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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 415 records · Page 23

All sources NASA NTRS DOE OSTI

NASA NTRS1991

Effects of elevated temperature on the viscoplastic modeling of graphite/polymeric composites

To support the development of new materials for the design of next generation supersonic transports, a research program is underway at NASA to assess the long term durability of advanced polymer matrix composites (PMC's). One of main objectives of the program was to explore the effects of elevated temperature (23 to 200 C) on the constitutive model's material parameters. To achieve this goal, test data on the observed nonlinear, stress-strain behavior of IM7/5260 and IM7/8320 composites under tension and compression loading were collected and correlated against temperature. These tests, conducted under isothermal conditions using variable strain rates, included such phenomena as stress relaxation and short term creep. The second major goal was the verification of the model by comparison of analytical predictions and test results for off axis and angle ply laminates. Correlation between test and predicted behavior was performed for specimens of both material systems over a range of temperatures. Results indicated that the model provided reasonable predictions of material behavior in load or strain controlled tests. Periods of loading, unloading, stress relaxation, and creep were accounted for.

Gates, Thomas S.↗

NASA NTRS2010

Magnetic Shielding of the Acceleration Channel Walls in a Long-Life Hall Thruster

In a Qualification Life Test (QLT) of the BPT-4000 Hall thruster that recently accumulated greater than 10,000 h it was found that the erosion of the acceleration channel practically stopped after approximately 5,600 h. Numerical simulations of this thruster using a 2-D axisymmetric, magnetic field-aligned-mesh (MFAM) plasma solver reveal that the process that led to this significant reduction of the erosion was multifaceted. It is found that when the channel receded from its early-in-life geometry to its steady-state configuration several changes in the near-wall plasma and sheath were induced by the magnetic field that, collectively, constituted an effective shielding of the walls from any significant ion bombardment. Because all such changes in the behavior of the ionized gas near the eroding surfaces were caused by the topology of the magnetic field there, we term this process "magnetic shielding."

life modeling↗

NASA NTRS1982

Tensile and compressive constitutive response of 316 stainless steel at elevated temperatures

It is demonstrated that creep rate of 316 SS is lower by factors of 2 to 10 in compression than in tension if the microstructure is the same and tests are conducted at identical temperatures and equal but opposite stresses. Such behavior was observed for both monotonic creep and conditions involving cyclic creep. In the latter case creep rate in both tension and compression progressively increases from cycle to cycle, rendering questionable the possibility of expressing a time-stabilized constitutive relationship. The difference in creep rates in tension and compression is considerably reduced if the tension specimen is first subjected to cycles of tensile creep (reversed by compressive plasticity), while the compression specimen is first subjected to cycles of compressive creep (reversed by tensile plasticity). In both cases, the test temperature is the same and the stresses are equal and opposite. Such reduction is a reflection of differences in microstructure of the specimens resulting from different prior mechanical history.

Manson, S. S.↗

DOE OSTI2024

Systematic Study of Solid-State U(VI) Photoreactivity: Long-Lived Radicalization and Electron Transfer in Uranyl Tetrachloride

Reported are the syntheses, structural characterizations and luminescence properties of three novel [UO 2 Cl 4 ] 2- bearing compounds containing substituted 1,1’-dialkyl-4,4’-bipyridinum dications (i.e. viologens). These compounds undergo photoinduced luminescence quenching upon exposure to UV radiation. Further, this reactivity is concurrent with two phenomena: radicalization of the uranyl tetrachloride anion and photoelectron transfer to the viologen which constitutes the formal transfer of one electron from the [UO 2 Cl 4 ] 2- to the viologen species. This behavior is elucidated using electron paramagnetic resonance (EPR) spectroscopy and further probed through a series of characterization and computational techniques including Rehm-Weller analysis, time-dependent density functional theory (TD-DFT), and density of states (DOS). This work provides a systematic study of the photoreactivity of the uranyl unit in the solid state, an under-described aspect of fundamental uranyl chemistry.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1985

Constitutive modeling for isotropic materials

The objective is to develop a unified constitutive model for finite element structural analysis of turbine engine hot-section components. This effort constitutes a different approach for non-linear finite-element computer codes which have heretofore been based on classical inelastic methods. The unified constitutive theory to be developed will avoid the simplifying assumptions of classical theory and should more accurately represent the behavior of superalloy materials under cyclic loading conditions and high temperature environments. During the first two years of the program, extensive experimental correlations were made with two representative unified models. The experiments were both uniaxial and biaxial at temperatures up to 1093 C (2000 F). In addition, the unified models were adopted to the MARC finite element code and used for stress analysis of notched bar and turbine blade geometries.

