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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 415 records · Page 23
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

Io: Generation of Silicate Magma by Shear Melting at the Base of a Basaltic Lithosphere

Tidal theory and observational evidence indicates that about 1 w/sq. m. of energy is released at the surface of Io. In order to place limits on how much tidal energy can be dissipated within a rigid lithosphere, depth-temperature profiles were calculated for different lithosphere thickness assuming that the tidal energy was dissipated uniformly throughout the lithosphere. Thus a thick lithosphere implies that a significant fraction of the tidal energy is dissipated below the depth where solidus temperatures are reached. One possibility is that Io has a crust consisting of a low melting temperature fraction such as basalt, overlying a mantle of a high melting temperature fraction such as peridotite. Thus, if the lithosphere of Io is thicker than 30 km, as appears probable, then high rates of silicate volcanism are implied and a significant fraction of the tidal energy must be dissipated by viscous deformation rather than rigid flexure.

Carr, M. H.↗
NASA NTRS1999

Follow-on Low Noise Fan Aerodynamic Study

The focus of the project was to investigate the effects of turbulence models on the prediction of rotor wake structures. The Advanced Ducted Propfan Analysis (ADPAC) code was modified through the incorporation of the Spalart-Allmaras one-equation turbulence model. Suitable test cases were solved numerically using ADPAC employing the Spalart-Allmaras turbulence model and another prediction code for comparison. A near-wall spacing study was also completed to determine the adequate spacing of the first computational cell off the wall. Solutions were also collected using two versions of the algebraic Baldwin-Lomax turbulence model in ADPAC. The effects of the turbulence model on the rotor wake definition was examined by obtaining ADPAC solutions for the Low Noise Fan rotor-only steady-flow case using the standard algebraic Baldwin-Lomax turbulence model, a modified version of the Baldwin-Lomax turbulence model and the one-equation Spalart-Allmaras turbulence model. The results from the three different turbulence modeling techniques were compared with each other and the available experimental data. These results include overall rotor performance, spanwise exit profiles, and contours of axial velocity taken along constant axial locations and along blade-to-blade surfaces. Wake characterizations were also performed on the experimental and ADPAC predicted results including the definition of a wake correlation function. Correlations were evaluated for wake width and wake depth. Similarity profiles of the wake shape were also compared between all numerical solutions and experimental data.

Heidegger, Nathan J.↗
DOE OSTI2021

Joint inversion of electromagnetic measurements for the determination of water saturation profiles in concrete structures

Highlights: • DC-electrical and dielectric data are combined to estimate concrete saturation degree. • A joint inversion approach of the electromagnetic measurements is proposed. • The sensitivity of the measurements to the saturation model parameters is analysed. • The new joint approach was developed and is applied to synthetic and real data. • The benefits of the joint approach over the inversion of one data type are highlighted. Water saturation profiles in concrete are essential to assess its durability and can be determined using non-destructive techniques, especially the electric and the capacitive methods. In this paper, we propose a new inversion scheme where both resistivity and permittivity measurements are inverted jointly to retrieve the saturation profile. The finite element method is used to model the measurements in 3D, the concrete having a saturation profile with depth, represented by a continuous model taking the form of a Weibull curve with four parameters. A non-linear least-squares optimization based on the Levenberg-Marquardt scheme is developed for the inversion of measurements. Results show that information gathered from both measurements enriches the reconstructed profile, leading to a more reliable estimation of saturation profiles. We believe that the joint inversion method herein developed could lead to the study of more complex phenomena, such as the coupled water-chloride ingress.

36 MATERIALS SCIENCE↗
NASA NTRS2008

Absorption in Extended Inhomogeneous Clouds

The launch of several different sensors, including CloudSat, into the A-train constellation of satellites allows us for the first time to compute absorption that can occur in realistic vertically inhomogeneous clouds including multiple cloud decks. CloudSat data show that these situations are common. Therefore, understanding vertically inhomogeneous clouds is important from both climate and satellite atmospheric composition remote sensing perspectives. Satellite passive sensors that operate from the near IR to the UV often rely on radiative cloud pressures derived from absorption in oxygen bands (A, B, gamma, or O2-O2 bands) or from rotational-Raman scattering in order to retrieve information about atmospheric trace gases. The radiative cloud pressure is distinct from the physical cloud top derived from thermal infrared measurements. Therefore, the combination of information from different passive sensors yields some information about the cloud vertical profile. When either or both the clouds or atmospheric absorbers (trace gases and aerosols) are vertically inhomogeneous, the use of an effective cloud pressure derived from these approaches may lead to errors. Here, we focus on several scenarios (deep convective clouds and distinct two layer clouds) based on realistic cloud optical depth vertical profiles derived from the CloudSatfMODIS combination. We focus on implications for trace-gas column amount retrievals (specifically ozone and NO2) and derived surface UV irradiance from the Ozone Monitoring Instrument (OMI) on the Atrain Aura platform.

