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At least 415 records · Page 23

Effects of Chlorine Capture and a Proposed Density Law on the Reactivity of Plutonium Solution Systems

During fissionable material processing, all normal and credible abnormal conditions must remain safely subcritical. Nuclear Criticality Safety (NCS) uses a number of methods to determine subcriticality, one of which is the use of neutron transport codes such as MCNP6. In order to create models for use with MCNP6, both the geometry and materials in fissionable material processes must be known, or assumptions must be made and quantified for the impact to bias. One of the systems with a significant amount of bias due to material modeling assumptions is in the area of aqueous plutonium processing. These solutions are typically plutonium nitrate solutions or plutonium chloride solutions, which are modeled as fictitious plutonium metal-water mixtures because little is known about the actual density of the solution and there is no current predictive capability approved for use at Los Alamos National Laboratory (LANL) for modeling them. This research is currently underway to fill the gap and develop an algorithm for use with MCNP6 to model the density of plutonium chloride solutions. The method is to be validated with experimental data for density, and also validated with critical experiments using MCNP6. Note that the Chlorine Worth Study (CWS) was performed in December 2021 to help bridge the gap in chlorine data for critical experiments, and is currently awaiting International Criticality Safety Benchmark Evaluation Project (ICSBEP) review. This study was performed by LANL at the National Criticality Experiments Research Center (NCERC) at the Nevada National Security Site (NNSS). Additional information regarding this experiment may currently be found in LA-UR- 22-29180. Additionally, the Chemistry-Actinide Analytical Chemistry (C-AAC) at LANL has performed a number of solution density measurements for PuCl 3 -HC 1 -H 2 O, allowing for such data be used to create a semi-empirical density via the Pitzer method. The published dataset for the measurements is documented in LA-UR-22-25454. This method has already been tested successfully for aqueous plutonium nitrate solutions in SCALE. Current solution density measurements exist of plutonium concentrations of 0-~142g/L, all at 2M HC1, at temperatures 20-40°C. Additional data was taken for HC1-corrected density values, which essentially mimics the data for a pure PuCl x -water solution. The calculations in this report aim to support the current research by demonstrating the difference in system reactivity for the current modeling method when compared to the new proposed modeling with a density law implementation, which is being written as a Python tool to be used with MCNP6.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Microwave radiation measurements near the electron plasma frequency of the NASA Lewis bumpy torus plasma

Microwave emission near the electron plasma frequency was observed, and its relation to the average electron density and the dc toroidal magnetic field was examined. The emission was detected using a spectrum analyzer and a 50 omega miniature coaxial probe. The radiation appeared as a broad amplitude peak that shifted in frequency as the plasma parameters were varied. The observed radiation scanned an average plasma density ranging from 10 million/cu cm to 8 hundred million/cu cm. A linear relation was observed betweeen the density calculated from the emission frequency and the average plasma density measured with a microwave interferometer. With the aid of a relative density profile measurement of the plasma, it was determined that the emissions occurred from the outer periphery of the plasma.

Mallavarpu, R.↗

Free-stream temperature, density, and pressure measurements in an expansion tube flow

An experimental study was conducted to determine test-flow conditions in the Langley pilot model expansion tube. Measurements of temperature, density, wall pressure, pitot pressure, and shock and interface velocities were compared with theoretical calculations based on various models of the flow cycle. The vibrational temperature and integrated density of the molecular oxygen component of the flow were measured by use of vacuum ultraviolet absorption techniques. These measurements indicate both the presence and possible degree of nonequilibrium in the flow. Data are compared with several simplified models of the flow cycle, and data trends are discussed.

Haggard, K. V.↗

Development of non-intrusive instrumentation for NASA-Ames Ballistic Range and Shock Tunnel

The use of nonintrusive instrumentation in high-enthalpy facilities offers the opportunity to collect data that has previously been difficult or impossible to obtain. Three such instruments, now under development, are described: an OH absorption system which can measure OH species concentration and temperature, a holographic interferometer for flow visualization and density measurement at low density, and a telemetry system which allows the measurement of surface quantities on model in free-flight at hypervelocity. The challenges and opportunities encountered when employing these advanced diagnostics to high-enthalpy facilities are discussed.

Strawa, A. W.↗

Density of molten oxides measured in an aero-acoustic levitator

Knowing the thermophysical properties of high-temperature melts can aid the design of melt processes and validate atomic structural models, such as those used in studying glass formation. Property measurements on such melts are challenging, however, due to container-related contamination and heterogeneous nucleation. Containerless processing techniques that employ levitation can be used to avoid these obstacles. In that context, we demonstrate here the application of silhouette imaging to measure the density of molten oxides in an aero-acoustic levitation instrument (AAL). The AAL combines gas jet levitation with actively controlled acoustic positioning to enable full optical access to samples ca. 2–4 mm in diameter, which are laser beam heated and melted. The cross sections of molten drops are imaged using a monochromatic light source and narrowband-filtered camera. Melt volume is calculated from the cross sections and used to find density at several temperatures ranging 1530–1920 K, including up to 350 K of supercooling. We report densities for CaAl 2 O 4 , Ca 12 Al 14 O 33 , CaSiO 3 , their Fe 2 O 3 -bearing analogs, and 83TiO 2 -17RE 2 O 3 (RE = La or Nd). These provide important benchmarks of the capabilities, measurement uncertainties, and future outlook for this technique.

