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At least 415 records · Page 23

Major Ion Toxicity to Glochidia of Common and Imperiled Freshwater Mussel Species

Freshwater mussel taxa are severely imperiled and among the most sensitive to several contaminants, including chloride. Relatively little is known of the toxicity of major ions to glochidia (larvae), particularly for rare species, or the effects of hardness on major ion toxicity to glochidia. Therefore, the primary objectives of this work were to: (1) determine the acute toxicity of major ion salts to glochidia, (2) compare chloride sensitivity of glochidia from common and rare species, and (3) evaluate the relationship between water hardness and chloride toxicity to glochidia. We assessed 24 h EC50s for fatmucket (Lampsilis siliquoidea) glochidia exposed to NaCl, KCl, MgCl 2 , CaCl 2 , Na 2 SO4, MgSO 4 , CaSO 4 , and NaHCO 3 in moderately hard water. We determined NaCl EC50s for four species and KCl EC50s for glochidia of three species. Toxicity of chloride was generally consistent among the various chloride salts except for KCl, which was more toxic than all others by 1–2 orders of magnitude. Our results suggest that commonly tested species may be generally representative of rare species. Water hardness ameliorated the toxicity of chloride for all species to varying degrees. Results of this work indicate that some existing water quality criteria that do not include mussel toxicity data may not be protective of freshwater mussels.

59 BASIC BIOLOGICAL SCIENCES↗

Nuclear-Driven Integrated Energy Systems: A State-of-the-Art Review

Because of the growing concerns regarding climate change and energy sustainability, a transition toward a modern energy sector that reduces environmental effects while promoting social and economic growth has gained traction in recent years. Sustainable energy solutions, which include renewable and low-carbon sources such as nuclear energy and natural gas, could minimize emissions of greenhouse gases, enhance air and water quality, and encourage energy independence. Yet, the shift to a sustainable energy industry is fraught with difficulties, including governmental and regulatory obstacles, technological and economic limits, and societal acceptability hurdles. Addressing these issues would necessitate the development of long-term, durable, and cost-effective energy systems containing nuclear energy and associated with the generation of both electricity and other by-products required by industry. Integrated energy systems (IES) are a novel way to maximize the use of various energy resources and technologies in order to deliver dependable, efficient, and sustainable energy services. IES entail the integration of various energy systems, such as electricity, heating, cooling, and transportation, in respect to energy sustainability and a system’s resilience and flexibility. Their development and implementation require the cooperation of several parties, including energy providers and policymakers. This study provides a state-of-the-art literature review of the most creative nuclear-driven hybrid energy system applications and methodologies, from which the research challenges and prospects for effective IES implementation emerge.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Simulator for Hydrologic Unstructured Domains (SHUD v1.0): numerical modeling of watershed hydrology with the finite volume method

Abstract. Hydrologic modeling is an essential strategy for understanding and predicting natural flows, particularly where observations are lacking in either space or time or where complex terrain leads to a disconnect in the characteristic time and space scales of overland and groundwater flow. However, significant difficulties remain for the development of efficient and extensible modeling systems that operate robustly across complex regions. This paper introduces the Simulator for Hydrologic Unstructured Domains (SHUD), an integrated, multiprocess, multiscale, flexible-time-step model, in which hydrologic processes are fully coupled using the finite volume method. SHUD integrates overland flow, snow accumulation/melt, evapotranspiration, subsurface flow, groundwater flow, and river routing, thus allowing physical processes in general watersheds to be realistically captured. SHUD incorporates one-dimensional unsaturated flow, two-dimensional groundwater flow, and a fully connected river channel network with hillslopes supporting overland flow and baseflow. The paper introduces the design of SHUD, from the conceptual and mathematical description of hydrologic processes in a watershed to the model's computational structures. To demonstrate and validate the model performance, we employ three hydrologic experiments: the V-catchment experiment, Vauclin's experiment, and a model study of the Cache Creek Watershed in northern California. Ongoing applications of the SHUD model include hydrologic analyses of hillslope to regional scales (1 m2 to 106 km2), water resource and stormwater management, and interdisciplinary research for questions in limnology, agriculture, geochemistry, geomorphology, water quality, ecology, climate and land-use change. The strength of SHUD is its flexibility as a scientific and resource evaluation tool where modeling and simulation are required.

