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At least 415 records · Page 23

X‐Ray Absorption Studies of Local Structure of Dilute Ionic Species in Molten Salts

Molten salts are crucial materials with exceptional properties that make them suitable for applications such as heat transfer media, coolants, and liquid fuels in molten salt nuclear reactors and the concentrated solar power industry. Understanding their properties requires unraveling the intricate mysteries of their structure. To achieve this, advanced characterization tools are essential. Among various techniques, X‐ray absorption fine structure (XAFS) stands out as a versatile method capable of studying the structure of molten salts under in situ conditions. This review highlights recent advancements in the application of XAFS for investigating the local structure of molten salts, discusses its limitations and potential improvements, and explores complementary approaches such as simulations, machine learning, and correlative experimental methods.

22 - GENERAL STUDIES OF NUCLEAR REACTORS↗

Synthesis, Stability, and Magnetic Properties of Antiperovskite Co 3 PdN

Experimental synthesis and characterization of theoretically predicted compounds are important steps in the materials discovery pipeline. Here, we report on the synthesis of Co 3 PdN, which was recently predicted to be a stable magnetic antiperovskite. The Co 3 PdN thin films were grown by reactive sputtering and were confirmed to form in an antiperovskite crystal structure. The thermal stability of the compound is demonstrated up to 600 K by in situ X-ray diffraction, though the phase persists at slightly higher temperatures (700 K) in an air-free magnetometer. Both ab initio calculations and magnetization measurements find Co 3 PdN to be ferromagnetic with an experimentally determined Curie temperature of T C = 560 ± 5 K. The saturation magnetization of 1.2 μ B /Co found in the experiment is slightly lower than the 1.7 μ B /Co value expected by theory. A narrow magnetic hysteresis loop with a coercive field of 100 Oe at low temperature suggests that Co 3 PdN might be useful in electronic applications requiring fast switching of the magnetization vector. While prior prediction of Co 3 PdN showed a gapped electronic band structure for each spin channel, we show that this was due to incomplete sampling of Brillouin zone paths and that band crossings exist along R-X|M and X|M-R paths. The metallic nature of Co 3 PdN is further confirmed by temperature-dependent transport measurements, which also show a considerable anomalous Hall effect. Altogether, this work represents an appreciable step toward understanding the synthesis, structure, stability, and properties of a new magnetic material.

14 SOLAR ENERGY↗

Photophysical Properties and Phase Behavior of Ultrawide Photovoltaic Bandgap Cesium–Lead-Based Triple Halide Perovskites

Metal halide perovskite films in the top cell of triple-junction tandems require bandgaps around 2.0 eV to achieve current matching, assuming that the middle absorbing layer is the commonly used FAPbI 3 composition and the bottom cell has a bandgap around 1.1 eV. Unfortunately, mixed organic/inorganic metal halide perovskites that have the necessary Br content to reach a bandgap of 2.0 eV segregate into iodine-rich and bromine-rich phases under illumination, limiting their obtainable voltage. Previous reports have shown improved photostability using either Cs-based inorganic compositions or Cl incorporation on the X-site. Here, we investigate the inorganic triple halide compositional space CsPb­(I 1–x–y Br y Cl x ) 3 where bandgaps near 2.0 eV are expected based on the knowledge that CsPbI2Br has a bandgap of 1.90 eV. Incorporation of Cl occurs readily for x ≤ 0.07–0.10 within perovskites with a Br content of 0.3 ≤ y ≤ 0.42. When x >0.1, X-ray diffraction and photoluminescence (PL) measurements indicate that multiple compositional phases form. We hypothesize that the variable sizes of the three halide ions are not supported within the rigid Cs lattice, resulting in the formation of multiple compositional phases. The photoluminescence quantum yield of the single-phase compositional space–CsPb­(I 1–x–y Br y Cl x ) 3 where x ≤ 0.07was typically 0.001–0.004%, most likely as a result of a high defect density, including mobile iodine species. PL light-soaking measurements of many perovskite compositions with bandgaps in the range of 1.89–2.05 eV demonstrate that phase segregation occurs when initial bandgaps are above 1.95 eV regardless of halide content: indicating further iodide oxidation and corresponding migration under illumination. The conclusion is that further compositional or additive engineering is necessary for the development of inorganic triple halide compositions that accomplish the elusive goal of fabricating high-quality and photostable 2.0 eV films for use in multijunction tandems.

