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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 415 records · Page 23

Spatiotemporal flame propagations, combustion and solid particle emissions from lean and stoichiometric gasoline direct injection engine operation

Increased particle number and mass emissions in gasoline direct injection (GDI) engines should require to investigate in-cylinder flame and combustion characteristics associated with primary source of particle emissions. In this article, in-cylinder spatiotemporal flame luminosity is quantitatively characterized to features combustion process and solid particle emissions from a GDI engine operating in two lean and one stoichiometric modes. Low- and high-steady state operating points were used to compare combustion strategies on flame development and emission characteristics. A fiber-optic sensor composed of eight measurement channels detected the flame front and the direction of the flame propagation in the combustion chamber. Solid particle emissions in the exhaust were measured using an engine exhaust particle sizer and a micro soot sensor. Results of the experiments showed that two lean combustion modes by injection strategies resulted in distinct combustion and flame development. Lean combustion modes generated high diffusion flame by burning stratified rich-mixture. Although the lean cases resulted in strong diffusion flames, the lean-homogeneous produced similar particle size distributions with the stoichiometric mode with high ash particles. Piston pool fires on the piston surface in the lean-stratified mode induced a large accumulation mode with high particle mass concentrations.

42 ENGINEERING↗

The current status of high temperature electrochemistry-based CO 2 transport membranes and reactors for direct CO 2 capture and conversion

The concept of direct CO 2 capture and conversion has attracted significant interest from industries and academia in recent decades due to its potential to address the current grand challenge of global warming/climate change, rapid depletion of fossil fuels and realization of a future carbon neutral ecosystem. The incumbent benchmark technology for CO 2 capture is the post-combustion flue-gas “amine washing”, which is energy intensive and costly for large-scale commercial implementation. The CO 2 conversion technologies, on the other hand, are still at their infancy with many technical challenges to overcome, but primarily being explored in laboratory-scale, low-temperature, solution-based and high-temperature, solid-oxide-based electrochemical cells with renewable electricity perceived as the energy input. In this article, we provide a comprehensive overview on an emergent class of high-temperature electrochemical CO 2 transport membranes that can capture and convert CO 2 into valuable chemicals in single catalytic reactor fashion. The review starts with the chemistry and transport theory of three basic types of membranes purposely designed for different CO 2 feedstocks and downstream conversions. A range of key functional materials used in these membranes and their microstructural/electrochemical properties important to the CO 2 transport are then thoroughly discussed in conjunction with the effects of surface modifications and operating conditions. Several types of combined CO 2 capture and conversion catalytic reactors based on these membranes are also assessed with a focus on their working principles, system configurations and performance demonstrations. Finally, challenges and prospective of these electrochemical CO 2 transport membranes and their associated conversion reactors are candidly discussed for future development.

10 SYNTHETIC FUELS↗

Kinetics and extinction of non-premixed cool and warm flames of dimethyl ether at elevated pressure

Here, the growing demand of clean and efficient propulsion and energy systems has sparked an interest in understanding low-temperature combustion at high pressure. Cool flame transition and extinction limits as well as oxygen concentration dependence at elevated pressures provide insights of the low-temperature and high-pressure fuel reactivity. A new experimental high-pressure counterflow burner platform was designed and developed to achieve the studies of high-pressure cool flames. Dimethyl ether (DME) was chosen to study its non-premixed cool flame in high-pressure counterflow burner at pressure up to 5 atm, perhaps for the first time. This paper investigates the effects of pressure on cool flame structure, extinction and transition limits, and oxygen concentration dependence as well as ozone assisted warm flames of DME in experiments and numerical simulations. The results show that the reignition transition from cool flame to hot flame occurs either with the decrease of the strain rate at a given fuel concentration and pressure or with the increase of fuel mole fraction or pressure at a given strain rate. Furthermore, it is shown that the higher pressure shifts the cool flame to higher strain rates and results in higher cool flame extinction strain rates. However, the existing kinetic model of DME fails in predicting the cool flame extinction limit at elevated pressures. Besides, the cool flame extinction limits are proportional to nth power of the oxygen concentration, [O 2 ] n , and the increase of pressure leads to stronger extinction limit dependence (larger n) on oxygen concentration. The present experiment and detailed kinetic analysis show clearly that increasing pressure promotes the low-temperature chemistry including the oxygen addition reactions. In addition, stable warm flame was first experimentally observed by using DME at elevated pressure with ozone sensitization.