58 GEOSCIENCES↗

Big Sky Regional Carbon Sequestration Partnership (Phase III Final Scientific/Technical Report)

The Big Sky Carbon Sequestration Partnership (BSCSP) pursued a Phase III demonstration project at Kevin Dome in north central Montana. Kevin Dome covers approximately 700 square miles and is a naturally occurring CO 2 reservoir that is flanked by oil and gas fields. The carbon dioxide (CO 2 ) is in the upper Devonian Duperow (carbonate) formation and does not reach the spill point of the dome; therefore, the dome has potential as a CO 2 sequestration reservoir, a CO 2 supply, or as both if anthropogenic sources and enhanced oil recovery (EOR) operations are associated with the dome. Kevin Dome could potentially act as a buffer to continue accepting anthropogenic CO 2 when EOR flooding operations are interrupted or completed. The project objective was to produce one million tonnes of CO 2 from the gas cap of Kevin Dome, pipe it laterally, inject, and re-store it in the brine leg of the same formation to test the hub / buffer storage concept. This was to be accomplished by drilling up to five production wells, building a short pipeline and compression facilities, and drilling an injection well and several monitoring wells. BSCSP commenced outreach and site characterization activities including acquiring baseline data for near-surface insurance monitoring, acquiring 3-dimensional, 9-component surface seismic over the project area, drilling two test wells (one in the production area and one in the injection area), coring key intervals, and performing comprehensive logging. Well tests of those wells revealed two barriers to the project. The production (Danielson 33-17) well was perforated in multiple zones but failed to produce any significant CO 2 . This was despite being drilled in the near vicinity of a historic well that had produced 3700 MCF per day in a drill stem test. Modeling indicated that this was likely due to a phase change during production causing a temperature drop resulting in hydrate and/or water ice formation that clogged the formation. Tests of the injection zone (Wallewein 22-1) well indicated total dissolved solids (TDS) slightly below the EPA required 10,000 parts per million (ppm) for a Class VI underground injection control permit. While the project was initiated before Class VI rules were promulgated, and this was an experimental project (seemingly qualified for a Class V permit), the Environmental Protection Agency (EPA) indicated that injection would require a Class VI permit. The low salinity result was unexpected as contours plotted based on regional formation water quality data indicated an expected TDS above 20,000 ppm, and wells between the recharge zone and the Wallewein well tested above 10,000 ppm. Faced with the inability to obtain an injection permit, the demonstration project could not proceed. However, the project had generated valuable samples and data on a large natural analog including 32 sq. mi. of 3-D, 9-C seismic, 430 ft. of carbonate core covering seven different depositional environments taken from areas with, and without the presence of CO 2 , 30 ft. of core of two caprocks, a tight carbonate and an anhydrite, a full set of modern logs on both wells, and well tests. DOE decided to re-scope the project around completing studies utilizing this data. This report covers both the initial scope and the re-scope (Task / Section numbers preceded with an R). While the report covers a wide range of project activities, highlights of this work include: Development of a geostatic model using neural nets to match well logs to facies and using multi-waveform seismic to inform reservoir heterogeneity; Unique mechanical testing of permeability – stress relationship in two caprock materials; Development of full waveform inversion to generate a high resolution velocity model; Model development for dual permeability (fracture and matrix) systems to better account for matrix-matrix interactions; Joint seismic wave inversion (including the first quadr-joint inversion) exhibiting better imaging of a challenging reservoir zone in stiff rock; Core flow and core flood results on a reactive carbonate; and Innovative laboratory measurements of seismic response of fractured core as a function of fluid fill.

54 ENVIRONMENTAL SCIENCES↗

Anaerobic Digestion Implementation at Dairies in Colorado

Anaerobic digestion (AD) of animal manure to produce biogas (methane) fuel has a wide variety of environmental benefits to air and water quality in addition to reducing greenhouse gas (GHG) emissions. In addition, the resulting biogas fuel and digestate products can help meet the energy needs and provide revenue to the farm. This case study explores the potential benefits and drawbacks of implementing an AD system at the Aurora Organic Dairy (AOD) High Plains Complex in Gill, Colorado. The project is envisioned as digester located at the AOD Complex with a single feed stream of manure from the Complex. The project would be implemented by a third-party contractor who would build and operate the system and pay the dairy a fraction of the profits, in addition to providing by-products such as digestate solids and liquids for fertilizer.

