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Results for “Polarization phenomena”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 415 records · Page 23
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Photonically active bowtie nanoassemblies with chirality continuum

Chirality is a geometrical property described by continuous mathematical functions. However, in chemical disciplines, chirality is often treated as a binary left or right characteristic of molecules rather than a continuity of chiral shapes. Although they are theoretically possible, a family of stable chemical structures with similar shapes and progressively tuneable chirality is yet unknown. Here we show that nanostructured microparticles with an anisotropic bowtie shape display chirality continuum and can be made with widely tuneable twist angle, pitch, width, thickness and length. The self-limited assembly of the bowties enables high synthetic reproducibility, size monodispersity and computational predictability of their geometries for different assembly conditions. The bowtie nanoassemblies show several strong circular dichroism peaks originating from absorptive and scattering phenomena. Unlike classical chiral molecules, these particles show a continuum of chirality measures that correlate exponentially with the spectral positions of the circular dichroism peaks. Finally, Bowtie particles with variable polarization rotation were used to print photonically active metasurfaces with spectrally tuneable positive or negative polarization signatures for light detection and ranging (LIDAR) devices.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

A study of mechanoelectrical transduction behavior in polyvinyl chloride (PVC) gel as smart sensors

Abstract Polyvinyl chloride (PVC) gels are soft electroactive polymers (EAPs) being researched for soft robotic applications. Sensing properties of these EAPs have not been investigated in detail in regard to fundamental mechanoelectrical transduction behavior, but this smart material has been shown to exhibit a detectable response to external stimuli. This study shows PVC gels to be an extremely sensitive material when undergoing mechanoelectrical transduction and explores some response dependencies and proposes a theoretical framework for mechanoelectrical transduction within the gel. The work presented here also uncovers a very interesting phenomena under extremely low compressive loads during the initial contact with the gel. This phenomenon is attributed to a surface tension creeping motion onto the loading surface with an accompanying polarity inversion in the sensing signal relative to fully loaded gels in compression. Experimental work on hysteresis was also completed showing very little memory in steady state mechanoelectrical response to repeated stepped loading cycles. This study demonstrates the mechanoelectric ability of PVC gels to perform in sensing experiments and acts as a fundamental framework to further broaden the applications of PVC gel sensors.

Instruments & Instrumentation↗
DOE OSTI2023

Floquet engineering multichannel Kondo physics

Floquet engineering has been used to engineer novel interactions in uncorrelated and magnetic insulating materials. Here, we apply this technique to simple heavy fermion models, showing that driving these systems with periodic light introduces emergent Kondo screening channels with distinct symmetries, where the allowed channels are controlled by the light polarization. Furthermore, these systems can be driven through multi-channel degeneracy points, dynamically realizing multi-channel Kondo impurities and lattices that can be used to explore quantum critical phenomena and potentially enhance superconductivity.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1973

Mars atmosphere during the Mariner 9 Extended Mission - Television results.

The Extended Mission of Mariner 9 provided data from 23 revolutions and recorded seasonal changes in the atmosphere of Mars during northern spring and early summer. The visibility of the surface was exceptional, indicating atmospheric clarity greater than that previously observed by Mariner 9 or by Mariner 6 and 7. Cloud systems were observed over both polar regions and indicated westerly winds in the -45 to -65 deg latitude zone (southern winter) and easterly winds in the vicinity of +75 deg (northern summer). The puzzling brightening phenomena that recur seasonally and diurnally over Tharsis, Amazonis, and Nix Olympica were seen to be clouds of a generally diffuse character but with some indications of convective activity. These clouds show a remarkable degree of topographic control, and their large-scale patterns are closely duplicated from day to day.

Leovy, C. B.↗
NASA NTRS1974

Multi-slit spectrograph and H alpha Doppler system

Description of the design and operation of a multiple-entrance-slit spectrograph, built for time-lapse photography of the spectra of flares and other transient solar phenomena. This spectrograph employs narrow-band filters to limit the wavelength range of the spectrograph to a few angstroms centered at H-alpha or other spectral lines. A polarizing beamsplitter, prior to the slits, provides a prefiltered second solar image to a narrow band H-alpha Doppler filter for simultaneous photography in the wings of the H-alpha line. The spectrograph and the H-alpha Doppler system constitute a flexible instrument in which components may be substituted to achieve different passband widths, image scales, dispersions, and corresponding numbers and spacings of adjacent spectra at a selected wavelength.