Joiner, Joanna↗
NASA NTRS1991

Lunar regolith densification

Core tube samples of the lunar regolith obtained during the Apollo missions showed a rapid increase in the density of the regolith with depth. Various hypotheses have been proposed for the possible cause of this phenomenon, including the densification of the loose regolith material by repeated shaking from the seismic tremors which have been found to occur at regular monthly intervals when the moon and earth are closest to one another. A test bed was designed to study regolith densification. This test bed uses Minnesota Lunar Simulant (MLS) to conduct shaking experiments in the geotechnical centrifuge with an inflight shake table system. By reproducing realistic in-situ regolith properties, the experiment also serves to test penetrator concepts. The shake table system was designed and used for simulation experiments to study effects of earthquakes on terrestrial soil structures. It is mounted on a 15 g-ton geotechnical centrifuge in which the self-weight induced stresses are replicated by testing an n-th scale model in a gravity field which is n times larger than Earth's gravity. A similar concept applies when dealing with lunar prototypes, where the gravity ratio required for proper simulation of lunar gravity effects is that between the centrifugal acceleration and the lunar gravity. Records of lunar seismic tremors, or moonquakes, were obtained. While these records are being prepared for use as the input data to drive the shake table system, records from the El Centro earthquake of 1940 are being used to perform preliminary tests, using a soil container which was previously used for earthquake studies. This container has a laminar construction, with the layers free to slide on each other, so that the soil motion during the simulated earthquake will not be constrained by the otherwise rigid boundaries. The soil model is prepared by pluviating the MLS from a hopper into the laminar container to a depth of 6 in. The container is mounted on the shake table and the centrifuge is operated to generate an acceleration of 10 times Earth's gravity or 60 times the lunar gravity, thus simulating a lunar regolith thickness of 30 ft. The shake table is then operated using the scaled 'moonquake' as the input motion. One or more model moonquakes are used in each experiment, after which the soil is analyzed for its density profile with depth. This is accomplished by removing from the soil bed a column of soil contained within a thin rubber sleeve which has been previously embedded vertically in the soil during pluviation. This column of soil is transferred to a gamma ray device, in which the gamma ray transmission transversely through the soil is measured and compared with standard calibration samples. In this manner, the density profile can be determined. Preliminary results to date are encouraging, and the Center plans to study the effects of duration of shaking, intensity of the shaking motion, and the frequency of the motion.

Ko, Hon-Yim↗
NASA NTRS1977

Optimal spatial sampling techniques for ground truth data in microwave remote sensing of soil moisture

The paper examines optimal sampling techniques for obtaining accurate spatial averages of soil moisture, at various depths and for cell sizes in the range 2.5-40 acres, with a minimum number of samples. Both simple random sampling and stratified sampling procedures are used to reach a set of recommended sample sizes for each depth and for each cell size. Major conclusions from statistical sampling test results are that (1) the number of samples required decreases with increasing depth; (2) when the total number of samples cannot be prespecified or the moisture in only one single layer is of interest, then a simple random sample procedure should be used which is based on the observed mean and SD for data from a single field; (3) when the total number of samples can be prespecified and the objective is to measure the soil moisture profile with depth, then stratified random sampling based on optimal allocation should be used; and (4) decreasing the sensor resolution cell size leads to fairly large decreases in samples sizes with stratified sampling procedures, whereas only a moderate decrease is obtained in simple random sampling procedures.

Rao, R. G. S.↗
DOE OSTI2024

Methods of controllable interstitial oxygen doping in niobium

A method for vacuum heat treating Nb, such as is used in superconducting radio frequency cavities, to engineer the interstitial oxygen profile with depth into the surface to conveniently optimize the low-temperature rf surface resistance of the material. An example application is heating of 1.3 GHz accelerating structures between 250-400° C. to achieve a very high quality factor of 5×1010 at 2.0 K. With data supplied by secondary ion mass spectrometry measurements, application of oxide decomposition and oxygen diffusion theory was applied to quantify previously unknown parameters crucial in achieving the oxygen alloy concentration profiles required to optimize the rf surface resistance. RF measurements of vacuum heat treated Nb superconducting radio frequency cavities confirmed the minimized surface resistance (higher Q0) previously expected only from 800° C. diffusive alloying with nitrogen.

