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At least 415 records · Page 23

Thermophysical Property Measurement and Materials Research in the NASA/MSFC Electrostatic Levitator

Containerless processing is an important tool for materials research. The freedom from a crucible allows processing of liquid materials in a metastable undercooled state, as well as allowing processing of high temperature and highly reactive melts. Electrostatic levitation (ESL) is a containerless method which provides a number of unique advantages, including the decoupling of positioning force from sample heating, the ability to operate in ultra-high vacuum or at moderate gas pressure (approx. 3 atm), and the ability to process non-conducting materials. ESL also has the potential to reduce internal flow velocities below those possible with electromagnetic, acoustic, or aero-acoustic techniques. In electrostatic levitation, the acceleration of gravity (or residual acceleration in reduced gravity) is opposed by the action of an applied electric field on a charged sample. Microgravity allows electrostatic levitation to work even more effectively. In microgravity, ESL can position larger samples than is possible on the ground, or it can position samples which maintain their charge poorly. Microgravity also reduces the effects of buoyant convection and sedimentation. The ESL facility at NASA's Marshall Space Flight Center (MSFC) is in use for thermophysical property measurements and materials research by a number of different internal and external investigators. The methods for obtaining access to the facility, as well as a summary of current capabilities and some future directions will be discussed.

Rogers, J. R.↗

Nongassing nickel-cadmium battery electrodes and cells

The failure of nickel-cadmium storage batteries due to severe gassing during charging is discussed. In order to increase the life of such cells, nongassing positive and negative electrodes are used. The gassing characteristics of nickel electrodes were evaluated as a function of their loading, charge rate, and charge temperature.

Luksha, E.↗

The polarization electric field and its effects in an anisotropic rotating magnetospheric plasma

Spatial variations of density and temperature along a magnetic field line are evaluated for a plasma undergoing adiabatic motion in a rotating magnetosphere. The effects of centrifugal and gravitational forces are accounted for, as is anisotropy in the pitch angle distribution functions of individual species. A polarization electric field is invoked to eliminate the net electric charge density resulting from the aforementioned mass dependent forces and different anisotropies. The position of maximum density in a two-component, electron-ion plasma is determined both in the absence and in the presence of the polarization effect and compared. A scale height, generalized to include anisotropies, is derived for the density fall-off. The polarization electric field is also included in the parallel guiding center equation; equilibrium points are determined and compared in both individual and average senses with the position of density maximum. Finally a transverse (to magnetic field lines) electric component is deduced as a consequence of dissimilar charge neutralization on adjacent field lines. The E x B velocity resultant from such a 'fringing' electric field is calculated and compared with the magnitude of other drifts.

Huang, T. S.↗

An experimental investigation of mesospheric ionization

Mesospheric ionization and its variability are examined. Data were obtained primarily by the parachute-borne blunt probe technique conducted in coordinated rocket experiments at White Sands Missile Range, New Mexico and Wallops Island, Virginia. Electrical conductivity measurements and deduced charge density values from ten rocket launches are presented and discussed. Positive ion conductivity and electron density were found to be relatively invariant with height between 45 and 60 km. Variations in positive conductivity of a factor of two and enhancements in negative conductivity by as much as a factor of four were measured by the blunt probe. A simple lumped parameter ion chemistry model is shown to satisfactorily explain the charge density values for the undisturbed lower D-region. Implications of the data in terms of this model are considered. The principal loss mechanism for positive ions in the 45 to 60 km. region is concluded to be dissociative recombination. Electron densities deduced from the conductivity data are explained by detachment involving a minor neutral constituent which is mixed between 65 and 45 km. and then cuts off sharply below 45 km. A correlation study involving blunt probe measurements shows relatively good agreement between variations in positive conductivity and temperature.