Electrical conductivity↗

Early photometric and spectroscopic observations of the extraordinarily bright INTEGRAL-detected GRB 221009A

Context. GRB 221009A, initially detected as an X-ray transient by Swift, was later revealed to have triggered the Fermi satellite about an hour earlier, marking it as a post-peak observation of the event’s emission. This GRB distinguished itself as the brightest ever recorded, presenting an unparalleled opportunity to probe the complexities of GRB physics. The unprecedented brightness, however, challenged observation efforts, as it led to the saturation of several high-energy instruments.Aims. Our study seeks to investigate the nature of the INTEGRAL-detected GRB 221009A and elucidate the environmental conditions conducive to these exceptionally powerful bursts. Moreover, we aim to understand the fundamental physics illuminated by the detection of teraelectronvolt (TeV) photons emitted by GRB 221009A.Methods. We conducted detailed analyses of early photometric and spectroscopic observations that span from the Fermi trigger through to the initial days following the prompt emission phase in order to characterize GRB 221009A’s afterglow, and we complemented these analyses with a comparative study.Results. Our findings from analyzing INTEGRAL data confirm GRB 221009A as the most energetic event observed to date. Early optical observations during the prompt phase negate the presence of bright optical emissions with internal or external shock origins. Spectroscopic analyses enabled us to measure GRB 221009A’s distance and line-of-sight properties. The afterglow’s temporal and spectral analysis suggests prolonged activity of the central engine and a transition in the circumburst medium’s density. Finally, we discuss the implications for fundamental physics of detecting photons as energetic as 18 TeV from GRB 221009A.Conclusions. Early optical observations have proven invaluable for distinguishing between the potential origins of optical emissions in GRB 221009A, underscoring their utility in GRB physics studies. However, the rarity of such data underscores the need for dedicated telescopes capable of synchronous multiwavelength observations. Additionally, our analysis suggests that the host galaxies of TeV GRBs share commonalities with those of long and short GRBs. Expanding the sample of TeV GRBs could further solidify these findings.Key words: techniques: photometric / techniques: spectroscopic / gamma-ray burst: general / gamma-ray burst: individual: GRB 221009A

79 ASTRONOMY AND ASTROPHYSICS↗

Characterization of the Cherenkov Photon Background for Low-noise Silicon Detectors in Space

Future space observatories that seek to perform imaging and spectroscopy of faint astronomical sources will require ultra-low-noise detectors that are sensitive over a broad wavelength range. Silicon charge-coupled devices (CCDs), such as EMCCDs, skipper CCDs, multi-amplifier sensing CCDs, and single-electron sensitive read out CCDs have demonstrated the ability to detect and measure single photons from X-ray energies to near the silicon band gap (∼1.1 μm), making them candidate technologies for this application. Here, in this context, we study a relatively unexplored source of low-energy background coming from Cherenkov radiation produced by energetic cosmic rays traversing a silicon detector. We present a model for Cherenkov photon production and absorption that is calibrated to laboratory data, and we use this model to characterize the residual background rate for ultra-low-noise silicon detectors in space. We study how the Cherenkov background rate depends on detector thickness, variations in solar activity, and the contribution of heavy cosmic ray species (Z > 2). We find that for thick silicon detectors, such as those required to achieve high quantum efficiency at long wavelengths, the rate of cosmic-ray-induced Cherenkov photon production is comparable to other detector and astrophysical backgrounds. We apply our Cherenkov background model to simulated spectroscopic observations of extra-solar planets, and we find that thick detectors continue to outperform their thinner counterparts at longer wavelengths despite a larger Cherenkov background rate. Furthermore, we find that minimal masking of cosmic-ray tracks continues to maximize the signal-to-noise ratio of very faint sources despite the existence of extended halos of Cherenkov photons.

Astronomical detectors↗

Proceedings of the Space Shuttle Sortie Workshop. Volume 2: Working group reports

Details are presented on the mission planning progress in each of the working paper reports. The general topics covered are the following: space technology; materials processing and space manufacturing; communications and navigation; earth and ocean physics; oceanography; earth resources and surface environmental quality; meteorology and atmospheric environmental quality; life sciences; atmospheric and space physics; solar physics; high energy cosmic rays; X-ray and gamma ray astronomy; ultraviolet-optical astronomy; planetary astronomy; and infrared astronomy.

Source record↗

On the physical parameters for Centaurus X-3 and Hercules X-1.

