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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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A lithium-sulfur battery with a solution-mediated pathway operating under lean electrolyte conditions
Lithium-sulfur (Li-S) battery is one of the most promising candidates for the next generation energy storage systems. However, several barriers, including polysulfide shuttle effect, the slow solid-solid surface reaction pathway in the lower discharge plateau, and corrosion of Li anode still limit its practical applications, especially under the lean electrolyte condition required for high energy density applications. Here, we propose a solution-mediated sulfur reduction pathway to improve the capacity and reversibility of the sulfur cathode and suppress dendrite growth on the Li metal anode simultaneously. With this method, a high coulombic efficiency (99%) and stable cycle life over 100 cycles were achieved under application-relevant conditions (S loading: 6.2 mg cm-2; electrolyte to sulfur ratio: 3 mLE gs-1; sulfur weigh ratio: 72 wt%). This result is enabled by a specially designed Li2S4-rich electrolyte, in which Li2S is formed through a chemical disproportionation reaction instead of electrochemical routes. A diglyme solvent was used to obtain electrolytes with the optimum range of Li2S4 concentration. Operando X-ray absorption spectroscopy confirms the solution pathway in a practical Li-S cell. This solution pathway not only introduces a new electrolyte regime for practical Li-S batteries, but also provides a new perspective for bypassing the inefficient surface pathway for other electrochemical processes.
Combiner-based method for efficiency enhancement of power amplifiers operating in a broad dynamic range
Not provided.
First feedback-controlled divertor detachment in W7-X: Experience from TDU operation and prospects for operation with actively cooled divertor
In the last experimental campaign (OP1.2b) of the stellarator Wendelstein 7-X (W7-X), boronisation as a mean for first wall conditioning was applied for the first time which led to strongly reduced impurity fluxes from plasma-facing components. Thermal detachment at the uncooled target plates of the test divertor unit (TDU) was reached at higher plasma densities and was accompanied by high recycling of neutrals at the target plate. A feedback control system was established in W7-X to actively control the gas injection (actuator) for plasma fuelling and impurity seeding [3] through the divertors. It allowed very successful stabilisation of the detached plasma condition state as well as mitigation of thermal overloads to some baffle tiles. Different routinely available diagnostic signals were used as input parameters (sensors). We describe the setup of the feedback control system, its performance and provide some example results with the main focus on the development of the control scheme which led to the detachment stabilisation over the entire longest (30 s) high-power discharge at W7-X so far. In view of the achieved very successful detachment stabilisation and the necessity to include simultaneous optimisation of the core performance in the future, the feedback control system is being upgraded for the upcoming campaign (OP2.1) in which the water cooled and hereby inherently steady-state capable divertor has been currently installed. The prospects and some experiment ideas for active detachment control are discussed.
2D analysis of tokamak divertor-plasma detachment-bifurcation with operational parameters and geometries
UEDGE simulations with density scans for various input power, transport coefficients and outer poloidal leg length are performed to study the conditions for the existence of a bifurcation-like drop of T e at the outer strike point, commonly referred to as a detachment cliff, when transitioning to a detached plasma from an attached plasma in the outer divertor as the upstream density increases (McLean et al., 2015). The simulation results show that a detachment cliff tends to occur with a higher power input regardless of diffusivities and leg length. Further analysis of change of plasma profiles at a cliff indicate that, in addition to the sharp reduction of the E x B drift fluxes in the outer divertor studied in Jaervinen et al., (2018), the substantial change of the Mach number in the outer divertor and the decrease of the outer mid-plane T e due to the radiation front moving across the separatrix into the confinement region above the X-point consistently occur for all UEDGE density scans that have a detachment cliff. UEDGE time-dependent simulation of the evolution of a detachment cliff shows that the rapid increase of radiation above the X-point occurs in a time scale of ~0.3–0.5, which could possibly be the trigger for the formation of a detachment cliff, quicker than the Mach number change in a time scale of ~1 ms and the drop of T e in a time scale of ~2–3 ms in the outer divertor.
Simulation-based machine shop operations scheduling system for energy cost reduction
Not provided.
Hybrid radiation modeling for multi-phase solar-thermal reactor systems operated at high-temperature
Not provided.
Prediction of the Thermal Runaway Limit and Optimal Operation of Heat Transfer-Limited, Fixed-Bed Reactor Systems
Here, we derive a new prediction for thermal runaway starting from the alpha model for fixed-bed reactor systems. This method accounts for thermal resistance internal to the reactor tube and the radial temperature gradients that result. To showcase our method, we compare its predictions to other common criteria for thermal runaway using o-xylene oxidation as the example chemistry. Even in systems where internal heat transfer is negligible, the empirical practical design criterion for thermal runaway is inaccurate. For cases where internal heat transfer is relevant, our runaway limit is more stringent than limits derived from simpler 1-D models. To augment our work, we optimize the product yield with the thermal runaway constraint using orthogonal collocation. Using the alpha model, the results illustrate that the thermal runaway limit can be accurately determined using either numerical or analytical methods.
Nanoscale Imaging of Lithium Ion Distribution During In Situ Operation of Battery Electrode and Electrolyte
Explore the source record for details and available documents.
A magnesium–sodium hybrid battery with high operating voltage
Here, we report a high performance magnesium-sodium hybrid battery utilizing a magnesium-sodium dual-salt electrolyte, a magnesium anode, and a Berlin green cathode. The cell delivers an average discharge voltage of 2.2 V and a reversible capacity of 143 mA h g –1 . We also demonstrate the cell with an energy density of 135 W h kg –1 and a high power density of up to 1.67 kW kg –1 .
Sulfur-fused perylene diimide electron transport layers allow >400 h operational lifetime of methylammonium lead iodide photovoltaics
The lifetime of hybrid organic perovskite solar cells under 1 sun illumination can be extended using electron transport layers made with fused perylene diimide acceptors with disulfide moieties.
Three-Dimensional Numerical Analysis on Blade Response of a Vertical-Axis Tidal Current Turbine Under Operational Conditions
Abstract not provided
Erratum: “Sharp transition between two regimes of operation of dc discharge with two anodes and thermionic emission from cathode” [Phys. Plasmas 21, 053508 (2014)]
No abstract prepared.
Riding on irrelevant operators
We investigate the stability of a class of derivative theories known as P(X) and Galileons against corrections generated by quantum effects. We use an exact renormalisation group approach to argue that these theories are stable under quantum corrections at all loops in regions where the kinetic term is large compared to the strong coupling scale. This is the regime of interest for screening or Vainshtein mechanisms, and in in ationary models that rely on large kinetic terms. Next, we clarify the role played by the symmetries. While symmetries protect the form of the quantum corrections, theories equipped with more symmetries do not necessarily have a broader range of scales for which they are valid. We show this by deriving explicitly the regime of validity of the classical solutions for P(X) theories including Dirac- Born-Infeld (DBI) models, both in generic and for specific background field configurations. Indeed, we find that despite the existence of an additional symmetry, the DBI effective field theory has a regime of validity similar to an arbitrary P(X) theory. We explore the implications of our results for both early and late universe contexts. Conversely, when applied to static and spherical screening mechanisms, we deduce that the regime of validity of typical power-law P(X) theories is much larger than that of DBI.