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At least 415 records · Page 23

Milestones for Selection, Characterization, and Analysis of the Performance of a Repository for Spent Nuclear Fuel and High-Level Radioactive Waste at Yucca Mountain

This report presents a concise history in tabular form of events leading up to site identification in 1978, site selection in 1987, subsequent characterization, and ongoing analysis through 2008 of the performance of a repository for spent nuclear fuel and high-level radioactive waste at Yucca Mountain in southern Nevada. The tabulated events generally occurred in five periods: (1) commitment to mined geologic disposal and identification of sites; (2) site selection and analysis, based on regional geologic characterization through literature and analogous data; (3) feasibility analysis demonstrating calculation procedures and importance of system components, based on rough measures of performance using surface exploration, waste process knowledge, and general laboratory experiments; (4) suitability analysis demonstrating viability of disposal system, based on environment-specific laboratory experiments, in-situ experiments, and underground disposal system characterization; and (5) compliance analysis, based on completed site-specific characterization. Because the relationship is important to understanding the evolution of the Yucca Mountain Project, the tabulation also shows the interaction between four broad categories of political bodies and government agencies/institutions: (a) technical milestones of the implementing institutions, (b) development of the regulatory requirements and related federal policy in laws and court decisions, (c) Presidential and agency directives and decisions, and (d) critiques of the Yucca Mountain Project and pertinent national and world events related to nuclear energy and radioactive waste.

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Removal of Metal Oxides from Reactor Metals/Alloys by Laser Ablation

Storage of low and intermediate level radioactive waste in a deep geological repository (L and ILW DGR): - Large volumes of metallic waste = increased production of hydrogen gas. - Large fraction of the metallic wastes are out-of-core reactor components. - Carbon steel feeder pipes. - Radioactive contamination is concentrated within the surface oxides. - Removal of surface contaminants would lead to volume reduction of metallic waste that is stored in L and ILW DGR. - Current decontamination techniques generate large volumes of secondary waste. Objectives: Oxide removal from carbon steel using a ytterbium fiber laser (1064 nm) with a particular focus on identifying the key laser parameters that affect the removal efficiency. Advantages of laser ablation: Generate low volumes of waste, Flexibility of deployment, Remote operation. Grow an oxide film on carbon steel with the incorporation of cobalt. Optimize laser cleaning technology for the removal of surface oxides. Incorporate an oxide collection system for the ablated particles. Conclusions: Objective 1 - Simulated inactive oxides on carbon steel, using Co{sup 2+} as a surrogate for Co radionuclide. Objective 2 - Optimized laser parameters (200 MW/cm{sup 2}, 3 scans, 15 μm overlap); Complete removal of cobalt from surface and bulk metal with optimized cleaning settings. Objective 3 - Glass fiber media H14 HEPA filters had highest collection yield; High oxide collection yields (∼100%). Future Work: Further testing of the liquid trap will verify the efficacy of the HEPA filter and determine the amount of ablated oxides that pass through. Testing of the laser ablation system needs to be done on other reactor materials along with the incorporation of different transition metal cations. Improvements to the oxide collection system are required to improve collection yields.

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Overview of Salt Repository Research and Development for Spent Nuclear Fuel and High-level Nuclear Waste in the United States - 20307

This paper summarizes the current US Department of Energy Office of Nuclear Energy's (DOE-NE) work towards developing and executing a research and development program that addresses both scientific and technical issues related to long-term disposal of spent nuclear fuel (SNF) and high-level waste (HLW) in a hypothetical bedded salt based geological repository. A primary goal of the program is to create a generic Geologic Disposal Safety Assessment (GDSA) Framework that can be used to help guide decisions on siting a possible future bedded salt repository. The generic GDSA work includes analysis of the impacts of heat generation caused by decay of short-lived radionuclides. We report progress in four primary areas. First, we discuss the development and recent modifications of a research and development road-map. Second, we briefly describe an experimental approach to better understand thermal processes in salt. Third, we highlight collaborations with the international research community that leverage salt-based repository science around the world. Finally, we discuss how our findings are being used to aid in the development of a generic safety assessment for a bedded salt repository containing SNF and HLW. (authors)

