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At least 415 records · Page 23

Lightweight, Durable, and Multifunctional Electrical Insulation Material Systems for High Voltage Applications

Newly developed multilayer structures of well-known polymer insulation materials significantly improved dielectric breakdown voltage, VB, or dielectric strength, K, if well-bonded, when compared to those of single material insulations or the commercial SOA systems, such as Teflon-Kapton-Teflon (TKT), at the same overall thickness. To date, the greatest improvement of the new structures from a few candidate materials, including various types of Kapton PIs and PFA or PET as bond layer (BL), was about 61% higher than that of the Kapton PI alone films, 40.1 vs. 24.9 kV, which was translated to 86.3% decrease in insulation thickness, thus significant volume and weight reduction of the final system. However, it was of interest to note that most improvements of the multilayer structures occurred at thicker overall thicknesses, above ~ 0.15 mm. Extensive analyses also showed that K of the multilayer structures increased with (i) decreasing individual layer thickness regardless of material type, (ii) increasing total accumulated thickness of PI or overall PI/BL ratio, and (iii) increasing number of interface or total number of layers, but only above the aforementioned overall thickness limit. Increases in VB of the multilayer structures were directly correlated with damage evolution and failure mode. With further material-design-process optimizations of the multilayer structures, it was expected to achieve other multifunctionalities, such as high partial discharge (PD) resistance, improved durability, EMI shielding, and high thermal dissipation in addition to high dielectric strength. These new structures can be used in various high voltage and high temperature applications, such as future hybrid or all electric aircraft wiring and power transmission as well as many other non-aerospace high power cables, electronic parts and components, printed circuit board, and so forth. The multilayer insulation system can be easily processed and manufactured with various conductor types via calendaring, compression-molding, stamping, laminating, vacuum-bagging and autoclaving, or 3D printing, even for complex 3-D components. Based on their unique structural configurations and potential capabilities, the new insulation system was identified as micro-multilayer multifunctional electrical insulation (MMEI). Patent application of the MMEI concept and current design configurations was filed for a 1-year provisional application (OAI-58834, Serial No.: 62/659,234), pending conversion to a U.S. utility application. This paper presents details of the MMEI structures, their dielectric performance analyses, potential mechanisms, and commercial scaleup feasibility assessment.

Multifunctional↗

Using GPS Receivers 1PPS Output to Verify Time Stamp Accuracy and Measure Propagation Delay

A simple Pulse Overlay (PO) circuit using a logic OR gate was developed to overlay a precise leading edge 1 Pulse Per Second (1PPS) time reference marker from a GPS receiver onto a Non-Return -to- Zero-Level (NRZ-L) Pulse Code Modulation (PCM) telemetry data stream to validate time stamp accuracy and measure propagation delay (PD) in telemetry equipment.

telemetry↗

International Space Station (ISS) Payload Autonomous Operations Past, Present and Future

Draper Laboratorys Timeliner is a scripting and automation system that runs onboard computers in the International Space Station (ISS). Timeliner is fully integrated with ISS and can be used to automate ISS operations tasks. Some of the most challenging aspects of operating a payload in low earth orbit are communication delays, ground equipment failures, and human errors. How does a Payload Developer (PD) know their equipment is operating nominally and collecting science in the most efficient way possible or even powered at any given time? During a ground Loss of Signal (LOS) data outage, PDs have no insight into their experiments state, and benefit greatly from Timeliner scripts executing on ISS to perform telemetry monitoring and commanding operations. This paper will discuss current software designs, and new operational uses for Timeliner. Existing Timeliner capabilities discussed will include: autonomous EXPRESS Rack activation and deactivation; autonomous science data downlinks; Minus Eighty Degree Freezer (MELFI) Dewar autonomous safing; JAXA and ESA module autonomous payload facility safing; as well as many others. New operational concepts discussed will include allowing Timeliner on the payload computer to issue core commands (Thermal, Power, Fire Detection), creation of new ground tools that will monitor the current status of Payload Racks as well as all the messaging from autonomous scripts executing, decreasing approval time for Timeliner bundles, and opening up the Payload MDM Enhanced Processor Integrated Communications Card (EPIC) interface. The EPIC interface could provide a new crew interface for PL Timeliner execution. The new interface could operate on either a Payload Computer System (PCS) or a Station Support Computer (SSC) that is plugged into either the Payload LAN or the Operations LAN which will make communicating to the PL MDM more flexible and greatly increase band width for communication.

