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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 415 records · Page 23
All sourcesNASA NTRSDOE OSTI
NASA NTRS1978

Dual polarized long wavelength radar for discrimination of agricultural land use

The scattered return of imaging radars is primarily sensitive to target structure or roughness and to composition of complex permittivity. The relative degree of penetration, or the depth of material to which the return is sensitive, also varies directly with the wavelength. Where vegetation can be eliminated as a factor, the surface return may be analyzed for variations in roughness or composition (primarily moisture content). L-band (25-cm) imagery has provided evidence that long-wavelength systems with improved penetration capability have the potential for minimizing the vegetation contribution and enhancing the surface return variations. However, the increased wavelength increases the sensitivity to large-scale structure. In the present paper, it is shown that addition of a cross polarized channel enables the interpreter to distinguish vegetation and orientation perturbations in the surface return.

Waite, W. P.↗
DOE OSTI2023

Targeting Oxide Concentration in Tantalum Oxide-Fluoride Anions

The design of both molecular and non-molecular solid materials with specific properties fundamentally relies on the controlled synthesis of crystals with desired functional groups, bonding motifs, polarity, chirality, and more. To this end, fluoride and oxide-fluoride anions have been utilized as basic building units (BBUs) in the synthesis of noncentrosymmetric racemic materials for their ability to create polar axes that facilitate the breaking of an inversion center as demonstrated in a series of compounds with [MF6]2- anions (M = Ti, Zr, Hf). Targeting an analog with a [TaOF5]2- anion, the phase space of (CuO, Ta2O5)/bpy/HF(aq)/H2O (bpy = 2,2′-bipyridine) was investigated and three new compounds with Cu-bpy cations and Ta-fluoride or Ta-oxyfluoride anions were synthesized: [Cu(bpy)2][TaF6], [Cu(bpy)2][Ta2OF10], and [Cu(bpy)F(H2O)2]2[TaF7]∙H2O with the anions [TaF6]-, [Ta2OF10]2-, and [TaF7]2-, respectively. The formation of these anions was found to be a product of both the concentration of hydrofluoric acid in solution and the ratio of metal-oxide starting materials to ligand. This work contributes to the understanding of mixed anion formation in the solid state.

Kamp, Kendall R.↗
DOE OSTI2024

Discovery of Ternary Antimonides A–Al–Sb (A = Rb or Cs) with Desired Structural Motifs Guided by Machine Learning

Specific structural motifs in inorganic solids are often related to their targeted physical properties. For many classes of solids, such as Zintl phases and polar intermetallics, the crystal structures are diverse and not easy to predict. Various antimonides that are potential thermoelectric materials were proposed to be synthesizable on the basis of their estimated formation energies. Their structures were broadly classified as clathrate, channel, layered, or network through a machine learning model trained on existing ternary phases and features based on elemental properties using the sure independence screening and sparsifying operator algorithm. Through experimental validation, three new ternary antimonides were synthesized and confirmed to form layered structures: tetragonal RbAlSb 2 and CsAlSb 2 , which are isopointal but not isotypic to LiBSi 2 ; and monoclinic Rb 2 Al 2 Sb 3 , which adopts the Na 2 Al 2 Sb 3 -type structure. Finally, reinvestigation of the related compound Cs 2 In 2 Sb 3 revealed a low thermal conductivity and p-type semiconducting behavior.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Controlling and Optimizing Photoinduced Charge Transfer across Ultrathin Silica Separation Membrane with Embedded Molecular Wires for Artificial Photosynthesis