43 PARTICLE ACCELERATORS↗

Mastering Medaka Culture: Improved Techniques for Increasing Egg and Fry Production in Japanese Rice Fish ( Oryzias latipes )

Aquatic systems are integral to ecosystem function and human health. By trapping sediments and retaining nutrients, wetlands protect our water quality. However, a wetland’s capacity to trap sediments and nutrients also means they can capture many contaminants (e.g., heavy metals and radionuclides) released into the environment due to anthropogenic activities. Both heavy metals and radionuclides have detrimental effects on wildlife at acute dosages. However, little is known regarding underlying biological responses associated with chronic low dose exposure to both ionizing radiation and heavy metals. Our long-term research goal is to work to fill this knowledge gap using Medaka (Oryzias latipes), small fish amenable to experimental manipulation. However, the current study focused on altering the husbandry protocol of a laboratory colony of Medaka in a way that would increase colony size to at least 400 individual fish over a six-week period. At the beginning of our work, we followed a strict cleaning, feeding and egg harvesting protocol. Two weeks into our work, we suspected that food limitations may be negatively impacting egg production and noticed fungal growth on eggs. Thus, we altered the feeding regime and egg harvesting protocol. The altered protocol more than tripled egg production and almost doubled of fry production. By the end of our study the colony had 673 individuals: 191 adults and 482 fry. Furthermore, our protocol changes resulted in growth of the colony at sufficient numbers to begin experiments related to investigating sub-lethal impacts of heavy metals and radionuclides on Medaka.

Thompson, Melissa↗

Water Management Cost Assessment of CO2 Storage Operations

A three panel poster providing an analysis of treatment of produced waters from potential CO2 storage reservoirs. Selected water treatment technologies are modeled for several formations in five sedimentary basins in the lower 48 states assessing storage costs across a range of water quality present in these potential CO2 storage reservoirs.

Wendt, Anna↗

The Nuclear Fuel Cycle: Safe Management of Spent Nuclear Fuel

The aim for storage of spent nuclear fuel (SNF) either in wet or in dry storage systems is to ensure general safety objective s are met throughout a desired storage period. Staff at the Savannah River National Laboratory (SRNL), in collaborations with partners at other national laboratories, industry research organizations, and the University of South Carolina (UofSC), have performed materials aging testing and analyses, and have established nuclear materials aging management programs to support extended periods of safe storage of research reactor (RR) SNF and of commercial power reactor (PR) SNF pending ultimate disposal. Several example challenges include susceptibility of aluminum SNF from research reactors to corrosion in poor quality water (wet storage). In dry storage, aluminum SNF can release hydrogen via radiolysis of the hydrated oxides on the aluminum cladding. Austenitic stainless steel canisters used for dry storage are susceptible to chloride-induced stress corrosion cracking (outside-in attack) that threaten the confinement boundary provided by the canister. This paper further describes these challenges, among others, and the formulated solutions to support extended safe storage of SNF.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A next-generation toolset for the life-cycle analysis of electricity use

This works presents an overview--including background, data flow, and case study--of a tool for analyzing impacts utilizing the electricity baseline provided by ElectricityLCI and the impact-modeling techniques of Grid Mix Explorer (along with air and water quality) as a part of a next-generation LCA analytical framework.

Davis, Tyler↗

Miscanthus: An Environmental Choice for Marginal Lands

Miscanthus x giganteus, or Giant Miscanthus, is a tall, perennial grass originally from Asia. It is considered a sterile hybrid that has been bred to not produce viable seeds. Instead, rhizomes are planted to establish the crop. Here, the rhizome is an underground modified stem mass that puts out shoots and roots supporting new growth each year. This perennial crop takes two to three years to reach maturity, but established stands can reach upwards of 12 ft. tall with a very thick canopy (Pyter, 2007). Miscanthus has shown potential for high dry matter yields compared to other biomass crops, which could in turn lead to more efficient land use especially when applied to a bioenergy and bioproduct supply chain. In one study, switchgrass (Panicum virgatum) yielded 10.3 Mg/ha of biomass on average, while miscanthus yielded 22.4 Mg/ha (Heaton et al., 2004). Additionally, miscanthus production has been associated with many environmental benefits, including benefits to water quality, nutrient load removal, soil stabilization, and soil health (Bhardwaj et al., 2011; Hussain et al., 2019). Many of the possible practical and environmental benefits that are associated with miscanthus production may be attractive to stakeholders who are interested in alternative land use options, particularly in areas considered to be marginal in productivity.

