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At least 415 records · Page 23

Wide Tuning Capability for Spacecraft Transponders

A document presents additional information on the means of implementing a capability for wide tuning of microwave receiver and transmitter frequencies in the development reported in the immediately preceding article, VCO PLL Frequency Synthesizers for Spacecraft Transponders (NPO- 42909). The reference frequency for a PLL-based frequency synthesizer is derived from a numerically controlled oscillator (NCO) implemented in digital logic, such that almost any reference frequency can be derived from a fixed crystal reference oscillator with microhertz precision. The frequency of the NCO is adjusted to track the received signal, then used to create another NCO frequency used to synthesize the transmitted signal coherent with, and at a specified frequency ratio to, the received signal. The frequencies can be changed, even during operation, through suitable digital programming. The NCOs and the related tracking loops and coherent turnaround logic are implemented in a field-programmable gate array (FPGA). The interface between the analog microwave receiver and transmitter circuits and the FPGA includes analog-to-digital and digital-toanalog converters, the sampling rates of which are chosen to minimize spurious signals and otherwise optimize performance. Several mixers and filters are used to properly route various signals.

Lux, James↗

Rising Above the Cloud - Toward High-Rate Delay-Tolerant Networking in Low-Earth Orbit

The High Data Rate Architecture (HiDRA) project is implementing a High-rate Delay Tolerant Networking (HDTN) capability that can support Low Earth Orbit (LEO) applications and environments. The present state of the effort, future work, and other elements of the work to date are described in this paper. This implementation is intended to support applications that run at 1+ Gbps, per the requirements of modern optical and high-frequency RF links. Uniquely, this implementation is also tuned to support relay and data trunking applications, which might require support for large numbers of small bundles per second. The design for this platform is based entirely on commercial-off-the-shelf (COTS) components, and possesses buffering capabilities in the 5 TB range. This document takes results from previous individual tests and integrates them to demonstrate results in the presence of a coherent use-case: consider a network aboard the ISS which intends to utilize an upcoming optical communications capability. For this use-case, orbital analysis software is used to analyze orbital dynamics, from which a list of access times are generated that might take in to account weather, schedule competition, etc. A variant of Contact Graph Routing (CGR) is applied to these windows to determine an optimal schedule. This schedule is then loaded into the HDTN prototype and, in conjunction with various measurement tools, a complete end-to-end analysis of HDTN's performance is conducted. Various bottlenecks (including storage) are identified: these bottlenecks are expected to help us focus our future work on the elements of the system that are most likely to present issues moving forward. Finally, we discuss possible paths for evolution beyond the present rates supported by the system, including (but not limited to) hardware acceleration.

Hylton, Alan↗

A French Industrial Management Plan for Very Low Level Radioactive Wastes (VLLW) at the CIRES Facility - 17012

Since 2003, very-low-level waste has been disposed of at the Andra CIRES disposal facility, the first disposal facility in the world for this type. It is now the main route in terms of volumes for the management of French radioactive waste. The 2015 national inventory has identified 1.1 million m{sup 3} of VLLW to be produced until 2030. Several waste management scenarios were then analyzed, including issues associated with the flow reduction of the waste to be stored. The key avenues to reduce the volumes of waste, technical and economic viability of which still needing to be challenged, are at this stage: - Favor the reuse of large amounts of metallic VLLW to be produced within the next decade. - To service the recycling of metals, different opportunities for reuse should be considered -including within the non-nuclear sector. - 30% to 50% of VLLW produced in the so-called 'nuclear waste' areas probably have zero or non-detectable radioactivity levels and questions about the introduction of a clearance level. - A disposal route based on a concept derived from waste storage facility for non-nuclear and non-hazardous wastes could be an alternative to the clearance level for the least active inert waste. Therefore volumetric optimizations appear possible, even if the waste management costs will be higher than the current route. Furthermore, efficiency gains and progresses in operating modes would increase the technical capacity of the CIRES of about 250 000 m{sup 3}. In all cases studied, it appears essential to create around 2030 a new VLLW disposal facility, particularly for the dismantling of the current fleet of reactors. According to the proposed optimizations, the necessary capacity for a second VLLW disposal facility would range between 600 000 m{sup 3} and 1.2 million m{sup 3}. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Performance Evaluation of Conflict-Free Trajectory Taxiing in Airport Ramp Area Using Fast-Time Simulations

