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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 415 records · Page 23
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

A Tone-Aided/Dual Vestigial Sideband (TA/DVSB) system for mobile satellite channels

Tone-aided modulation is one way of combatting the effects of multipath fading and Doppler frequency shifts. A new tone-aided modulation format for M-ary phase-shift keyed signals (MPSK) is discussed. A spectral null for the placement of the tone is created in the center of the MPSK signal by translating the upper sideband upwards in frequency by the same amount. The key element of the system is the algorithm for recombining the data sidebands in the receiver, a function that is performed by a specialized phase-locked loop (PLL). The system structure is discussed and simulation results showing the PLL acquisition performance are presented.

Saulnier, Gary J.↗
NASA NTRS1993

Cloud, dust, and ozone vertical profiles from solar occultation measurements: Implications for dynamics

An instrument was designed for solar occultation measurements of the martian atmosphere from the Phobos spacecraft. It was composed of three different dispersive systems working in the ultraviolet (UV: 0.22-0.32 microns) for the measurement of O3 and aerosols, in the near infrared (NIR: 0.76 microns, 0.94 microns) for the detection of O2 and H2O, and in the infrared (IR: 1.9 microns, 3.7 microns) where CO2 and H2O were measured. A detailed description of the instrument may be found in the special issue of Nature. Its principle objective is to measure from the Phobos orbit the spectrum of the Sun, modified by atmospheric extinction, during sunset. The UV-NIR spot has an angular diameter of 1 arcmin, or approximately 3 km vertical resolution, and is located near the center of the solar disk. The IR field is about twice as large and its line of sight is shifted by 8.5 arcmin, or approximately 20 km, relative to the previous one. It is therefore located near the edge of the solar disk. Sampling times are generally 0.5, 1, and 2 s for IR, UV, and NIR channels respectively, corresponding to vertical excursions of the line of sight of 1, 2, and 4 km respectively under nominal conditions. The instrument operated from February 8 to March 26 (the martian equinox occurred on February 17). The latitude of the intersection of the Sun-spacecraft axis with the surface of Mars varied from -11 to +20, the seasonal date L(sub s) being in the range 0 - 20. All measurements were therefore made near northern spring equinox in equatorial regions. Due to an error in the pointing system, only partial results were obtained, the region below approximately equals 30 km altitude being never sounded by the UV-NIR spectrometer. On the contrary, nine complete occultations were obtained in the IR channels, whose line of sight was fortunately approximately equals 20 km below the UV-NIR axis.

Chassefiere, E.↗
NASA NTRS1996

Development of an automated control center for the EUVE mission

The Automated Project Operations Control Center (APOCC) was developed to enable automated data acquisition, ground system management and spacecraft health and safety monitoring. The control center will be used for the Extreme Ultraviolet Explorer (EUVE) project to reduce operations staffing from three to one shift per day, while maintaining the science return and performing routine health and safety monitoring activities. The staff reduction is expected to yield a cost reduction of 250,000 dollars per year in comparison with a fully staffed, 24 hour/day operation. The APOCC infrastructure was designed to be reusable and extensible. Configurable data items are stored in data bases and spacecraft-specific information is stored in a health and safety monitoring knowledge base.

Penafiel, Catherine↗
NASA NTRS1997

SUMER observations detecting downward propagating waves in the solar transition region

The O IV density sensitive emission lines around 1400 A, using the solar ultraviolet measurement of emitted radiation (SUMER) instrument onboard the Solar and Heliospheric Observatory (SOHO), are reported on. The data for the quiet sun, obtained close to the disk center and the solar limb were acquired. A systematic correlation between a density sensitive emission line ratio and Doppler shift across the same emission profiles was obtained. The correlation is such that the density is higher in the downflowing than in the upflowing plasma. The results are in good agreement with the simulations of downward propagating waves.