Martin, S. F.↗
NASA NTRS1981

Optical polarimetry of Comet West 1976 VI

Four narrowband filters covering the 440-850 nm wavelengths were used to measure the polarization of the continuum of Comet West 1976 VI. Postperihelion observations indicated wavelength-independent linear polarization in all of the three measurements made, in agreement with other polarization measurements of the comet from the visible to the near-infrared but in contrast with the general tendency in comets toward polarization increase with wavelength. No circular polarization was detected, and it is suggested by (1) the magnitude of polarization as a function of scattering angle, (2) wavelength independence, and (3) infrared and optical photometric properties, that dirty silicates with radii approaching 5 microns may be responsible for the phenomena observed.

Michalsky, J. J.↗
NASA NTRS1996

Radar Interferometric and Penetration Investigations using SIR-C Data

Progress, significant results, publications and future plans are discussed in relation to the following objectives: (1) To model, experimentally characterize, and verify penetration phenomena in hyperarid and vegetated regions using the SIR-C/X-SAR multiparameter radar system and groundbased receivers; (2) To invert measured radar backscatter as a function of frequency and polarization in terms of geophysical parameters of the surface, subsurface and vegetation canopy such as surface roughness, subsurface geomorphology, or tree height and density; and (3) To display subsurface and within-canopy features in an image format, thus easing the interpretability of the results.

Zebker, Howard A.↗
NASA NTRS1992

Computational modeling of nonlinear electromagnetic phenomena

A new algorithm has been developed that permits, for the first time, the direct time integration of the full-vector nonlinear Maxwell's equations. This new capability permits the modeling of linear and nonlinear, instantaneous and dispersive effects in the electric polarization material media. Results are presented of first-time calculations in 1D of the propagation and collision of femtosecond electromagnetic solitons that retain the optical carrier.

Goorjian, Peter M.↗
NASA NTRS2018

Solar Wind Induced Waves in the Skies of Mars: Ionospheric Compression, Energization, and Escape Resulting from the Impact of Ultralow Frequency Magnetosonic Waves Generated Upstream of the Martian Bow Shock

Using data from the National Aeronautics and Space Administration Mars Atmosphere and Voltatile EvolutioN and the European Space Agency Mars Express spacecraft, we show that transient phenomena in the foreshock and solar wind can directly inject energy into the ionosphere of Mars. We demonstrate that the impact of compressive ultralow frequency waves in the solar wind on the induced magnetospheres drive compressional, linearly polarized, magnetosonic ultralow frequency waves in the ionosphere, and a localized electromagnetic "ringing" at the local proton gyro frequency. The pulsations heat and energize Ionospheric plasmas. A preliminary survey of events shows that no special upstream conditions are required in the interplanetary magnetic field or solar wind. Elevated ion densities and temperatures in the solar wind near to Mars are consistent with the presence of an additional population of Martian ions, leading to ion-ion instabilities, associated wave-particle interactions, and heating of the solar wind. The phenomenon was found to be seasonal, occurring when Mars is near perihelion. Finally, we present simultaneous multipoint observations of the phenomenon, with the Mars Express observing the waves upstream, and Mars Atmosphere and Voltatile EvolutioN observing the response in the ionosphere. When these new observations are combined with decades of previous studies, they collectively provide strong evidence for a previously undemonstrated atmospheric loss process at unmagnetized planets: ionospheric escape driven by the direct impact of transient phenomena from the foreshock and solar wind.

Collinson, Glyn↗
NASA NTRS1978

Modelling of physical influences in sea level records for vertical crustal movement detection

Attempts to specify and evaluate such physical influences are reviewed with the intention of identifying problem areas and promising approaches. An example of linear modelling based on air/water temperatures, atmospheric pressure, river discharges, geostrophic and/or local wind velocities, and including forced period terms to allow for the long period tides and Chandlerian polar motion is evaluated and applied to monthly mean sea levels recorded in Atlantic Canada. Refinement of the model to admit phase lag in the response to some of the driving phenomena is demonstrated. Spectral analysis of the residuals is employed to assess the model performance. The results and associated statistical parameters are discussed with emphasis on elucidating the sensitivity of the technique for detection of local episodic and secular vertical crustal movements, the problem areas most critical to the type of approach, and possible further developments.