Space Mission Automation↗

Pressurized Payloads Interface Requirements Document: International Space Station Program

This Interface Requirements Document (IRD) is the principle source for interface design requirements for all National Aeronautics and Space Administration (NASA) developed payloads operating in the pressurized volume of the ISS, and for ESA and JAXA payloads operated in the USOS (all non-Russian modules except JEM and Columbus). Payload developers must verify the applicable requirements in this document to ensure the safety of the ISS crew, transport vehicles, on-orbit ISS systems hardware, and neighboring payloads. This document also provides design guidance that ensures the basic operation of the payload and affects the payload's mission success. It is the responsibility of the payload developer (PD) to design in accordance with the design guidance.

Nelson, George C.↗

Mutual Orbit Orientations of Transneptunian Binaries

We present Keplerian orbit solutions for the mutual orbits of 17 transneptunian binary systems (TNBs). For ten of them, the orbit had not previously been known: 60458 2000 CM (sub 114), 119979 2002 WC (sub 19), 160091 2000 OL (sub 67), 160256 2002 PD (sub 149), 469514 2003 QA (sub 91), 469705 ǂKagara, 508788 2000 CQ (sub 114), 508869 2002 VT (sub 130), 1999 RT (sub 214), and 2002 XH (sub 91). Seven more are systems where the size, shape, and period of the orbit had been published, but new observations have now eliminated the sky plane mirror ambiguity in its orientation: 90482 Orcus, 120347 Salacia-Actaea, 1998 WW (sub 31), 1999 OJ (sub 4), 2000 QL (sub 251), 2001 XR (sub 254), and 2003 TJ (sub 58). The dynamical masses we obtain from TNB mutual orbits can be combined with estimates of the objects' sizes from thermal observations or stellar occultations to estimate their bulk densities. The ǂKagara system is currently undergoing mutual events in which one component casts its shadow upon the other and/or obstructs the view of the other. Such events provide valuable opportunities for further characterization of the system. Combining our new orbits with previously published orbits yields a sample of 35 binary orbits with known orientations that can provide important clues about the environment in which outer solar system planetesimals formed, as well as their subsequent evolutionary history. Among the relatively tight binaries, with semimajor axes less than about 5 percent of their Hill radii, prograde mutual orbits vastly outnumber retrograde orbits. This imbalance is not attributable to any known observational bias. We suggest that this distribution could be the signature of planetesimal formation through gravitational collapse of local density enhancements such as caused by the streaming instability. Wider binaries, with semimajor axes greater than 5 percent of their Hill radii, are somewhat more evenly distributed between prograde and retrograde orbits, but with mutual orbits that are aligned or anti-aligned with their heliocentric orbits. This pattern could perhaps result from Kozai-Lidov cycles coupled with tidal evolution eliminating high inclination wide binaries.

Grundy, W. M.↗

Thermal Impact of Cosmic Ray Interaction with an XRay Microcalorimeter Array

The X-ray Integral Field Unit (X-IFU) instrument on the Athena mission will be positioned at the Lagrangian point L2 and be subject to cosmic rays generated by astrophysics sources, primarily relativistic protons. Previous simulations have shown that particles of energy higher than 150 MeV will make it through the outer layers of the satellite. They will reach the detector wafer with a rate of 3 cts/sq. cm/s and a most probable energy deposited in the Si frame supporting the array at 150 keV. These events can affect the energy resolution of the detectors through the thermal fluctuations that they produce. This study assesses this potential problem and discusses two suggested design approaches to decrease the impact of cosmic ray in order to limit their effect to their allocation of 0.2 eV within the Athena/X-IFU energy-resolution budget. The first is the addition of a coating layer of high heat capacity material (e.g., Pd) and the second is the splitting of this coating into two thermal regions near the TES array to keep the heat away from the array. Implementing these two features is predicted to cause a decrease in the number of events above 1 μK by more than a factor 10 to ~ 1.5 cps when compared to an equivalent design without these features.

