for the interactions of N(4S0) + N(4S0), O(3P) + O(3P), and N(4S0) + O(3P) are reported. These are computed from a semiclassical formulation of the scattering using the best available representations of all of the potential energy curves needed to describe the collisions. Spectroscopic curves and other accurate measured data are used where available; the results of accurate ab initio electronic structure calculations are used to determine the remaining potential curves. The high-lying states are found to give the largest contributions to the collision cross sections. The nine collision integrals needed to determine transport properties to second order are tabulated for translational temperatures in the range 250-100,000 K. The viscosity, thermal conductivity, diffusion coefficient, and thermal diffusion factor for a gas composed of nitrogen and oxygen atoms in thermal equilibrium have been calculated. It is found that the second-order contribution to the transport properties is small. Graphs of these transport properties for various mixture ratios are presented for temperatures in the range 5000-15,000 K.

Levin, E.↗

NASA NTRS2001

Deterioration of left ventricular chamber performance after bed rest : "cardiovascular deconditioning" or hypovolemia?

BACKGROUND: Orthostatic intolerance after bed rest is characterized by hypovolemia and an excessive reduction in stroke volume (SV) in the upright position. We studied whether the reduction in SV is due to a specific adaptation of the heart to head-down tilt bed rest (HDTBR) or acute hypovolemia alone. METHODS AND RESULTS: We constructed left ventricular (LV) pressure-volume curves from pulmonary capillary wedge pressure and LV end-diastolic volume and Starling curves from pulmonary capillary wedge pressure and SV during lower body negative pressure and saline loading in 7 men (25+/-2 years) before and after 2 weeks of -6 degrees HDTBR and after the acute administration of intravenous furosemide. Both HDTBR and hypovolemia led to a similar reduction in plasma volume. However, baseline LV end-diastolic volume decreased by 20+/-4% after HDTBR and by 7+/-2% after hypovolemia (interaction P<0.001). Moreover, SV was reduced more and the Starling curve was steeper during orthostatic stress after HDTBR than after hypovolemia. The pressure-volume curve showed a leftward shift and the equilibrium volume of the left ventricle was decreased after HDTBR; however, after hypovolemia alone, the curve was identical, with no change in equilibrium volume. Lower body negative pressure tolerance was reduced after both conditions; it decreased by 27+/-7% (P<0.05) after HDTBR and by 18+/-8% (P<0.05) after hypovolemia. CONCLUSIONS: Chronic HDTBR leads to ventricular remodeling, which is not seen with equivalent degrees of acute hypovolemia. This remodeling leads to a greater decrease in SV during orthostatic stress after bed rest than hypovolemia alone, potentially contributing to orthostatic intolerance.

NASA Discipline Cardiopulmonary↗

NASA NTRS1975

Pulsed electromagnetic gas acceleration

Terminal voltage measurements with long cathodes in a high power, quasi-steady MPD discharge show that the critical current for the onset of voltage fluctuations, which was previously shown to be a function of cathode area, approaches an asymptote for cathodes of very large surface area. Floating potential measurements and photographs of the discharge luminosity indicate that the fluctuations are confined to the vicinity of the cathode and hence reflect a cathode emission process rather than a fundamental limit on MPD performance. Photoelectric measurements of particular argon neutral and ion transitions show that the higher electronic states are populated more heavily than would be calculated on the basis of Saha-Boltzmann equilibrium at the local electron temperature and number density. Preliminary optical depth measurements show that for a current of 4 kA and an argon mass flow of 12 g/sec, a population inversion exists between the upper and lower states of the 4880 A argon ion transition.

Jahn, R. G.↗

NASA NTRS1994

Chemical models of the deep atmospheres of Jupiter and Saturn

New and updated chemical kinetic data, elemental abundances, and thermodynamic data are used for thermochemical equilibrium and, where relevant, thermochemical kinetic calculations of gas abundances and condensate stability in the hot, deep atmospheres of Jupiter and Saturn. Over 2000 compounds of all naturally occurring elements in the periodic table are considered. The calculations range from 298 to 2000 K and are done for adiabatic models of the two planetary atmospheres. The results predict the abundances of many gases which are potentially observable by the Galileo probe to Jupiter, by the Cassini mission to Saturn, and by Earth-based and Earth-orbital telescopes. In addition, the results also predict many new species which are potentially observable by a new generation of entry probes capable of penetrating deeper into the atmospheres of Jupiter and Saturn.

