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At least 415 records · Page 23

Demonstrating the Error Budget for the Climate Absolute Radiance and Refractivity Observatory Through Solar Irradiance Measurements

The Climate Absolute Radiance and Refractivity Observatory (CLARREO) mission addresses the need to observe highaccuracy, long-term climate change trends and to use decadal change observations as a method to determine the accuracy of climate change. A CLARREO objective is to improve the accuracy of SI-traceable, absolute calibration at infrared and reflected solar wavelengths to reach on-orbit accuracies required to allow climate change observations to survive data gaps and observe climate change at the limit of natural variability. Such an effort will also demonstrate National Institute of Standards and Technology (NIST) approaches for use in future spaceborne instruments. The current work describes the results of laboratory and field measurements with the Solar, Lunar for Absolute Reflectance Imaging Spectroradiometer (SOLARIS) which is the calibration demonstration system (CDS) for the reflected solar portion of CLARREO. SOLARIS allows testing and evaluation of calibration approaches, alternate design and/or implementation approaches and components for the CLARREO mission. SOLARIS also provides a test-bed for detector technologies, non-linearity determination and uncertainties, and application of future technology developments and suggested spacecraft instrument design modifications. Results of laboratory calibration measurements are provided to demonstrate key assumptions about instrument behavior that are needed to achieve CLARREO's climate measurement requirements. Absolute radiometric response is determined using laser-based calibration sources and applied to direct solar views for comparison with accepted solar irradiance models to demonstrate accuracy values giving confidence in the error budget for the CLARREO reflectance retrieval.

CLARREO↗

Climate Absolute Radiance and Refractivity Observatory (CLARREO)

The Climate Absolute Radiance and Refractivity Observatory (CLARREO) is a mission, led and developed by NASA, that will measure a variety of climate variables with an unprecedented accuracy to quantify and attribute climate change. CLARREO consists of three separate instruments: an infrared (IR) spectrometer, a reflected solar (RS) spectrometer, and a radio occultation (RO) instrument. The mission will contain orbiting radiometers with sufficient accuracy, including on orbit verification, to calibrate other space-based instrumentation, increasing their respective accuracy by as much as an order of magnitude. The IR spectrometer is a Fourier Transform spectrometer (FTS) working in the 5 to 50 microns wavelength region with a goal of 0.1 K (k = 3) accuracy. The FTS will achieve this accuracy using phase change cells to verify thermistor accuracy and heated halos to verify blackbody emissivity, both on orbit. The RS spectrometer will measure the reflectance of the atmosphere in the 0.32 to 2.3 microns wavelength region with an accuracy of 0.3% (k = 2). The status of the instrumentation packages and potential mission options will be presented.

Leckey, John P.↗

Determination of the Complex Refractive Indices of Aerosol Analogs Formed at Low Temperatures with the NASA Ames Optical Constants Facility (OCF)

The NASA Ames COsmic SImulation Chamber (COSmIC) [1] is a unique experimental facility that allows: 1) cooling a gas mixture to low temperature (150 K) in a jet expansion before inducing chemistry by plasma; and 2) controlling the extent of the chemical reactions by employing a pulsed plasma discharge. This enables the study of the early stages of aerosol production, as well as specific chemical pathways in planetary environments (e.g. Titan’s and Pluto’s atmospheres). Both the gas and solid products can be studied. For a decade COSmIC has been used to simulate Titan’s atmospheric chemistry at low, Titan-like temperature [2]. New developments on the COSmIC facility are investigating formation of aerosols in tenuous, or transitory, atmospheres of other icy bodies [3-5], as well as cool exoplanets atmospheres having a hydrocarbon component, that results in formation of hazes and/or surface deposits of refractory materials. The new Ames Optical Constants Facility enables determination of the aerosol analogs' complex refractive indices, n and k, from 0.59 to 200 μm [2]. Here we report efforts of determining n and k from ex-situ transmission measurements of solid samples produced from binary N-CH and Ar-CH, and tertiary N-CH-CH and Ar-CH-CHgas mixtures in COSmIC, and deposited onto various substrates. A computational technique [6] that addresses interference fringes observed in the laboratory transmission data, particularly at wavelengths < 3 μm, has been implemented and applied to determine n and k for the samples. At visible and near-infrared wavelengths(0.4-1.6 μm) the deposit thickness, and its variation, as well as n and k were determined by a commercial entity. These data provide the ability to compare results, from independent methods, in the region of overlap between the two approaches.

Ella M Sciamma-O'Brien↗

Climate Absolute Radiance and Refractivity Observatory (CLARREO) Pathfinder Intercalibration Data Analysis Strategy

One of the prime science objectives of NASA’s Climate Absolute Radiance and Refractivity Observatory (CLARREO) Pathfinder (CPF) mission is to acquire unprecedentedly accurate Système Internationale (SI)-traceable Earth-view measurements that can be used as reference for intercalibrating the Clouds and the Earth’s Radiant Energy System (CERES) and Visible Infrared Imaging Radiometer Suite (VIIRS) instruments onboard NOAA-20 satellite. The hyperspectral nature of CPF measurements will significantly reduce spectrally induced biases when intercalibrating multiband or broadband satellite instruments with CPF. This advancement eliminates the requirement for spectral band adjustment factors, representing a substantial improvement in sensor intercalibration studies. The CPF intercalibration team is aiming to achieve a maximum intercalibration methodology uncertainty of 0.3 % (k=1). Our studies have revealed that the most significant contribution to the targeted uncertainty budget originates from the combined effects of spatial and temporal matching errors. Spatial matching error arises from discrepancies in CPF and target instrument pixel resolution and geolocation uncertainty, while temporal matching error is caused by changes in scene radiances over time, occurring between when the target and reference instruments observe the same scenes. To estimate the maximum expected uncertainty contribution from these sources, spatial and temporal matching noise analyses were conducted using algorithmically filtered Landsat 9 Operational Land Imager (OLI) and Geostationary Operational Environmental Satellite (GOES)-16 ABI CONUS scan data as proxies for CPF and target instruments. In the upcoming conference presentation, we will elaborate on the methodology employed in these experiments, provide details of the data filtering algorithms, and present results of the spatial and temporal matching uncertainty analyses.