Lindholm, Ulric S.↗

NASA NTRS2004

Mechanical Properties of Plasma-Sprayed ZrO2-8 wt% Y2O3 Thermal Barrier Coatings

Mechanical behavior of free standing, plasma-sprayed ZrO2-8 wt% Y2O3 thermal barrier coatings, including strength, fracture toughness, fatigue, constitutive relation, elastic modulus, and directionality, has been determined under various loading-specimen configurations. This report presents and describes a summary of mechanical properties of the plasma-sprayed coating material to provide them as a design database.

Choi, Sung R.↗

NASA NTRSDate not supplied

Test Results for Autonomous Assembly of Modular Space Structures

This paper presents test results for autonomous assembly of a modular space structure. A Universal Robots UR10e manipulator with a custom end-effector, known as the Grapple Tool, was used to join TriTruss structural modules. The TriTrusses and their assembly configuration were developed for an in-space assembled telescope conceptual design. The tests presented here were performed with a 1:2.8 dimensionally scaled version of the Tri-Trusses. Robot trajectories were generated autonomously using a sample-based motion planner and an a-priori worksite model. The test results verify the assembly concept of operations as well as the software requirements for the Grapple Tool. While the Grapple Tool used in the tests was designed for the 1:2.8 scale Tri-Trusses, it has the same actuators, software, and computation architecture as the version designed for the full scale structure. The test operations consist of picking up two TriTrusses from their stowed locations and joining them to a third TriTruss mounted on a test stand and joining them to each other. This constitutes the first three modules of the in-space assembled telescope conceptual design. The paper presents the robot behavioral architecture, the generated trajectories commanded, the actual trajectories of the robot, and actuator performance of the Grapple Tool.

test↗

NASA NTRSDate not supplied

Test Results for Autonomous Assembly of Modular Space Structures

test↗

NASA NTRS1984

Biaxial constitutive equation development

In developing the constitutive equations an interdisciplinary approach is being pursued. Specifically, both metallurgical and continuum mechanics considerations are recognized in the formulation. Experiments will be utilized to both explore general qualitative features of the material behavior that needs to be modeled and to provide a means of assessing the validity of the equations being developed. The model under development explicitly recognizes crystallographic slip on the individual slip systems. This makes possible direct representation of specific slip system phenomena. The present constitutive formulation takes the anisotropic creep theory and incorporates two state variables into the model to account for the effect of prior inelastic deformation history on the current rate-dependent response of the material.

Jordan, E. H.↗

NASA NTRS2001

Rheology of Diabase: Implications for Tectonics on Venus and Mars

Two important goals of our experimental investigation of the rheological behavior of diabase rocks were: (1) to determine flow laws describing their creep behavior over wide ranges of temperature, stress and strain rate and (2) to develop an understanding of the physical mechanisms by which these rocks flow under laboratory conditions. With this basis, a primary objective then was to construct constitutive equations that can be used to extrapolate from laboratory to planetary conditions. We specifically studied the rheological properties of both natural rock samples and synthetic aggregates. The former provided constraints for geologic systems, while the latter defined the relative contributions of the constituent mineral phases and avoided the influence of glass/melt found in natural samples. In addition, partially molten samples of crustal rock composition were deformed in shear to large strains (greater than 200%) important in crustal environments. The results of this research yielded essential rheological properties essential for models of crustal deformation on terrestrial planets, specifically Venus and Mars, as well as on the geodynamical evolution of these planets. Over the past three years, we also completed our investigation of the creep behavior of water ice with applications to the glaciers, ice sheets and icy satellites. Constitutive equations were determined that describe flow over a wide ranged of stress, strain rate, grain size and temperature. In the case of ice, three creep regimes were delineate. Extrapolation demonstrates that dislocation glide and grain boundary sliding processes dominate flow in ice I under planetary conditions and that diffusion creep is not an important deformation mechanism either in the laboratory or on icy satellites. These results have already been incorporated by other investigators into models describing, for example, the thickness and stability of the ice shell on Europa and to unravel long-standing discrepancies between field observations on glaciers and laboratory results.