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New High-Throughput Measurement Systems for Radioactive Wastes Segregation and Free Release - 16166

The European Metrology Research Program (EMRP) is a coordinated research-and-development program that pursues the closer integration of national research programs. The EMRP Metrology for Decommissioning Nuclear Facilities 'MetroDecom' Joint Research Project ENV54 (JRP ENV54), a 36-month project started in September 2014, delivers research products addressing all aspects of the decommissioning process. This includes the characterization of waste materials present on the decommissioning site, pre-selection prior to free release or repository acceptance measurement, free-release measurement, the measurement of waste packages thermal power prior to the repository storage, and the monitoring of stored wastes and repositories in the very long term. This paper describes the track record of two JRP ENV54 working packages, which address the measurement facilities for pre-selection of waste materials prior to measurement for repository acceptance or possible free release (segregation measurement system); and free release (free release measurement system), based on a single standardized concept characterized by unique, patented lead-free shielding. The key objective is to improve the throughput, accuracy, reliability, modularity and mobility of segregation and free-release measurement. This will result in more reliable decision-making with regard to the safe release and disposal of radioactive wastes into the environment and, resulting in positive economic outcomes. (authors)

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Generic Argillite/Shale Disposal Reference Case

Radioactive waste disposal in a deep subsurface repository hosted in clay/shale/argillite is a subject of widespread interest given the desirable isolation properties, geochemically reduced conditions, and widespread geologic occurrence of this rock type (Hansen 2010; Bianchi et al. 2013). Bianchi et al. (2013) provides a description of diffusion in a clay-hosted repository based on single-phase flow and full saturation using parametric data from documented studies in Europe (e.g., ANDRA 2005). The predominance of diffusive transport and sorption phenomena in this clay media are key attributes to impede radionuclide mobility making clay rock formations target sites for disposal of high-level radioactive waste. The reports by Hansen et al. (2010) and those from numerous studies in clay-hosted underground research laboratories (URLs) in Belgium, France and Switzerland outline the extensive scientific knowledge obtained to assess long-term clay/shale/argillite repository isolation performance of nuclear waste. In the past several years under the UFDC, various kinds of models have been developed for argillite repository to demonstrate the model capability, understand the spatial and temporal alteration of the repository, and evaluate different scenarios. These models include the coupled Thermal-Hydrological-Mechanical (THM) and Thermal-Hydrological-Mechanical-Chemical (THMC) models (e.g. Liu et al. 2013; Rutqvist et al. 2014a, Zheng et al. 2014a) that focus on THMC processes in the Engineered Barrier System (EBS) bentonite and argillite host hock, the large scale hydrogeologic model (Bianchi et al. 2014) that investigates the hydraulic connection between an emplacement drift and surrounding hydrogeological units, and Disposal Systems Evaluation Framework (DSEF) models (Greenberg et al. 2013) that evaluate thermal evolution in the host rock approximated as a thermal conduction process to facilitate the analysis of design options. However, the assumptions and the properties (parameters) used in these models are different, which not only make inter-model comparisons difficult, but also compromise the applicability of the lessons learned from one model to another model. The establishment of a reference case would therefore be helpful to set up a baseline for model development. A generic salt repository reference case was developed in Freeze et al. (2013) and the generic argillite repository reference case is presented in this report. The definition of a reference case requires the characterization of the waste inventory, waste form, waste package, repository layout, EBS backfill, host rock, and biosphere. This report mainly documents the processes in EBS bentonite and host rock that are potentially important for performance assessment and properties that are needed to describe these processes, with brief description other components such as waste inventory, waste form, waste package, repository layout, aquifer, and biosphere. A thorough description of the generic argillite repository reference case will be given in Jové Colon et al. (2014).