Mitchell, J. D.↗

Initial observations of low energy charged particles near the earth's bow shock on ISEE-1

Initial measurements from the ULECA sensor of the Max-Planck-Institut/University of Maryland experiment on ISEE 1 are reported. ULECA is an electrostatic deflection - total energy sensor consisting of a collimator, a deflection analyzer, and an array of solid-state detectors. The position of a given detector, which determines the energy per charge of an incident particle, together with the measured energy, determines the particle's charge state. It is found that a rich variety of phenomena are operative in the transthermal energy regime (about 10 keV/Q to 100 keV/Q) covered by ULECA. Specifically, observations are presented of locally accelerated protons, alpha particles, and heavier ions in the magnetosheath and upstream of earth's bow shock. Preliminary analysis indicates that the behavior of these locally accelerated particles is most similar at the same energy per charge.

Ipavich, F. M.↗

Plasma analyzer for the Pioneer Jupiter missions

A description is given of the NASA/Ames Research Center Plasma Probe on board the Jupiter Missions of the Pioneer 10 and 11 spacecraft. The instrument has two quadrispherical electrostatic analyzer units; one has high sensitivity and resolution and the other is capable of measuring large fluxes of solar wind particles. The two analyzer units measure particle energy-to-charge ratio, flux, and direction of flow for positive ions and electrons over the wide range of particle densities found in the solar wind during the Jupiter missions. Data formats in space and ground data processing, the NASA/Ames Research Center plasma probe calibration facility, and the instrument response functions are also described.

Mckibbin, D. D.↗

Plasma Interaction Experiment (PIX) flight results

An auxiliary payload package called PIX (plasma interaction experiment) was launched on March 5, 1978, on the LANDSAT 3 launch vehicle to study interactions between the space charged-particle environment and surfaces at high applied positive and negative voltages. Three experimental surfaces were used in this package: a plain disk to act as a control, a disk on a Kapton sheet to determine the effect of surrounding insulation on current collection, and a small solar-array segment to evaluate the effect of distributing biased surfaces among an array of insulators. Only half of the results from the 4 hours of PIX operations were recovered. The results did verify effects found in ground simulation testing. The results of this experiment are discussed in detail.

Grier, N. T.↗

Numerical simulation of the flow and fuel-air mixing in an axisymmetric piston-cylinder arrangement

The implicit factored method of Beam and Warming was employed to describe the flow and the fuel-air mixing in an axisymmetric piston-cylinder configuration during the intake and compression strokes. The governing equations were established on the basis of laminar flow. The increased mixing due to turbulence was simulated by appropriately chosen effective transport properties. Calculations were performed for single-component gases and for two-component gases and for two-component gas mixtures. The flow field was calculated as functions of time and position for different geometries, piston speeds, intake-charge-to-residual-gas-pressure ratios, and species mass fractions of the intake charge. Results are presented in graphical form which show the formation, growth, and break-up of those vortices which form during the intake stroke and the mixing of fuel and air throughout the intake and compression strokes. It is shown that at bore-to-stroke ratio of less than unity, the vortices may break-up during the intake stroke. It is also shown that vortices which do not break-up during the intake stroke coalesce during the compression stroke. The results generated were compared to existing numerical solutions and to available experimental data.

Shih, T. I. P.↗

Measuring Air-Ionizer Output

Test apparatus checks ion content of airstream from commercial air ionizer. Apparatus ensures ion output is sufficient to neutralize static charges in electronic assembly areas and concentrations of positive and negative ions are balanced.

Lonborg, J. O.↗

Generating Hyperthermal Atomic Oxygen

Atomic oxygen diffused through silver desorbed by low-energy electron impact. Oxygen atoms diffuse through silver foil and emerge on high-vacuum side, aided by electron-stimulated desorption. Atomic-oxygen flux levels range up to 10 to the 12th power cm to the negative 2 power S to the negative 1 power, and kinetic energies range from 1 to 10 eV. O positive and O negative ions swept aside by charged cylindrical grids.

