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At least 415 records · Page 23

On the Jet–Ejecta Interaction in 3D GRMHD Simulations of a Binary Neutron Star Merger Aftermath

Short γ-ray burst (sGRB) jets form in the aftermath of a neutron star merger, drill through disk winds and dynamical ejecta, and extend over four to five orders of magnitude in distance before breaking out of the ejecta. We present the first 3D general-relativistic magnetohydrodynamic sGRB simulations to span this enormous scale separation. They feature three possible outcomes: jet+cocoon, cocoon, and neither. Typical sGRB jets break out of the dynamical ejecta if (i) the bound ejecta's isotropic equivalent mass along the pole at the time of the BH formation is ≲10 -4 M ⊙ , setting a limit on the delay time between the merger and BH formation, otherwise, the jets perish inside the ejecta and leave the jet-inflated cocoon to power a low-luminosity sGRB; (ii) the postmerger remnant disk contains a strong large-scale vertical magnetic field, ≳1015 G; and (iii) if the jets are weak (≲10 50 erg), the ejecta's isotropic equivalent mass along the pole must be small (≲10 -2 M ⊙ ). Generally, the jet structure is shaped by the early interaction with disk winds rather than the dynamical ejecta. As long as our jets break out of the ejecta, they retain a significant magnetization (≲1), suggesting that magnetic reconnection is a fundamental property of sGRB emission. The angular structure of the outflow isotropic equivalent energy after breakout consistently features a flat core followed by a steep power-law distribution (slope ≳3), similar to hydrodynamic jets. In the cocoon-only outcome, the dynamical ejecta broadens the outflow angular distribution and flattens it (slope ~1.5).

Jets↗

Dissect two-halo galactic conformity effect for central galaxies: the dependence of star formation activities on the large-scale environment

We investigate the two-halo galactic conformity effect for central galaxies, which is the spatial correlation of the star formation activities for central galaxies to several Mpcs, by studying the dependence of the star formation activities of central galaxies on their large-scale structure in our local Universe using the SDSS data. Here we adopt a novel environment metric using only central galaxies quantified by the distance to the nth nearest central galaxy. This metric measures the environment within an aperture from ∼1 to ≳ 10 Mpc, with a median value of ∼4 Mpc. We found that two kinds of conformity effects in our local Universe. The first one is that low-mass central galaxies are more quenched in high-density regions, and we found that this effect mainly comes from low-mass centrals that are close to a more massive halo. A similar trend is also found in the IllustrisTNG simulation, which can be entirely explained by backsplash galaxies. The second conformity effect is that massive central galaxies in low-density regions are more star-forming. This population of galaxies also possesses a higher fraction of spiral morphology and lower central stellar velocity dispersion, suggesting that their low quiescent fraction is due to less-frequent major merger events experienced in the low-density regions and, as a consequence, less-massive bulges and central black holes.

79 ASTRONOMY AND ASTROPHYSICS↗

Continental-Scale Geographic Trends in Barometric-Pumping Efficiency Potential: A North American Case Study

Barometric pumping is a gas transport mechanism that has important implications for many applications involving subsurface gas seepage processes. Here, this study provides the first continental-scale analysis of barometric-pumping efficiency potential based on meteorology. We quantified the barometric-pumping efficiency potential at 1,257 locations across the continental US and Canada. The results provide continental-scale geographic dependencies of barometric-pumping efficiency potential, indicating a significant correlation with latitude and a nonlinear dependence on longitude. The analysis also indicates that variability in barometric-pumping efficiency potential decreases with distance from the coast and as elevation increases. Locations far from the coastline are more likely to have upper mid-range potentials, while higher elevation locations are more likely to have low potentials. The highest barometric-pumping efficiency potentials are mostly found around the Gulf of St. Lawrence around 50°N. Locations along the Atlantic coast exhibit large-scale variations in potentials with a clear increasing trend with latitude.