Anderson, E. G.↗
NASA NTRS1982

Additional extensions to the NASCAP computer code, volume 2

Particular attention is given to comparison of the actural response of the SCATHA (Spacecraft Charging AT High Altitudes) P78-2 satellite with theoretical (NASCAP) predictions. Extensive comparisons for a variety of environmental conditions confirm the validity of the NASCAP model. A summary of the capabilities and range of validity of NASCAP is presented, with extensive reference to previously published applications. It is shown that NASCAP is capable of providing quantitatively accurate results when the object and environment are adequately represented and fall within the range of conditions for which NASCAP was intended. Three dimensional electric field affects play an important role in determining the potential of dielectric surfaces and electrically isolated conducting surfaces, particularly in the presence of artificially imposed high voltages. A theory for such phenomena is presented and applied to the active control experiments carried out in SCATHA, as well as other space and laboratory experiments. Finally, some preliminary work toward modeling large spacecraft in polar Earth orbit is presented. An initial physical model is presented including charge emission. A simple code based upon the model is described along with code test results.

Stannard, P. R.↗
NASA NTRS1984

A possible source for the Martian circumpolar dune material

The properties of freeze dried dilute dispersions of dust in water are of considerable interest in studies of sedimentary processes in the polar regions of Mars. The formation of a rind residue due to the sublimation of water ice containing various amounts of clay may be an important step in these processes. Such phenomena may occur as the result of seasonal or long term (climatic) sublimation of dirty ice caps on Mars. The development and disruption of dust residues on the surface of ice dust mixtures as a result of preferential ice sublimation were simulated in the laboratory. The characteristics of the resulting particles are described and a scenario for the formation of a Martian circumpolar dune field is suggested.

Saunders, R. S.↗
NASA NTRS1961

Solar Influences on Geomagnetic and Related Phenomena

A discussion of the geomagnetic effects of streams of electromagnetic and particular radiation from the sun. The interplay of forces between the geomagnetic field and solar streams is outlined; and the theoretical relationship between these, the solar storms, the trapped Van Allen radiations, the polar aurora, and geomagnetic field distortion are presented.

Vestine, E. H.↗
DOE OSTI2024

The Significant Differences in Solvation Thermodynamics of C1–C3 Oxygenates in Hydrophilic versus Hydrophobic Pores of a Hydrophilic Ti-FAU Zeolite Model

The rates of catalytic reactions have been observed to be dramatically different in zeolites, depending on if they are hydrophobic or hydrophilic. Hypotheses aimed at explaining this behavior have pointed to various solvent molecule and zeolite properties as having influence on entropy. Herein, the influence of various solvent and adsorbate properties on the solvation energies, entropies, and free energies of eleven C1-C3 oxygenates in hydrophobic and hydrophilic pores within a hydrophilic model of Ti-FAU zeolite are tested. The results indicate significant variation in the calculated solvation thermodynamics depending on the adsorbate type, as well as if it is bound within a hydrophobic or hydrophilic pore. Further, while solvation energies are related to solvent-adsorbate interactions, solvation entropies have multiple contributions, and these differ depending on if the adsorbate is in a hydrophobic or hydrophilic pore. Specifically, solvation entropies in hydrophobic pores are related to solvent structural properties, whereas solvation entropies in hydrophilic pores are related to adsorbate polarity. Here, the large range of results obtained from two different pores within one zeolite model with minimal unique adsorption sites suggests that solvation behavior in zeolites is complicated and that the phenomena that control observed performance depend on the zeolite, reaction, and solvent.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Ferroelectric phase-transition frustration near a tricritical composition point

Phase transition describes a mutational behavior of matter states at a critical transition temperature or external field. Despite the phase-transition orders are well sorted by classic thermodynamic theory, ambiguous situations interposed between the first- and second-order transitions were exposed one after another. Here, we report discovery of phase-transition frustration near a tricritical composition point in ferroelectric Pb(Zr 1-x Ti x )O 3 . Our multi-scale transmission electron microscopy characterization reveals a number of geometrically frustrated microstructure features such as self-assembled hierarchical domain structure, degeneracy of mesoscale domain tetragonality and decoupled polarization-strain relationship. Associated with deviation from the classic mean-field theory, dielectric critical exponent anomalies and temperature dependent birefringence data unveil that the frustrated transition order stems from intricate competition of short-range polar orders and their decoupling to long-range lattice deformation. With supports from effective Hamiltonian Monte Carlo simulations, our findings point out a potentially universal mechanism to comprehend the abnormal critical phenomena occurring in phase-transition materials.