Ultrathin amorphous silica membranes with embedded organic molecular wires (oligo( p -phenylenevinylene), three aryl units) provide chemical separation of incompatible catalytic environments of CO 2 reduction and H 2 O oxidation while maintaining electronic and protonic coupling between them. For an efficient nanoscale artificial photosystem, important performance criteria are high rate and directionality of charge flow. Here, the visible-light-induced charge flow from an anchored Ru bipyridyl light absorber across the silica nanomembrane to Co 3 O 4 water oxidation catalyst is quantitatively evaluated by photocurrent measurements. Charge transfer rates increase linearly with wire density, with 5 nm -2 identified as an optimal target. Accurate measurement of wire and light absorber densities is accomplished by the polarized FT-IRRAS method. Guided by density functional theory (DFT) calculations, four wire derivatives featuring electron-donating (methoxy) and -withdrawing groups (sulfonate, perfluorophenyl) with highest occupied molecular orbital (HOMO) potentials ranging from 1.48 to 0.64 V vs NHE were synthesized and photocurrents evaluated. Charge transfer rates increase sharply with increasing driving force for hole transfer from the excited light absorber to the embedded wire, followed by a decrease as the HOMO potential of the wire moves beyond the Co 3 O 4 valence band level toward more negative values, pointing to an optimal wire HOMO potential around 1.3 V vs NHE. Comparison with photocurrents of samples without nanomembrane indicates that silica layers with optimized wires are able to approach undiminished electron flux at typical solar intensities. Combined with the established high proton conductivity and small-molecule blocking property, the charge transfer measurements demonstrate that oxidation and reduction catalysis can be efficiently integrated on the nanoscale under separation by an ultrathin silica membrane.

photocurrent measurements↗
DOE OSTI2023

Electron scattering and neutrino physics

Abstract A thorough understanding of neutrino–nucleus scattering physics is crucial for the successful execution of the entire US neutrino physics program. Neutrino–nucleus interaction constitutes one of the biggest systematic uncertainties in neutrino experiments—both at intermediate energies affecting long-baseline deep underground neutrino experiment, as well as at low energies affecting coherent scattering neutrino program—and could well be the difference between achieving or missing discovery level precision. To this end, electron–nucleus scattering experiments provide vital information to test, assess and validate different nuclear models and event generators intended to test, assess and validate different nuclear models and event generators intended to be used in neutrino experiments. Similarly, for the low-energy neutrino program revolving around the coherent elastic neutrino–nucleus scattering (CEvNS) physics at stopped pion sources, such as at ORNL, the main source of uncertainty in the evaluation of the CEvNS cross section is driven by the underlying nuclear structure, embedded in the weak form factor, of the target nucleus. To this end, parity-violating electron scattering (PVES) experiments, utilizing polarized electron beams, provide vital model-independent information in determining weak form factors. This information is vital in achieving a percent level precision needed to disentangle new physics signals from the standard model expected CEvNS rate. In this white paper, we highlight connections between electron- and neutrino–nucleus scattering physics at energies ranging from 10 s of MeV to a few GeV, review the status of ongoing and planned electron scattering experiments, identify gaps, and lay out a path forward that benefits the neutrino community. We also highlight the systemic challenges with respect to the divide between the nuclear and high-energy physics communities and funding that presents additional hurdles in mobilizing these connections to the benefit of neutrino programs.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS1973

High pulse rate high resolution optical radar system

The system is composed of an optical cavity with a laser and a mode locking means to build up an optical pulse. An optical switch is also provided within the cavity to convert the polarization of the optical pulse generated within the cavity. The optical switch comprises an electro-optical crystal driven by a time delayed driver circuit which is triggered by a coincident signal made from an optical pulse signal and a gating pulse signal. The converted optical pulse strikes a polarization sensitive prism and is deflected out of the cavity toward the pending target in the form of a pulse containing most of the optical energy generated by the laser in the pulse build-up period. After striking the target, the reflected energy is picked up by a transceiver with the total travel time of the pulse being recorded.

Goss, W. C.↗
NASA NTRS1985

The change of depolarization of backscattering light from the polar stratospheric aerosol layer

The change of polarization properties of scattered light strongly depends on the non-spherisity of target particles. It should be helpful information for the study of stratospheric aerosols to know the non-spherisity of stratospheric aerosol particles. The change of the total backscatter depolarization ratio of the stratospheric aerosol layer measured at Syowa Station (69.00 deg S, 39.35 deg E), Antarctica is described.