Outlaw, Ronald A.↗

Negative-ion formation in the explosives RDX, PETN, and TNT using the Reversal Electron Attachment Detection (READ) technique

In the search for high sensitivity and direct atmospheric sampling of trace species, techniques have been developed such as atmospheric-sampling, glow-discharge ionization (ASGDI), corona discharge, atmospheric pressure ionization (API), electron-capture detection (ECD), and negative-ion chemical ionization (NICI) that are capable of detecting parts-per-billion to parts-per-trillion concentrations of trace species. These techniques are based on positive- or negative-ion formation via charge-transfer to the target, or electron capture under multiple-collision conditions in a Maxwellian distribution of electron energies at the source temperature. One drawback of the high-pressure, corona- or glow-discharge devices is that they are susceptible to interferences either through indistinguishable product masses, or through undesired ion-molecule reactions. The ASGDI technique is relatively immune from such interferences, since at target concentrations of less than 1 ppm the majority of negative ions arises via electron capture rather than through ion-molecule chemistry. A drawback of the conventional ECD, and possibly of the ASGDI, is that they exhibit vanishingly small densities of electrons with energies in the range 0-10 millielectron volts (meV), as can be seen from a typical Maxwellian electron energy distribution function at T = 300 K. Slowing the electrons to these subthermal (less than 10 meV) energies is crucial, since the cross section for attachment of several large classes of molecules is known to increase to values larger than 10(exp -12) sq cm at near-zero electron energies. In the limit of zero energy these cross sections are predicted to diverge as epsilon(exp -1/2), where epsilon is the electron energy. In order to provide a better 'match' between the electron energy distribution function and attachment cross section, a new concept of attachment in an electrostatic mirror was developed. In this scheme, electrons are brought to a momentary halt by reversing their direction with electrostatic fields. At this turning point the electrons have zero or near-zero energy. A beam of target molecules is introduced, and the resultant negative ions extracted. This basic idea has been recently improved to allow for better reversal geometry, higher electron currents, lower backgrounds, and increased negative-ion extraction efficiency. We present herein application of the so-called reversal electron attachment detector (READ) to the study of negative-ion formation in the explosives molecules RDX, PETN, and TNT under single-collision conditions.

Chutijian, Ara↗

Measurements of Sheath Currents and Equilibrium Potential on the Explorer VIII Satellite (1960 xi)

Experimental data were obtained from the Explorer VIII satellite on five parameters pertinent to the problem of the interaction of space vehicles with an ionized atmosphere. The five parameters are: photoemission current due to electrons emitted from the satellite surfaces as a result of solar radiation; electron and positive ion currents due to the diffusion of charged particles from the medium to the spacecraft; the vehicle potential relative to the medium, and the ambient electron temperature. Included in the experimental data is the aspect dependence of the photoemission and diffusion currents. On the basis of the observations, certain characteristics of the satellite's plasma sheath are postulated.

Bourdeau, R. E.↗

Solar Powered CO.Sub.2 Conversion

Methods and devices for reducing CO.sub.2 to produce hydrocarbons are disclosed. A device comprises a photoanode capable of splitting H.sub.2O into electrons, protons, and oxygen; an electrochemical cell cathode comprising an electro-catalyst capable of reducing CO.sub.2; H.sub.2O in contact with the surface of the photoanode; CO.sub.2 in contact with the surface of the cathode; and a proton-conducting medium positioned between the photoanode and the cathode. Electrical charges associated with the protons and the electrons move from the photoanode to the cathode, driven in part by a chemical potential difference sufficient to drive the electrochemical reduction of CO.sub.2 at the cathode. A light beam is the sole source of energy used to drive chemical reactions. The photoanode can comprise TiO.sub.2 nanowires or nanotubes, and can also include WO.sub.3 nanowires or nanotubes, quantum dots of CdS or PbS, and Ag or Au nanostructures. The cathode can comprise a conductive gas diffusion layer with nanostructures of an electro-catalyst such as Cu or Co.