Fegley, Bruce, Jr.↗

NASA NTRS2005

Partial Model of Insulator/Insulator Contact Charging

Two papers present a two-phase equilibrium model that partly explains insulator/ insulator contact charging. In this model, a vapor of ions within a gas is in equilibrium with a submonolayer of ions of the same species that have been adsorbed on the surface of an insulator. The surface is modeled as having localized states, each with a certain energy of adsorption for an ion. In an earlier version of the model described in the first paper, the ions do not interact with each other. Using the grand canonical ensemble, the chemical potentials of both vapor and absorbed phases are derived and equated to determine the vapor pressure. If a charge is assigned to the vapor particles (in particular, if single ionization is assumed), then the surface charge density associated with adsorbed ions can be calculated as a function of pressure. In a later version of the model presented in the second paper, the submodel of the vapor phase is extended to include electrostatic interactions between vapor ions and adsorbed ones as well as the screening effect, at a given distance from the surface, of ions closer to the surface. Theoretical values of this model closely match preliminary experimental data on the discharge of insulators as a function of pressure.

Hogue, Michael↗

NASA NTRS2021

Residual Temperature Bias Effects in Stratospheric Species Distributions from LIMS

The Nimbus 7 Limb Infrared Monitor of theStratosphere (LIMS) instrument operated from 25 Octo-ber 1978 through 28 May 1979. Its version 6 (V6) profileswere processed and archived in 2002. We present severaldiagnostic examples of the quality of the V6 stratospheric species distributions based on their level 3 zonal Fourier co-efficient products. In particular, we show that there are smalldifferences in the ascending (A) minus descending (D) or-bital temperature–pressure orT(p) profiles (theirA−Dval-ues) that affect (A−D) species values. SystematicA−Dbi-ases inT(p) can arise from small radiance biases and/or fromviewing anomalies along orbits. There can also be (A−D)differences inT(p) due to not resolving and correcting forall of the atmospheric temperature gradient along LIMS tan-gent view-paths. An error inT(p) affects species retrievalsthrough (1) the Planck blackbody function in forward calcu-lations of limb radiance that are part of the iterative retrievalalgorithm of LIMS, and (2) the registration of the measuredLIMS species radiance profiles in pressure altitude, mainlyfor the lower stratosphere. There are clearA−Ddifferencesfor ozone, H2O, and HNO3but not for NO2. Percentage differences are larger in the lower stratosphere for ozone andH2O because those species are optically thick. We evaluateV6 ozone profile biases in the upper stratosphere with the aid of comparisons against a monthly climatology of UV–ozone soundings from rocketsondes. We also provide resultsof time series analyses of V6 ozone, H2O, and potential vor-ticity for the middle stratosphere to show that their average(A+D) V6 level 3 products provide a clear picture of the evolution of those tracers during Northern Hemisphere win-ter. We recommend that researchers use the average V6 level3 product for their science studies of stratospheric ozone andH2O, while keeping in mind that there are uncorrected non-local thermodynamic equilibrium effects in daytime ozone inthe lower mesosphere and in daytime H2O in the uppermoststratosphere. We also point out that the present-day Soundingof the Atmosphere using Broadband Emission Radiometry(SABER) experiment provides measurements and retrievalsof temperature and ozone that are nearly free of anomalousdiurnal variations and of effects from gradients at low and middle latitudes.

Ellis Remsberg↗

NASA NTRS1978

Infrared spectra of molecules and materials of astrophysical interest

The Raman spectra of gaseous, liquid and solid, and infrared spectra of gaseous and solid isopropylamine-d sub 0 and -d sub 2 was investigated between 4000 and 50 cm superscript -1. Differences between the spectrum of the solid phase and that of the fluid phases were interpreted in terms of an equilibrium between low energy s-trans and high energy gauche conformers, and a complete vibrational assignment was proposed for the s-trans conformer. The far infrared spectra of the gaseous compounds contained bands due to the asymmetric amino and coupled methyl torsions; the assignment of these bands was aided by observation of a number of two quantum transitions for each vibrational mode. The asymmetric potential functions were calculated, which resulted in values for the enthalpy differences between conformers in the gaseous phase of 446 and 523 callmole for the sub 0 -d and -d sub 2 compounds, respectively. The methyl torsional potential function of isopropylamine-d sub 0 was calculated which led to a value for the barrier height to internal rotation of the methyl rotors of 4.23 + or - 0.06 kcal/mole. Values for the ideal gas thermodynamic functions were calculated over a range of temperatures.