Wikstol, O.↗
NASA NTRS1998

Thermal Water Vapor Emission from Shocked Regions in Orion

Using the Long Wavelength Spectrometer on board the Infrared Space Observatory, we have observed thermal water vapor emission from a roughly circular field of view approximately 75" in diameter centered on the Orion BN-KL region. The Fabry-Perot line strengths, line widths, and spectral line shifts observed in eight transitions between 71 and 125 micron show good agreement with models of thermal emission arising from a molecular cloud subjected to a magnetohydrodynamic C-type shock. Both the breadth and the relative strengths of the observed lines argue for emission from a shock rather than from warm quiescent gas in the Orion core. Although one of the eight transitions appears anomalously strong and may be subject to the effects of radiative pumping, the other seven indicate an H2O/H2 abundance ratio on the order of 5 x 10(exp -4) and a corresponding gas-phase oxygen-to-hydrogen abundance ratio on the order of 4 x 10(exp -4). Given current estimates of the interstellar, gas-phase, oxygen and carbon abundances in the solar vicinity, this value is consistent with theoretical shock models that predict the conversion into water of all the gas-phase oxygen that is not bound as CO. The overall cooling provided by rotational transitions of H2O in this region appears to be comparable to the cooling through rotational lines of CO but is an order of magnitude lower than cooling through H2 emission. However, the model that best fits our observations shows cooling by H2O and CO dominant in that portion of the postshock region where temperatures are below approximately 800 K and neither vibrational nor rotational radiative cooling by H2 is appreciable.

Harwitt, Martin↗
NASA NTRS2013

Insights into Collisional between Small Bodies: Comparison of Impacted Magnesium-rich Minerals

Impacts are sustained by comets and asteroids throughout their lives, especially early in the Solar system's history, as described by the Nice model. Identifying observable properties that may be altered due to impacts can lead to a better understanding their collisional histories. Here, we investigate spectral effects and physical shock features observed in infrared spectra and Transmission Electron Microscope (TEM) images, respectively, of magnesium-rich minerals subjected to shock through impact experiments. Samples of magnesium-rich forsterite (Mg2SiO4, olivine), orthoenstatite (Mg2SiO3, pyroxene), diopside (MgCaSi2O6, monoclinic pyroxene), and magnesite (MgCO3, carbonate) were impacted at speeds of 2.4 km/s, 2.6 km/s and 2.8 km/s. Impact experiments were conducted in the Johnson Space Center Experimental Impact Laboratory using the vertical gun. Clear signatures are observed in both the mid-IR spectra (shift in wavelengths of the spectral peaks and relative amplitude changes) of all minerals except magnesite, and in TEM images (planar dislocations) of both the forsterite and orthoenstatite samples. Further discussion on forsterite and enstatite analyses can be found in Jensen et al., this meeting.

Lederer, Susan M.↗
NASA NTRSDate not supplied

Robustness of Semi-Superjunction 4H-SiC Power DMOSFETs to Single-Event Burnout from Heavy Ion Bombardment

We compare the failure mechanism and performance of a silicon carbide (SiC) semi-superjunction (semi-SJ) power DMOSFET against pure SJ and conventional DMOSFET when struck by a single heavy ion. The Single-Event Burnout (SEB) failure mechanism was identified as the thermal runaway from second breakdown resulting in mesoplasma formation. The semi-SJ design shifts the mesoplasma location from the drift/substrate interface seen in the control device structures to a location along the center of the P-pillar and closer towards the DMOSFET surface, thus significantly improving the SEB threshold voltage. The SEB threshold voltage varies with pillar width and ratio of pillar thickness to drift layer thickness. A maximum value of SEB threshold voltage is reached when the pillar to drift layer ratio is 0.9 and the pillar width is 2.4 μm. The semi-SJ SEB/breakdown voltage ratio is 100% and 13% higher than the pure SJ and conventional DMOSFET, respectively. Using a new figure of merit (FOM), which accounts for the tradeoff between SEB threshold voltage and on-state performance, we find that the SiC semi-SJ DMOSFET achieves a FOM that is 1.8 and 8 times higher than SJ and conventional DMOSFET, respectively, making the semi-SJ a competitive candidate for radiation hardened applications.