Palczewski, Ari D.↗
NASA NTRS1993

Enhanced decoding for the Galileo S-band mission

A coding system under consideration for the Galileo S-band low-gain antenna mission is a concatenated system using a variable redundancy Reed-Solomon outer code and a (14,1/4) convolutional inner code. The 8-bit Reed-Solomon symbols are interleaved to depth 8, and the eight 255-symbol codewords in each interleaved block have redundancies 64, 20, 20, 20, 64, 20, 20, and 20, respectively (or equivalently, the codewords have 191, 235, 235, 235, 191, 235, 235, and 235 8-bit information symbols, respectively). This concatenated code is to be decoded by an enhanced decoder that utilizes a maximum likelihood (Viterbi) convolutional decoder; a Reed Solomon decoder capable of processing erasures; an algorithm for declaring erasures in undecoded codewords based on known erroneous symbols in neighboring decodable words; a second Viterbi decoding operation (redecoding) constrained to follow only paths consistent with the known symbols from previously decodable Reed-Solomon codewords; and a second Reed-Solomon decoding operation using the output from the Viterbi redecoder and additional erasure declarations to the extent possible. It is estimated that this code and decoder can achieve a decoded bit error rate of 1 x 10(exp 7) at a concatenated code signal-to-noise ratio of 0.76 dB. By comparison, a threshold of 1.17 dB is required for a baseline coding system consisting of the same (14,1/4) convolutional code, a (255,223) Reed-Solomon code with constant redundancy 32 also interleaved to depth 8, a one-pass Viterbi decoder, and a Reed Solomon decoder incapable of declaring or utilizing erasures. The relative gain of the enhanced system is thus 0.41 dB. It is predicted from analysis based on an assumption of infinite interleaving that the coding gain could be further improved by approximately 0.2 dB if four stages of Viterbi decoding and four levels of Reed-Solomon redundancy are permitted. Confirmation of this effect and specification of the optimum four-level redundancy profile for depth-8 interleaving is currently being done.

Dolinar, S.↗
NASA NTRS1994

Laboratory simulation of intact capture of cometary and asteroidal dust particles in ISAS

In order to develop a collector for intact capturing of cometary dust particles in the SOCCER mission and regolith dust particles released from asteroid surfaces by the impact of projectiles launched from a flying-by spacecraft, various kinds of materials as the collector candidates have been exposed to hypervelocity projectiles in our laboratory. Data based on the penetration characteristics of various materials (penetration depth, hole profile, effectiveness for intact capturing) are greatly increased. The materials tested for these simulation experiments include various kinds of low-density media and multisheet stacks; these are foamed plastics (polystyrene 0.01 g/cc), silica aerogels (0.04 g/cc), air (0.001 g/cc), liquid, and multisheet stack consisting of thin Al sheets (thickness 0.002 to 0.1 mm) or polyethylene sheets. Projectiles used are spheres or cylinders of nylon, polycarbonate, basalt, copper, iron, and volatile organics (e.g.,paradichlorobenzene) of size ranging from 30 micrometers to 1 cm launched by a two-stage light gas gun and a rail gun in ISAS at velocity up to about 7 km/s. Some results obtained by using nylon projectiles of velocity less than about 5 km/s are presented; the penetration depth vs. bulk density of the collector material for several kinds of materials and the velocity at which the projectiles begin to fragment vs. material density for foamed polystyrene.

Fujiwara, A.↗
DOE OSTI2021

Interface Aspects in All‐Solid‐State Li‐Based Batteries Reviewed

Abstract Extensive efforts have been made to improve the Li‐ionic conductivity of solid electrolytes (SE) for developing promising all‐solid‐state Li‐based batteries (ASSB). Recent studies suggest that minimizing the existing interface problems is even more important than maximizing the conductivity of SE. Interfaces are essential in ASSB, and their properties significantly influence the battery performance. Interface problems, arising from both physical and (electro)chemical material properties, can significantly inhibit the transport of electrons and Li‐ions in ASSB. Consequently, interface problems may result in interlayer formation, high impedances, immobilization of moveable Li‐ions, loss of active host sites available to accommodate Li‐ions, and Li‐dendrite formation, all causing significant storage capacity losses and ultimately battery failures. The characteristic differences of interfaces between liquid‐ and solid‐type Li‐based batteries are presented here. Interface types, interlayer origin, physical and chemical structures, properties, time evolution, complex interrelations between various factors, and promising interfacial tailoring approaches are reviewed. Furthermore, recent advances in the interface‐sensitive or depth‐resolved analytical tools that can provide mechanistic insights into the interlayer formation and strategies to tailor the interlayer formation, composition, and properties are discussed.