Durig, J. R.↗

NASA NTRS1984

Atmospheric limitations to clock synchronization at microwave frequencies

Clock synchronization schemes utilizing microwave signals that pass through the Earth's atmosphere are ultimately limited by our ability to correct for the variable delay imposed by the atmosphere. The atmosphere is non-dispersive at microwave frequencies and imposes a delay of roughly 8 nanosec times the cosecant of the elevation angle. This delay is composed of two parts, the delay due to water vapor molecules (i.e., the wet delay), and the delay due to all other atmospheric constituents (i.e., the dry delay). Water vapor contributes approximately 5 to 10% of the total atmospheric delay but is highly variable, not well mixed, and difficult to estimate from surface air measurements. However, the techniques of passive remote sensing using microwave radiometry can be used to estimate the line of sight delay due to water vapor with potential accuracies of 10 to 20 picosec. The devices that are used are called water vapor radiometers and simply measure the power emitted by the water vapor molecule at the 22.2 GHz spectral line. An additional power measurement is usually included at 31.4 GHz in order to compensate for the effect of liquid water (e.g., clouds). The dry atmosphere is generally in something close to hydrostatic equilibrium and its delay contribution at zenith can be estimated quite well from a simple barometric measurement. At low elevation angles one must compensate for refractive bending and possible variations in the vertical refractivity profile. With care these effects can be estimated with accuracies on the order of 30 picosec down to elevation angles of 10 degree.

Resch, G. M.↗

NASA NTRS1985

Collisionless tearing in a field-reversed sheet pinch assuming nonparallel propagation

The problem of collisionless linear tearing is examined assuming a wave vector with a component normal to the equilibrium field. The geometry is defined and the general form of the linear dispersion equation is calculated. The linear theory results when k is parallel to B are reviewed, and Ampere's law is calculated for the external adiabatic region when k times B does not equal zero, using two-fluid theory. A solution is obtained for the approximate form of the perturbed currents and vector potential assuming quasi-parallel k. The resonant current contributions within the singular layer are calculated, obtaining an estimate of the dispersion equation. The form of the adiabatic currents within the singular layer is calculated, showing that an x-z current system persists even in the limit k perpendicular to B goes to zero. Finally, the perturbed vector potential solutions across the singular layer are matched to obtain the shape of the complete eigenfunction.

Quest, K. B.↗

NASA NTRS2020

The Spectral Radiance of Indirectly Illuminated Surfaces in Regions of Permanent Shadow on the Moon

Regions of permanent shadow at the lunar poles have been suggested to host water ice and potentially other volatile compounds owing to their extremely low temperatures. Imaging in permanent shadow using indirect lighting from nearby topographic highs illuminated by the Sun has demonstrated the feasibility of optical remote sensing of permanent shadow surfaces, and a near-IR detection of water ice spectral features demonstrates the ability to collect usable spectroscopic data. The infrared emission of the lunar surface is largely in radiative equilibrium, so the temperature of surfaces in permanent shadow is driven by the intensity of the indirect illumination. This means that surfaces at very low temperatures, of high interest owing to their ability to trap and retain volatile compounds, will be the most challenging to measure. We provide estimates of indirect spectral radiance as a function of permanent shadow temperature from 400 nm to 14 μm using empirical data on permanent shadow temperature and broadband visible and near IR radiance, coupled with known reflectance properties of lunar materials. The relationships show there is ample radiance and photon radiance for reflectance imaging and spectroscopy from 400 nm to 8 μm at temperatures of regions of permanent shadow above 60K with appropriately designed instruments. Beyond 8 μm lunar spectral properties reduce the available radiance substantially, making reflectance observations challenging.

P. G. Lucey↗

NASA NTRS1980

Atomic data for S IV and solar observations of the 3x/2/3p /2/P-3s3p/2/ /4/P multiplet

High resolution observations of intersystem lines of S IV near 1400 A are available from Skylab. These lines are potentially useful as density diagnostics for the solar atmosphere. Energy levels, transition probabilities and collision strengths have, therefore, been calculated for S IV, including the configurations 3x(2)3p, 3s3p(2), and 3s(2)3d. Line intensities and level populations have been calculated as a function of electron density. The calculated population of the 3s3p(2) (4)P(5/2) level is found to reach a pseudo-Boltzmann equilibrium at a density which is four times higher than is inferred from solar spectra and level population calculations of lighter ions such as O IV.

Bhatia, A. K.↗

NASA NTRS1985

Multiple-scale turbulence closure modeling of confined recirculating flows

A multiple-scale turbulence closure scheme is developed for the numerical predictions of confined recirculating flows. This model is based on the multiple-time-scale concepts of Hanjalic et al. (1980) and takes into account the non-equilibrium spectra energy transfer mechanism. Problems concerning new formulation of energy transfer rate equations and subsequent model coefficient redefinition and energy spectrum partition are discussed. Comparisons are made with several experiments of internal recirculating flows for the purpose of model validation. Numerical results using the present model show significant improvement of predictive capability over that obtained with the single-scale k-epsilon model and show promising potential for complex turbulent flow predictions.