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Solubility constants of hydroxyl sodalite at elevated temperatures evaluated from hydrothermal experiments: Applications to nuclear waste isolation

In this study, solubility constants of hydroxyl sodalite (ideal formula, Na 8 [Al 6 Si 6 O 24 ][OH] 2 ·3H 2 O) from 25°C to 100°C are obtained by applying a high temperature Al—Si Pitzer model to evaluate solubility data on hydroxyl sodalite in high ionic strength solutions at elevated temperatures. A validation test comparing model-independent experimental data to model predictions demonstrates that the solubility values produced by the model are in excellent agreement with the experimental data. In addition, the equilibrium constants obtained in this study have a wide range of applications, including synthesis of hydroxyl sodalite, de-silication in the Bayer process for extraction of alumina, and the performance of proposed sodalite waste forms in geological repositories in various lithologies including salt formations. The thermodynamic calculations based on the equilibrium constants obtained in this work indicate that the solubility products in terms of m ΣAl ×m ΣSi for hydroxyl sodalite are very low (e.g., ~10 -13 [mol·kg -1 ] 2 at 100°C) in brines characteristic of salt formations, implying that sodalite waste forms would perform very well in repositories located in salt formations. Finally, the information regarding the solubility behavior of hydroxyl sodalite obtained in this study provides guidance to investigate the performance of other pure end-members of sodalite such as chloride- and iodide-sodalite, which may be of interest for geological repositories in various media.

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Generic HLW Repository In Bedded Salt In Germany: Emplacement Technologies and Repository Designs - 18288

In Germany, a new site selection act for a repository for HLW and SNF entered into force in July 2013 and was amended in spring 2017 [1]. It stipulates that the safety of repository systems for heat-generating radioactive waste and spent nuclear fuel in different host rock formations be compared. This requires that generic repository concepts and adequate safety- and safety demonstration concepts for all potential host rock formations in Germany (salt, clay and crystalline rock) exist. For several decades, development of disposal concepts and safety analyses for a repository in a salt dome was prioritized while repository concepts for clay and crystalline rock have been taken into account for two decades only. So far, bedded salt formations have not been the subject of comparative investigations. Thus, in summer 2015, the Federal Ministry for Economic Affairs and Energy (BMWi) launched the R and D project KOSINA to develop repository designs and carry out safety analyses for different emplacement alternatives in a generic bedded salt formation and a generic salt pillow. KOSINA is an acronym for 'Concept development for a generic repository for heat-generating waste in bedded salt formations in Germany as well as development and testing of a safety and demonstration concept'. Together with its partners BGR, GRS, and IfG, DBE Technology GmbH has successfully carried out an almost three years lasting scientific programme, which will be concluded in April 2018. The core areas of the programme are the development of generic geologic models, including derivation of model parameters, the development of a safety and safety demonstration concept, the development of technical repository designs for four different emplacement alternatives, the analysis of geomechanical integrity, the evaluation of operational safety as well as the analysis of radiological consequences. An interim report, which compiles the basic data of the waste inventory, the repository design requirements, the data basis for geologic model developments, and the outline of a safety and safety demonstration concept, was already published in February 2016. The main achievements of the R and D project KOSINA are the development of four different repository designs, two per each generic geologic model (flat-bedded salt, salt pillow) based on thermomechanical calculations. This includes the implementation of a safety concept that provides containment of the radioactive materials with regard to the technical designs of waste packages, transport and emplacement technologies, and backfilling and sealing concepts. Furthermore, the integrity of the geologic barriers could be demonstrated for all four repository designs, and the long-term predictions showed no radiological releases during the demonstration period of one million years. (authors)

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Management and Disposal of U.S. Department of Energy Spent Nuclear Fuel - 19133