Kohlstedt, David L.↗

NASA NTRS2008

Constitutive Soil Properties for Unwashed Sand and Kennedy Space Center

Accurate soil models are required for numerical simulations of land landings for the Orion Crew Exploration Vehicle. This report provides constitutive material models for one soil, unwashed sand, from NASA Langley's gantry drop test facility and three soils from Kennedy Space Center (KSC). The four soil models are based on mechanical and compressive behavior observed during geotechnical laboratory testing of remolded soil samples. The test specimens were reconstituted to measured in situ density and moisture content. Tests included: triaxial compression, hydrostatic compression, and uniaxial strain. A fit to the triaxial test results defines the strength envelope. Hydrostatic and uniaxial tests define the compressibility. The constitutive properties are presented in the format of LS-DYNA Material Model 5: Soil and Foam. However, the laboratory test data provided can be used to construct other material models. The four soil models are intended to be specific to the soil conditions discussed in the report. The unwashed sand model represents clayey sand at high density. The KSC models represent three distinct coastal sand conditions: low density dry sand, high density in-situ moisture sand, and high density flooded sand. It is possible to approximate other sands with these models, but the results would be unverified without geotechnical tests to confirm similar soil behavior.

Thomas, Michael A.↗

NASA NTRS1985

The effects of molecular weight on the single lap shear creep and constant strain rate behavior of thermoplastic polyimidesulfone adhesive

The bonded shear creep and constant strain rate behaviors of zero, one, and three percent endcapped thermoplastic polyimidesulfone adhesive were examined at room and elevated temperatures. Endcapping was accomplished by the addition of phthalic anhydrides. The primary objective was to determine the effects of molecular weight on the mechanical properties of the adhesive. Viscoelastic and nonlinear elastic constitutive equations were utilized to model the adhesive. Ludwik's and Crochet's relations were used to describe the experimental failure data. The effects of molecular weight changes on the above mentioned mechanical behavior were assessed. The viscoelastic Chase-Goldsmith and elastic nonlinear relations gave a good fit to the experimental stress strain behavior. Crochet's relations based on Maxwell and Chase-Goldsmith models were fit to delayed failure data. Ludwik's equations revealed negligible rate dependence. Ultimate stress levels and the safe levels for creep stresses were found to decrease as molecular weight was reduced.

Dembosky, Stanley K.↗

DOE OSTI2021

Numerical study of the chemo-mechanical behavior of FEBEX bentonite in nuclear waste disposal based on the Barcelona expansive model

Experimental studies show that compacted bentonite used as a backfill material for nuclear waste repository experiences strong coupling between chemical and mechanical processes. Here, we use a dual-structure expansive soil model, referred to as the Barcelona Expansive Model (BExM), to predict the behavior of bentonite buffer in subsurface emplacement tunnels for high-level radioactive waste. After emplacement, the bentonite is subjected to complex and coupled Thermal-Hydraulic-Mechanical-Chemical (THMC) processes. The BExM constitutive model is implemented in a multi-phase reactive transport and geomechanics simulator, TOUGHREACT-FLAC3D, and the model is verified with one benchmark test on FEBEX bentonite. We utilize a one-way Chemo-Mechanical (C-M) coupling approach, in which chemical changes affect the mechanical behavior of bentonite through the BExM linked with the evolution of mass fraction of smectite, exchangeable cation concentration, and ionic strength via osmotic suction. The parameters of the new coupled model for FEBEX bentonite are calibrated against a series of laboratory experiments with various salinity solutions. Finally, coupled THMC modeling is conducted for a generic argillite repository with bentonite buffer under high temperature, focusing on the long-term chemical change and its effect on the mechanical process.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2021

On the origin of internal obstacles to dislocation glide in single-phase NiFe random alloys

Over the past decade, a new class of unconventional alloys, where several constitutive elements are presented in close to equal concentrations, is considered as promising structural materials in many applications. Properties and behavior of many concentrated solid solution alloys (CSSAs) under different conditions, including mechanical loading, differs from that of conventional alloys and has been the subject of intensive studies by different techniques. A key feature of these materials is that there is no clear distinction between solute and solvent species of atoms, which is the conventional approach to considering dislocation motion in alloys. To understand this regime, we have recently reported on the glide of a screw dislocation glide in a simple equiatomic NiFe alloy and reported the two-mode character. At low applied stress, the dislocation motion is similar to a glide through a field of obstacles. In this work, we report the results of a detailed study on the nature of these internal obstacles. We demonstrate that these are not conventional localized “obstacles” but is the result of significantly different energies of instantaneous dislocation configurations over the alloy bulk. The strong pinning positions are associated with composition changes in the partial dislocation cores, while observing no significant composition changes along the stacking faults. Local energies can vary significantly, as demonstrated using simulations of short-periodicity dislocation lines. Therefore, the critical stress to move a dislocation under such conditions is not a constant Peierls stress but represents a wide spectrum of barriers between different non-straight valleys that the dislocation line accommodates in the bulk at particular stress/strain conditions.