The German Aerospace Center (DLR) and the National Aeronautics and Space Administration (NASA) have been collaborating to conduct joint research addressing future surface traffic management challenges. The surface management tool from DLR, called Taxi Routing for Aircraft: Creation and Controlling (TRACC), was adapted to be integrated in NASA's fast-time simulation environment called Surface Operations Simulator and Scheduler (SOSS). The research described in this paper 1) applied TRACC to trajectory-based ramp traffic management, where TRACC generates conflict-free aircraft trajectories in a congested ramp area, 2) investigated the feasibility of the concept through the integrated TRACC-SOSS fast-time simulation, and 3) evaluated the performance of the integrated system. For this activity, TRACC was adapted for ramp operations at Charlotte Douglas International Airport, called TRACC_PB (TRACC for pushback optimization). TRACC_PB provides four-dimensional taxi trajectories with a command speed profile for each aircraft following standard taxi routes within the ramp area. In this study, departures are given the Target Movement Area entry Times (TMATs) provided by the baseline surface metering scheduler based on NASA's Spot and Runway Departure Advisor (SARDA). TRACC_PB also calculates optimal pushback times for departures, as well as the times when arrivals shall enter the ramp, the Target Movement area Exit Times (TMETs). The initial results showed that the TRACC_PB successfully generated conflict-free trajectories for the ramp area taxi operations and improved taxiing efficiency compared to the baseline results. TRACC_PB aimed to provide conflict-free taxi routes avoiding any stops while taxiing. This resulted in longer gate hold times for departures and postponed throughput values compared to the baseline simulation without trajectory optimization. Having conflict-free routes without stoppage also created shorter taxi times but required renegotiation of the given TMATs. TRACC_PB also achieved reductions in both fuel consumption and engine emissions (17% for departures and 10% for arrivals), which correlate with the ramp taxi time reduction.

trajectory-based taxi operations↗

Ultrasound assisted sonochemically engineered effective red luminescent labeling agent for high resolution visualization of latent fingerprints

Highlights: • BaTiO{sub 3}:Eu{sup 3+} NPs were prepared by facile bio-template assisted sonochemical route. • The obtained samples displayed superstructures of various regular morphological shapes. • The optimized product was used for forensic and anti-counterfeiting applications. • CIE, CCT studies indicate the present phosphor was highly useful in LED’s. - Abstract: Nanoscience and technology finds wide range of benefits in the area of surface based science due to its nano size and high surface area. This offers new potentials in surface-based science comprising latent fingerprint (LFP) and to develop luminescent ink for anti-counterfeiting applications. Due to high backward hindrance, low sensitivity, complicated setup, and poor universality of traditionally developed techniques were main drawbacks for the visualization of LFPs. To overcome these problems, we explored the superstructures (SS) of europium ions doped BaTiO{sub 3} nanophosphors (NPs) prepared via sonochemical route with bio-template as surfactant for the detection of LFPs and as an anti-counterfeiting ink. The morphologies of SS were highly dependent on the concentration of Aloe vera (A.V.) gel as well as ultrasound irradiation time. The obtained SS displayed pure red emission which corresponds to the {sup 5}D{sub 0} → {sup 7}F{sub J} transitions of Eu{sup 3+} ions under UV light. The results clearly evident that the optimized BaTiO{sub 3}:Eu{sup 3+} NPs will create a new prospect for research in LFPs visualization and anti-counterfeiting technology.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Optimal calibration of gates in trapped-ion quantum computers

Abstract To harness the power of quantum computing, it is essential that a quantum computer provide maximal possible fidelity for a quantum circuit. To this end, much work has been done in the context of qubit routing or embedding, i.e., mapping circuit qubits to physical qubits based on gate performance metrics to optimize the fidelity of execution. Here, we take an alternative approach that leverages a unique capability of a trapped-ion quantum computer, i.e., the all-to-all qubit connectivity. We develop a method to determine a fixed number (budget) of quantum gates that, when calibrated, will maximize the fidelity of a batch of input quantum programs. This dynamic allocation of calibration resources on randomly accessible gates, determined using our heuristics, increases, for a wide range of calibration budget, the average fidelity from 70% or lower to 90% or higher for a typical batch of jobs on an 11-qubit device, in which the fidelity of calibrated and uncalibrated gates are taken to be 99% and 90%, respectively. Our heuristics are scalable, more than 2.5 orders of magnitude faster than a randomized method for synthetic benchmark circuits generated based on real-world use cases.