Congress created the U.S. Nuclear Waste Technical Review Board (NWTRB) in the 1987 Nuclear Waste Policy Amendments Act (Public Law 100-203) to evaluate the technical and scientific validity of activities undertaken by the Secretary of Energy to implement the Nuclear Waste Policy Act. In accordance with this mandate, the NWTRB reviewed the U.S. Department of Energy's (DOE) efforts to manage the inventory of spent nuclear fuel (SNF) that is under its control (DOE SNF) at several facilities around the country: the Hanford Site in Washington, the Idaho National Laboratory (INL) in Idaho, the Savannah River Site (SRS) in South Carolina, and the Fort St. Vrain independent spent fuel storage installation (ISFSI) in Colorado. While disposal of SNF and high-level radioactive waste (HLW) in a deep geologic repository remains the ultimate objective of the DOE nuclear waste management program, there is significant uncertainty about when such a repository will be constructed in the United States. Until disposal occurs, it is essential to manage DOE SNF in a way that will facilitate its eventual disposal, and it is also important to improve understanding of processes related to packaging and storage of the SNF that could affect its future transportation and disposal. The NWTRB's review, which was a multi-year effort, was documented in a report to Congress and the Secretary of Energy and is summarized here. The NWTRB reviewed the quantities and characteristics of DOE SNF at each of the four sites. It also examined DOE packaging and storage activities and plans at each of the sites. The NWTRB highlighted three main issue areas in its review. First, the review identified issues related to managing the aging of DOE SNF and the facilities used to store the DOE SNF. Second, the review addressed issues related to packaging of stored non-naval DOE SNF into a standard canister. Third, the NWTRB assessed issues that could affect disposal of DOE SNF if DOE continues to evaluate a range of repository settings. Based on the information and findings developed as part of its review, the NWTRB made six recommendations to Congress and the Secretary of Energy related to aging management, packaging, and disposal of DOE SNF. DOE has begun to address some of the NWTRB recommendations. (author)

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The Challenges of Repository Operation in an Existing Mine - 19339

A generally accepted principle related to long term management of radioactive waste/ spent fuel is the isolation in a geological repository. In Germany, the disposal operation of low-level waste (LLW) and intermediate-level waste (ILW) started in the Asse II mine in 1967 and in the former German Democratic Republic in the Morsleben repository in 1971. After the German reunification, the responsibility for the existing sites changed several times until the Bundesgesellschaft fuer Endlagerung (BGE) became new license holder for both sites in 2017. The BGE is responsible to carry out the operative tasks of searching for a high-level waste (HLW) repository, the planning and construction of the Konrad repository for the emplacement of low- and intermediate-level waste (LILW), the operation of the Asse II mine including the retrieval of the emplaced waste, and the preparation for the closure of the Morsleben repository. Nevertheless, the challenges of repository operation in an existing mine have not changed in all these years, as the regulatory framework is mainly written for Nuclear Power Plants (NPPs) and is difficult to adapt for a repository mine. In particular, conditions in a mine are substantially different from 'clean' above-ground nuclear installations. Dust due to mining activities, relatively high temperatures, and a corrosive atmosphere in a salt mine might be present. Therefore, the usability of the repository for several decades during the different operational phases, i.e. planning, construction, emplacement, and closure, can only be ensured by continuous maintenance. Furthermore, the atomic law is applicable for above-ground facilities and the mining law for mines of every description. The difficulty of geological repositories is to ensure that both laws are going to be applied above and below ground with no regulatory framework tailored especially for such sites. A special case is the Asse II mine where the mining law was applied from the very beginning, before the atomic law needed to be established later on and now requires the retrieval of the radioactive waste before decommissioning. In this presentation, similarities and differences in the legal framework of the repositories in the responsibility of BGE and some operational experiences throughout the years are described. This applies to the radiation protection regime, the excavation ratio, the host rock stability and the backfilling concepts of the mining areas. Further challenges arise from the demonstration of long term safety according to the state-of-the-art of science and technology for either existing repositories/ mines or those under construction or planned. (authors)

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Historic and modern nuclear graphite impurities: Pathways to improved waste strategies

Graphite has been used in large volumes as a structural material and neutron moderator since the earliest days of nuclear fission. However, no international consensus exists on the disposal of irradiated graphite, leaving much of the historic radioactive graphite inventory in interim vault or silo storage. With several new graphite-moderated reactors planned or under construction, the issue of graphite waste management is becoming increasingly urgent. This paper reviews and quantifies impurities in both historic and modern nuclear graphite, with emphasis on nitrogen—responsible for much of the 14 C inventory—and chlorine, which plays a critical role in repository performance and design. Modern graphites, benefitting from stringent quality-control measures developed for non-nuclear industries, meet or exceed the ASTM Ultra-High Purity nuclear standards, even without halide purification. Both chlorine and nitrogen concentrations have declined over time. For chlorine, identified as a key impurity influencing U.S. waste repository design, we propose a target of 0.1 appm in as-fabricated billets as a reasonable benchmark. Nitrogen sources are traced throughout the graphite production process, with surface and bulk concentrations characterized for all materials studied. Modern graphites commonly exhibit nitrogen levels below 5 appm, with values approaching 1 appm achievable. Using such reduced-nitrogen grades is critical to keeping graphite-induced radioactivity below the greater-than-Class-C waste threshold, thereby avoiding disposal cost penalties of nearly an order of magnitude.