58 GEOSCIENCES↗

Test of the Gravitational Force Law on Cosmological Scales Using the Kinematic Sunyaev-Zeldovich Effect

The mean pairwise velocity of massive halos reflects the gravitational force law on cosmic scales. For this work, we combine cosmic microwave background intensity maps from the Atacama Cosmology Telescope and a galaxy catalog from the Sloan Digital Sky Survey to estimate the mean pairwise velocity using the kinematic Sunyaev-Zeldovich (kSZ) effect. On scales from 30 to 230 megaparsecs, we constrain the gravitational acceleration between pairs of halos at separation 𝑟 to be 𝑔 ∝ 1/𝑟 𝑛 with 𝑛 = 2.1 ± 0.3, which is consistent with Newtonian gravity in an expanding spacetime (i.e., the standard Λ⁢ CDM model). This constraint shows agreement with an inverse quadratic radial dependence over the large distances separating galaxy halos, as expected in standard cosmology. Upcoming surveys have the potential to rule out 𝑛 = 1 at 10⁢𝜎 significance. Our results establish the kSZ effect as a powerful tool for testing gravity on cosmological scales.

alternative gravity theories↗

Growth of organized flow coherent motions within a single-stream shear layer: 4D-PTV measurements

Abstract This study investigates the evolution of a single-stream shear layer (SSSL) originating from a wall boundary layer past a backward-facing step. Utilizing a time-resolved 3D-Particle Tracking Velocimetry (4D-PTV) technique, we track the trajectories of fluorescent particles to gain insight into the flow characteristics of the SSSL. A compact water tunnel facility ( $$\textrm{Re}_\tau =1\,240$$ Re τ = 1 240 ) is fabricated to obtain an SSSL with a perpendicular slow entrainment stream past the separation edge. A hybrid interpolation approach that combines ensemble binning and Gaussian weighting is implemented to derive minimally filtered mean and instantaneous lower- and higher-order flow field parameters. Spanwise-dominant coherent motion accompanied by finer flow scales is observed to grow due to flow entrainment through “nibbling” actions of small-scale vortices, “engulfing” by large-scale vortices, and vortex pairing events. Furthermore, the non-zero-speed stream edge grows relatively faster than the zero-speed stream edge, showing a strong asymmetry in mixing composition across a mixing layer. The SSSL reaches self-similarity at a streamwise distance of $$\approx 55\,\theta _{0}$$ ≈ 55 θ 0 , where $$\theta _0$$ θ 0 is the initial momentum thickness from the separation edge, i.e., considerably shorter than reported in previous studies. A literature comparison of growth rate parameters raises intriguing questions regarding a potential inclusive growth scaling unifying the free shear layers. A turbulent kinetic energy (TKE) budget analysis reveals a negative production region immediately downstream of the separation edge attributed to a large positive streamwise gradient of streamwise velocity. In the self-similar region, the phase-averaged flow mapping demonstrates a larger concentration of turbulence production rate around the outer edges of spanwise vortices, specifically at the intersection of braids and vortices. Furthermore, a spatial separation exists in the regions of peak production and dissipation rates within the vortex core region favoring dissipation. The braids exhibit a larger concentration of turbulence diffusion rates, indicating their function as a conduit for exchanging turbulence between neighboring coherent motions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Characterization of oceanic post-cold frontal clouds and their model representation. Final report

Low-level clouds are ubiquitous over the oceans, and their impact on the Earth’ radiative budget is important. However, general circulation models (GCMs) that are used to represent our climate and its evolution still experience problems to represent their correct amount and radiative impact. In the extratropical latitudes (~30-60 N/S), cloud properties are strongly modulated by the occurrence of anti-cyclones (high pressure systems) and cyclones (low pressure systems). While deep clouds dominate in cyclones near the center and along the cold and warm fronts, low-level clouds populate the colder regions of the cyclones, and more specifically the region in the wake of the cold fronts, the post-cold frontal region (PCF). The GCMs mentioned above were found to underestimate the amount of these PCF clouds, and this caused errors in their representation of the amount of solar radiation at the surface of the southern hemisphere oceans, causing an excess in absorption and errors in long-term predictions. To better understand which processes are ill-represented in the GCMs to cause such issues, we used ground-based observations from the Eastern North Atlantic (ENA) ARM site and a high resolution regional model (called WRF) to examine the properties of PCF clouds. With the WRF model, we simulated the passage of a cold front at the ENA site using theoretically distinct representations of convection and the physics of the boundary layer. While these physical representations had little impact on the timing, structure and circulation of the cold front, we found a high sensitivity to how the large scale information was fed into the model. Errors rapidly developed if the incoming flow information was injected too far from the site, but 1000 km was found to be an optimal distance between the outer boundary and the ENA site for a realistic cold front passage. With this model, we then conducted a series of experiment where convection and boundary layer schemes were changed, and revealed that 1) the clouds were more sensitive to the convection than boundary layer schemes and 2) the interaction between the two has a large impact. Furthermore, changing the representation of the physics in the model had greater impacts on PCF clouds than changing the initial conditions. As large-scale models increase their spatial resolution, convection will eventually be resolved but it remains that their representation of the physics of the boundary layer will matter for the correct representation of shallow (low-level) clouds. Observations were used to find which large-scale information had a clear relationship with PCF cloud and precipitation properties, in view of helping with GCM parameterizations and evaluation. Both lower troposphere stability and surface forcing were found to be important for PCF clouds that experience more vigorous dynamics than their tropical or subtropical counterparts. For cloud base and top heights, a simple measure of the change in potential temperature between the surface and the 800 hPa was found to be a good predictor. This relationship was found to hold as well when using data from campaigns recently conducted in the southern ocean south of Tasmania. A recent GCM was found to succeed in representing similar relations. For cloud depth, water content, and different characteristics of precipitation both the temperature contrast between the surface and near-air and the near-surface wind speed had a strong relationship. To summarize, through observational constraints and regional model experiments, the project has provided guidance to evaluate GCMs and tools to improve their representation of low-level clouds in the extratropics. It has also highlighted differences in behavior between these clouds and those typically found in the subtropics, thus opening new avenues of research for shallow clouds in general.