33 ADVANCED PROPULSION SYSTEMS↗

Black-hole powered quantum coherent amplifier

Abstract Atoms falling into a black hole (BH) through a cavity are shown to enable coherent amplification of light quanta powered by the BH-gravitational vacuum energy. This process can harness the BH energy towards useful purposes, such as propelling a spaceship trapped by the BH. The process can occur via transient amplification of a signal field by falling atoms that are partly excited by Hawking radiation reflected by an orbiting mirror. In the steady-state regime of thermally equilibrated atoms that weakly couple to the field, this amplifier constitutes a BH-powered quantum heat engine. The envisaged effects substantiate the thermodynamic approach to BH acceleration radiation.

Physics↗

A Dual-Mode Hybrid System Combining Solar Thermal With Pumped Thermal Energy Storage

A hybrid system that delivers renewable electricity generation and electricity storage capabilities is introduced. This dual-mode hybrid system is based on Pumped Thermal Energy Storage (PTES) which uses a heat pump to convert electricity into thermal energy that is trans-ferred to silica particles which are stored in concrete silos. The stored heat is later converted back to electricity in a heat engine. The heat pump and heat engine use a closed Joule-Brayton cycle and fluidized bed heat exchangers. If the PTES system is co-located with an array of concentrating solar mirrors and a particle receiver, then the silica particles may also be heated up by the concentrating solar power (CSP) system. The PTES heat engine may also be used to convert the stored solar heat into electricity, thereby sharing this system between the PTES and CSP systems and reducing costs. However, this requires careful management of the heat engine off-design parameters. A thermodynamic model is used to evaluate the performance of the dual mode PTES-CSP hybrid system. The model accounts for turbomachinery effi-ciency, and approach temperature and pressure loss in heat exchangers, as well as other sources of inefficiency, such as motor-generator losses, and air fan power. The hybrid system also requires the evaluation of the turbomachinery efficiency and pressure ratio at off-design conditions since the CSP system operates over different temperature ratios than the Carnot Battery. Several design variables and design modifications are investigated, such as pressure ratios and maximum temperatures.

14 SOLAR ENERGY↗

Solar Tower Experiments for Radiometric Calibration and Validation of Infrared Imaging Assets and Analysis Tools for Entry Aero-Heating Measurements

The NASA Engineering and Safety Center sponsored Hypersonic Thermodynamic Infrared Measurements assessment team has a task to perform radiometric calibration and validation of land-based and airborne infrared imaging assets and tools for remote thermographic imaging. The IR assets and tools will be used for thermographic imaging of the Space Shuttle Orbiter during entry aero-heating to provide flight boundary layer transition thermography data that could be utilized for calibration and validation of empirical and theoretical aero-heating tools. A series of tests at the Sandia National Laboratories National Solar Thermal Test Facility were designed for this task where reflected solar radiation from a field of heliostats was used to heat a 4 foot by 4 foot test panel consisting of LI 900 ceramic tiles located on top of the 200 foot tall Solar Tower. The test panel provided an Orbiter-like entry temperature for the purposes of radiometric calibration and validation. The Solar Tower provided an ideal test bed for this series of radiometric calibration and validation tests because it had the potential to rapidly heat the large test panel to spatially uniform and non-uniform elevated temperatures. Also, the unsheltered-open-air environment of the Solar Tower was conducive to obtaining unobstructed radiometric data by land-based and airborne IR imaging assets. Various thermocouples installed on the test panel and an infrared imager located in close proximity to the test panel were used to obtain surface temperature measurements for evaluation and calibration of the radiometric data from the infrared imaging assets. The overall test environment, test article, test approach, and typical test results are discussed.