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Deep Isolation - Innovation for the Storage and Disposal of High-level Waste and Spent Nuclear Fuel - 19367

Deep Isolation, Inc. is a private, Berkeley based company that has brought innovation to nuclear waste disposal. Deep Isolation has developed a disposal technique that adapts mature drilling technology and customizes it for the purpose of providing a safe and secure solution. Though the stalled nuclear waste program in the US has created unwanted burdens and costs, it has also provided object lessons which Deep Isolation has learned from and designed a novel approach. The solution proposed by Deep Isolation combines the best of the geosciences and social sciences to present the US and other countries with an optimized and tailored approach to disposing of a variety of nuclear waste. This system can complement existing potential storage and disposal sites, or in the case of countries with smaller amounts of waste--the national solution. Deep Isolation innovates where others have stalled and offers a means of deep geological disposal that costs less, takes less time to implement, and cuts down and in some cases eliminates the need for transportation of the waste. The technical solution optimized by Deep Isolation uses established directional drilling technology from the oil and gas industry to drill a vertical drill hole thousands of meters deep and then transition to a horizontal drill hole that is thousands of meters in length. The target media is in or below shale formations, which are present at various depths throughout much of the United States and throughout the world. The availability of suitable geology allows for permanent disposal at multiple locations - including existing nuclear sites, without a need to transport the waste to a central repository. This innovative solution not only offers options for commercial used nuclear fuel and defense spent nuclear fuel and high-level waste, but also other nuclear wastes such as those considered by DoE's past deep bore-hole program, i.e. cesium and strontium capsules. Greater-Than-Class-C (GTCC) waste is also an opportunity for Deep Isolation. DoE's preferred alternative for GTCC includes 'land disposal at generic commercial facilities.' Deep Isolation could provide safe, secure, and permanent disposal at a commercial facility. Deep Isolation complements the technical innovation with best practices from the social sciences. In acknowledgement that the past challenges to implement nuclear waste disposal facilities have been primarily due to socio-political failings, we have designed a means to deeply engage with public and stakeholders. Our approach is committed to partnering with communities, local jurisdictions, states, and Tribes to determine a path forward that benefits all involved, that is fully transparent, collaborative and accountable. (authors)

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Cost estimation inputs for spent nuclear fuel geologic disposal concepts (Revision 1)

A set of 16 geologic disposal concepts is described in sufficient detail for rough-order-of-magnitude repository cost estimates, for disposal of spent nuclear reactor fuel in generic crystalline, argillaceous, and salt host geologic media. The description includes total length, diameter, and volume for all underground shafts, ramps, drifts and large-diameter borings. Basic types of ground support are specified. Total repository capacity is assumed to be approximately 140,000 MT of spent fuel, but concepts are described in terms of modular panels each containing 10,000 MT. Waste packaging is described, and the materials and outer dimensions for disposal overpacks are given. The manner of emplacement is specified, with any additional fixturing, lining, buffer materials, and backfill needed. Thermal limits for waste package emplacement or repository closure are given, as appropriate for enclosed and open emplacement modes, respectively. The 16 disposal concepts are based on disposal concept studies performed for the Used Fuel Disposition R&D program between 2011 and 2014, and the accompanying engineering analyses. Revision 1 results from review and checking of repository spacings, drift length estimates, repository plan area estimates, closure power limits, and estimates of fuel age at closure.