Chen, Bin↗

Distribution of NO2/+/ in the lower ionosphere.

The positive nitrogen peroxide ion is discussed as an ionic constituent of the lower ionosphere in the light of recently observed concentrations at altitudes between 87.8 and 93.2 km. Photoionization and charge exchange reactions appear to be insufficient to account for the positive nitrogen peroxide ion concentration observed at 90 km. A possible alternative reaction is proposed, and its implications are briefly reviewed.

Aikin, A. C.↗

Plasma Environments and Spacecraft Charging for Lunar Programs

Space systems interacting with the space plasma environment charge to potentials of a few tens of volts positive in interplanetary space or on the lunar surface in daylight, a few hundred volts negative in the dark lunar plasma wake and in some regions of the Earth s radiation belts, and to multiple kilovolt negative potentials for worst case conditions in the Earth s magnetosphere near geostationary orbit. Good design practices are required to assure that space systems operate successfully in these environments without detrimental effects due to transient currents and insulator failure produced by electrostatic discharges. Cold lunar environments in particular are challenging because detrimental effects of charging are often exacerbated by cold, highly resistive dielectrics which can integrate charge for long periods of time. We will describe the cold plasma and energetic particle environments relevant to lunar missions responsible for surface and bulk charging of space systems and discuss program requirements under development for assuring that systems operate successfully in these environments.

Minow, Joseph I.↗

"Coulombic Viscosity" In Granular Materials: Planetary and Astrophysical Implications

