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Reference NO2 calibration system for ground-based intercomparisons during NASA's GTE/CITE 2 mission

An NO2 calibration system, based on a permeation device and a two-stage dynamic dilution system, was designed, constructed, and characterized at the National Bureau of Standards. In this system, calibrant flow entering the second stage was controlled without contacting a metal flow controller, and permeation oven temperature and flow were continuously maintained, even during transport. The system performance and the permeation emission rate were characterized by extensive laboratory tests. This system was capable of accurately delivering known NO2 concentrations in the ppbv and sub-ppbv concentration range with a total uncertainty of approximately 10 percent. The calibration system was placed on board NASA research aircraft at both the Wallops Island and Ames research facilities. There it was employed as the reference standard in NASA's Global Tropospheric Experiment/Chemical Instrumental Test and Evaluation 2 mission in August 1986.

Fried, Alan↗

Atmospheric emissions and trends of nitrous oxide deduced from 10 years of ALE-GAGE data

Long-term measurements of nitrous oxide (N2O) obtained during the Atmospheric Lifetime Experiment (ALE) and the Global Atmospheric Gases Experiment (GAGE) for a period from 1978 to 1988 are presented and interpreted. It is observed that the average concentration in the Northern Hemisphere is 0.75 +/- 0.16 ppbv higher than in the Southern Hemisphere and that the global average linear trend in N2O lies in the range from 0.25 to 0.31 percent/year. The measured trends and latitudinal distributions are shown to be consistent with the hypothesis that stratospheric photodissociation is the major atmospheric sink for N2O, while the cause of the N2O trend is suggested to be a combination of a growing tropical source and a growing Northern mid-latitude source. A 10-year average global N2O emission rate of (20.5 +/- 2.4) x 10 to the 12th g N2O/year is deduced from the ALE/GAGE data.

Prinn, R.↗

Methane fluxes in wetland and forest soils, beaver ponds, and low-order streams of a temperate forest ecosystem

This study was conducted to determine whether temperate wetlands and forests play important roles in the global balances of atmospheric methane. Flux measurements for methane in several different wetland, forest, and open-water (e.g., beaver pond and low-order stream) sites were determined using collection chambers placed over the soil- or water-air interface. All of the sites were located in the Appalachian Mountain region of West Virginia and western Maryland. Between June 1987 and April 1989 the wetland sites acted as small sources of atmospheric methane, with emission rates for methane usually lower than 200 mg CH4/sq m per day; consumption of atmospheric methane in the wetland soils was observed frequently.

Yavitt, J. B.↗

Theoretical predictions

In order to understand the impact of man made chemicals on the atmospheric ozone layer, it is essential to develop models that can perform long term predictions of future ozone changes. An advantage of using two dimensional models is that they can be used to predict latitudinal and seasonal changes in ozone. The formulation and recent improvements are described in 2-D models, which are used herein, along with the three dimensional models that are currently being developed to better simulate transport of chemically active trace gases, especially in polar regions. The range in 2-D model calculations is described. Selected fields calculated by these models are compared with observations. A number of scenarios have been defined, which encompass possible emission rates of different halocarbons. Because of the large uncertainties in the rates for heterogeneous processes, the calculated responses of the models include only the effects of homogeneous chemistry. One important distinction among the models is their ability to account for temperature feedbacks on the calculated ozone changes.

Brasseur, G.↗

The Apollo 17 Ultraviolet Spectrometer - Lunar atmosphere measurements revisited

Ultraviolet resonance fluorescence of solar radiation provides the most sensitive means of detecting the expected major constituents of the tenuous daytime lunar atmosphere. Such an experiment was carried out with the Apollo 17 Ultraviolet Spectrometer in December 1972 and produced only upper limits to the number density of H, H2, O, C, N, CO, and two noble gases near the surface of the moon. The complete data set of 47 terminator crossing observations, which were not utilized in the earlier analysis, has been reexamined, and more stringent upper limits to the column emission rates for several species have been derived. These results, together with most recent values for the atomic and molecular fluorescence efficiencies, lead to more definitive limits on the content of the lunar atmosphere. The revised upper limit on atomic oxygen density allows for the possibility of comparable O/Na ratios in the atmosphere of both the moon and Mercury.