54 ENVIRONMENTAL SCIENCES↗

Dimensional analysis on microscale gas breakdown with electric field nonuniformity and positive space charge effects

A dimensional method was employed to evaluate the microscale gas breakdown characteristics at atmospheric pressure, resulting in a universal breakdown curve applicable to different types of gases (e.g., Ar, Xe, Ne, and N2). As the gap distance decreases, the breakdown mode transitions from ion-induced secondary electron emission to the field emission regime. In the field emission regime, the positive space charge effect becomes more significant. We discovered that incorporating the positive space charge effect in the field emission regime can be achieved by modifying the local electric field enhancement factor β. Consequently, we propose an effective electric field enhancement factor, βeff, which scales linearly with β, to accurately reproduce the breakdown curve while considering the positive space charge effect. This proposed approach significantly simplifies the numerical model. Additionally, we examined the effects of gas pressure, gap distance, cathode properties (e.g., work function and secondary electron emission coefficient), and electric field nonuniformity.

Physics↗

Quantitative comparison of power production and power quality onshore and offshore: a case study from the eastern United States

Abstract. A major issue in quantifying potential power generation from prospective wind energy sites is the lack of observations from heights relevant to modern wind turbines, particularly for offshore where blade tip heights are projected to increase beyond 250 m. We present analyses of uniquely detailed data sets from lidar (light detection and ranging) deployments in New York State and on two buoys in the adjacent New York Bight to examine the relative power generation potential and power quality at these on- and offshore locations. Time series of 10 min wind power production are computed from these wind speeds using the power curve from the International Energy Agency 15 MW reference wind turbine. Given the relatively close proximity of these lidar deployments, they share a common synoptic-scale meteorology and seasonal variability with lowest wind speeds in July and August. Time series of power production from the on- and offshore location are highly spatially correlated with the Spearman rank correlation coefficient dropping below 0.4 for separation distances of approximately 350 km. Hence careful planning of on- and offshore wind farms (i.e., separation of major plants by > 350 km) can be used reduce the system-wide probability of low wind energy power production. Energy density at 150 m height at the offshore buoys is more than 40 % higher, and the Weibull scale parameter is 2 m s−1 higher than at all but one of the land sites. Analyses of power production time series indicate annual energy production is almost twice as high for the two offshore locations. Further, electrical power production quality is higher from the offshore sites that exhibit a lower amplitude of diurnal variability, plus a lower probability of wind speeds below the cut-in and of ramp events of any magnitude. Despite this and the higher resource, the estimated levelized cost of energy (LCoE) is higher from the offshore sites mainly due to the higher infrastructure costs. Nonetheless, the projected LCoE is highly competitive from all sites considered.