Chen, C. P.↗

NASA NTRS2012

Internal Structure and Mineralogy of Differentiated Asteroids Assuming Chondritic Bulk Composition: The Case of Vesta

Bulk composition (including oxygen content) is a primary control on the internal structure and mineralogy of differentiated asteroids. For example, oxidation state will affect core size, as well as Mg# and pyroxene content of the silicate mantle. The Howardite-Eucrite-Diogenite class of meteorites (HED) provide an interesting test-case of this idea, in particular in light of results of the Dawn mission which provide information on the size, density and differentiation state of Vesta, the parent body of the HED's. In this work we explore plausible bulk compositions of Vesta and use mass-balance and geochemical modelling to predict possible internal structures and crust/mantle compositions and mineralogies. Models are constrained to be consistent with known HED samples, but the approach has the potential to extend predictions to thermodynamically plausible rock types that are not necessarily present in the HED collection. Nine chondritic bulk compositions are considered (CI, CV, CO, CM, H, L, LL, EH, EL). For each, relative proportions and densities of the core, mantle, and crust are quantified. Considering that the basaltic crust has the composition of the primitive eucrite Juvinas and assuming that this crust is in thermodynamic equilibrium with the residual mantle, it is possible to calculate how much iron is in metallic form (in the core) and how much in oxidized form (in the mantle and crust) for a given bulk composition. Of the nine bulk compositions tested, solutions corresponding to CI and LL groups predicted a negative metal fraction and were not considered further. Solutions for enstatite chondrites imply significant oxidation relative to the starting materials and these solutions too are considered unlikely. For the remaining bulk compositions, the relative proportion of crust to bulk silicate is typically in the range 15 to 20% corresponding to crustal thicknesses of 15 to 20 km for a porosity-free Vesta-sized body. The mantle is predicted to be largely dominated by olivine (>85%) for carbonaceous chondrites, but to be a roughly equal mixture of olivine and pyroxene for ordinary chondrite precursors. All bulk compositions have a significant core, but the relative proportions of metal and sulphide can be widely different. Using these data, total core size (metal+ sulphide) and average core densities can be calculated, providing a useful reference frame within which to consider geophysical/gravity data of the Dawn mission.

Toplis, M. J.↗

NASA NTRS1999

Effects of g-Jitter on Diffusion in Binary Liquids

The microgravity environment offers the potential to measure the binary diffusion coefficients in liquids without the masking effects introduced by buoyancy-induced flows due to Earth s gravity. However, the background g-jitter (vibrations from the shuttle, onboard machinery, and crew) normally encountered in many shuttle experiments may alter the benefits of the microgravity environment and introduce vibrations that could offset its intrinsic advantages. An experiment during STS-85 (August 1997) used the Microgravity Vibration Isolation Mount (MIM) to isolate and introduce controlled vibrations to two miscible liquids inside a cavity to study the effects of g-jitter on liquid diffusion. Diffusion in a nonhomogeneous liquid system is caused by a nonequilibrium condition that results in the transport of mass (dispersion of the different kinds of liquid molecules) to approach equilibrium. The dynamic state of the system tends toward equilibrium such that the system becomes homogeneous. An everyday example is the mixing of cream and coffee (a nonhomogeneous system) via stirring. The cream diffuses into the coffee, thus forming a homogeneous system. At equilibrium the system is said to be mixed. However, during stirring, simple observations show complex flow field dynamics-stretching and folding of material interfaces, thinning of striation thickness, self-similar patterns, and so on. This example illustrates that, even though mixing occurs via mass diffusion, stirring to enhance transport plays a major role. Stirring can be induced either by mechanical means (spoon or plastic stirrer) or via buoyancy-induced forces caused by Earth s gravity. Accurate measurements of binary diffusion coefficients are often inhibited by buoyancy-induced flows. The microgravity environment minimizes the effect of buoyancy-induced flows and allows the true diffusion limit to be achieved. One goal of this experiment was to show that the microgravity environment suppresses buoyancy-induced convection, thereby mass diffusion becomes the dominant mechanism for transport. Since g-jitter transmitted by the shuttle to the experiment can potentially excite buoyancy-induced flows, we also studied the effects of controlled vibrations on the system.

Duval, Walter M. B.↗