It is shown how upper and lower limits on the physical parameters of X-ray sources in Centaurus X-3 and Hercules X-1 may be determined from a reasonably simple and straightforward consideration. The basic assumption is that component A (the non-X-ray emitting component) is not a star collapsing toward its Schwartzschild radius (i.e., a black hole). This assumption appears reasonable since component A (the radius of the central occulting star) appears to physically occult component X. If component A is a 'normal' star, both observation and theory indicate that its mass is not greater than about 60 solar masses. The possibility in which component X is either a neutron star or a white dwarf is considered.

Mccluskey, G. E., Jr.↗

International Cosmic Ray Conference, 13th, University of Denver, Denver, Colo., August 17-30, 1973, Proceedings. Volumes 1 & 2

Topics discussed include diffuse gamma rays, gamma ray sources (in particular, the Crab Nebula and Crab Pulsar), X-ray sources, isotopic and nuclear composition, spectra of nuclei, searches for antinuclei, studies of VH and VVH nuclei, measurements of electrons and positrons, the spectra of high-energy electrons, cosmic gamma rays, cosmic ray sources, interplanetary radial gradients, the theory and observation of electron modulation, short-period cosmic ray intensity variations, atmospheric and coupling effects on neutron monitors and muon telescopes, secondary particles and photons in the atmosphere, harmonics of diurnal variations, geomagnetic effects and cutoffs, planetary and interplanetary effects, solar particle access observations, long-term cosmic ray intensity modulation by solar activity and interplanetary effects, Forbush decreases, modulation and anisotropy of low-energy particles, the theory and models of solar particle propagation, solar flare particle composition, and relativistic solar particles. Individual items are announced in this issue.

Source record↗

International Cosmic Ray Conference, 13th, University of Denver, Denver, Colo., August 17-30, 1973, Proceedings. Volume 5

An X-ray observation of the Norma-Lupus region, charge and isotope measurements of heavy cosmic ray nuclei and their role in the determination of cosmic ray age, and the possibility of a contribution to primary cosmic ray spectra from pulsars are among the topics covered in papers concerned with some of the results of recent cosmic ray research. Other topics covered include multiple scattering of charged particles in magnetic fields, absorption of primary cosmic rays in the atmosphere, and phase lag effects on cosmic ray modulation during a recent solar cycle. Individual items are announced in this issue.

Source record↗

Summary of spacecraft technology, systems reliability, and tracking data acquisition

Goddard activities are reported for 1973. An eight-year flight schedule for projected space missions is presented. Data acquired by spacecraft in the following disciplines are described: stellar ultraviolet, stellar X-rays, stellar gamma rays, solar radiation, radio astronomy, particles/fields, magnetosphere, aurora, and the upper atmosphere.

Source record↗

Astronomy satellites in the U.S. program

The Orbiting Astronomical Observatory (OAO) series demonstrated that necessary thermal control systems and high pointing stability are feasible on astronomical satellites. A geosynchronous International Ultraviolet Explorer (IUE) is being planned by the US, UK, and ESRO for stellar spectroscopy. High Energy Astronomy Observatories, HEAO-A B, and C, will concentrate on stellar X-ray objects, cosmic ray physics, and gamma ray astronomy. A Shuttle-compatible Solar Maximum Mission (SMM) is planned for studying solar flares and flare related phenomena during the next solar maximum. Now in the instrumentation definition stage is the Large Space Telescope (LST), to provide higher resolution and sensitivity, larger wavelength range (from ultraviolet to far infrared), and higher time resolution than ground-based telescopes.

Aucremanne, M. J.↗

Apollo scientific experiments data handbook

A brief description of each of the Apollo scientific experiments was described, together with its operational history, the data content and formats, and the availability of the data. The lunar surface experiments described are the passive seismic, active seismic, lunar surface magnetometer, solar wind spectrometer, suprathermal ion detector, heat flow, charged particle, cold cathode gage, lunar geology, laser ranging retroreflector, cosmic ray detector, lunar portable magnetometer, traverse gravimeter, soil mechanics, far UV camera (lunar surface), lunar ejecta and meteorites, surface electrical properties, lunar atmospheric composition, lunar surface gravimeter, lunar seismic profiling, neutron flux, and dust detector. The orbital experiments described are the gamma-ray spectrometer, X-ray fluorescence, alpha-particle spectrometer, S-band transponder, mass spectrometer, far UV spectrometer, bistatic radar, IR scanning radiometer, particle shadows, magnetometer, lunar sounder, and laser altimeter. A brief listing of the mapping products available and information on the sample program were also included.

Eichelman, W. F.↗