Foody, Rebecca↗

Rapid Quantum Ground State Preparation via Dissipative Dynamics

Inspired by natural cooling processes, dissipation has become a promising approach for preparing low-energy states of quantum systems. However, the potential of dissipative protocols remains unclear beyond certain commuting Hamiltonians. This work provides significant analytical and numerical insights into the power of dissipation for preparing the ground state of noncommuting Hamiltonians. For quasi-free dissipative dynamics, including certain 1D spin systems with boundary dissipation, our results reveal a new connection between the mixing time in trace distance and the spectral properties of a non-Hermitian Hamiltonian, leading to an explicit and sharp bound on the mixing time that scales polynomially with system size. For more general spin systems, we develop a tensor network-based algorithm for constructing the Lindblad jump operator and for simulating the dynamics. Using this algorithm, we demonstrate numerically that dissipative ground state preparation protocols can achieve rapid mixing for certain 1D local Hamiltonians under bulk dissipation, with a mixing time that scales logarithmically with the system size. We then prove the rapid mixing result for certain weakly interacting spin and fermionic systems in arbitrary dimensions, extending recent results for high-temperature quantum Gibbs samplers to the zero-temperature regime. Together, these results show that dissipation can be a powerful tool for ground state preparation, with potential applications across condensed matter physics, quantum materials science, and beyond.

decoherence↗

From individual leaves to forest stands: importance of niche, distance decay, and stochasticity vary by ecosystem type and functional group for fungal community composition

Abstract Community assembly is influenced by environmental niche processes as well as stochastic processes that can be spatially dependent (e.g. dispersal limitation) or independent (e.g. priority effects). Here, we sampled senesced tree leaves as unit habitats to investigate fungal community assembly at two spatial scales: (i) small neighborhoods of overlapping leaves from differing tree species and (ii) forest stands of differing ecosystem types. Among forest stands, ecosystem type explained the most variation in community composition. Among adjacent leaves within stands, variability in fungal composition was surprisingly high. Leaf type was more important in stands with high soil fertility and dominated by differing tree mycorrhizal types (sugar maple vs. basswood or red oak), whereas distance decay was more important in oak-dominated forest stands with low soil fertility. Abundance of functional groups was explained by environmental factors, but predictors of taxonomic composition within differing functional groups were highly variable. These results suggest that fungal community assembly processes are clearest for functional group abundances and large spatial scales. Understanding fungal community assembly at smaller spatial scales will benefit from further study focusing on differences in drivers for different ecosystems and functional groups, as well as the importance of spatially independent factors such as priority effects.

59 BASIC BIOLOGICAL SCIENCES↗

Experimental study of crystallization fouling by calcium carbonate: Effects of surface structure and material

We report mitigation of crystallization fouling on heat transfer surface is crucial for developing highly efficient desalination techniques, because the tenacious and porous crystal layer can drastically deteriorate system efficiency. Surface modification is a potential approach to decrease scale formation and promote crystal removal, but some of the mechanisms between crystallization and substrate properties are still not fully understood. In this study, we use dual-angle microscopic visualization and image processing to quantify three-dimensional crystallization behavior and analyze the impact of surface structure and material. The transition of crystal size and distance with roughness and wettability are identified from statistical analysis. The determination of crystal porosity and effective thermal conductivity is enabled by visualized geometry and measured deposition mass. This study shed lights on potential strategies of surface modification to mitigate scaling in desalination by enhancing scale removal and localizing crystal growth.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Skyshine Calculations for a Large Spent Nuclear Fuel Storage Facility with SCALE 6.2.3

The SCALE code system developed at Oak Ridge National Laboratory includes state-of-the-art capabilities for radiation source term and radiation transport simulations that can be used in numerous applications, including dose rate analyses of complex consolidated interim storage facilities (CISFs). A licensed CISF could be used to store tens of thousands of tonnes of spent nuclear fuel discharged from commercial power reactors using various cask and storage pad designs. A CISF design must comply with the regulatory requirements provided in 10 CFR Part 72, including requirements related to annual dose limits applicable to real individuals located beyond the area controlled by the licensee. Therefore, calculating a dose to the public is a necessary part of the licensing process for the construction of a CISF. These calculations are very challenging because of the complexity of the CISF design and the low magnitude of dose rate at large distances from the facility. This paper describes detailed far-field dose rate calculations performed for a proposed CISF using MAVRIC, the Monte Carlo radiation shielding sequence in SCALE 6.2.3, with automated variance reduction based on discrete ordinates calculations. The method presented in this paper uses a detailed Monte Carlo radiation transport simulation in one step from source to dose rate. A series of independent simulations was made using the complete site geometry (all casks present), but with only one cask containing radiation sources to obtain the dose rate maps produced by each storage cask. The CISF dose rate map was obtained by adding the dose rate maps produced by the independent individual cask simulations. Ample volumes of air and soil extending beyond the location of interest for dose rate calculation were included in the calculation model to properly simulate important radiation attenuation and scattering events that affect far-field dose rates. Furthermore, a comprehensive sensitivity study is included in this paper to illustrate the importance of selecting appropriate air volume, mass density, and composition for CISF skyshine dose rate calculations. Dry soil and soil containing water were analyzed to determine their effects on groundshine radiation.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Polymer Conformations and Diffusion Through a Monolayer of Confining Nanoparticles