Antoine R. Miniussi↗

Transmutations Observed from Pressure Cycling Palladium Silver Metals with Deuterium Gas

Hydrogen, deuterium, and helium gases were separately cycled through a Johnson-Mattheypurifier containing coiled palladium silver alloy tubing: Pd25Ag (75 wt% Pd and 25 wt% Ag).During the cycling of D2 gas, evidence of anomalous heat production was observed. However,during the cycling of H2 and He,very little (H2) or no (He) unusual heat events were observed.After cycling the D2 gas through the coiled tubing for several months, Pd25Ag samples showedan increase in Cu and Fe compared with the amounts in unexposed Pd25Ag. Chromium,manganese, and zinc were detected in gas-cycled Pd25Ag samples, whereas they were notdetected in unexposed Pd25Ag samples. In particular, Zn was present in the gas-cycled Pd25Agmaterial in larger quantities than either Cr or Mn. Although a small amount of Cu was present inthe Pd25Ag coil before the D2 gas cycling, 7 times more was present after the cycling. Multiplematerial characterization techniques were used to obtain both pre-test and post-test elementalcomposition. The results indicate that novel post-test elements, primarily on the surface, werecreated by unknown nuclear mechanisms at low energy.

Gustave C Fralick↗

Metal-silicate Partitioning of Re, Ru, Pt, Os, Ti, Nb, and Ta in Reduced Differentiated Planetary Bodies

Siderophile (iron-loving) elements are strongly fractionated during differentiation of planetary bodies into core and mantle [1]. Because the fractionation is controlled by the pressure, temperature, redox conditions, and composition, this group of elements can provide important constraints on the conditions of accretion and core formation in early solar system bodies (planetesimals) and planets (Earth, Mercury, Venus)[2]. At the reducing conditions thought to prevail in the early solar system, Si is known to alloy with FeNi metallic liquids (e.g., [3]) affecting the activity coefficients of siderophile elements in FeNi liquids and thus ultimately their detailed partitioning between metal and silicate melt. The effect of Si can be significant for some siderophile elements, as demonstrated previously by (e.g., [4]: Ni, Co; [5,6]: Ge, As, Sb, Pd, Pt, Au). The effect of Si has not yet been determined for several key groups of siderophile elements including the highly siderophile Re, Ru and Os, and the weakly siderophile Ta, Nb, and Ti. Here, we report new experiments designed to quantify the effect of Si on the partitioning of Re, Pt, Os, Ru, Ti, Ta and Nb between metal and silicate melts. The results will be used to evaluate metal/silicate equilibrium for Nb, Ta, Ti and Nb/Ta ratios in planetary mantles, mantle concentrations of Ru, Re, Pt, Os during accretion, the evolution of Re/Os, Pt/Os ratios in magma oceans, and the role of late veneer in establishing Re and Ru abundances in the terrestrial mantle.

core formation↗

Introduction to ISS Crew Displays

The International Space Station (ISS) began payload operations in earnest in 2000 with the arrival of the Expedition 1. To date, ISS has offered Principal Investigators (PIs) a reliable platform for microgravity research, having hosted thousands of onboard science experiments. Most of this research is supported by experiment hardware and software and many include a crew‐operated Graphical User Interface (GUI). The purpose of this article is to share information with PIs and Payload Developer (PD) teams about the processes, standards, and guidelines applicable to crew GUI design that must be complied with when planning payload software. The goal is not to enumerate all of the ISS display standards, but rather to highlight design guidelines and the ISS Program milestones for verification and approval of onboard crew displays.

Graphical User Interface↗

Progresses in Developing Micro-Multilayer Multifunctional Electrical Insulation (MMEI) System for High Voltage Applications

Development of the novel patented high voltage insulation system, namely micro-multilayer multifunctional electrical insulation (MMEI) was continued particularly for the future hybrid or all electric aircraft applications. Initially, the concept and feasibility of the MMEI system were successfully demonstrated with its exceptionally high dielectric breakdown voltage via optimizing the multilayer structures of the Kapton® PI films and binder layers such as PFA in terms of individual film thickness and layer configuration. Overall, MMEI structures outperformed most of the state-of-the-art (SOA) polymer insulation materials or structures. Since then, further optimizations and improvement of the system were pursued with specific emphasis on multifunctionalities such as moisture blocking, partial discharge (PD) resistance, durability, etc. Efforts have been also continued to identify the controlling mechanisms for the major improvement in dielectric strength of the MMEI structures via 3-dimensional dielectric failure mode analysis. At the same time, significant progress has been made in scaling up the MMEI structures and assessing their commercial applicability and manufacturability by developing full-scale prototypes of electrical components, such as power cable and bus bar. Overall progresses on the MMEI development to date will be presented in this paper.