Feldman, Paul D.↗

Upper limits on spacecraft-induced ultraviolet emissions from the Space Shuttle (STS-61C)

Results are reported from a search for band emission of N2, OH, O2, and NO in nightglow spectra obtained in January 1986 with the Johns Hopkins UV background experiment (UVX) flown on the Space Shuttle Columbia (STS-61C) at an altitude of 330 km. The experiment consisted of two Ebert monochromators spanning the spectral range from 1200 to 1700 A at 17-A resolution and from 1600 to 3200 A at 29-A resolution. UV shuttle glow emission was not detected at a 330-km altitude with 3-sigma upper limits based on counting statistics on N2 LBH, O2 Herzberg, and NO delta, gamma, and beta of 5.3, 4.5, 0.6, 0.7, and 3.5 R of total band emission, respectively. The upper limit on the OH (A 2Sigma-u(+) - X2Pi)(0,0) and (1,0) band emission is 0.1 R. The branching ratio of the NO C2Pi state to the A2Sigma(+) state was determined from the UVX experiment by measuring the ratio of the total emission rate from the delta-band system to that of the gamma-band system. The branching ratio for the C2Pi state to the A2Sigma(+) state is 0.37 +/-0.03.

Morrison, D.↗

Low-latitude particle precipitation and associated local magnetic disturbances

The paper investigates the O(+) ion and NO(+) ion temperature and temperature anisotropy for a spatially homogeneous auroral F region in the presence of large electric fields perpendicular to the geomagnetic field. The maximum optical emissions at midlatitudes occur in concert with the maximum positive (northward) excursions in the H trace and with rapid fluctuations in the D trace of nearby magnetograms. The source of the particles is inferred to be the ring current, with precipitation occurring when the Dst index is large at the time of the large short-term excursions in the local magnetic field. This result is consistent with the finding of Voss and Smith (1979), derived from a series of rocket measurements of precipitating heavy particles, that the flux correlates better with the product of Dst and the exponential of Kp than with either alone. It is shown that the product of Dst and the amplitude of the short-term excursions in the horizontal component in local magnetograms has better time resolution and better correlation with the observed emission rates than the index using Kp.

Rassoul, H. K.↗

Neutral winds in the lower thermosphere from Dynamics Explorer 2

Doppler line profile measurements of the OI lambda 557.7 nm 'green line' emission, made by the Fabry-Perot interferometer on Dynamics Explorer 2, have provided altitude profiles of the meridional component of the lower thermospheric neutral wind. The wind inversion technique of Nardi has been used to extract the neutral wind profiles from the line-of-sight measurements. Individual lambda 557.7 nm Doppler line profiles and inverted volume-emission-rate and neutral-wind profiles are presented. Neutral wind measurements from the about 120 km altitude level, obtained on multiple orbital passes over the summer hemisphere polar region, have been merged to produce a synthesized averaged 'vector' wind field in geomagnetic coordinates. The wind pattern exhibits a region of anticyclonic vorticity in the daytime sector of the magnetic polar cap. Averaged winds of about 300 m/sec in the equatorial direction are observed in the early morning sector. The satellite winds are in reasonable agreement with the predictions of the NCAR and UCL thermosphere general circulation models, with significant regional discrepancies evident in both magnitude and direction.

Killeen, T. L.↗

Measurements of NO(x) and NO(y) concentrations and fluxes over Arctic tundra

Measurements of the atmospheric concentrations of NO, NO2, total NO(y), and O3 were made during the NASA Arctic Boundary Layer Expedition (ABLE 3A) at a remote location in a tundra bog ecosystem in southeastern Alaska during the growing season (July-August 1988). Concentrations of NO(x) and NO(y) were found to be very low compared to other remote continental sites, indicating that anthropogenic influences were small at this site during this time of year. The NO(y) emission rate from the soil were 0.13 +/- 0.05 x 10 exp 9 molecules/sq cm/s. Direct measurements of the flux of total NO(y) were made for the first time, indicating downward flux of NO(y) at all times of day, with maximum deposition of 2.5 +/- 0.9 x 10 exp 9 molecules/sq cm/s in the afternoon. Deposition of HNO3 appears to dominate the atmosphere/surface exchange of NO(y). The mean dry deposition rate of NO(y) to the tundra was 1.8 +/- 1.0 x 10 exp 9 molecules/sq cm/s.