Iwasaka, Y.↗
NASA NTRS1993

A hypersonic vehicle approach to planetary exploration

An enhanced Mars network class mission using a lifting hypersonic entry vehicle is proposed. The basic vehicle, derived from a mature hypersonic flight system called SWERVE, offers several advantages over more conventional low L/D or ballistic entry systems. The proposed vehicle has greatly improved lateral and cross range capability (e.g., it is capable of reaching the polar regions during less than optimal mission opportunities), is not limited to surface target areas of low elevation, and is less susceptible to problems caused by Martian dust storms. Further, the integrated vehicle has attractive deployment features and allows for a much improved evolutionary path to larger vehicles with greater science capability. Analysis of the vehicle is aided by the development of a Mars Hypersonic Flight Simulator from which flight trajectories are obtained. Atmospheric entry performance of the baseline vehicle is improved by a deceleration skirt and transpiration cooling system which significantly reduce TPS (Thermal Protection System) and flight battery mass. The use of the vehicle is also attractive in that the maturity of the flight systems make it cost-competitive with the development of a conventional low L/D entry system. Finally, the potential application of similar vehicles to other planetary missions is discussed.

Murbach, Marcus S.↗
NASA NTRS2004

The X-ray Polarimetry Explorer (XPE)

We present details of a Thomson scattering polarimeter suitable for a small-explorer- class mission. Termed XPE, for X-Ray Polarimetry Explorer, the instrument consists of a beryllium scattering cone surrounded by an annular multiwire proportional counter which registers the energy and position of scattered source photons. The polarimeter is sensitive over an energy range of 7-27 keV and will achieve 3% minimum detectable polarization of Her X-1 in a 1/2-day observation, and cover a 30-target core observation program, at the same sensitivity level, in approximately 8 months.

Ramsey, Brian↗
NASA NTRS2005

Polarization and Color Filtering Applied to Enhance Photogrammetric Measurements of Reflective Surfaces

Techniques for enhancing photogrammetric measurement of reflective surfaces by reducing noise were developed utilizing principles of light polarization. Signal selectivity with polarized light was also compared to signal selectivity using chromatic filters. Combining principles of linear cross polarization and color selectivity enhanced signal-to-noise ratios by as much as 800 fold. More typical improvements with combining polarization and color selectivity were about 100 fold. We review polarization-based techniques and present experimental results comparing the performance of traditional retroreflective targeting materials, cornercube targets returning depolarized light, and color selectivity.

Wells, Jeffrey M.↗
NASA NTRS2006

Water Vapor Sensors Go Sky-High to Assure Aircraft Safety

JPL used a special tunable diode laser, which NASA scientists could tune to different wavelengths, like a radio being tuned to different frequencies, to accurately target specific molecules and detect small traces of gas. This tunable diode laser was designed to emit near-infrared light at wavelengths absorbed by the gas or gases being detected. The light energy being absorbed by the target gas is related to the molecules present. This is usually measured in parts per million or parts per billion. Multiple measurements are made every second, making the system quick to respond to variations in the target gas. NASA scientists developed this technology as part of the 1999 Mars Polar Lander mission to explore the possibility of life-giving elements on Mars. NASA has since used the tunable diode laser-based gas sensor on aircraft and on balloons to successfully study weather and climate, global warming, emissions from aircraft, and numerous other areas where chemical gas analysis is needed. SpectraSensors, Inc., was formed in 1999 as a spinoff company of JPL, to commercialize tunable diode laser-based analyzers for industrial gas-sensing applications (Spinoff 2000). Now, the San Dimas, California-based firm has come back to the market with a new product featuring the NASA-developed instrument for atmospheric monitoring. This instrument is now helping aircraft avoid hazardous weather conditions and enabling the National Weather Service to provide more accurate weather forecasts.