The term "Coulombic viscosity" is introduced here to define an empirically observed phenomenon from experiments conducted in both microgravity, and in ground-based 1-g conditions. In the latter case, a sand attrition device was employed to test the longevity of aeolian materials by creating two intersecting grain-circulation paths or cells that would lead to most of the grain energy being expended on grain-to-grain collisions (simulating dune systems). In the areas in the device where gravitationally-driven grain-slurries recycled the sand, the slurries moved with a boundary-layer impeded motion down the chamber walls. Excessive electrostatic charging of the grains during these experiments was prevented by the use of an a.c. corona (created by a Tesla coil) through which the grains passed on every cycle. This created both positive and negative ions which neutralized the triboelectrically-generated grain charges. When the corona was switched on, the velocity of the wall-attached slurries increased by a factor of two as approximately determined by direct observation. What appeared to be a freely-flowing slurry of grains impeded only by intergranular mechanical friction, had obviously been significantly retarded in its motion by electrostatic forces between the grains; with the charging reduced, the grains were able to move past one another without a flow "viscosity" imposed by the Coulombic intergranular forces. A similar phenomenon was observed during microgravity experiments aboard Space Shuttle in USML-1 & USML-2 spacelabs where freely-suspended clouds of sand were being investigated for their potential to for-m aggregates. In this environment, the grains were also charged electrostatically (by natural processes prior to flight), but were free from the intervention of gravity in their interactions. The grains were dispersed into dense clouds by bursts of air turbulence and allowed to form aggregates as the ballistic and turbulent motions damped out. During this very brief (30-60 sec) damping period, motion of the grains was observed to be retarded by the electrostatic interactions. The fact that the grains almost instantly formed aggregates was evidence that their ballistic motions had been constrained and redirected by the dipole-dipole interactions that led to filamentary aggregate development. Undoubtedly, the "Coulombic viscosity" of the cloud assisted in damping grain motion so rapidly. The electrostatically-induced grain-cloud viscosity or drag exerted on grain motion, is a complex function of three major parameters: charge magnitude, charge sign, and mean intergranular distance. The above experiments illustrate one particular type of granular behavior. The discussion here will therefore be restricted to drag relationships: (a) between grains that are naturally charged triboelectrically and thus exhibit dipole-dipole attractions between one another even if there are slight net charges present (which can be overwhelmed by dipole coupling at short distances), and (b) between grains that are densely spaced where the intergranular distance varies between zero and some value (usually tens or hundreds of grain diameters) that permits each grain to detect the dipole moment of another grain -- the distance is not so great that other grains appears as neutral electrical "singularities. I. Aeolian transport: During motion of grains in a saltation cloud (on Earth, Mars, or Venus), triboelectric charging must occur as a result of multiple grain contacts, and by friction with the entraining air. A situation might develop that is similar to the one described above in the attrition device: grain motion becoming significantly retarded (reduced flux) as grains find it increasingly difficult to either separate from the surface, or to pass one another without Coulombic retarding forces. A "Coulombic drag" will exist at flux initiation and increase with time to work in direct opposition to the aerodynamic drag that drives the grain motion. It is predicted that this will lead to an increase with time of both the aerodynamic and bed-dilatancy thresholds (3). Because of Paschen discharge effects in the martian atmosphere, the electrostatic charging in a saltation cloud may be partially abated, but this will lead to greater grain mobility, more charging, and thus to a charge-discharge steady state mediated by mechanical interactions. II. Dry colluvial systems: Sand avalanches on dunes, dry debris flows, talus flows, avalanches, and pyroclastic surges are examples of gravity-driven, dense granular flows where rock/grain fragmentation and grain-to-grain interactions cause triboelectrification (sometimes augmented by other electrical charging processes), and where the grain densities of the systems are such that strong dipole-dipole interactions between grains might be expected to be present. Because it is expected that the Coulombic forces between grains will cause a sluggishness or enhanced granular-flow viscosity, the motion of a grain mass will be retarded or damped so that this will assist, ultimately, in terminating the flow. The greatest Coulombic viscosity will be created in the most highly charged systems, which will also be the most energetic. Thus, grain flows have some tendency to be self-limiting by internal energy partitioning; gravitational potential is converted to Coulombic potential, which manifests itself as a drag force between the grains. III. Volcanic eruption plumes and impact ejecta curtains: The violence of these systems leads to powerful electrical charging of particulates. Lightning storms emanating from volcanic plumes are a testimony to the levels of charging. As pyroclastic grains interact forcefully and frequently within eruption plumes, it is reasonable to predict that the internal turbulent motions of the plume will be significantly damped by the Coulombic viscosity exerted by grain charges. Additional information is contained in the original.

Marshall, J. R.↗

Investigation of ion-beam machining methods for replicated x-ray optics

The final figuring step in the fabrication of an optical component involves imparting a specified contour onto the surface. This can be expensive and time consuming step. The recent development of ion beam figuring provides a method for performing the figuring process with advantages over standard mechanical methods. Ion figuring has proven effective in figuring large optical components. The process of ion beam figuring removes material by transferring kinetic energy from impinging neutral particles. The process utilizes a Kaufman type ion source, where a plasma is generated in a discharge chamber by controlled electric potentials. Charged grids extract and accelerate ions from the chamber. The accelerated ions form a directional beam. A neutralizer outside the accelerator grids supplies electrons to the positive ion beam. It is necessary to neutralize the beam to prevent charging workpieces and to avoid bending the beam with extraneous electro-magnetic fields. When the directed beam strikes the workpiece, material sputters in a predicable manner. The amount and distribution of material sputtered is a function of the energy of the beam, material of the component, distance from the workpiece, and angle of incidence of the beam. The figuring method described here assumes a constant beam removal, so that the process can be represented by a convolution operation. A fixed beam energy maintains a constant sputtering rate. This temporally and spatially stable beam is held perpendicular to the workpiece at a fixed distance. For non-constant removal, corrections would be required to model the process as a convolution operation. Specific figures (contours) are achieved by rastering the beam over the workpiece at varying velocities. A unique deconvolution is performed, using series-derivative solution developed for the system, to determine these velocities.

Drueding, Thomas W.↗