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The role of Aspo Hard Rock laboratory for the Swedish nuclear fuel and waste management's research, developing and demonstration programme for a final repository of spent nuclear fuel - 15378

The Aspo Hard Rock Laboratory (HRL), located in the Simpevarp area in the municipality of Oskarshamn in Sweden, Figure 1, constitutes an important part of the Swedish Nuclear Fuel and Waste Management (SKB) work with design and construction of a deep geological repository for final disposal of spent nuclear fuel. One of the fundamental reasons behind SKB's decision to construct an underground laboratory was to create an opportunity for research, development and demonstration in a realistic and undisturbed rock environment down to repository depth. Most of the research has concerned with processes of importance for the long-term safety of a future final repository and the capability to model the processes taking place at repository depth. Demonstration addresses the performance of the engineered barriers and practical means of constructing a repository and emplacing the canisters containing spent fuel. SKB will in the coming years more focus on using the Aspo HRL for demonstrating technology for and function of important parts of the repository system before constructing and operate the spent nuclear fuel repository in Forsmark. Aspo HRL includes both a research village with office space for 100 persons and different laboratories, e.g. Chemistry and Material Science Laboratory and Bentonite Laboratory, and an underground research laboratory to a depth of 460 m. The Aspo HRL is also open for other organisations to be used for their own projects and experiments not only related to nuclear waste management research. (authors)

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Requalification and Declaration of High-alpha Cemented TRU-waste from the Late 70's and Early 80's - 20499

KTE and Siemens launched a project to qualify a series of 391 waste drums and 115 concrete containers produced from 1979 to 1984. The waste is characterized by a high content of long-lived alpha-nuclides (TRU-waste - Pu, U, Am in the range of 1 E+11-1 E+12 Bq/ drum. This high radionuclide inventory requires a special packaging according to the waste acceptance criteria (WAC) of the repository Konrad [1] despite the fact, that the waste was treated manually. The raw waste originally was delivered in nitric acid solution and was solidified using ordinary Portland cement. The existing documentation comprises analyses, transfer documentation for the nuclear fuel nuclides and waste treatment documentation yielding information, which waste was treated together in a batch. Additionally all drums were subjected to non-destructive gamma-spectrometry assay. A small number of 7 drums were opened and sampled to support the existing declaration. For the entire series the waste products were attributed to defined batches using the accountancy data supported by the analyses and the gamma-spectrometry. Each batch was produced from a homogeneous stock of waste solution and can therefore be declared and documented together. The declaration concept is based on the gamma spectrometry results performed on the entire drums, which were corrected and extended for the uncertainty of the analyses. The declaration concept is verified by the regulator and its independent expert. The state of the project is in the documentation of the solidification campaigns followed by the planning of the container configuration. (authors)

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Cost Estimation Inputs for Spent Nuclear Fuel Geologic Disposal Concepts

A set of 16 geologic disposal concepts is described in sufficient detail for rough-order-of-magnitude repository cost estimates, for disposal of spent nuclear reactor fuel in generic crystalline, argillaceous, and salt host geologic media. The description includes total length, diameter, and volume for all underground shafts, ramps, drifts and large-diameter borings. Basic types of ground support are specified. Total repository capacity is assumed to be approximately 140,000 MT of spent fuel, but concepts are described in terms of modular panels each containing 10,000 MT. Waste packaging is described, and the materials and outer dimensions for disposal overpacks are given. The manner of emplacement is specified, with any additional fixturing, lining, buffer materials, and backfill needed. Thermal limits for waste package emplacement or repository closure are given, as appropriate for enclosed and open emplacement modes, respectively. The 16 disposal concepts are based on disposal concept studies performed for the Used Fuel Disposition R&D program between 2011 and 2014, and the accompanying engineering analyses.

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Geology and Design of Major Spent Fuel Repositories

This report summarizes the geology and design concepts of four major spent fuel repositories from around the world. The crystalline rock with bentonite backfill is currently implemented in Finland with another repository being constructed in Sweden. The salt formation design focuses on the Waste Isolation Pilot Plant (WIPP) repository in the United States. The volcanic tuff open air design is based on the Yucca Mountain location. The volcanic tuff open air design at Yucca Mountain is only a concept as this repository has not been approved for operations. The last spent fuel repository design, clay/shale formation with backfill, focuses on the Cigeo Project in France, which is also pending.

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