54 ENVIRONMENTAL SCIENCES↗

Improving Discovery, Sharing, and Use of Water Data: Initial Findings and Suggested Future Work

Collaborative management of water resources requires a broad suite of “water data” that extends beyond basic information about water quantity and quality to other related topics such as water infrastructure, aquatic ecosystem health, socioeconomic factors, and power generation. Water data are disparate in nature because they are collected and provided by many entities, and in some cases, remain challenging to access and use. The U.S. Department of Energy’s Water Power Technologies Office initiated a project to characterize relevant categories of water data; describe the current state of accessing, using, and visualizing water data; and outline investigatory pathways for future efforts aimed at improving the discovery, sharing, and use of water data. Input on these topics was solicited from a small but diverse cross section of members of the water resources community. Fourteen broad categories of water data were identified: dams; ecology; flood control; hydroclimatology; hydrography; hydrology; hydropower; management landscape; migratory barriers; recreation and aesthetic importance; socioeconomic; water quality; water availability and use; and weather. Stakeholder perspectives on the accessibility and usability of water data indicate these aspects are affected by a complex set of technical and social factors. However, stakeholders generally agreed that better access to water data can provide a range of benefits to water management, and they stressed the need to generate broad support from water data users and producers. Two investigatory pathways were outlined that, taken together, provide a logical progression toward the goals of the project. The first pathway emphasizes further investigation to better define target audiences and data needs, identify opportunities for collaboration between related efforts, and conduct value demonstration activities to generate further support for improving discovery and access of water data. The second pathway focuses on creating a comprehensive vision for potential solutions that improve the discovery of water data. Several activities that align with the first pathway are suggested for the next phase of the project.

13 HYDRO ENERGY↗

Underground sources of drinking water chemistry changes in response to potential CO 2 leakage

The purpose of this study was to quantify changes to underground sources of drinking water (USDW) quality in response to potential CO 2 leakage from geologic CO 2 sequestration (GCS) reservoirs. Here, the developed a framework of combined laboratory experiments and reactive transport simulations and used this framework to evaluate the Ogallala aquifer overlying the Farnsworth Unit (FWU), an active GCS site, as a case study. Using chemical reaction parameters obtained from laboratory experiments and numerical simulations, site-specific mechanisms of CO 2 -water-sediment interactions at the USDW aquifer were interpreted. Long-term risks of potential CO 2 leakage were then evaluated with field-scale numerical models using the regional hydrogeological characteristics and reaction parameters obtained from our experiments and simulations. Results suggest that carbonate mineral impurity and cation exchange are key mechanisms for interactions between CO 2 and the aquifer sediment. Additionally, for a large leakage rate of 0.1 % injection from one leaky well, the leakage plume might impact an area of 300 m in diameter and significantly affect the local water quality by changing pH and cation concentrations (e.g., Zn, Ba and Sr). After leakage ceases, the zone of impacted fluids would not migrate significantly in subsequent decades due to a low regional groundwater flowrate (for this case study). The relatively small area of impact might not be detected in a monitoring well given the broader spacing in a typical field scenario. Effective early leakage detection may require additional tools, e.g., borehole CO 2 movement, four-dimensional seismicity, CO 2 soil flux, samples from deeper aquifers, etc., to ensure effective leakage detection and long-term safety of GCS projects.