42 ENGINEERING↗
DOE OSTI2024

Dark states of electrons in a quantum system with two pairs of sublattices

A quantum state of matter that is forbidden to interact with photons and is therefore undetectable by spectroscopic means is called a dark state. This basic concept can be applied to condensed matter where it suggests that a whole band of quantum states could be undetectable across a full Brillouin zone. Here we report the discovery of such condensed-matter dark states in palladium diselenide as a model system that has two pairs of sublattices in the primitive cell. By using angle-resolved photoemission spectroscopy, we find valence bands that are practically unobservable over the whole Brillouin zone at any photon energy, polarization and scattering plane. Our model shows that two pairs of sublattices located at half-translation positions and related by multiple glide-mirror symmetries make their relative quantum phases polarized into only four kinds, three of which become dark due to double destructive interference. This mechanism is generic to other systems with two pairs of sublattices, and we show how the phenomena observed in cuprates, lead halide perovskites and density wave systems can be resolved by the mechanism of dark states. Our results suggest that the sublattice degree of freedom, which has been overlooked so far, should be considered in the study of correlated phenomena and optoelectronic characteristics.

electronic properties and materials↗
DOE OSTI2024

Developing Platinum-Group-Metal-Free Catalysts for Oxygen Reduction Reaction in Acid: Beyond the Single Metal Site

This project is to develop M (x) -N-C catalysts with dense multiple metal center (MMC) sites to meet the DOE 2025 activity target of 0.044 mA/cm 2 at 0.9 V IR-free ., as well as other goals such as durability. We have made important contributions to both catalyst development and fundamental understandings of the active sites in M-N-C catalysts in this project. We successfully made M (x) -N-C catalysts with some multiple metal center (MMC) sites by combining ionothermal carbonization with chemical vapor deposition (CVD). These catalysts, however, are not as active as the most active single-atom Fe-N-C catalysts made by the similar CVD process, owing likely to the low site density and the presence of inorganic Fe species such as iron carbides and nanoparticles. The most significant accomplishments we achieved in this project are: (1) we unraveled the formation pathway of Fe-N 4 sites during pyrolysis step-by-step and identified the trans-metalation mechanism, in collaboration with Deborah Myers and her colleagues at Argonne National Laboratory (ANL); (2) inspired by this finding, we pioneered the CVD synthesis of M-N-C catalysts (M = Mn, Fe, and Co), in which the Fe-N-C catalyst by CVD demonstrated an ORR activity of 33 mA/cm 2 at 0.9 V in H 2 -O 2 proton exchange membrane fuel cells (PEMFCs), very close to the ultimate goal of 35 mA/cm 2 of our project. This catalyst is the first Fe-N-C catalyst that contains only D1 sites without the D2 sites; whereas D1 and D2 sites have been always identified by Mossbauer in previous Fe-N-C catalysts. This finding helps to understand what the D1 and D2 sites are and their roles in catalyzing the ORR. (3) by improving the mass transport of the carbon matrix prior to the CVD process, the revised Fe-N-C catalyst made by CVD delivered a maximum power density of 0.53 W/cm 2 in H 2 -air PEMFCs. The improvement strategy was partly inspired by the computational modeling work by Adam Weber from LBNL, the Co-PI of this project, by developing, coding, and exercising a continuum level model of transport phenomena within a PGM-free catalyst layer. The model demonstrated that local resistances combined with limited site density of the PGM-free catalyst can result in limiting currents and poor polarization performance. The model also gave design guidance for impact of ECSA and overall catalyst-layer thickness. However, both Fe-N-C and Co-N-C catalysts developed by CVD showed poor durability in PEMFCS, in comparison with the traditional M-N-C catalysts synthesized via regular pyrolysis process. Consequently, we did not achieve the proposed durability targets. Despite so, we believe the FeNC-CVD catalysts with the poor durability and D1 sites only provides an excellent platform to understand the degradation mechanism of Fe-N-C in PEMFCs, the most important challenge in the development of M-N-C catalysts.

08 HYDROGEN↗
NASA NTRS1992

Status of the Olympus experiment at CRC

The status of the Olympus Propagation Experiment of the Communications Research Centre in Ottawa, Canada, is briefly summarized. Path attenuation measurements at multiple frequencies correlated with concurrent dual polarized radar data provide a unique method to investigate propagation effects. An experiment of this type is being implemented by the Communications Research Centre (CRC) on the grounds of the National Research Council of Canada in Ottawa. Beacon receivers monitor signals from the Olympus satellite at 12.5, 19.77, and 29.66 GHz at a path elevation angle of 14.2 deg. Sky noise radiometers operating near the same frequencies and pointed along the same path provide additional propagation information. A colocated dual-polarized 9.6-GHz radar probes the precipitation state on the path, permitting identification of precipitation regimes that cause the observed impairments. The Olympus experiment configuration is displayed pictorially. Information on path propagation phenomena can be deduced by correlating the radar, beacon, and sky noise data. Melting layer effects and propagation losses for higher time percentages are prime interests. Data collected by Diversitel Communications during equipment verification tests are presented.

Rogers, David V.↗