SiC↗
DOE OSTI2025

Tuning optical properties and local lone-pair off-centering in “hollow” FA 1− x { en } x Pb η−y Sn y Br 3 perovskites

Hollow metal halide perovskites, while a relatively recent discovery, have already been shown to push the boundaries of tuneability within an inherently limited compositional space. Here, we further expand our knowledge of these complex materials demonstrating the ability to control optical properties and local structure, notably lone-pair induced off-centering. We focus on the mixed metal FA 1−x en x Pb η−y Sn y Br 3 hollow perovskites. These compounds have wide ranging optical gaps from 1.9 eV (deep red) to 2.6 eV (light yellow), combining the anomalous bandgap red-shifting of Pb/Sn mixing with the blue-shifting effects of the organic substitution. Average and local structural studies employing single crystal X-ray diffraction and total X-ray scattering pair distribution function analyses respectively suggest strong incoherent off-centering distortions that are locally correlated with Sn concentration. The inclusion of ethylenediammonium dications appears to regulate metal off-centering, opening new opportunities of research into this phenomenon.

Balvanz, Adam [Northwestern University, Evanston, ↗
DOE OSTI2020

First-principles predictions of temperature-dependent infrared dielectric function of polar materials by including four-phonon scattering and phonon frequency shift

Recently, first-principles calculations based on density functional theory have been widely used to predict the temperature-dependent infrared spectrum of polar materials, but the calculations are usually limited to the harmonic frequency (0 K) and three-phonon scattering damping for the zone-center infrared-active optical phonon modes, and fail to predict the high-temperature infrared optical properties of materials such as sapphire (α–Al 2 O 3 ), GaAs, TiO 2 , etc., due to the neglect of high-order phonon scattering damping and phonon frequency shift. In this work, we implemented first-principles calculations to predict the temperature-dependent infrared dielectric function of polar materials by including four-phonon scattering and phonon frequency shift. The temperature-dependent phonon damping by including three- and four-phonon scattering as well as the phonon frequency shift by including cubic and quartic anharmonicity and the thermal expansion effect are calculated based on anharmonic lattice dynamics method. The infrared dielectric function of α–Al 2 O 3 is parameterized, and then the temperature-dependent infrared optical reflectance is determined. We find that our predictions agree better with the experimental data than the previous density functional theory-based methods. Lastly, this work will help to effectively predict the thermal radiative properties of polar materials at elevated temperature, which is generally difficult to measure, and will enable predictive design of new materials for radiative applications.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1991

Relative abundances in the lower solar transition region

Properties of the lower solar transition region as determined from UV spectral lines recorded by the Naval Research Laboratory HRTS are investigated. The spectra were obtained from a rocket flight in July 1975. Variations of intensity ratios of strong lines of C IV, Si IV, C II, Si III, and O IV over the entire field of view of the HRTS instrument, which extends from disk center to the solar limb are discussed. The largest apparent abundance variations appear to be in the active regions surrounding a sunspot. The C/Si ratio is lower in the active regions than anywhere else in the instrument field of view, implying a lower C/Si abundance ratio in the active regions. There is a possible correlation of line intensity variation in the active region with Doppler shift of the lines; the explanation for this is unclear. The magnitude and reality of intensity ratio variations of all observed solar features are discussed, and monotonic center-to-limb intensity ratio variations due to the opacity of some of the spectral lines are measured.

Doschek, G. A.↗
DOE OSTI2022

Materials under high pressure: a chemical perspective

At high pressure, the typical behavior of elements dictated by the periodic table, including oxidation numbers, stoichiometries in compounds, and reactivity, to name but a few, is altered dramatically. As pressure is applied, the energetic ordering of atomic orbitals shifts, allowing core orbitals to become chemically active, atypical electron congurations to occur, and in some cases,non-atom-centered orbitals to form in the interstices of solid structures. Strange stoichiometries, structures, and bonding motifs result. Crystal structure prediction tools, not burdened by preconceived notions about structural chemistry learned at atmospheric pressure, have been applied to great success to explore phase diagrams at high pressure, identifying novel structures in diverse chemical systems. Several of these phases have been subsequently synthesized. Experimentally, access to high-pressure regimes has been bolstered by advances in diamond anvil cell and dynamic com- pression techniques. Here, the joint efforts of experiment and theory have led to startling success stories in the realm of high-temperature superconductivity, identifying many novel phases (some of which have been synthesized) whose superconducting transition approaches room temperature.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Development of sterically hindered siloxide-functionalized polyoxotungstates for the complexation of 5d-metals

