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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 415 records · Page 23

Cyano-ambivalence: Spectroscopy and photophysics of [Ru(diimine)(CN-BR 3 ) 4 ] 2- complexes

The UV–visible absorption and luminescence spectra of [Ru(diimine)(CN) 4 ] 2- derivatives have been tuned over wide ranges through variations in solvent, substituents on the diimine ligand, and boronation of the cyanide ligands. Here, trifluoromethyl substitution at the 4 and 4' positions of the diimine induces red shifts in metal-to-ligand charge-transfer (MLCT) absorption and luminescence bands. Boronation of the cyanide ligands produces substantial blue shifts in MLCT energies. The combination of diimine trifluoromethylation and cyanide boronation produces MLCT blue shifts that are about 75% as large as those produced by boronation alone.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Electronic Structure of the Primary Electron Donor P 700 +• in Photosystem I Studied by Multifrequency HYSCORE Spectroscopy at X- and Q-Band

The primary electron donor P 700 of the photosystem I ( PS I) is a heterodimer consisting of two chlorophyll molecules. A series of electron-transfer events immediately following the initial light excitation leads to a stabilization of the positive charge by its cation radical form, P 700 +• . Here, the electronic structure of P 700 +• and, in particular, its asymmetry with respect to the two chlorophyll monomers is of fundamental interest and is not fully understood up to this date. Here, we apply multifrequency X- (9 GHz) and Q-band (35 GHz) hyperfine sublevel correlation (HYSCORE) spectroscopy to investigate the electron spin density distribution in the cation radical P 700 +• of PS I from a thermophilic cyanobacterium Thermosynechococcus elongatus . Six 14 N and two 1 H distinct nuclei have been resolved in the HYSCORE spectra and parameters of the corresponding nuclear hyperfine and quadrupolar hyperfine interactions were obtained by combining the analysis of HYSCORE spectral features with direct numerical simulations. Based on a close similarity of the nuclear quadrupole tensor parameters, all of the resolved 14 N nuclei were assigned to six out of total eight available pyrrole ring nitrogen atoms (i.e., four in each of the chlorophylls), providing direct evidence of spin density delocalization over the both monomers in the heterodimer. Using the obtained experimental values of the 14 N electron-nuclear hyperfine interaction parameters, the upper limit of the electron spin density asymmetry parameter is estimated as R A/B upper = 7.7 ± 0.5, while a tentative assignment of 14 N observed in the HYSCORE spectra yields R B/A = 3.1 ± 0.5.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Baseline Characterization Database Verification Report - NBG-18 Billet 635-14

The purpose of this Engineering Calculations and Analysis Report is to present the data being collected in the Baseline Graphite Characterization program, which is directly tasked with supporting the Idaho National Laboratory’s (INL’s) research and development efforts on the Next Generation Nuclear Plant (NGNP)/Very High Temperature Reactor (VHTR)/Advanced Reactor Technology (ART). This program is populating a comprehensive database that will reflect the baseline properties of nuclear-grade graphite regarding individual grade, billet, and position within individual billets. The physical and mechanical property information being collected will be transferred to the NGNP Data Management and Analysis System (NDMAS), and from that database will help populate handbook of property data available to member nations of the Generation IV International Forum (GIF).

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A closed loop cryogenic environment pressure regulating system

Nonlinear closed loop control system to regulate the pressure in a cryogenic environment is described. System employs four position contactor with two control bands to react to the signals. Diagrams of element transfer function and required equipment are included.

Huguley, J. C.↗

Characteristics of the unsteady shock-induced laminar boundary layer on a flat plate.

The unsteady shock-induced laminar boundary layer on a flat plate is theoretically studied for shock speeds ranging from 1.12 to 9 km/sec. Boundary layer flows for real air, assumed to be in thermochemical equilibrium, are analyzed by extending Lam's work on shock-induced laminar boundary layers to equilibrium dissociated and ionized flows. A complete description of the unsteady nature of the boundary layer is presented in terms of heat transfer and several boundary layer thickness quantities as functions of a single time-position variable. Boundary layer development is considered for two points of view. Time-dependent boundary layer development and approach to steady state for any fixed position on the plate is described, as is the configuration of the boundary layer with position on the plate at any point in time.

Cook, W. J.↗

Radiative transfer in circumstellar dust shells

An iterative numerical procedure is developed to calculate the radiation field as a function of position, direction, and wavelength within a spherically symmetric circumstellar dust shell. The dust shell is assumed to consist of gray, isotropically scattering dust particles in thermal equilibrium with the radiation field and to be characterized by seven parameters: radius of the central star, inner radius of the shell, outer radius of the shell, total optical depth of the shell, an index which specifies the density distribution, albedo of the dust particles, and temperature of the central star. When the shell is close to the star, the angular distribution of the stellar component of the radiation field is determined by direct integration along lines of sight to the stellar surface, and the back-warming effect of the shell is included in the calculations to determine the net stellar flux. Using this procedure, the temperature distributions and radiation fields within several model dust shells are determined and used to calculate for each shell the spectral-energy and spatial-energy distributions of the radiation emitted at 11 wavelengths from 0.4 to 20 microns. For shells of moderate optical depth, it is found that the radiation field is quite anisotropic, especially at shorter wavelengths, and that the shape of the spectral-energy distribution is strongly dependent on all seven model parameters. The Eddington factor as a function of wavelength and optical depth is calculated for each model.