58 GEOSCIENCES↗

Using Neural Network Force Fields to Ascertain the Quality of Ab Initio Simulations of Liquid Water

Accurately simulating the properties of bulk water, despite the apparent simplicity of the molecule, is still a challenge. In order to fully understand and reproduce its complex phase diagram, it is necessary to perform simulations at the ab initio level, including quantum mechanical effects both for electrons and nuclei. This comes at a high computational cost, given that the structural and dynamical properties tend to require long timescales and large simulation cells. In this work, we evaluate the errors that density functional theory (DFT)-based simulations routinely incur into due time- and size-scale limitations. These errors are evaluated using neural-network-trained force fields that are accurate at the level of DFT methods. We compare different exchange and correlation potentials for properties of bulk water that require large timescales. Here we show that structural properties are less dependent on the system size and that dynamical properties such as the diffusion coefficient have a strong dependence on the simulation size and timescale. Our results facilitate comparisons of DFT-based simulation results with experiments and offer a path to discriminate between model and convergence errors in these simulations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Policy Innovation and Governance for Irrigation Sustainability in the Arid, Saline San Joaquin River Basin

This paper provides a chronology and overview of events and policy initiatives aimed at addressing irrigation sustainability issues in the San Joaquin River Basin (SJRB) of California. Although the SJRB was selected in this case study, many of the same resource management issues are being played out in arid, agricultural regions around the world. The first part of this paper provides an introduction to some of the early issues impacting the expansion of irrigated agriculture primarily on the west side of the San Joaquin Valley and the policy and capital investments that were used to address salinity impairments to the use of the San Joaquin River (SJR) as an irrigation water supply. Irrigated agriculture requires large quantities of water if it is to be sustained, as well as supply water of adequate quality for the crop being grown. The second part of the paper addresses these supply issues and a period of excessive groundwater pumping that resulted in widespread land subsidence. A joint federal and state policy response that resulted in the facilities to import Delta water provided a remedy that lasted almost 50 years until the Sustainable Groundwater Management Act of 2014 was passed in the legislature to address a recurrence of the same issue. The paper describes the current state of basin-scale simulation modeling that many areas, including California, are using to craft a future sustainable groundwater resource management policy. The third section of the paper deals with unique water quality issues that arose in connection with the selenium crisis at Kesterson Reservoir and the significant threats to irrigation sustainability on the west side of the San Joaquin Valley that followed. The eventual policy response to this crisis was incremental, spanning two decades of University of California-led research programs focused on finding permanent solutions to the salt and selenium contamination problems constraining irrigated agriculture, primarily on the west side. Arid-zone agricultural drainage-induced water quality problems are becoming more ubiquitous worldwide. One policy approach that found traction in California is an innovative variant on the traditional Total Maximum Daily Load (TMDL) approach to salinity regulation, which has features in common with a scheme in Australia’s Hunter River Basin. The paper describes the real-time salinity management (RTSM) concept, which is geared to improving coordination of west side agricultural and wetland exports of salt load with east side tributary reservoir release flows to improve compliance with river salinity objectives. RTSM is a concept that requires access to continuous flow and electrical conductivity data from sensor networks located along the San Joaquin River and its major tributaries and a simulation model-based decision support designed to make salt load assimilative capacity forecasts. Web-based information dissemination and data sharing innovations are described with an emphasis on experience with stakeholder engagement and participation. The last decade has seen wide-scale, global deployment of similar technologies for enhancing irrigation agriculture productivity and protecting environmental resources.

54 ENVIRONMENTAL SCIENCES↗

Predicting lake surface water phosphorus dynamics using process-guided machine learning

Phosphorus (P) loading to lakes is degrading the quality and usability of water globally. Accurate predictions of lake P dynamics are needed to understand whole-ecosystem P budgets, as well as the consequences of changing lake P concentrations for water quality. However, complex biophysical processes within lakes, along with limited observational data, challenge our capacity to reproduce short-term lake dynamics needed for water quality predictions, as well as long-term dynamics needed to understand broad scale controls over lake P. Here we use an emerging paradigm in modeling, process-guided machine learning (PGML), to produce a phosphorus budget for Lake Mendota (Wisconsin, USA) and to accurately predict epilimnetic phosphorus over a time range of days to decades. In our implementation of PGML, which we term a Process-Guided Recurrent Neural Network (PGRNN), we combine a process-based model for lake P with a recurrent neural network, and then constrain the predictions with ecological principles. We test independently the process-based model, the recurrent neural network, and the PGRNN to evaluate the overall approach. The process-based model accounted for most of the observed pattern in lake P; however it missed the long-term trend in lake P and had the worst performance in predicting winter and summer P in surface waters. The root mean square error (RMSE) for the process-based model, the recurrent neural network, and the PGRNN was 33.0 μg P L -1 , 22.7 μg P L -1 , and 20.7 μg P L -1 , respectively. All models performed better during summer, with RMSE values for the three models (same order) equal to 14.3 μg P L -1 , 10.9 μg P L -1 , and 10.7 μg P L -1 . Although the PGRNN had only marginally better RMSE during summer, it had lower bias and reproduced long-term decreases in lake P missed by the other two models. For all seasons and all years, the recurrent neural network had better predictions than process alone, with root mean square error (RMSE) of 23.8 μg P L -1 and 28.0 μg P L -1 , respectively. The output of PGRNN indicated that new processes related to water temperature, thermal stratification, and long term changes in external loads are needed to improve the process model. By using ecological knowledge, as well as the information content of complex data, PGML shows promise as a technique for accurate prediction in messy, real-world ecological dynamics, while providing valuable information that can improve our understanding of process.