We present coarse-grained molecular dynamics simulations to probe chain-scale polymer conformations and diffusion between confining nanoparticles (NPs). By constructing a monolayer of hexagonally-packed NPs in a polymer melt with athermal interactions, we observe the magnitude and length-scale over which homogeneously confining NPs impact the polymer behavior, which provides fundamental insights into more complex polymer nanocomposites. We show that polymer conformations are more perturbed under strong confinement (i.e. when the interparticle distance, ID, is less than twice the polymer radius of gyration, 2R g ) as compared to around an isolated NP, and the effect depends on the ratio of R NP /R g rather than either independently. In fact, these conformations can be quantitatively replicated by executing a simple random walk in a similarly confining environment. We also show that polymer diffusion is slowed by the presence of NPs and the slowing persists far beyond the length-scale over which polymer conformations are perturbed. Although the slowing is strongest ~R g from the NPs, the diffusion coefficient is slower even beyond ~5R g from the NPs. Furthermore, by analyzing the directional van Hove distributions, we show polymer diffusion away from the NP monolayer is bulk-like while diffusion through the monolayer is slower with increasing NP confinement. Furthermore, these molecular dynamics simulations provide fundamental insights into the temporal and spatial effect of confining, athermal NPs on chain-scale polymer conformations and diffusion.

36 MATERIALS SCIENCE↗

In situ recording of Mars soundscape

Abstract Before the Perseverance rover landing, the acoustic environment of Mars was unknown. Models predicted that: (1) atmospheric turbulence changes at centimetre scales or smaller at the point where molecular viscosity converts kinetic energy into heat 1 , (2) the speed of sound varies at the surface with frequency 2,3 and (3) high-frequency waves are strongly attenuated with distance in CO 2 (refs. 2–4 ). However, theoretical models were uncertain because of a lack of experimental data at low pressure and the difficulty to characterize turbulence or attenuation in a closed environment. Here, using Perseverance microphone recordings, we present the first characterization of the acoustic environment on Mars and pressure fluctuations in the audible range and beyond, from 20 Hz to 50 kHz. We find that atmospheric sounds extend measurements of pressure variations down to 1,000 times smaller scales than ever observed before, showing a dissipative regime extending over five orders of magnitude in energy. Using point sources of sound (Ingenuity rotorcraft, laser-induced sparks), we highlight two distinct values for the speed of sound that are about 10 m s −1 apart below and above 240 Hz, a unique characteristic of low-pressure CO 2 -dominated atmosphere. We also provide the acoustic attenuation with distance above 2 kHz, allowing us to explain the large contribution of the CO 2 vibrational relaxation in the audible range. These results establish a ground truth for the modelling of acoustic processes, which is critical for studies in atmospheres such as those of Mars and Venus.

79 ASTRONOMY AND ASTROPHYSICS↗

A Q-band frequency tunable Doppler backscattering (DBS) system for pedestal and scrape-off layer density fluctuation and flow measurements in the DIII-D tokamak

We present the design and laboratory tests for a new Q-band frequency tunable Doppler backscattering (DBS) system suitable for probing poloidal wavenumber kñ = 6–8 cm−1 density fluctuations and their flow velocities in the pedestal and scape-off layer (SOL) of the DIII-D tokamak. This system will provide new measurements in the increasingly important and under-diagnosed far pedestal and SOL plasma regions. These results are important for experimental transport studies and necessary for the validation of transport models, both of which are important to fusion energy research. The use of a single tunable frequency reduces the complexity and potential failure points as compared to a multichannel system. This new system utilizes a 33–50 GHz tunable source and will be integrated into the current V-band DBS in DIII-D using a broadband Q- and V-band multiplexer. A full-scale mockup of the quasi-optical system was used to test and optimize the performance. These tests include beam profile measurements at different distances (and angles) from a paraboloidal focusing and steering mirror. The measurements cover the full frequency range 33–75 GHz of the integrated/combined Q–V band DBS system and target a large radial coverage of the low-field side of the plasma from ρ = 1.1 to ρ = 0.5, where ρ is the normalized flux surface radial coordinate.