Intercalibration↗

An automated approach to the alignment of compound refractive lenses

Compound refractive lenses (CRLs) are established X-ray focusing optics, and are thus a key element of many beamlines at X-ray facilities, used to either to focus a beam or image a sample. While CRLs are quite established, the stack of single lens elements affords a very small numerical aperture because of the thick lens profile, making them far more difficult to align than classical optical lenses that obey the thin-lens approximation. This means that the alignment must be very precise and is highly sensitive to changes to the incident beam; aligning CRLs is thus typically treated as a time-consuming manual process. Many groups circumvent day-to-day realignment by using engineering controls (e.g. mounting optics) that sacrifice some of the beam’s focusing characteristics, i.e. spot size, or resolution. While these choices minimize setup time, there are clear disadvantages. This work presents a new automated approach to align CRLs using a simple alignment apparatus that is easy to adapt and install at different types of X-ray experiments or facilities. Our approach builds on recent CRL modeling efforts, using an approach based on the Stochastic Nelder-Mead (SNM) simplex method. We demonstrate the efficacy of this method by numerical simulation and then extend this test to real experiments conducted at the Advanced Photon Source to confirm its performance with a synchrotron X-ray beam. This work provides an opportunity to automate key instrumentation at X-ray facilities.

97 MATHEMATICS AND COMPUTING↗

Electro-refractive modulation in photonic structures

Methods, systems, and devices are described for electro-optic tuning. An example device may comprise a first layer comprising a transition metal di-chalcogenide material, a second layer comprising a conductive material, and a third layer comprising a dielectric material. The third layer may be disposed at least partially between the first layer and the second layer. An electrical potential difference applied between the first layer and the second layer may cause a tunable refractive index change in the first layer.

Lipson, Michal↗

Low refractive index surface layers and related methods

The disclosure relates to a method for forming a low refractive index layer on a substrate. The method generally includes (a) applying a block copolymer layer on a substrate, the block copolymer including a polar polymeric block and a non-polar polymeric block; (b) swelling the block copolymer layer with a solvent to increase the block copolymer layer thickness; (c) depositing a metal oxide or metalloid oxide layer on polar polymeric blocks of the block copolymer layer; and (d) removing the block copolymer layer from the substrate, thereby forming a porous metal oxide or metalloid oxide layer on the substrate.

Shevchenko, Elena↗

Methodology to Account for Radiation and Temperature Influences on Optical Fibers compaction and Index of Refraction

The effects of radiation induced compaction and index of refraction change can cause significant drift in the measurements from intrinsic fiber optic temperature sensors. The work presented here aims to develop and test a methodology to measure these macroscopic properties that are responsible for the drift in order to correct the measurement. This report discusses the measurement methodology, theory, and sensor construction. Preliminary results from the first irradiation test using this sensor are provided here.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Methods for Determining the Infrared Complex Refractive Indices n (λ) and k (λ) from Organic Solid Powders: Comparison of a Sucrose Single Crystal and a Pressed Pellet

There exists a need to measure optical constants n and k for many materials, especially organic solids in the infrared spectral region, but at present, there are only two established methods for making such measurements: single-angle (SA) reflectance and infrared spectroscopic ellipsometry (IRSE). The former derives the n/k vectors via measurement of the change in the amplitude of light reflected from the sample and then uses the Kramers–Kronig transform, while the latter measures the change in polarization of the reflected light from the sample to derive n/k. Here we make a direct comparison between the n/k vectors derived from SA measurements of a sucrose single crystal and the n/k values obtained after the crystal had been crushed, ground to powder, and pressed into a pellet form. The pellet was measured not only by SA but also via the IRSE method, and we found that pressing specular-quality pellets was critical, especially for the SA data. The n/k values of this typical organic molecule all agree to within 0.04 root-mean-square error, confirming that a pressed pellet can be used instead of a crystal to derive the intrinsic n/k vectors. In conclusion, this result is important for the many organic materials that, unlike sugar, do not have centimeter-sized crystals readily available.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Seismic refraction tracks porosity generation and possible CO 2 production at depth under a headwater catchment

Significance To understand groundwater in weathered bedrock aquifers, we explore (bio)geochemical reactions using geophysical measurements. The result leads to a conceptual model for the three-dimensional distribution of geochemical alteration in the subsurface—well beyond the typical approach of inferring (bio)geochemical reactions in the subsurface from pits, boreholes, and outcrops. With this geophysical technique we discovered the prevalence of gas beneath the water table at this site. This geophysical viewing of the subsurface highlights patterns of water movement, reactions of clays, and microbial and abiotic gas-producing reactions recorded in the subsurface and thus illuminates storage, flow, and reactions of groundwater in bedrock systems. Protecting the groundwater resource beneath our feet will rely on such enhanced capacities to see into the subsurface.

58 GEOSCIENCES↗