25 ENERGY STORAGE↗
DOE OSTI2020

Calibration, measurement, and characterization of soil moisture dynamics in a central Amazonian tropical forest

Soil moisture plays a key role in hydrological, biogeochemical, and energy budgets of terrestrial ecosystems. Accurate soil moisture measurements in remote ecosystems such as the Amazon are difficult and limited because of logistical constraints. Time domain reflectometry (TDR) sensors are widely used to monitor soil moisture and require calibration to convert the TDR's dielectric permittivity measurement (K a ) to volumetric water content (θ v ). In this study, our objectives were to develop a field-based calibration of TDR sensors in an old-growth upland forest in the central Amazon, to evaluate the performance of the calibration, and then to apply the calibration to determine the dynamics of soil moisture content within a 14.2 -m-deep vertical soil profile. Depth-specific TDR calibration using local soils in a controlled laboratory setting yielded a novel K a –θ v third-degree polynomial calibration. The sensors were later installed to their specific calibration depth in a 14.2-m pit. The widely used K a –θ v relationship (Topp model) underestimated the site-specific θ v by 22–42%, indicating significant error in the model when applied to these well-structured, clay-rich tropical forest soils. The calibrated wet- and dry-season θ v data showed a variety of depth and temporal variations highlighting the importance of soil textural differentiation, root uptake depths, as well as event to seasonal precipitation effects. Data such as these are greatly needed for improving our understanding of ecohydrological processes within tropical forests and for improving models of these systems in the face of changing environmental conditions.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

ToF-SIMS in material research: A view from nanoscale hydrogen detection

Hydrogen in materials has attracted tremendous interest as its incorporation leads to significant alterations in nanoscale structure, composition, and chemistry, impacting functional properties. It has also been integral to nuclear fusion reactors and is considered a future clean energy source. However, nanoscale characterization and manipulation of hydrogen in materials are challenging as only a selected few analytical techniques can readily detect hydrogen, among which time-of-flight secondary ion mass spectrometry (ToF-SIMS) is a unique and powerful one due to its excellent detection limit along with decent depth and lateral resolutions. Here, in this review, we discuss, using selected examples, how to detect and quantify hydrogen in materials by ToF-SIMS and its impact on revealing the hydrogenation/protonation-induced novel functional states in different classes of materials. In addition, we present our protocols on sample preparation and experimental conditions optimization, allowing us to achieve the best possible results. Finally, we highlight future research directions that can lead to the discovery of novel functional states and ultimately provide a deeper understanding of scientific questions in materials science.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Valence Effects of Fe Impurity for Recovered LiNi 0.6 Co 0.2 Mn 0.2 O 2 Cathode Materials

Iron impurities are generally included in the obtained leaching liquor solution during the hydrometallurgical recycling method of spent lithium-ion batteries (LIBs) due to the usage of iron in battery casings and machinery parts of recycling equipment, which would definitely affect the physical and electrochemical features of the recovered active materials. In this paper, the effects of iron impurity with different valence states (Fe 2+ and Fe 3+ ) and gradient concentrations (0.2, 1.0, and 5.0 at. %) for the obtained LiNi 0.6 Co 0.2 Mn 0.2 O 2 (NCM622) cathodes are fully studied. It is found that Fe3+ impurity could easily lower the tap density and average size of NCM622 particles and even introduce some impurity phases in the NCM622 structure at high concentration (5.0 at. %), leading to much lower specific capacity, worse rate capability, and cycling performance of the Fe 3+ -based NCM622 cathode. On contrast, with certain concentrations of Fe 2+ impurity (0.2 and 1.0 at. %), the NCM622 cathode material exhibits comparable and much better electrochemical properties compared with the virgin NCM622 materials. Based on these results, the valence of Fe impurity should be considered and controlled as well as its concentration during the recycling process design for spent LIBs.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Role of Alkali-Metal Cations in Electronic Structure and Halide Segregation of Hybrid Perovskites