Source record↗
NASA NTRS2011

Further Constraints and Uncertainties on the Deep Seismic Structure of the Moon

The Apollo Passive Seismic Experiment (APSE) consisted of four 3-component seismometers deployed between 1969 and 1972, that continuously recorded lunar ground motion until late 1977. The APSE data provide a unique opportunity for investigating the interior of a planet other than Earth, generating the most direct constraints on the elastic structure, and hence the thermal and compositional evolution of the Moon. Owing to the lack of far side moonquakes, past seismic models of the lunar interior were unable to constrain the lowermost 500 km of the interior. Recently, array methodologies aimed at detecting deep lunar seismic reflections found evidence for a lunar core, providing an elastic model of the deepest lunar interior consistent with geodetic parameters. Here we study the uncertainties in these models associated with the double array stacking of deep moonquakes for imaging deep reflectors in the Moon. We investigate the dependency of the array stacking results on a suite of parameters, including amplitude normalization assumptions, polarization filters, assumed velocity structure, and seismic phases that interfere with our desired target phases. These efforts are facilitated by the generation of synthetic seismograms at high frequencies (approx. 1Hz), allowing us to directly study the trade-offs between different parameters. We also investigate expected amplitudes of deep reflections relative to direct P and S arrivals, including predictions from arbitrarily oriented focal mechanisms in our synthetics. Results from separate versus combined station stacking help to establish the robustness of stacks. Synthetics for every path geometry of data were processed identically to that done with data. Different experiments were aimed at examining various processing assumptions, such as adding random noise to synthetics and mixing 3 components to some degree. The principal stacked energy peaks put forth in recent work persist, but their amplitude (which maps into reflector impedance contrast) and timing (which maps into reflector depth) depend on factors that are not well constrained -- most notably, the velocity structure of the overlying lunar interior. Thus, while evidence for the lunar core remains strong, the depths of imaged reflectors have associated uncertainties that will require new seismic data and observations to constrain. These results strongly advocate further investigations on the Moon to better resolve the interior (e.g., Selene missions), for the Moon apparently has a rich history of construction and evolution that is inextricably tied to that of Earth.

Lin, Pei-Ying Patty↗
NASA NTRS2016

Orbit Transfers for Dawn's Ceres Operations: Navigation and Mission Design Experience at a Dwarf Planet

Dawn, a mission belonging to NASA’s Discovery Program, was launched on September 27, 2007 to explore two objects in the main asteroid belt in order to yield insights into important questions about the formation and evolution of the solar system. Successfully completing all mission objectives at Vesta, Dawn arrived at dwarf planet Ceres in March 2015 and continued its journey to a series of four near circular polar science orbits. Dawn became the first mission to orbit around two extraterrestrial targets; such a mission would have been impossible without the low thrust ion propulsion system (IPS). Maneuvering a spacecraft using only the IPS for the transfers between the mapping orbits posed many technical challenges to Dawn’s flight team at NASA’s Jet Propulsion Laboratory. Failure of the second reaction wheel assembly, shortly before leaving Vesta, added another challenge for Dawn’s flight team. This paper discusses the mission design and navigational experience and challenges during Dawn’s Ceres operations.

Han, Dongsuk↗
NASA NTRSDate not supplied

GeoNEX-SUBSETS: Geostationary Satellite Observations Over International Observing Network Sites