36 MATERIALS SCIENCE↗

DOE OSTI2021

densegranFoam

densegranFoam is a dense granular material flow solver developed using the OpenFoam Computational Fluid Dynamics (CFD) tool. It is developed using Euler-Euler framework. The transport model is implemented using the shear rate dependant constitutive model. The primary focus of the solver is to simulate shear rate dependency on the dense granular flow bulk behavior.

Ahsan, Syed↗

NASA NTRS1979

A general method for the layout of ailerons and elevators of gliders and motorplanes

A method is described which allows the layout of the spatial driving mechanism of the aileron for a glider or a motorplane to be performed in a systematic manner. In particular, a prescribed input-output behavior of the mechanism can be realized by variation of individual parameters of the spatial four-bar mechanisms which constitute the entire driving mechanism. By means of a sensitivity analysis, a systematic choice of parameters is possible. At the same time the forces acting in the mechanism can be limited by imposing maximum values of the forces as secondary conditions during the variation process.

Hiller, M. H.↗

NASA NTRS1990

Microgravity polymer and crystal growth at the Advanced Materials Center for the Commercial Development of Space

The microgravity research programs currently conducted by the Advanced Materials Center for the Commercial Development of Space (CCDS) are briefly reviewed. Polymer processing in space, which constitutes the most active microgravity program at the Advanced Materials CCDS, is conducted in three areas: membrane processing, multiphase composite behavior, and plasma polymerization. Current work in microgravity crystal growth is discussed with particular reference to the development of the Zeolite Crystal Growth facility.

Mccauley, Lisa A.↗

NASA NTRS2009

Complexity for Survival of Living Systems

A logical connection between the survivability of living systems and the complexity of their behavior (equivalently, mental complexity) has been established. This connection is an important intermediate result of continuing research on mathematical models that could constitute a unified representation of the evolution of both living and non-living systems. Earlier results of this research were reported in several prior NASA Tech Briefs articles, the two most relevant being Characteristics of Dynamics of Intelligent Systems (NPO- 21037), NASA Tech Briefs, Vol. 26, No. 12 (December 2002), page 48; and Self-Supervised Dynamical Systems (NPO- 30634) NASA Tech Briefs, Vol. 27, No. 3 (March 2003), page 72. As used here, living systems is synonymous with active systems and intelligent systems. The quoted terms can signify artificial agents (e.g., suitably programmed computers) or natural biological systems ranging from single-cell organisms at one extreme to the whole of human society at the other extreme. One of the requirements that must be satisfied in mathematical modeling of living systems is reconciliation of evolution of life with the second law of thermodynamics. In the approach followed in this research, this reconciliation is effected by means of a model, inspired partly by quantum mechanics, in which the quantum potential is replaced with an information potential. The model captures the most fundamental property of life - the ability to evolve from disorder to order without any external interference. The model incorporates the equations of classical dynamics, including Newton s equations of motion and equations for random components caused by uncertainties in initial conditions and by Langevin forces. The equations of classical dynamics are coupled with corresponding Liouville or Fokker-Planck equations that describe the evolutions of probability densities that represent the uncertainties. The coupling is effected by fictitious information-based forces that are gradients of the information potential, which, in turn, is a function of the probability densities. The probability densities are associated with mental images both self-image and nonself images (images of external objects that can include other agents). The evolution of the probability densities represents mental dynamics. Then the interaction between the physical and metal aspects of behavior is implemented by feedback from mental to motor dynamics, as represented by the aforementioned fictitious forces. The interaction of a system with its self and nonself images affords unlimited capacity for increase of complexity. There is a biological basis for this model of mental dynamics in the discovery of mirror neurons that learn by imitation. The levels of complexity attained by use of this model match those observed in living systems. To establish a mechanism for increasing the complexity of dynamics of an active system, the model enables exploitation of a chain of reflections exemplified by questions of the form, "What do you think that I think that you think...?" Mathematically, each level of reflection is represented in the form of an attractor performing the corresponding level of abstraction with more details removed from higher levels. The model can be used to describe the behaviors, not only of biological systems, but also of ecological, social, and economics ones.

Zak, Michail↗