Maksymov, Andrii (ORCID:0000000282442851)↗

Multi‐Objective Optimization for Rapid Identification of Novel Compound Metals for Interconnect Applications

Abstract Interconnect materials play the critical role of routing energy and information in integrated circuits. However, established bulk conductors, such as copper, perform poorly when scaled down beyond 10 nm, limiting the scalability of logic devices. Here, a multi‐objective search is developed, combined with first‐principles calculations, to rapidly screen over 15,000 materials and discover new interconnect candidates. This approach simultaneously optimizes the bulk electronic conductivity, surface scattering time, and chemical stability using physically motivated surrogate properties accessible from materials databases. Promising local interconnects are identified that have the potential to outperform ruthenium, the current state‐of‐the‐art post‐Cu material, and also semi‐global interconnects with potentially large skin depths at the GHz operation frequency. The approach is validated on one of the identified candidates, CoPt, using both ab initio and experimental transport studies, showcasing its potential to supplant Ru and Cu for future local interconnects.

Chemistry↗

Cell-free prototyping enables implementation of optimized reverse β-oxidation pathways in heterotrophic and autotrophic bacteria

Abstract Carbon-negative synthesis of biochemical products has the potential to mitigate global CO 2 emissions. An attractive route to do this is the reverse β-oxidation (r-BOX) pathway coupled to the Wood-Ljungdahl pathway. Here, we optimize and implement r-BOX for the synthesis of C4-C6 acids and alcohols. With a high-throughput in vitro prototyping workflow, we screen 762 unique pathway combinations using cell-free extracts tailored for r-BOX to identify enzyme sets for enhanced product selectivity. Implementation of these pathways into Escherichia coli generates designer strains for the selective production of butanoic acid (4.9 ± 0.1 gL −1 ), as well as hexanoic acid (3.06 ± 0.03 gL −1 ) and 1-hexanol (1.0 ± 0.1 gL −1 ) at the best performance reported to date in this bacterium. We also generate Clostridium autoethanogenum strains able to produce 1-hexanol from syngas, achieving a titer of 0.26 gL −1 in a 1.5 L continuous fermentation. Our strategy enables optimization of r-BOX derived products for biomanufacturing and industrial biotechnology.

59 BASIC BIOLOGICAL SCIENCES↗

Microstructural Engineering of Cu-Rich Nanoprecipitate formation in NiCoFeCrCu0.12 High-Entropy Alloy via Severe Plastic Deformation for Enhanced Irradiation Tolerance

This study demonstrates a defect-engineering approach for controlling Cu-rich precipitates in FeNiCrCoCu0.2 high-entropy alloys (Cu-HEAs), delivering a novel pathway for next-generation nuclear reactor materials with superior irradiation resistance. This work establishes that severe plastic deformation (SPD) processing via Shear Assisted Processing and Extrusion (ShAPE) and Friction Stir Layer Deposition (FSLD) creates dense dislocation networks and subgrain boundaries that fundamentally alter precipitation behavior under identical thermal treatments. Atom probe tomography (APT) indicates that SPD produces a metastable, atomically homogeneous solid solution that, upon moderate heat treatment (500°C/10 hour), develops remarkedly stronger Cu clustering than the as-cast counterpart. High-temperature exposure (800°C/100 h) produces near-pure Cu precipitates (~90 at% Cu) with significantly enhanced defect-sink efficacy in SPD-processed alloys: precipitate sizes of 50-60 nm and number densities of 2.7-3.8 × 10¹7 m?³, compared to 89 nm and 0.44 × 10¹7 m?³ in as-cast materials. Collectively, the findings establish defect-mediated precipitation control as a scalable, high-impact route to tailor sink density and distribution in HEAs, enabling microstructures optimized for irradiation tolerance and mechanical robustness in nuclear reactor environments.