The ability to control or prevent phase segregation in perovskites is crucial to realizing stable and tunable mixed-halide optoelectronic devices. Here, we systematically examine the impact of alkali-metal-cation (Cs + and K + ) concentration on the band structure, chemical composition, phase segregation, and polycrystalline microstructure on formamidinium-dominated mixed-halide mixed-cation perovskite films. It was found that the incorporation of Cs + and K + cations decreases the work function and the core levels of all components shift toward higher binding energy consistent with n-doping the perovskite film, which facilitates electron transfer to the electron transport layer TiO 2 . A concentration-dependent film structure was observed by X-ray photoemission spectroscopy and grazing incidence wide-angle X-ray scattering where the halides and cations are distributed evenly across perovskite films at low metallic cation concentration (5%). A high metal-cation ratio (20%) leads to halide segregation within the perovskite film and the surface becomes bromide-poor, whereas the bromide and metal cations diffuse more deeply within the film. These differences in electronic properties, element distribution, and film morphology were reflected in the device performance where the power conversion efficiency of low-metallic-cation concentration (5% of Cs + and K + ) perovskite solar cells is ≈5% higher than the high-concentration ones (20%). This study provides valuable chemical and physical insight into the underlying trade-offs in the careful tuning of electrical properties and film structure to optimize multication and mixed-halide hybrid perovskites.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Chemistry and Interfacial Structure Promoting Quasi-van der Waals Epitaxial Growth of WS 2 Nanosheets on Sapphire for Prospective Application in Field-Effect Transistors

How do chemical and structural modifications to the supporting crystal surface affect the subsequent van der Waals (vdW) or quasi(Q)-vdW epitaxial growth of 2D nanocrystals? Developing an atomic-scale picture of such an interfacial system is crucial for understanding its impact on the physical and chemical properties of the supported 2D materials. The elucidation of the interfacial structure and chemistry needed to promote the Q-vdW epitaxial growth of 2D tungsten disulfide (WS 2 ) nanocrystals contributes to the growth mechanism understanding, thus pushing forward the integration of such atomically thin semiconductors toward real field-effect transistor applications. In addition to an atomic-force microscopy top view, we showcase a combination of X-ray techniques for a top-to-bottom investigation of the complexities of the buried interface structures. Furthermore, this approach uses X-ray photoelectron spectroscopy, X-ray standing wave excited X-ray fluorescence, and crystal truncation rod scattering to produce a highly resolved chemical-state-specific 3D atomic map for the extended interface structure of WS 2 /α-Al 2 O 3 (001). Employing these detailed analysis methods, along with density functional theory to further refine the picoscale structure, we demonstrate how two different types of interface engineering during the pregrowth stage lead to significant differences in the chemical and structural modifications to the terminal surface of c-face sapphire, which in turn leads to substantial differences in the submonolayer growth of supported WS 2 2D nanocrystals in terms of lateral domain sizes, epitaxial registry, vdW gaps, and stability.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Uranium Attenuated by a Wetland 50 Years after Release into a Stream

: Wetlands have several important roles in the hydrological cycle, including maintaining water quality by removing surface and groundwater contaminants. Over time, the wetlands themselves can become contaminated, posing a secondary environmental threat. The objective of this study was to calculate the inventory of uranium (U) remaining in a wetland 50 years after the Fuel Fabrication Facility on the Savannah River Site located in South Carolina released 43.5 Mg of U into the nearby environment. Over 232 700 gamma spectra and their associated global positioning system (GPS) coordinates were collected and collated into a map of the contaminated land area. Five core samples were also collected that contained U concentrations as high as 14 099 mg/kg (background levels are about 2.7 mg/kg U). The contaminated area was 278 000 m2 , and it contained 36.2 Mg U, about 83% of the U released. About 80% of the U in the wetland was concentrated in a former beaver pond, a 73 000 m2 area (26% of the contaminated area). This contaminated wetland area was almost 2 km from the source, indicating that it comprised unique hydro-biogeochemical properties for immobilizing the released U. To the best of our knowledge, this is the first data-rich study to quantify the long-term effectiveness of a wetland to immobilize inorganic contaminants. Significant environmental changes to the system, such as those associated with hydrology, forest fires, or anthropogenic land use, may alter the complex hydro-biogeochemical interactions necessary for the long-term immobilization of the U.

Contaminant inventory↗
DOE OSTI2020

Recovery from plasma etching-induced nitrogen vacancies in p-type gallium nitride using UV/O 3 treatments

Plasma etching of p-type GaN creates n-type nitrogen vacancy (V N ) defects at the etched surface, which can be detrimental to device performance. In mesa isolated diodes, etch damage on the sidewalls degrades the ideality factor and leakage current. Here a treatment was developed to recover both the ideality factor and leakage current, which uses UV/O 3 treatment to oxidize the damaged layers followed by HF etching to remove them. The temperature dependent I–V measurement shows that the reverse leakage transport mechanism is dominated by Poole–Frenkel emission at room temperature through the etch-induced V N defect. Depth resolved cathodoluminescence confirms that the damage is limited to first several nanometers and is consistent with the V N defect.

42 ENGINEERING↗