Novel Electrical Insulation↗

Multi-Anvil Experimentation Applied to Planetary Differentiation

Planets undergo differentiation that includes segregation of metal from silicate at high temperatures and pressures ranging from deep planetary core pressures (>300 GPa for Earth)to very shallow conditions of asteroids (<100 MPa).The multi-anvil solid media apparatus accesses the middle part of this range from 3 to 30 GPa –pressure relevant to the interior of Mercury, Venus, Earth, Earth’s Moon, and Mars. Early planets are thought to have experienced high temperatures from a combination of heat sources including radioactive decay, gravitational and accretional heating, and impact processes. These heating events led to melting of mantles and cores, thus requiring an understanding of solid-liquid equilibria in metal-silicate systems. In 2006 we established a multi-anvil facility at NASA-JSC combining an 880 ton press and a Kawai/Walker type module from Rockland Research. Our high PT work has been greatly facilitated by use of the COMPRES multi-anvil assemblies (1). Our recent work has included studies of element partitioning between liquid metal and liquid silicate(e.g., 2), as well as between minerals and melts(e.g., 3), both of which have led to better constraints on the timing and conditions of planetary differentiation(e.g. 4). Several examples involving sustained efforts will be summarized below and for the presentation. The distribution of siderophile (iron-loving) elements between core and mantle is controlled by metal-silicate equilibrium across a wide range of pressures. Therefore, experimentation across this pressure range helps to calibrate elemental partitioning models that can be applied to planets, and used to predict mantle chemistry and composition during planetary differentiation. Our studies have focused on a wide range of siderophile elements (refractory Ni, Co, W, Mo; volatile P, Ga, Cu, Sn, Sb; highly siderophile Au, Pd) that have constrained partitioning, valence, and isotopic fractionation, and applied to Earth, Moon, and Mars. When molten mantles (magma oceans) cool enough to initiate crystallization, the solids precipitate at depth and in large planets this involves high pressure phases like garnet, majorite, akimotoite, and ringwoodite. As these solids precipitate they can segregate from liquid by density contrasts, thus causing elemental fractionation which can be used to decipher timing of differentiation. Mineral/melt and metal/silicate equilibria in our lab have helped to better understand high pressure fractionation of isotopic parent/daughter pairs Hf/W, Mn/Cr, Pd/Ag, Pt/Os, Re/Os, and U/Pb, and their application to Earth, Moon and Mars. There remains great potential for multi-anvil experimentation to shed light on many pressure–dependent aspects of planetary evolution such as core formation, high pressure phase equilibria, redox equilibria, and volatile evolution and storage. References1. Leinenweber, K., et al.(2012) American Mineralogist,97, 353–368. 2.Righter, K., et al.(2020) Geochem. Persp. Lett.15, 1-6.3. Righter, K., et al.(2020) Met. Planet. Sci 55, 2741-2757.4. Righter, K., et al.(2020)Earth and Planetary Science Letters,552, 116590.

pressure↗

MLtool++ package for machine learning and its applications to materials data

We are developing Mltool++ package of software programs for machine learning (ML). Given the MLtool Python code, we create a faster C++ code with the potential for parallelization. We have extracted materials data from the literature. One dataset contains melting temperatures of stoichiometric 1:1 metallic compounds XZ, composed by elements X={Al, Ti, V, Cr, Zr, Nb, Mo, Hf, Ta, W} and Z={Co, Ni, Cu, Rh, Pd, Ag, Ir, Pt, Au}, and another contains solid-solid symmetry-breaking phase transition temperatures. We studied dependences of temperatures on composition, found several correlations, and parametrized them by analytical functions. Mltool++ package is generic and applicable to any tabulated numeric data.

Pierce M. Pettit↗

A Comprehensive Machine Learning Study to Classify Precipitation Type over Land from Global Precipitation Measurement Microwave Imager (GPM-GMI) Measurements

Precipitation type is a key parameter used for better retrieval of precipitation characteristics as well as to understand the cloud–convection–precipitation coupling processes. Ice crystals and water droplets inherently exhibit different characteristics in different precipitation regimes (e.g., convection, stratiform), which reflect on satellite remote sensing measurements that help us distinguish them. The Global Precipitation Measurement (GPM) Core Observatory’s microwave imager (GMI) and dual-frequency precipitation radar (DPR) together provide ample information on global precipitation characteristics. As an active sensor, the DPR provides an accurate precipitation type assignment, while passive sensors such as the GMI are traditionally only used for empirical understanding of precipitation regimes. Using collocated precipitation type flags from the DPR as the “truth”, this paper employs machine learning (ML) models to train and test the predictability and accuracy of using passive GMI-only observations together with ancillary information from a reanalysis and GMI surface emissivity retrieval products. Out of six ML models, four simple ones (support vector machine, neural network, random forest, and gradient boosting) and the 1-D convolutional neural network (CNN) model are identified to produce 90–94% prediction accuracy globally for five types of precipitation (convective, stratiform, mixture, no precipitation, and other precipitation), which is much more robust than previous similar effort. One novelty of this work is to introduce data augmentation (subsampling and bootstrapping) to handle extremely unbalanced samples in each category. A careful evaluation of the impact matrices demonstrates that the polarization difference (PD), brightness temperature (Tc) and surface emissivity at high-frequency channels dominate the decision process, which is consistent with the physical understanding of polarized microwave radiative transfer over different surface types, as well as in snow and liquid clouds with different microphysical properties. Furthermore, the view-angle dependency artifact that the DPR’s precipitation flag bears with does not propagate into the conical-viewing GMI retrievals. This work provides a new and promising way for future physics-based ML retrieval algorithm development.