Harvel, C. A.↗

Nuclear alkylated pyridine aldehyde polymers and conductive compositions thereof

A thermally stable, relatively conductive polymer was disclosed. The polymer was synthesized by condensing in the presence of catalyst a 2, 4, or 6 nuclear alklylated 2, 3, or 4 pyridine aldehyde or quaternary derivatives thereof to form a polymer. The pyridine groups were liked by olefinic groups between 2-4, 2-6, 2-3, 3-4, 3-6 or 4-6 positions. Conductive compositions were prepared by dissolving the quaternary polymer and an organic charge transfer complexing agent such as TCNQ in a mutual solvent such as methanol.

Rembaum, A.↗

Measurements of acoustic sources in motion

Results of the far-field pressures measured from three different types of moving sources are presented. These acoustic sources consist of a point monopole, a small model jet, and an aircraft. Results for the pressure time history produced by the point source show good agreement with those predicted analytically. Both actual and simulated forward motion of the model jet show reductions in noise levels with forward speed at all angles between the source and observer. Measurement with the aircraft over both an anechoic floor and over the ground yields a method for evaluating the transfer function for ground reflections at various angles between the moving aircraft and measurement position.

Maestrello, L.↗

Experimental measurements of moving noise sources

The far-field pressure was measured from three different types of moving sources: a point monopole, a small model jet, and an aircraft. Results for the pressure time history produced by the point source show good agreement with those predicted analytically. Both actual and simulated forward motion of the model jet show reductions in noise levels with forward speed at all angles between the source and observer. Measurement with the aircraft over both an anechoic floor and over the ground yields a method for evaluating the transfer function for ground reflections at various angles between the moving aircraft and measurement position.

Maestrello, L.↗

Autonomous GPS/INS navigation experiment for Space Transfer Vehicle

An experiment to validate the concept of developing an autonomous integrated spacecraft navigation system using on board Global Positioning System (GPS) and Inertial Navigation System (INS) measurements is described. The feasibility of integrating GPS measurements with INS measurements to provide a total improvement in spacecraft navigation performance, i.e. improvement in position, velocity and attitude information, was previously demonstrated. An important aspect of this research is the automatic real time reconfiguration capability of the system designed to respond to changes in a spacecraft mission under the control of an expert system.

Upadhyay, Triveni N.↗

Dual spectra and mixed energy cascade of turbulence in the wavelet representation

The wavelet-transformed Navier-Stokes equations are used to define quantities such as the transfer of kinetic energy and the flux of kinetic energy through scale r at position x. Direct numerical simulations of turbulent shear flow reveal that although their mean spatial values agree with their traditional counterparts in Fourier space, their spatial variability at every scale is very large, exhibiting non-Gaussian statistics. The local flux of energy involving scales smaller than some r also exhibits large spatial intermittency, and it is negative quite often, indicative of local inverse cascades.

Meneveau, Charles↗

Design, Development and Testing of the GMI Launch Locks

Ball Aerospace will deliver the GPM Microwave Imager (GMI), to NASA as one of the 3 instruments to fly on the Global Precipitation Measurement (GPM) mission, for launch in 2013. The radiometer, when deployed, is over 8 feet tall and rotates at 32 revolutions per minute (RPM) can be described as a collection of mechanisms working to achieve its scientific objectives. This collection precisely positions a 1.2 meter reflector to a 48.5 degree off nadir angle while rotating, transferring electrical power and signals to and from the RF receivers, designs two very stable calibration sources, and provides the structural integrity of all the components. There are a total of 7 launch restraints coupling across the moving and stationary elements of the structure,. Getting from design to integration will be the focus of this paper.

Sexton, Adam↗

A 20 Year Retrospective of The Advanced Noise Control Fan - Contributions to Turbofan Noise Research

The Advanced Noise Control Fan (neé Active Noise Control Fan - ANCF) was utilized in the design, test, and evaluation for technical risk mitigation of most of the innovative fan noise reduction technologies developed by NASA over the past 20 years. The ANCF is a low-speed, ducted fan, testbed for measuring and understanding fan-generated aeroacoustics, duct propagation, and radiation to the farfield. It is considered a low Technology Readiness Level testbed. The international aeroacoustics research community employed the ANCF to facilitate advancement of multiple noise reduction and measurement technologies, and for code validation. From 1994 to 2016, it was located in the NASA Glenn Research Center’s Aero-Acoustic Propulsion Laboratory. In 2016 the ANCF was transferred to the University of Notre Dame where it is expected to continue to positively impact ducted fan aeroacoustic research and provide STEM support. This paper summarizes the capabilities and contributions of the ANCF to the field by documenting its history. Limited data is presented, focusing on a description of the configurations, goals, and objectives of representative ANCF tests. This provides an overview of the progress of aeroacosustic research as implemented on the ANCF, as well as a background for its continued usage.