In this study, we extend the family of organosilyl-functionalized trivacant Keggin polyoxotungstates, [PW 9 O 34 (RSiOH) 3 ] 3− (R = n Pr, i Pr, t Bu), through the introduction of bulky aryl and aliphatic silanol substituents, namely phenyl, cyclohexyl and biphenyl. This work was performed in order to study the impact of these large functional groups on the accessibility of the well-defined tridentate coordination site. Coordination of hafnium to these type II hybrid polyoxotungstates was conducted in order to study the ability of the bulkier ligand pockets to support larger cations in comparison to those previously reported (e.g. Ti 4+ , V 3+ , V 5+ , Ge 4+ ). Increased steric hindrance around the coordination site from the biphenyl groups resulted in much longer reaction times for the complexation reaction compared to the other functional groups used, but the impact of our design toward stabilizing reactive species proved limited, as all complexes easily undergo hydrolysis of the Hf-O t Bu bond in the presence of water. As a result, electrochemical investigations of the ligands and hafnium complexes reveal that the redox events centered on the polyoxotungstate core can be tuned by varying the substituents on the silyl fragment, and exhibit a cathodic shift after coordination of the redox inactive tetravalent cation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Optimal Sizing and Operation of a Hybrid Clean Energy Center

In this paper, we consider the deployment of battery energy storage systems (BESSs) paired with photovoltaics (PV) to form a hybrid clean energy center (HCEC), where the BESS is equipped for two main purposes: i) reducing the volatility of PV output and ii) shifting energy to meet an export limit. We develop a linear dynamical model to characterize the output of an HCEC and express the volatility and export power as functions of the battery's dispatch operations. We also propose an optimal sizing method via second-order cone programming (SOCP) to maximize the net benefits of the HCEC. Numerical studies are performed to illustrate and validate the proposed method.

Battery energy storage systems, photovoltaics, sec↗
DOE OSTI2025

Electricity Rate Designs for Large Loads: Evolving Practices and Opportunities

Electricity demand from large load customers such as data centers is projected to grow significantly in the near term. While data centers play an important role in advancing technology innovation and economic growth in the United States, data center energy needs present challenges and opportunities for electricity supply and infrastructure. This technical brief serves as a foundation for the discussion of issues and sharing of perspectives among utilities, regulators, large load customers, and other stakeholders. As utilities and regulators explore rate structures to address growing data center electricity demand, several issues have emerged: -Fair allocation of electricity system costs to large-load customers without unfair shifting of costs to other customers -Appropriate mitigation of the financial risks associated with stranded assets from underutilized utility system investments -Mitigation of operational and resource adequacy risks if electricity demand exceeds supply -Appropriate risk-sharing in commercializing newer electricity technologies such as advanced geothermal, small modular reactors, and long duration energy storage -Accommodating the diverse needs of large-load customers, such as having the option to match electricity consumption with output from carbon-free resources or using onsite generation to provide system capacity The technical brief also identifies key design elements that aim to address these issues and uses leading examples from pending and approved rate structures, agreements, and special contracts to ground the elements in practice.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2025

Long-Range Allosteric Communication Modulated by Active Site Mn(II) Coordination Drives Catalysis in Xanthobacter autotrophicus Acetone Carboxylase

Acetone carboxylase (AC) from Xanthobacter autotrophicus is a 360 KDa α2β2γ2 heterohexamer that catalyzes the ATP-dependent formation of phosphorylated acetone and bicarbonate intermediates that react at Mn(II) metal active sites to form acetoacetate. Structural models of X. autotrophicus AC (XaAC) with and without nucleotides reveal that the binding and phosphorylation of the two substrates occurs ~40 Å from the Mn(II) active sites where acetoacetate is formed. Based on the crystal structures, a significant conformational change was proposed to open and close a tunnel that facilitates the passage of reaction intermediates between the sites for nucleotide binding and phosphorylation of substrates and Mn(II) sites of acetoacetate formation. We have employed electron paramagnetic resonance (EPR), kinetic assays, and hydrogen/deuterium exchange mass spectrometry (HDX-MS) of poised ligand-bound states and site-specific amino acid variants to complete an in-depth analysis of Mn(II) coordination and allosteric communication throughout the catalytic cycle. In contrast with the established paradigms for carboxylation, our analyses of XaAC suggested a carboxylate shift that couples both local and long-range structural transitions. Shifts in the coordination mode of a single carboxylic acid residue (αE89) mediate both catalysis proximal to a Mn(II) center and communication with an ATP active site in a separate subunit of a 180 kDa α2β2γ2 complex at a distance of 40 Å. This work demonstrates the power of combining structural models from X-ray crystallography with solution-phase spectroscopy and biophysical techniques to elucidate functional aspects of a multi-subunit enzyme.