Bakwin, Peter S.↗

Theory, Image Simulation, and Data Analysis of Chemical Release Experiments

The final phase of Grant NAG6-1 involved analysis of physics of chemical releases in the upper atmosphere and analysis of data obtained on previous NASA sponsored chemical release rocket experiments. Several lines of investigation of past chemical release experiments and computer simulations have been proceeding in parallel. This report summarizes the work performed and the resulting publications. The following topics are addressed: analysis of the 1987 Greenland rocket experiments; calculation of emission rates for barium, strontium, and calcium; the CRIT 1 and 2 experiments (Collisional Ionization Cross Section experiments); image calibration using background stars; rapid ray motions in ionospheric plasma clouds; and the NOONCUSP rocket experiments.

Wescott, Eugene M.↗

Morphology and time variation of the Jovian Far UV aurora: Hubble Space Telescope observations

High spatial resolution images of the north polar region of Jupiter have been obtained with the Faint Object Camera (FOC) on board the Hubble Space Telescope (HST). The first set of two images collected 87 min apart in February 1992 shows a bright (approximately or equal to 180 kR) emission superimposed on the background in rotation with the planet. Both Ly alpha images show common regions of enhanced emission but differences are also observed, possibly due to temporal variations. The second group of images obtained on June 23 and 26, 1992 isolates a spectral region near 153 nm dominated by the H2 Lyman bands and continuum. Both pictures exhibit a narrow arc structure fitting the L = 30 magnetotail field line footprint in the morning sector and a broader diffuse aurora in the afternoon. They show no indication of an evening twilight enhancement. Although the central meridian longitudes were similar, significant differences are seen in the two exposures, especially in the region of diffuse emission, and interpreted as signatures of temporal variations. The total power radiated in the H2 bands is approximately or equal to 2 x 10(exp 12) W, in agreement with previous UV spectrometer observations. The high local H2 emission rates (approximately 450 kR) imply a particle precipitation carrying an energy flux of about 5 x 10(exp -2) W/sq m.

Gerard, Jean-Claude↗

Quantitative measurements of vaporization, burst ionization, and emission characteristics of shaped charge barium releases

Intensity-calibrated color video recordings of three barium-shaped charge injections in the ionopshere were used to determine the initial ionization, the column density corresponding to unity optical depth, and the yield of vaporized barium in the fast jet. It was found that the initial ionization at the burst was less than 1% and that 0% burst ionization was consistent with the observations. Owing to the Doppler shift, the column density for optical thickness in the neutral barium varies somewhat according to the velocity distribution. For the cases examined here, the column density was 2-5 x 10(exp 10) atoms/sq cm. This value, which occurred 12 to 15 s after release, should be approximately valid for most shaped charge experiments. The yield was near 30% (15% in the fast jet) for two of the releases and was somewhat lower in the third, which also had a lower peak velocity. This study also demonstrated the applicability of the computer simulation code developed for chemical releases by Stenbaek-Nielsen and provided experimental verification of the Doppler-corrected emission rates calculated b Stenbaek-Nielsen (1989).

Hoch, Edward L.↗

Tracer transport for realistic aircraft emission scenarios calculated using a three-dimensional model

A three-dimensional transport model, which uses winds from a stratospheric data assimilation system, is used to study the transport of supersonic aircraft exhaust in the lower stratosphere. A passive tracer is continuously injected into the transport model. The tracer source distribution is based on realistic scenarios for the daily emission rate of reactive nitrogen species for all forecasted flight routes. Winds are from northern hemisphere winter/spring months for 1979 and 1989; there are minimal differences between the tracer integrations for the 2 years. During the integration, peak tracer mixing ratios in the flight corridors are compared with the zonal mean and found to be greater by a factor of 2 or less. This implies that the zonal mean assumption used in two dimensional models is reasonable during winter and spring. There is a preference for pollutant buildup in the heavily traveled North Pacific and North Atlantic flight corridors. Pollutant concentration in the corridors depends on the position of the Aleutian anticyclone and the northern hemisphere polar vortex edge.

Weaver, Clark J.↗

A Remarkable Auroral Event on Jupiter Observed in the Ultraviolet with the Hubble Space Telescope

Two sets of ultraviolet images of the Jovian north aurora were obtained with the Faint Object Camera on board the Hubble Space Telescope. The first series shows an intense discrete arc in near corotation with the planet. The maximum apparent molecular hydrogen emission rate corresponds to an electron precipitation of approximately 1 watt per square meter, which is about 30,000 times larger than the solar heating by extreme ultraviolet radiation. Such a particle heating rate of the auroral upper atmosphere of Jupiter should cause a large transient temperature increase and generate strong thermospheric winds. Twenty hours after initial observations, the discrete arc had decreased in brightness by more than one order of magnitude. The time scale and magnitude of the change in the ultraviolet aurora leads us to suggest that the discrete Jovian auroral precipitation is related to large-scale variations in the current system as is the case of for Earth's discrete aurorae.