54 ENVIRONMENTAL SCIENCES↗

Water aging and the quality of organic carbon sources drive niche partitioning of the active bathypelagic prokaryotic microbiome

Abstract Due to the scarcity of organic matter (OM) sources in the bathypelagic (1000–4000 m depth), prokaryotic metabolism is believed to be concentrated on particles originating from the surface. However, the structure of active bathypelagic prokaryotic communities and how it changes across environmental gradients remains unexplored. Using a combination of 16S rRNA gene and transcripts sequencing, metagenomics, and substrate uptake potential measurements, here we aimed to explore how water masses aging and the quality of OM influence the structure of the active microbiome, and the potential implications for community function. We found that the relative contribution of taxa with a free‐living lifestyle to the active microbiome increased in older water masses that were enriched in recalcitrant OM, suggesting that these prokaryotes may also play a substantial role in the bathypelagic metabolism of vast areas of the ocean. In comparison to particle‐associated prokaryotes, free‐living prokaryotes exhibited lower potential metabolic rates, and harbored a limited number of two‐component sensory systems, suggesting they have less ability to sense and respond to environmental cues. In contrast, particle‐associated prokaryotes carried genes for particle colonization and carbohydrate utilization that were absent in prokaryotes with a free‐living lifestyle. Consistently, we observed that prokaryotic communities inhabiting older waters displayed reduced abilities to colonize particles, and higher capabilities to use complex carbon sources, compared to communities in waters with a higher proportion of labile OM. Our results provide evidence of regionalization of the bathypelagic active prokaryotic microbiome, unveiling a niche partitioning based on the quality of OM.

Marine & Freshwater Biology↗

Combined electrocoagulation-microfiltration-membrane distillation for treatment of hydraulic fracturing produced water

Hydraulic fracturing flowback and produced water is a highly impaired wastewater containing dissolved salts polar and non-polar organic compounds, oil and surfactants. Here a combined electrocoagulation - microfiltration – membrane distillation process has been used to treat this wastewater. Electrocoagulation followed by microfiltration was used to pretreat the wastewater prior membrane distillation. The initial total dissolved solids (TDS) concentration was extremely high being 245,300 mg L -1 . After electrocoagulation, the total organic carbon (TOC) was reduced from 120 mg L -1 to 64 mg L -1 . Tangential flow microfiltration using a 0.1 μm pore size polyethersulfone membrane was used to separate the particulate matter after electrocoagulation and to further reduce the TOC to 44 mg L -1 . Membrane distillation was used to desalinate the pretreated produced water resulting in a high quality treated water (TDS of 56 mg L -1 and TOC 1 mg L -1 ). Three membranes with very different surface morphology were used: commercially available polyvinylidene fluoride, electrospun poly(vinylidene fluoride-co-hexafluoropropylene) nanofibers and multiwalled carbon nanotube coated polytetrafluoroethylene. The TDS in the retentate increased to over 350,000 mg L -1 . During membrane distillation, the temperature of the feed tank was maintained at 36 °C while the feed entered the module at 60 °C in order to minimize scaling on the membrane. The surface properties of an ideal membrane that is resistant to wetting and provides high flux is likely to depend on the TDS and properties of the wastewater.

42 ENGINEERING↗