36 MATERIALS SCIENCE↗

Microwave radiation measurements near the electron plasma frequency of the NASA Lewis Bumpy Torus plasma

Microwave emission near the electron plasma frequency of the NASA Lewis Bumpy Torus plasma has been observed, and its relation to the average electron density and the dc toroidal magnetic field was examined. The emission was detected using a spectrum analyzer and a 50-ohm miniature coaxial probe. The radiation appeared as a broad amplitude peak that shifted in frequency as the plasma parameters were varied. The observed radiation scanned an average plasma density ranging from 20 billion to 800 billion per cu cm. A linear relation was observed between the density calculated from the emission frequency and the average plasma density measured with a microwave interferometer. With the aid of a relative density profile measurement of the plasma, it was determined that the emissions occurred from the outer periphery of the plasma.

Mallavarpu, R.↗

Coordinated rocket and satellite measurements of an auroral event. I - Satellite observations and analysis

Results of a coordinated auroral experiment involving the Atmosphere Explorer C satellite and a sounding rocket are reported. Auroral primary electron fluxes and neutral gas densities measured by instruments on the satellite are used in a model calculation of the thermospheric manifestation of the aurora. There is encouraging agreement between the calculated and measured electron density, electron temperature, secondary electron flux, and O I emissions at 5577 and 6300 A. A discrepancy between the calculated and the rocket-measured 3914-A emission profile is discussed in terms of experiment geometry and auroral physics. The coordinated measurements are used to infer vertical fluxes of ionization and of electron thermal energy at high altitudes

Rees, M. H.↗

Some characteristics of black spherules.

Black spherules from Greenland ice sheets compared to industrial weld-spatter spherules, using density measurements coupled with chemical analysis

EXTRATERRESTRIAL MATTER↗

Filamentary surface plasma discharge flow length and time scales

Nanosecond surface dielectric barrier discharges (ns-SDBDs) are a class of plasma actuators that utilize a high-voltage pulse of nanosecond duration between two surface-mounted electrodes to create an electrical breakdown of air, along with rapid heating. These actuators usually produce multiple filaments when operated at high pulse frequencies, and the rapid heating leads to the formation of shock waves and complex flow fields. In this work we replicate a single filament of the ns-SDBDs and characterize the induced flow using velocity measurements from particle image velocimetry and density measurements from background-oriented schlieren. The discharge is produced by a high voltage electrical pulse between two copper electrodes on an acrylic base. A hot gas kernel characterizes the flow field formed close to the electrodes that expands and cools over time and a vortex ring that propagates away from the surface while entraining cold ambient fluid. The gas density deficit inside the kernel displays a power-law decay over time. Based on the observations, we develop a simplified theoretical model based on vortex-driven cooling and perform a scaling analysis to obtain the induced flow length and time scales. The results show that the cooling process's time scales correspond to a circulation-based time scale of the vortex ring, and the length scale of the kernel corresponds to the vortex ring radius. Furthermore, these findings can guide the choice of optimal filament spacing and pulse frequencies in the design, deployment, and operation of ns-SDBDs for flow control.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Recent Results From Internal and Very-Near-Field Plasma Diagnostics of a High Specific Impulse Hall Thruster

Floating potential and ion current density measurements were taken on the laboratory model NASA-173Mv2 in order to improve understanding of the physical processes affecting Hall thruster performance at high specific impulse. Floating potential was measured on discharge chamber centerline over axial positions spanning 10 mm from the anode to 100 mm downstream of the exit plane. Ion current density was mapped radially up to 300 mm from thruster centerline over axial positions in the very-near-field (10 to 250 mm from the exit plane). All data were collected using a planar probe in conjunction with a high-speed translation stage to minimize probe-induced thruster perturbations. Measurements of floating potential at a xenon flow rate of 10 mg/s have shown that the acceleration layer moved upstream 3 1 mm when the voltage increased from 300 to 600 V. The length of the acceleration layer was 14 2 mm and was approximately constant with voltage and magnetic field. Ion current density measurements indicated the annular ion beam crossed the thruster centerline 163 mm downstream of the exit plane. Radial integration of the ion current density at the cathode plane provided an estimate of the ion current fraction. At 500 V and 5 mg/s, the ion current fraction was calculated as 0.77.

Hofer, Richard R.↗

Low-Temperature 2D/2D Ohmic Contacts in WSe 2 Field-Effect Transistors as a Platform for the 2D Metal–Insulator Transition

in this work, we report the fabrication of hexagonal-boron-nitride (hBN) encapsulated multiterminal WSe 2 Hall bars with 2D/2D low-temperature Ohmic contacts as a platform for investigating the two-dimensional (2D) metal-insulator transition. We demonstrate that the WSe 2 devices exhibit Ohmic behavior down to 0.25 K and at low enough excitation voltages to avoid current-heating effects. Additionally, the high-quality hBN-encapsulated WSe 2 devices in ideal Hall-bar geometry enable us to accurately determine the carrier density. Measurements of the temperature (T) and density (n s ) dependence of the conductivity σ(T, n s ) demonstrate scaling behavior consistent with a metalinsulator quantum phase transition driven by electron-electron interactions, but where disorder-induced local magnetic moments are also present. Our findings pave the way for further studies of the fundamental quantum mechanical properties of 2D transition metal dichalcogenides using the same contact engineering.

2D materials↗