Gerard, J. C.↗

On the Utility of the Molecular Oxygen Dayglow Emissions as Proxies for Middle Atmospheric Ozone

Molecular oxygen dayglow emissions arise in part from processes related to the Hartley band photolysis of ozone. It is therefore possible to derive daytime ozone concentrations from measurements of the volume emission rate of either dayglow. The accuracy to which the ozone concentration can be inferred depends on the accuracy to which numerous kinetic and spectroscopic rate constants are known, including rates which describe the excitation of molecular oxygen by processes that are not related to the ozone concentration. We find that several key rate constants must be known to better than 7 percent accuracy in order to achieve an inferred ozone concentration accurate to 15 percent from measurements of either dayglow. Currently, accuracies for various parameters typically range from 5 to 100 percent.

Mlynczak, Martin G.↗

Computational Pollutant Environment Assessment from Propulsion-System Testing

An asymptotic plume growth method based on a time-accurate three-dimensional computational fluid dynamics formulation has been developed to assess the exhaust-plume pollutant environment from a simulated RD-170 engine hot-fire test on the F1 Test Stand at Marshall Space Flight Center. Researchers have long known that rocket-engine hot firing has the potential for forming thermal nitric oxides, as well as producing carbon monoxide when hydrocarbon fuels are used. Because of the complex physics involved, most attempts to predict the pollutant emissions from ground-based engine testing have used simplified methods, which may grossly underpredict and/or overpredict the pollutant formations in a test environment. The objective of this work has been to develop a computational fluid dynamics-based methodology that replicates the underlying test-stand flow physics to accurately and efficiently assess pollutant emissions from ground-based rocket-engine testing. A nominal RD-170 engine hot-fire test was computed, and pertinent test-stand flow physics was captured. The predicted total emission rates compared reasonably well with those of the existing hydrocarbon engine hot-firing test data.

Wang, Ten-See↗

Satellite Investigations of Fire, Smoke, and Carbon Monoxide during April 1994 MAPS Mission: Case Studies over Tropical Asia

During April 9-19, 1994, the Measurement of Air Pollution from Satellites (MAPS) measured free tropospheric carbon monoxide (CO) concentrations on a near-global basis. For these eleven days the global lkm advanced very high resolution radiometer (AVHRR) Pathfinder data are used to detect fires and smoke over the Indo-Burma region (85 degrees E - 110 degrees E; 10 degrees N -30 degrees N). The fire activities are categorized for four major ecosystems that include (1) cropland/natural vegetation mosaic (CNVM), (2) evergreen broadleaf forest (EBF), (3) mixed forest (MFD), and (4) grassland (GL). Using published emission rates between particulate matter and carbon monoxide concentrations from temperate areas, the fire counts along with other information are used to obtain estimates of CO concentrations from the AVERR data. More than 7000 fires are detected during the study period with 23%, 43%, 24%, and 10% fires in the CNVM, EBF, MFD, and GL ecosystems, respectively. The enhanced CO concentrations over the area of study are either over or downwind of the fires detected by the AVHRR. The preliminary AVHRR estimates of CO concentrations are smaller than the MAPS-measured values by a factor of 4 to 5 for fire counts areater than 200. The differences are attributed to the lack of transport mechanisms and other assumptions in the current model. However, these results show a good potential for usino the AVHRR measurements to detect fires and smoke and also to estimate CO concentrations.

Christopher, Sundar A.↗

Infrared Emission and Thermal Processes in Spiral Galaxies

In this research we constructed theoretical models of the infrared and submillimeter line and continuum emission from the neutral interstellar medium in the Milky Way and external galaxies. The model line intensities were compared to observations of the Galactic disk and several galaxies to determine the average physical properties of the neutral gas including the density, temperature, and ultraviolet radiation field which illuminates the gas. In addition we investigated the heating mechanisms in the Galactic disk and estimated the emission rate of the [C 11] 158 micrometer line as a function of position in the Galaxy. We conclude that the neutral gas is heated mainly by the grain photoelectric effect and that a two phase (CNM+WNM) is possible between Galactic radii R = 3 kpc and R = 18 kpc. Listings of meeting presentations and publications are included.

Mundy, Lee↗