machine learning/artificial intelligence↗

Additional Trials & Tribulations in Synthesizing a Sulfide Standard

Well-characterized sulfide reference materials that can serve as matrix-matched calibrants for in-situ trace element analyses via laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) remain elusive. Here, we describe the creation an in-house sulfide standard at NASA JSC that will be used to measure siderophile and chalcophile trace elements in low pressure experimental products, specifically pentlandite ([FeNi]9S8) and pyrrhotite ([FeNi]1-xS), as well as natural sulfides in terrestrial and meteoritic mineral assemblages. Recent methods in creating a homogenous sulfide standard include pressed pellets, synthesized chips, or fused glass [e.g. 1-3]. Other studies, however, have had success in forming homogenous FeS standards via synthesization methods [e.g. 4-6]. We present a variation of the method described in [4], in which we create a pyrrhotite standard doped with a variety of trace elements (Zn, As, Se, Mo, Ru, Rh, Pd, Sn, Sb, Te, W, Os, Ir, Pt, Au) at ~10-40 ppm and Cu at ~200 ppm. Sulfide compositions were constructed using Fe and Ni metal and elemental sulfur powders. Trace elements were added to elemental sulfur from Atomic Absorption Spectroscopy (AAS) elemental standards as either nitrate or chloride solutions to prevent oxidation of the metal powders. The dried sulfur mixture was mixed with Fe and Ni powders and mechanically mixed before two aliquots were placed in separate SiO2 tubes. Each tube was held under vacuum for ~30 minutes, sealed under vacuum, and then heated at 800C for 48 hours. Like [4], the synthesis products were composed of pourous sulfide crystals. Major element analyses of both experimental aliquots, collected using an Electron Probe Microanalyser (EPMA), yield indistinguishable major element compositions (uncertainties in 2SE & 2RSE[%]), with an average of 57.90  0.09 (0.16 %), 4.95  0.03 (0.55 %), and 39.70  0.14 (0.34 %), for Fe, Ni, and S, respectively. Trace element data were measured using a Photon Machines 193nm laser ablation system coupled to a Thermo-Scientific Element-XR ICP-MS. Spot sizes were limited to 50 μm due to the porous nature of the sulfide target material. Trace element abundances, normalized to Fe as an internal standard, were also found to be homogenous between the two aliquots, with weighted mean 2RSE (%) values of <3.0 for all trace elements. Synthesized products were re-powdered and absolute concentrations measured via solution ICP-MS. Although the sulfide appears to be homogenous, sintering experiments will be performed to more closely match the standard density to natural sulfides and minimize differences in ablation behavior. Improved density also allows for higher sensitivity (i.e. more compact target material) and larger spot sizes or traverses, as void space is eliminated. Additional major and trace element analyses on the products of the sintering experiments will be undertaken.

Jacob B Setera↗

Automated Downlink Pipeline for Scientific Data Using TReK

ISS users generate scientific data files on orbit that require console operators to retrieve and deliver them for analysis. Automating the downlink process using TReK CFDP and DTN provides ground flight controllers and PD teams increased efficiency, reducing workload and resulting in cost savings without reduced services provided.