Biochemistry & Molecular Biology↗
NASA NTRS1993

Working group for planetary system nomenclature

Most of the activity of the Working Group and Task Group of the IAU during these three years has been centered on the nomenclature of Neptune's satellites and rings as revealed by the Voyager spacecraft. The emphasis is now shifting to Venus, in preparation for the detailed radar mapping of that planet begun by the Magellan spacecraft in August 1990. Approval has been asked for nomenclature of the Earth's moon, Venus, Mars, and Triton features as well as 4 other Neptune satellites and three Neptune rings.

Source record↗
NASA NTRS2000

Perl Tools for Automating Satellite Ground Systems

The freeware scripting language Pert offers many opportunities for automating satellite ground systems for new satellites as well as older, in situ systems. This paper describes a toolkit that has evolved from of the experiences gained by using Pert to automate the ground system for the Compton Gamma Ray Observatory (CGRO) and for automating some of the elements in the Earth Observing System Data and Operations System (EDOS) ground system at Goddard Space Flight Center (GSFC). CGRO is an older ground system that was forced to automate because of fund cuts. Three 8 hour shifts were cut back to one 8 hour shift, 7 days per week. EDOS supports a new mission called Terra, launched December 1999 that requires distribution and tracking of mission-critical reports throughout the world. Both of these ground systems use Pert scripts to process data and display it on the Internet as well as scripts to coordinate many of the other systems that make these ground systems work as a coherent whole. Another task called Automated Multimodal Trend Analysis System (AMTAS) is looking at technology for isolation and recovery of spacecraft problems. This effort has led to prototypes that seek to evaluate various tools and technology that meet at least some of the AMTAS goals. The tools, experiences, and lessons learned by implementing these systems are described here.

McLean, David↗
NASA NTRS2005

Enabling New Operations Concepts for Lunar and Mars Exploration

The planning and scheduling of human space activities is an expensive and time-consuming task that seldom provides the crew with the control, flexibility, or insight that they need. During the past thirty years, scheduling software has seen only incremental improvements; however, software limitations continue to prevent even evolutionary improvements in the operations concept that is used for human space missions. Space missions are planned on the ground long before they are executed in space, and the crew has little input or influence on the schedule. In recent years the crew has been presented with a job jar of activities that they can do whenever they have time, but the contents of the jar is limited to tasks that do not use scarce shared resources and do not have external timing constraints. Consequently, the crew has no control over the schedule of the majority of their own tasks. As humans venture farther from earth for longer durations, it will become imperative that they have the ability to plan and schedule not only their own activities, but also the unattended activities of the systems, equipment, and robots on the journey with them. Significant software breakthroughs are required to enable the change in the operations concept. The crew does not have the time to build or modify the schedule by hand. They only need to issue a request to schedule a task and the system should automatically do the rest. Of course, the crew should not be required to build the complete schedule. Controllers on the ground should contribute the models and schedules where they have the better knowledge. The system must allow multiple simultaneous users, some on earth and some in space. The Mission Operations Laboratory at NASA's Marshall Space flight Center has been researching and prototyping a modeling schema, scheduling engine, and system architecture that can enable the needed paradigm shift - it can make the crew autonomous. This schema and engine can be the core of a planning and scheduling system that would enable multiple planners, some on the earth and some in space, to build one integrated timeline. Its modeling schema can capture all the task requirements; its scheduling engine can build the schedule automatically, and its architecture can allow those (on earth and in space) with the best knowledge of the tasks to schedule them. This paper describes the enabling technology and proposes an operations concept for astronauts autonomously scheduling their activities and the activities around them.

Jaap, John↗