Instruments & Instrumentation↗

Unveiling the underlying interactions in Ta 2 NiSe 5 from photoinduced lifetime change

We present a generic procedure for quantifying the interplay of electronic and lattice degrees of freedom in photodoped insulators through a comparative analysis of theoretical many-body simulations and time- and angle-resolved photoemission spectroscopy (TR-ARPES) of the transient response of the candidate excitonic insulator Ta 2 NiSe 5 . Our analysis demonstrates that the electron-electron interactions dominate the electron-phonon ones. In particular, a detailed analysis of the TR-ARPES spectrum enables a clear separation of the dominant broadening (electronic lifetime) effects from the much smaller band-gap renormalization. Theoretical calculations show that the observed strong spectral broadening arises from the electronic scattering of the photoexcited particle-hole pairs and cannot be accounted for in a model in which electron-phonon interactions are dominant. The competing interactions were quantified using the scaling analysis in the weak fluence regime. We demonstrate that the magnitude of the weaker subdominant band-gap renormalization sensitively depends on the distance from the semiconductor/semimetal transition in the high-temperature state, which could explain the apparent contradictions between various TR-ARPES experiments. The analysis presented here indicates that electron-electron interactions play a vital role (albeit not the sole one) in stabilizing the insulating state, and establishes the comparison between lifetime and gap evolution as an important probe of correlated insulators.

36 MATERIALS SCIENCE↗

Quantifying the line-of-sight halo contribution to the dark matter convergence power spectrum from strong gravitational lenses

Galaxy-galaxy strong gravitational lenses have become a popular probe of dark matter (DM) by providing a window into structure formation on the smallest scales. In particular, the convergence power spectrum of subhalos within lensing galaxies has been suggested as a promising observable to study DM. However, the distances involved in strong-lensing systems are vast, and we expect the relevant volume to contain line-of-sight (LOS) halos that are not associated with the main lens. We develop a formalism to calculate the effect of LOS halos as an effective convergence power spectrum. Here, the multilens plane equation couples the angular deflections of consecutive lens planes, but by assuming that the perturbations due to the LOS halos are small, we show that they can be projected onto the main-lens plane as effective subhalos. We test our formalism by simulating lensing systems using the full multiplane lens equation and find excellent agreement. We show how the relative contribution of LOS halos and subhalos depends on the source and lens redshift, as well as the assumed halo and subhalo mass functions. For a fiducial system with fraction of DM halo mass in substructure f sub = 0.4% for subhalo masses [10 5 –10 8 ]M ⊙ , the interloper contribution to the power spectrum is at least several times greater than that of subhalos for source redshifts z s ≳ 0.5. Furthermore, it is likely that for the SLACS and BELLS lenses the interloper contribution dominates: f sub ≳ 2% (4%) is needed for subhalos to dominate in SLACS (BELLS), which is higher than current upper bounds on f sub for our mass range. Since the halo mass function is better understood from first principles, the dominance of interlopers in galaxy-galaxy lenses with high-quality imaging can be seen as a significant advantage when translating this observable into a constraint on DM.

79 ASTRONOMY AND ASTROPHYSICS↗

Scale-Up of Electrode Coating and Flow-Field for Commercial Hydrogen Peroxide Electrolyzer: Cooperative Research and Development Final Report, CRADA Number CRD-17-00687

Hydrogen peroxide is currently produced at central chemical plants via the anthraquinone oxidation process. This process produces environmental pollutants that are costly to remediate, requires hazardous long distance shipping of highly concentrated peroxide (50% or 70%), and necessitates extra handling costs related to storage and dilution. Peroxygen Systems, Inc. (PSi) is developing breakthrough technology for on-site hydrogen peroxide production. PSi’s on-site on-demand electrolyzer can reduce the cost of producing hydrogen peroxide by 50%, while also completely eliminating the cost and safety issues associated with shipping and handling of high concentration hydrogen peroxide. The challenge for PSi is scaling. To support the next step toward commercialization (customer pilot tests), scaling the prototype into larger single cells and 20-40 cell stacks is required. In addition to internal hardware and flow-field design efforts at PSi, NREL will address three critical problems for this scale-up effort: (1) demonstrating a large scale roll-to-roll (R2R) process to coat uniform electrode materials for 100 cm2 and 500 cm2 stack testing, (2) demonstrating an in-line diagnostic to achieve better electrode quality control, and (3) performing in situ cell/stack testing to better understand and optimize the performance of the flow field design.

28 EE - Advanced Manufacturing Office (EE-5A)↗