Satellite remote sensing is crucial for monitoring the Earth’s surface and for simulating global carbon and water cycles. Subsets of satellite data from sensors such as MODIS over established observing networks have been valuable for researchers for comparing the ground observed phenomena with satellite observations. Here, we introduce new subsets of the GeoNEX geostationary satellite datasets over locations of several ground observation networks. The NASA Earth Exchange group has been generating geostationary satellite products with our international partners and universities to cover the entire globe. In comparison to polar-orbiting satellite sensors such as MODIS, the new generation geostationary satellites observe target areas at a higher frequency (5-10 minutes), which also significantly increased the data volume. To reduce the burden of downloading and extracting geostationary time series data and provide easy access to the community, we provide subsets of GeoNEX products through our data portal [www.data.nas.nasa.gov]. The ready-to-use subset follows the same format as the MODIS fixed sites subset tools for users who are familiar with MODIS subset data and software. The selected networks include Fluxnet, AERONET, and Phenocam over the conterminous US. We demonstrate the usage of the GeoNEX fixed-site subset data and showcase thir advantages with three example studies. The first example is simulating the diurnal cycle of plant ecophysiology at Fluxnet sites. The high frequency of the GeoNEX time series allows us to run ecological models at sub-hour time steps and directly compare the simulated carbon and water fluxes with half-hourly Fluxnet data. The second example uses the geostationary data to track phenological changes. It highlights the high-frequent observations of geostationary satellites in helping mask cloud covers and capture the quick responses of vegetation to environmental changes. As such, these examples demonstrate the value of ready-to-use GeoNEX subsets data in terrestrial ecophysiology research.

GeoNEX↗
DOE OSTI2022

Search For Excited Cascade Hypersons (¿*-) Using the CLAS12 Spectrometer at Jefferson Laboratory

The number of experimentally observed doubly strange Cascade states to date is far fewer than has been predicted theoretically. The CLAS12 Very Strange physics program (E12- 11-005A) at the Thomas Jefferson National Accelerator Facility aims to study the electroproduction of these states using the newly upgraded CEBAF Large Acceptance Spectrometer for 12 GeV (CLAS12) in experimental Hall B. In this project, the reaction ep ! e0K+K+??? ! e0K+K+K?(?=?0) is studied using CLAS12 Run Group A (RG-A) data sets taken by impinging electron beams of 10:2 and 10:6 GeV energies on an LH2 target. Scattered electrons are detected with either the Forward Detector (FD), covering a polar angle range of 5? to 35? to study electroproduction, or with the Forward Tagger (FT), covering a polar angle range of 2:5? to 4:5?, to study quasi-real photoproduction. The CLAS12 detector with nearly a 4? solid angle coverage is used to detect scattered electrons and charged kaons in the ?final state. ?=?0 hyperons are reconstructed using the missing mass technique to explore intermediate doubly-strange hyperons (???) that decay to K? and ?=?0. No statistically significant ??? states other than the ???(1530) were found in the missing mass spectra based on the currently available statistics in the CLAS12-FD acceptance only. A maximum log-likelihood method is implemented to determine the statistical significance and the upper limits on the ???(1820) electroproduction cross section by constructing 95% confidence level boundaries on the ???(1820) yields. Additional research was conducted to investigate the upper limit electroproduction cross section of the reaction ep ! e0K+K+??? ! e0K+K+K?(?=?0) as a function of the electroproduced ??? mass and the differential cross section ( d?dMM(e0K+K+) ) as a function of missing mass MM(e0K+K+) for electroproduction and quasi-real photoproduction processes.

Khanal, Achyut↗
NASA NTRS2014

CLARREO Approach for Reference Intercalibration of Reflected Solar Sensors: On-Orbit Data Matching and Sampling