Fan Noise↗

A 20 Year Retrospective of The Advanced Noise Control Fan - Contributions to Turbofan Noise Research

The Advanced Noise Control Fan (Active Noise Control Fan - ANCF) was utilized in the design, test, and evaluation for technical risk mitigation of most of the innovative fan noise reduction technologies developed by NASA over the past 20 years. The ANCF is a low-speed ducted fan test bed for measuring and understanding fan-generated aeroacoustics, duct propagation, and radiation to the farfield. It is considered a low Technology Readiness Level testbed. The international aeroacoustics research community employed the ANCF to facilitate advancement of multiple noise reduction and measurement technologies, and for code validation. From 1994 to 2016, it was located in the NASA Glenn Research Center's Applied Aero Propulsion Laboratory. In 2016 the ANCF was transferred to the University of Notre Dame where it is expected to continue to positively impact ducted fan aeroacoustic research. This paper summarizes the capabilities and contributions of the ANCF to the field by documenting its history.

Duct Noise↗

The Gulf Nuclear Energy Infrastructure Institute: A Multidisciplinary Educational Approach for Integrated Nuclear Energy Safety Security and Safeguards in the Middle East

The Gulf Nuclear Energy Infrastructure Institute (GNEII) at Khalifa University of Science and Technology was created as a regional institute offering education, research and technical services to support nuclear energy safety, security and safeguards (3S) objectives. A mixed methods approach—using the (1) Course Evaluation, (2) GNEH Alumni Survey, (3) Capstone Project and, (4) GNEII-Related Literature data sets—was used to evaluate the effect of implementing this multidisciplinary `3S' educational program and the broader impact of the associated `3S' multidisciplinary institute on nuclear energy human resource development. Data sets (1), (2) and (3) illustrate how well GNEII implemented this novel 3S curriculum and resulted in successful knowledge transfer. Data sets (2), (3) and (4) illustrate how well GNEII's impact has positively influenced professional workplace behaviors and the institute's broader reputation to support responsible nuclear energy program education. Furthermore, GNEII demonstrates one option for successfully providing a multidisciplinary, 3S curriculum to support broader nuclear infrastructure and human resource development aims.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

ECAR-1930 BASELINE CHARACTERIZATION DATABASE VERIFICATION REPORT - NBG-18 BILLET 635-14

The purpose of this Engineering Calculations and Analysis Report is to present the data being collected in the Baseline Graphite Characterization program, which is directly tasked with supporting the Idaho National Laboratory’s (INL’s) research and development efforts on the Next Generation Nuclear Plant (NGNP)/Very High Temperature Reactor (VHTR). This program is populating a comprehensive database that will reflect the baseline properties of nuclear-grade graphite with regard to individual grade, billet, and position within individual billets. The physical and mechanical property information being collected will be transferred to the NGNP Data Management and Analysis System (NDMAS), and from that database will help populate handbook of property data available to member nations of the Generation IV International Forum (GIF). The transfer of this data from the applicable technical lead to the dissemination databases available to other end users requires a full review of the test procedures and data collection efforts through an analysis of the multiple summary spreadsheets and values being collected. This report represents that analysis for a single billet of nuclear grade graphite (NBG-18 billet 635-14) and facilitates the release of the associated data to the NDMAS custodians.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

ECAR: Baseline Characterization Database Verification Report – PCEA Billet 01D3-35

The purpose of this engineering calculations and analysis report (ECAR) is to present data collected in the Baseline Graphite Characterization Program, which is directly tasked with supporting the Idaho National Laboratory’s (INL’s) research and development efforts on the Advanced Reactor Technologies (ART) Program. This program populates a comprehensive database that reflects the baseline properties of nuclear-grade graphite with regard to individual grade, billet, and position within individual billets. The physical- and mechanical-property information collected will be transferred to the Nuclear Data Management and Analysis System (NDMAS), and that database will help populate the handbook of property data available to member nations of the Generation-IV International Forum. Transfer of these data from the applicable technical lead to the dissemination databases available to other end users requires a full review of the test procedures and data-collection efforts through an analysis of the multiple summary spreadsheets and values being collected. This report represents the analysis for PCEA Billet 01D3-35 and facilitates release of associated data to the NDMAS custodians.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Radiative transfer theory for inhomogeneous media with random extinction and scattering coefficients

The small-angle scattering approximation of the scalar radiative transfer equation (RTE) is examined for the case where the extinction and scattering coefficients have a component that is a deterministic function of position along the propagation path and a component that is a random function of position transverse to the propagation direction. It is found that the resulting stochastic RTE can be reduced to a system of two stochastic integrodifferential equations for the average and fluctuating components of the radiant intensity. Two transfer equations are obtained describing the average radiant intensity and the spatial correlation function of the intensity fluctuations. The average intensity equation is then solved and applied to a simple propagation scenario. An approximate solution is also derived for the equation giving the correlation function. The developed equations can be applied to problems involving short wavelength electromagnetic wave propagation through media possessing the variable characteristics of turbulence and turbidity, such as plasmas, the atmosphere, and the ocean.

Manning, Robert M.↗