Meher, Subhashish↗

Crystal Structure and Preparation of Li7La3Zr2O12 (LLZO) Solid-State Electrolyte and Doping Impacts on the Conductivity: An Overview

As an essential part of solid-state lithium-ion batteries, solid electrolytes are receiving increasing interest. Among all solid electrolytes, garnet-type Li7La3Zr2O12 (LLZO) has proven to be one of the most promising electrolytes because of its high ionic conductivity at room temperature, low activation energy, good chemical and electrochemical stability, and wide potential window. Since the first report of LLZO, extensive research has been done in both experimental investigations and theoretical simulations aiming to improve its performance and make LLZO a feasible solid electrolyte. These include developing different methods for the synthesis of LLZO, using different crucibles and different sintering temperatures to stabilize the crystal structure, and adopting different methods of cation doping to achieve more stable LLZO with a higher ionic conductivity and lower activation energy. It also includes intensive efforts made to reveal the mechanism of Li ion movement and understand its determination of the ionic conductivity of the material through molecular dynamic simulations. Nonetheless, more insightful study is expected in order to obtain LLZO with a higher ionic conductivity at room temperature and further improve chemical and electrochemical stability, while optimal multiple doping is thought to be a feasible and promising route. This review summarizes recent progress in the investigations of crystal structure and preparation of LLZO, and the impacts of doping on the lithium ionic conductivity of LLZO.

Raju, Md Mozammal (ORCID:0000000319040523)↗

A conflict analysis of 4D descent strategies in a metered, multiple-arrival route environment

A conflict analysis was performed on multiple arrival traffic at a typical metered airport. The Flow Management Evaluation Model (FMEM) was used to simulate arrival operations using Denver Stapleton's arrival route structure. Sensitivities of conflict performance to three different 4-D descent strategies (clear-idle Mach/Constant AirSpeed (CAS), constant descent angle Mach/CAS and energy optimal) were examined for three traffic mixes represented by those found at Denver Stapleton, John F. Kennedy and typical en route metering (ERM) airports. The Monte Carlo technique was used to generate simulation entry point times. Analysis results indicate that the clean-idle descent strategy offers the best compromise in overall performance. Performance measures primarily include susceptibility to conflict and conflict severity. Fuel usage performance is extrapolated from previous descent strategy studies.

Izumi, K. H.↗

Deconflicting Wind-Optimal Aircraft Trajectories in North Atlantic Oceanic Airspace

North Atlantic oceanic airspace accommodates more than 1000 flights daily, and is subjected to very strong winds. Flying wind-optimal trajectories yields time and fuel savings for each individual flight. However, when taken together, these trajectories induce a large amount of potential en-route conflicts. This paper analyses the detected conflicts, figuring out conflict distribution in time and space. It further describes an optimization algorithm aimed at reducing the number of conflicts for a daily set of flights on strategic level. Several trajectory modification strategies are discussed, followed with simulation results. Finally, an algorithm improvement is presented aiming at better preserving the trajectory optimality.

wind-optimal trajectories↗

Solar–Driven CO 2 Conversion via Optimized Photothermal Catalysis in a Lotus Pod Structure

Photothermal CO 2 reduction is one of the most promising routes to efficiently utilize solar energy for fuel production at high rates. However, this reaction is currently limited by underdeveloped catalysts with low photothermal conversion efficiency, insufficient exposure of active sites, low active material loading, and high material cost. Herein, we report a potassium-modified carbon-supported cobalt (K + –Co–C) catalyst mimicking the structure of a lotus pod that addresses these challenges. As a result of the designed lotus-pod structure which features an efficient photothermal C substrate with hierarchical pores, an intimate Co/C interface with covalent bonding, and exposed Co catalytic sites with optimized CO binding strength, the K + –Co–C catalyst shows a record-high photothermal CO 2 hydrogenation rate of 758 mmol gcat –1 h –1 (2871 mmol gCo –1 h –1 ) with a 99.8 % selectivity for CO, three orders of magnitude higher than typical photochemical CO 2 reduction reactions. Here, we further demonstrate with this catalyst effective CO 2 conversion under natural sunlight one hour before sunset during the winter season, putting forward an important step towards practical solar fuel production.

36 MATERIALS SCIENCE↗

Fuel Efficient Speed Optimization for Real-World Highway Cruising

This paper introduces an eco-driving highway cruising algorithm based on optimal control theory that is applied to a conventionally-powered connected and automated vehicle. Thanks to connectivity to the cloud and/or to infrastructure, speed limit and slope along the future route can be known with accuracy. This can in turn be used to compute the control variable trajectory that will minimize energy consumption without significantly impacting travel time. Automated driving is necessary to the implementation of this concept, because the chosen control variables (e.g., torque and gear) impact vehicle speed. An optimal control problem is built up where quadratic models are used for the powertrain. The optimization is solved by applying Pontryagin’s minimum principle, which reduces the problem to the minimization of a cost function with parameters called co-states. The proposed algorithm assumes piecewise constant slopes and speed limits, and it solves the transition vehicle speeds for each junction of such segments. In addition, a method to extract route information from digital maps is presented, which complies with the proposed optimization algorithm. The algorithms are evaluated in simulation, using Autonomie, a simulation tool for vehicle energy consumption modeling. The optimal control trajectory (e.g., torque, gear) is first computed offline. It is then applied in an open-loop fashion in online simulation, using a forward-looking model of the vehicle in Autonomie. Simulation results show over 8% fuel saving for two selected real-world routes.