Splinter, Scott C.↗

(Ca,Mg)-Carbonate and Mg-Carbonate at the Phoenix Landing Site: Evaluation of the Phoenix Lander's Thermal Evolved Gas Analyzer (TEGA) Data Using Laboratory Simulations

Calcium carbonate (4.5 wt. %) was detected in the soil at the Phoenix Landing site by the Phoenix Lander s The Thermal and Evolved Gas Analyzer [1]. TEGA operated at 12 mbar pressure, yet the detection of calcium carbonate is based on interpretations derived from thermal analysis literature of carbonates measured under ambient (1000 mbar) and vacuum (10(exp -3) mbar) conditions [2,3] as well as at 100 and 30 mbar [4,5] and one analysis at 12 mbar by the TEGA engineering qualification model (TEGA-EQM). Thermodynamics (Te = H/ S) dictate that pressure affects entropy ( S) which causes the temperature (Te) of mineral decomposition at one pressure to differ from Te obtained at another pressure. Thermal decomposition analyses of Fe-, Mg-, and Ca-bearing carbonates at 12 mbar is required to enhance the understanding of the TEGA results at TEGA operating pressures. The objectives of this work are to (1) evaluate the thermal and evolved gas behavior of a suite of Fe-, Mg-, Ca-carbonate minerals at 1000 and 12 mbar and (2) discuss possible emplacement mechanisms for the Phoenix carbonate.

Sutter, B.↗

Enhanced energy conversion efficiency promoted by cavitation in gasoline direct injection

High-pressure direct fuel injection plays the most crucial role in energy conversion and improving engine combustion efficiency and emission. The optimization of turbulent and multiphase fuel injection has focused on controlling hydrodynamic parameters such as injection pressure. While the thermodynamic influence is often considered in the flash boiling situation, we inquire into how gasoline-type fuel’s hydro- and thermodynamic properties impact the injection dynamics by fuel-temperature induced cavitation. The turbulent and cavitating flows emanating from the direct-injection nozzle is visualized by ultrafast x-ray imaging with an unprecedented spatiotemporal resolution. The ultrafast liquid-fuel dynamics are dominated by injection pressure as well as fuel temperature through cavitation, an important thermodynamic parameter but often difficult to control in engine combustion. With the most direct and quantitative measurement, we discovered that the near-nozzle fuel-jet dynamics can be perfectly scaled by a single dimensionless parameter, cavitation number, particularly sensitive to the fuel temperature, in a wide operation range. This universal scaling shows that cavitation can be harnessed to elevate the pneumatic-hydraulic to kinetic energy conversion efficiency, critical for promoting fuel atomization and engine combustion performance. This enhancement effect will have even more impact on engine combustion using alternative low-emission fuels with higher saturated vapor pressure.

30 DIRECT ENERGY CONVERSION↗

Computing Properties Of Chemical Mixtures At Equilibrium

Scientists and engineers need data on chemical equilibrium compositions to calculate theoretical thermodynamic properties of chemical systems. Information essential in design and analysis of such equipment as compressors, turbines, nozzles, engines, shock tubes, heat exchangers, and chemical-processing equipment. CET93 is general program that calculates chemical equilibrium compositions and properties of mixtures for any chemical system for which thermodynamic data are available. Includes thermodynamic data for more than 1,300 gaseous and condensed species and thermal-transport data for 151 gases. Written in FORTRAN 77.

Mcbride, B. J.↗

Recent Stirling engine loss-understanding results

For several years, NASA and other U.S. government agencies have been funding experimental and analytical efforts to improve the understanding of Stirling thermodynamic losses. NASA's objective is to improve Stirling engine design capability to support the development of new engines for space power. An overview of these efforts was last given at the 1988 IECEC. Recent results of this research are reviewed.