The implementation of the Climate Absolute Radiance and Refractivity Observatory (CLARREO) mission was recommended by the National Research Council in 2007 to provide an on-orbit intercalibration standard with accuracy of 0.3% (k = 2) for relevant Earth observing sensors. The goal of reference intercalibration, as established in the Decadal Survey, is to enable rigorous high-accuracy observations of critical climate change parameters, including reflected broadband radiation [Clouds and Earth's Radiant Energy System (CERES)], cloud properties [Visible Infrared Imaging Radiometer Suite (VIIRS)], and changes in surface albedo, including snow and ice albedo feedback. In this paper, we describe the CLARREO approach for performing intercalibration on orbit in the reflected solar (RS) wavelength domain. It is based on providing highly accurate spectral reflectance and reflected radiance measurements from the CLARREO Reflected Solar Spectrometer (RSS) to establish an on-orbit reference for existing sensors, namely, CERES and VIIRS on Joint Polar Satellite System satellites, Advanced Very High Resolution Radiometer and follow-on imagers on MetOp, Landsat imagers, and imagers on geostationary platforms. One of two fundamental CLARREO mission goals is to provide sufficient sampling of high-accuracy observations that are matched in time, space, and viewing angles with measurements made by existing instruments, to a degree that overcomes the random error sources from imperfect data matching and instrument noise. The data matching is achieved through CLARREO RSS pointing operations on orbit that align its line of sight with the intercalibrated sensor. These operations must be planned in advance; therefore, intercalibration events must be predicted by orbital modeling. If two competing opportunities are identified, one target sensor must be given priority over the other. The intercalibration method is to monitor changes in targeted sensor response function parameters: effective offset, gain, nonlinearity, optics spectral response, and sensitivity to polarization. In this paper, we use existing satellite data and orbital simulationmethods to determinemission requirements for CLARREO, its instrument pointing ability, methodology, and needed intercalibration sampling and data matching for accurate intercalibration of RS radiation sensors on orbit.

radiometry↗
DOE OSTI2021

Understanding Reproducibility of Sputter‐Deposited Metastable Ferroelectric Wurtzite Al 0.6 Sc 0.4 N Films Using In Situ Optical Emission Spectrometry

High‐Sc Al 1– x Sc x N thin films are of tremendous interest because of their attractive piezoelectric and ferroelectric properties, but overall film quality and reproducibility are widely reported to suffer as x increases. In this study, structural and electrical properties of metastable Al 0.6 Sc 0.4 N films are connected with plasma changes during film growth, identified via glow discharge optical emission spectroscopy (GD‐OES), and linked to the target mode changes. This in situ GD‐OES technique uses changes in the N 2 (I) intensity, correlated with DC bias hysteresis behavior of a Al 0.6 Sc 0.4 target in metallic and poisoned modes, to identify films that subsequently exhibit unacceptable structural and electrical performance. Two representative samples deposited under identical conditions but possessing distinct properties related to phases present in the films are focused on. Films sputtered under a poisoned target mode produce pure wurtzite ferroelectric Al 0.6 Sc 0.4 N with a reversible 80 μC cm −1 polarization and 3.1 MV cm −1 coercive field. When identical chamber settings are used but the process starts in metallic mode, a mixed wurtzite/rocksalt film is deposited which exhibits nanometer‐scale changes to the film microstructure and a nonferroelectric response. These results illustrate the utility of optical emission spectroscopy for tracking target mode fluctuations when fabricating metastable materials such as high‐Sc Al 1– x Sc x N films.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Evidence for Longitudinally Polarized 𝑊 Bosons in the Electroweak Production of Same-Sign 𝑊 Boson Pairs in Association with Two Jets in 𝑝⁢𝑝 Collisions at $\sqrt{𝑠}$ = 13 TeV with the ATLAS Detector

This Letter reports the first evidence of electroweak production of same-sign 𝑊 boson pairs where at least one of the 𝑊 bosons is longitudinally polarized and the most stringent constraint to date for the production of two longitudinally polarized same-sign 𝑊 bosons. The dataset used corresponds to an integrated luminosity of 140 fb −1 of proton-proton collisions at a center-of-mass energy of 13 TeV, collected with the ATLAS detector during run 2 of the Large Hadron Collider. The study is performed in final states including two same-sign leptons (electrons or muons), missing transverse momentum, and at least two jets with a large invariant mass and a large rapidity difference. Two independent fits are performed targeting the production of same-sign 𝑊 bosons with at least one, or two longitudinally polarized 𝑊 bosons. The observed (expected) significance of the production with at least one longitudinally polarized 𝑊 boson is 3.3 (4.0) standard deviations. An observed (expected) 95% confidence level upper limit of 0.45 (0.70) fb is reported on the fiducial production cross section of two longitudinally polarized same-sign 𝑊 bosons.

W & Z bosons↗