Simulation and modeling, Optimization, Vehicle net↗

Solar‐Driven CO 2 Conversion via Optimized Photothermal Catalysis in a Lotus Pod Structure

Abstract Photothermal CO 2 reduction is one of the most promising routes to efficiently utilize solar energy for fuel production at high rates. However, this reaction is currently limited by underdeveloped catalysts with low photothermal conversion efficiency, insufficient exposure of active sites, low active material loading, and high material cost. Herein, we report a potassium‐modified carbon‐supported cobalt (K + −Co−C) catalyst mimicking the structure of a lotus pod that addresses these challenges. As a result of the designed lotus‐pod structure which features an efficient photothermal C substrate with hierarchical pores, an intimate Co/C interface with covalent bonding, and exposed Co catalytic sites with optimized CO binding strength, the K + −Co−C catalyst shows a record‐high photothermal CO 2 hydrogenation rate of 758 mmol g cat −1 h −1 (2871 mmol g Co −1 h −1 ) with a 99.8 % selectivity for CO, three orders of magnitude higher than typical photochemical CO 2 reduction reactions. We further demonstrate with this catalyst effective CO 2 conversion under natural sunlight one hour before sunset during the winter season, putting forward an important step towards practical solar fuel production.

Wang, Hongmin↗

Effect of annealing after strip casting on microstructure, precipitates and texture in non-oriented silicon steel produced by twin-roll strip casting

Highlights: • Non-oriented silicon steel with superior magnetic properties was produced by twin-roll strip casting. • The effect of annealing after strip casting on microstructure, precipitates and texture was investigated. • Role of precipitates in microstructure and texture evolution along the entire route was explored. • High magnetic induction and strong λ-fiber texture was obtained by optimizing strip annealing process. - Abstract: A 3.1 mm thick non-oriented Fe-1.0% Si steel as-cast strip was produced by twin-roll strip casting. Samples with/without strip annealing were cold rolled to 0.5 mm and then annealed. The development of microstructure, precipitate and texture was characterized along the entire processing route. It was found that annealing after strip casting had a minor influence on the average grain size and texture of the as-cast strip. A large number of particles precipitated and coarsened during the strip annealing process. Meanwhile, precipitates hindered dislocation slip and crystal rotation such that more significant in-grain shear bands were formed in cold rolled sheets. During recrystallization annealing process, the newly formed fine precipitates in directly cold-rolled sheets consumed stored strain energy and also hindered grain growth. But the initial precipitates in the annealed strip grew further and the effect of pinning of dislocations and grain boundary was lost. Therefore, annealed sheets with strip annealing process showed homogeneous equiaxed grains and the recrystallization texture was characterized by strong λ-fiber texture, which led to high permeability.

36 MATERIALS SCIENCE↗

Joint optimal scheduling for electric vehicle battery swapping-charging system based on wind farms

Insufficiencies in charging facilities limit the broad application of electric vehicles (EVs). In addition, EV can hardly represent a green option if its electricity primarily depends on fossil energy. Considering these two problems, this paper studies a battery swapping-charging system based on wind farms (hereinafter referred to as W-BSCS). In a W-BSCS, the wind farms not only supply electricity to the power grid but also cooperate with a centralized charge station (CCS), which can centrally charge EV batteries and then distribute them to multiple battery swapping stations (BSSs). The operational framework of the W-BSCS is analyzed, and some preprocessing technologies are developed to reduce complexity in modeling. Then, a joint optimal scheduling model involving a wind power generation plan, battery swapping demand, battery charging and discharging, and a vehicle routing problem (VRP) is established. Then a heuristic method based on the exhaustive search and the Genetic Algorithm is employed to solve the formulated NP-hard problem. Numerical results verify the effectiveness of the joint optimal scheduling model, and they also show that the W-BSCS has great potential to promote EVs and wind power.

17 WIND ENERGY↗