Tew, Roy C.↗

Recent Stirling engine loss-understanding results

For several years, NASA and other U.S. government agencies have been funding experimental and analytical efforts to improve the understanding of Stirling thermodynamic losses. NASA's objective is to improve Stirling engine design capability to support the development of new engines for space power. An overview of these efforts was last given at the 1988 IECEC. Recent results of this research are reviewed.

Tew, Roy C.↗

Design, Activation, and Operation of the J2-X Subscale Simulator (JSS)

The purpose of this paper is to give a detailed description of the design, activation, and operation of the J2-X Subscale Simulator (JSS) installed in Cell 1 of the E3 test facility at Stennis Space Center, MS (SSC). The primary purpose of the JSS is to simulate the installation of the J2-X engine in the A3 Subscale Rocket Altitude Test Facility at SSC. The JSS is designed to give aerodynamically and thermodynamically similar plume properties as the J2-X engine currently under development for use as the upper stage engine on the ARES I and ARES V spacecraft. The JSS is a scale pressure fed, LOX/GH fueled rocket that is geometrically similar to the J2-X from the throat to the nozzle exit plane (NEP) and is operated at the same oxidizer to fuel ratios and chamber pressures. This paper describes the heritage hardware used as the basis of the JSS design, the newly designed rocket hardware, igniter systems used, and the activation and operation of the JSS.

Saunders, Grady P.↗

Model-based diagnostics for the SSME

This paper presents models to diagnose the condition of the Space Shuttle Main Engine (SSME). A qualitative physics based model derived from the thermodynamic processes and the flow characteristics underlying the SSME operation was developed to detect and isolate engine failures to the component level. This qualitative model was augmented with empirical models derived from the SSME test-stand data to rapidly detect faults which manifest themselves in engine parameter measurements as deviations from the nominal values. The empirical models integrated with the qualitative model offer the potential for building a complex modeling framework for performing comprehensive engine health monitoring.

Tulpule, S.↗

An Engineer's Tool For Prediction Of Airframe Integrated Scramjet Performance (SCRAM)

Program developed to support research on National Aero-Space Plane, which takes off horizontally and flies into orbit. SCRAM performs nose-to-tail simulation of real gas flow with equilibrium thermodynamic characteristics encountered in hydrogen-fueled ramjet/scramjet engine. Written for supersonic flows, code modified to handle subsonic flows and dual-mode combustor operation. Written in FORTRAN 77.

Walton, J. T.↗

Experimental Study of Instabilities in Hydrogen-Air Fueled Rotating Detonation Combustion Presentation

Conventional gas turbine engines rely on an idealized constant pressure combustion process that in reality produces a pressure decrease as a result of viscous and other non-reversible losses. An alternative approach is rotating detonation combustion (RDC) which is a form of pressure gain combustion in which one or more detonation waves propagate an annular channel resulting in an increase in pressure across, subsequently providing greater work availability compared to deflagration ultimately leading to opportunities for greater thermodynamic efficiency when used in gas turbine engines that conventionally relies on constant. Modern gas turbine engines often rely on pre-mixed reactants to limit NOx emissions, although this may result in greater susceptibility to instabilities such as flashback and thermoacoustic oscillation, particularly for applications that utilize hydrogen as the fuel. Research in RDC has focused on non-premixed reactants thus limiting the occurrence of flashback, and high frequency detonation wave propagation (kHz) may interfere with the occurrence of thermoacoustic oscillations. Thermal NOx emissions are controlled through rapid combustion and sudden expansion of the working fluid. Although RDC may not be susceptible to instabilities encountered in conventional state of the art gas turbine engine combustion, there may be other mechanisms occurring that support instabilities that could be detrimental to performance.