TReK↗

Pulse Response of the Short-Wave Infrared Detection System of the Ocean Color Instrument for the NASA PACE Mission

The Ocean Color Instrument (OCI) on NASA’s Plankton, Aerosol, Cloud, ocean Ecosystem (PACE) mission is a hyperspectral Earth imager with a spatial resolution of 1 km x 1 km and a spectral resolution of 5 nm in 2.5 nm steps over 342-887 nm. In addition, OCI provides 7 discrete bands in the 940-2260 nm Short-Wave InfraRed (SWIR) range. The front-end optical imager is a rotating mirror-based system that images the ground scene onto a slit with an instantaneous field of view of 16 km x 1 km. For the SWIR bands, the slit-image is re-imaged onto a 16x1 micro-lens array that effectively acts as the focal plane since each lens element is fiber coupled to wavelength filtered InGaAs and HgCdTe Photo Diodes (PDs). The pulse response of the detection system is critical to OCI SWIR performance. We find that PDs introduce an inherent slow tail in the pulse response due to slow diffusion moving carriers in their n and p regions. We show that this introduces response errors ranging from 1 down to 0.01 % for up to tens of science pixels after the pulse depending on the PD design and materials. It is shown that the response is distinctly different for the InGaAs and HgCdTe PDs. We explain how the front-end design can further increase this error. Finally, we detail the cause of the slow pulse response tail, how to model it, its impact on OCI performance and how it is characterized and corrected to meet OCI requirements.

ocean color↗

Pulse Response of the Short-Wave Infrared Detection System of the Ocean Color Instrument for the NASA Pace Mission

The Ocean Color Instrument (OCI) on NASA’s Plankton, Aerosol, Cloud, ocean Ecosystem (PACE) mission is a hyperspectral Earth imager with a spatial resolution of 1 km x 1 km and a spectral resolution of 5 nm in 2.5 nm steps over 342-887 nm. In addition, OCI provides 7 discrete bands in the 940-2260 nm Short-Wave InfraRed (SWIR) range. The front-end optical imager is a rotating mirror-based system that images the ground scene onto a slit with an instantaneous field of view of 16 km x 1 km. For the SWIR bands, the slit-image is re-imaged onto a 16x1 micro-lens array that effectively acts as the focal plane since each lens element is fiber coupled to wavelength filtered InGaAs and HgCdTe Photo Diodes (PDs). The pulse response of the detection system is critical to OCI SWIR performance. We find that PDs introduce an inherent slow tail in the pulse response due to slow diffusion moving carriers in their n and p regions. We show that this introduces response errors ranging from 1 down to 0.01 % for up to tens of science pixels after the pulse depending on the PD design and materials. It is shown that the response is distinctly different for the InGaAs and HgCdTe PDs. We explain how the front-end design can further increase this error. Finally, we detail the cause of the slow pulse response tail, how to model it, its impact on OCI performance and how it is characterized and corrected to meet OCI requirements.

ocean color↗

Martensitic Phase Transition in Complex NiTi-Based Shape Memory Alloys from First-Principles Calculations

Recent rapid progresses in physics theory and computational power have made it possible to accurately predict the phase transitions and martensitic transition temperatures (MTTs) in shape memory alloys (SMAs) from first principles. However, previously theory and calculations [1-4] were applied only to study highly ordered stoichiometric binary alloys such as NiTi, PdTi and NiHf. Here we report on our recent first-principles investigations [5,6] on Ni 0.5 Ti 0.5-x Hf x and Pd x Ni 0.5-x Ti 0.5 ternaries and off-stoichiometric NiTi, and the predicted martensitic phase transitions in these complex SMAs are in good agreement with experimental findings. In particular, the calculated MTTs for all these compositions are within 100 K compared with the corresponding measured data, and our results also reveal the origin of the striking asymmetry in MTT of the off-stoichiometric NiTi near equiatomic compositions. We will address various techniques to overcome the difficulty encountered in studying ternaries and off-stoichiometic binaries associated with disorder and/or much lowered symmetry. Our theoretical approach is expected to be a broadly applicable and predictive theory for designing complex SMAs with desirable properties. References: [1] J. B. Haskins, A. E. Thompson, and J. W. Lawson, Phys. Rev B 94 , 214110 (2016). [2] J. B. Haskins and J. W. Lawson, J. App. Phys. 121 , 205103 (2017). [3] J. B. Haskins, H. Malmir, S. J. Honrao, L. A. Sandoval, and J. W. Lawson, Acta Materialia 212 , 116872 (2017). [4] Z. Wu, J. W. Lawson, and O. Benafan, Phys. Rev. B 106 , L140102 (2022). [5] Z. Wu, H. Malmir, O. Benafan, and J. W. Lawson, Acta Materialia 261 , 119362 (2023). [6] Z. Wu, J. W. Lawson, and O. Benafan, Phys. Rev. B 108 , L140103 (2023).

Zhigang Wu↗