Weber, Justin↗

Quasi-One-Dimensional Modeling of Pulse Detonation Rocket Engines

Pulsed detonation rocket engines (PDREs) have generated considerable research interest in recent years as a chemical propulsion system potentially offering improved performance and reduced complexity compared to conventional rocket engines. The detonative mode of combustion employed by these devices offers a thermodynamic advantage over the constant-pressure deflagrative combustion mode used in conventional rocket engines and gas turbines. However, while this theoretical advantage has spurred a great deal of interest in building PDRE devices, the unsteady blowdown process intrinsic to the PDRE has made realistic estimates of the actual propulsive performance problematic. The recent review article by Kailasanath highlights some of the difficulties in comparing the available experimental measurements with numerical models. In a previous paper by the author, parametric studies of the performance of a single, straight-tube PDRE were reported. A 1-D, unsteady method of characteristics code, employing a constant-gamma assumption behind the detonation front, was developed for that study. Models of this type are computationally inexpensive, and are particularly useful for parametric performance comparisons. For example, a plot showing the specific impulse of various PDRE and steady-state rocket engine (SSRE) configurations as a function of blowdown pressure ratio. The performance curves clearly indicate that a straight-tube PDRE is superior in specific impulse to a SSRE with a sonic nozzle over the entire range of pressure ratios. Note, however, that a straight-tube PDRE in general does not compare favorably to a SSRE fitted with an optimized de Laval supersonic nozzle, particularly at the high pressure ratios typical for boost or in-space rocket applications. However, the calculations also show that if a dynamically optimized, supersonic de Laval nozzle could be could be fitted to a PDRE, then the specific impulse of the device would exceed that of a comparable SSRE. While such a nozzle is a considerable idealization, it is clear that nozzle design and optimization will play a critical role in whether the performance potential of PDREs can be effectively realized in practice. In order to study PDRE nozzle issues with greater accuracy, a quasi-one-dimensional, finite-rate chemistry CFD code has been developed by the author. Comparisons of the code with both the previous MOC model and experimental data from Stanford University are reported. The effect of constant-gamma and finite-rate chemistry assumptions on the flowfield and performance is examined. Parametric studies of the effect of nozzle throat size and expansion ratio, at various blowdown pressure ratios, are reported.

Morris, Christopher I.↗

Axisymmetric Numerical Modeling of Pulse Detonation Rocket Engines

Pulse detonation rocket engines (PDREs) have generated research interest in recent years as a chemical propulsion system potentially offering improved performance and reduced complexity compared to conventional rocket engines. The detonative mode of combustion employed by these devices offers a thermodynamic advantage over the constant-pressure deflagrative combustion mode used in conventional rocket engines and gas turbines. However, while this theoretical advantage has spurred considerable interest in building PDRE devices, the unsteady blowdown process intrinsic to the PDRE has made realistic estimates of the actual propulsive performance problematic. The recent review article by Kailasanath highlights some of the progress that has been made in comparing the available experimental measurements with analytical and numerical models. In recent work by the author, a quasi-one-dimensional, finite rate chemistry CFD model was utilized to study the gasdynamics and performance characteristics of PDREs over a range of blowdown pressure ratios from 1-1000. Models of this type are computationally inexpensive, and enable first-order parametric studies of the effect of several nozzle and extension geometries on PDRE performance over a wide range of conditions. However, the quasi-one-dimensional approach is limited in that it cannot properly capture the multidimensional blast wave and flow expansion downstream of the PDRE, nor can it resolve nozzle flow separation if present. Moreover, the previous work was limited to single-pulse calculations. In this paper, an axisymmetric finite rate chemistry model is described and utilized to study these issues in greater detail. Example Mach number contour plots showing the multidimensional blast wave and nozzle exhaust plume are shown. The performance results are compared with the quasi-one-dimensional results from the previous paper. Both Euler and Navier-Stokes solutions are calculated in order to determine the effect of viscous effects in the nozzle flowfield. Additionally, comparisons of the model results to performance data from CalTech, as well as experimental flowfield measurements from Stanford University, are also reported.

Morris, Christopher I.↗