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At least 415 records · Page 23

Glass Veins in the Unequilibrated Eucrite Yamato 82202

The unequilibrated eucrite Yamato 82202 (Y82202) contains a network of glass veins, which are relatively thick (up to 1 mm in width) and are not devitrified. The host of the meteorite represents volcanic rock that crystallized >4.3 Gyr ago, probably as a lava flow on the surface of 4 Vesta. The impact event that formed the glass veins occurred at approx. 3.9 Gyr under conditions of low effective fo2 and very rapid cooling. A S-rich vapor probably was generated by impact vaporization of sulfides. The impact melt was not superheated and it retains some disordered structural characteristics of the original pyroxene and feldspar of the eucritic target lithology. The unequilibrated pyroxenes of this eucrite and the pristine character of the glass indicate that the meteorite experienced no significant metamorphism after initial crystallization. Hence, it was not buried to a significant depth or covered by a lava flow or hot layer of impact ejecta. The meteorite resided at a shallow level (though not at the surface) on 4 Vesta or on one of the vestoids until it was ejected and traveled to Earth, probably with other HED materials that have Ar-36 exposure ages of approx. 13 Myr.

Bogard, Donald↗

Mineralogy at Gusev Crater and Meridiani Planum from the Moessbauer Spectrometers on the Mars Exploration Rovers

The Moessbauer spectrometers on the twin MER rovers Spirit and Opportunity have provided significant new information on the distribution of iron among its oxidation states, the identification of the mineralogical composition of iron-bearing phases, and the distribution of iron among those phases for rock and soil at Gusev Crater and Meridiani Planum. The plains of Gusev Crater are dominated by olivine-bearing basalt (approximately Fo(60)) and Fe(3+)/Fe(total)=0.1 - 0.5. The oxide mineral generally present is magnetite. In contrast, initial results for the Columbia Hills are consistent with the presence of hematite and a ferrous iron phase, possibly pyroxene. Gusev spectra also have a ferric doublet (not jarosite) that is tentatively associated with nano-phase ferric oxide. A wider diversity of material is present at Meridiani Planum. Significantly, jarosite-bearing outcrop is present throughout the region, with good exposures in impact craters such as Eagle and Endurance (Fe(3+)/Fe (total) approx. 0.9). The Moessbauer identification of jarosite (a hydroxyl-bearing sulfate mineral) is evidence for aqueous, acid-sulfate processes on Mars. Hematite is observed within the outcrop matrix and in the spheroidal particles (Blueberries) found within the outcrop and as a surface lag. An isolated rock (Bounce Rock) was the only sample at either landing site whose iron-bearing phase was dominated by pyroxene. The basaltic sand in the central portion of Eagle crater, in the intercrater plains, and between slabs of outcrop at both Eagle and Endurance craters is olivine-bearing basalt. The widespread occurrence of olivine-bearing basalt at both MER landing sites implies that physical, rather than chemical, weathering processes dominate at the surface of contemporary Mars.

Morris, Richard V.↗

Comet Dust After Deep Impact

When the Deep Impact Mission hit Jupiter Family comet 9P/Tempel 1, an ejecta crater was formed and an pocket of volatile gases and ices from 10-30 m below the surface was exposed (A Hearn et aI. 2005). This resulted in a gas geyser that persisted for a few hours (Sugita et al, 2005). The gas geyser pushed dust grains into the coma (Sugita et a1. 2005), as well as ice grains (Schulz et al. 2006). The smaller of the dust grains were submicron in radii (0-25.3 micron), and were primarily composed of highly refractory minerals including amorphous (non-graphitic) carbon, and silicate minerals including amorphous (disordered) olivine (Fe,Mg)2SiO4 and pyroxene (Fe,Mg)SiO3 and crystalline Mg-rich olivine. The smaller grains moved faster, as expected from the size-dependent velocity law produced by gas-drag on grains. The mineralogy evolved with time: progressively larger grains persisted in the near nuclear region, having been imparted with slower velocities, and the mineralogies of these larger grains appeared simpler and without crystals. The smaller 0.2-0.3 micron grains reached the coma in about 1.5 hours (1 arc sec = 740 km), were more diverse in mineralogy than the larger grains and contained crystals, and appeared to travel through the coma together. No smaller grains appeared at larger coma distances later (with slower velocities), implying that if grain fragmentation occurred, it happened within the gas acceleration zone. These results of the high spatial resolution spectroscopy (GEMINI+Michelle: Harker et 4. 2005, 2006; Subaru+COMICS: Sugita et al. 2005) revealed that the grains released from the interior were different from the nominally active areas of this comet by their: (a) crystalline content, (b) smaller size, (c) more diverse mineralogy. The temporal changes in the spectra, recorded by GEMIM+Michelle every 7 minutes, indicated that the dust mineralogy is inhomogeneous and, unexpectedly, the portion of the size distribution dominated by smaller grains has a more diverse mineralogy. The lower spatial resolution, high sensitivity Spitzer IRS data reveal resonances of refractory minerals (those seen by GEMINI+Michelle plus ortho-pyroxene)) as well resonances that can be attributed to phillosilicates (layer lattice silicates such as Montmorillonite) (Lisse et al. 2006). Pre- and post-impact, micron to submicron grains were deciphered to be present in the coma by the modeling the high spatial resolution images to account for nucleus plus inner coma fluxes (Wooden et al. 2005, 2006; Harker et al. 2005, 2006a). Note also that crystalline silicates were released from the interior of 73P-B/SW-3 as it disintegrated (Harker et al. 2006b). From the Deep Impact and the disintegration of 73P-B, we are led to ask the questians: Why is the mineralogy of the dust released from a volatile-rich pocket beneath the surface different from the dust that is released from the nominally active areas? Could the most volatile pockets be exhausted quickly? Why would crystalline silicates be associated with more volatile materials? Perhaps the structure of the comet is so inhomogeneous, e.g., the layered pile mode2 of the nucleus (Belton et al. 2006), that a reservoir of crystalline silicate and submicron grains just happens to not be released by the nominally active areas of comet 9P? Perhaps comets lose matter through their mantles from below their surfaces, thus preserving ancient topographic structures and radiation damaged silicates and carbon? We will discuss and ponder different scenarios. We will discuss future directions for coordinated observations of JF comets.

Wooden, Diane H.↗

Oxidation State of Nakhlites as inferred from Fe-Ti oxide Equilibria and Augite/Melt Europium Partitioning

Recent studies have shown that Martian magmas had wide range of oxygen fugacities (fO2) and that this variation is correlated with the variation of La/Yb ratio and isotopic characteristics of the Martian basalts, shergottite meteorites. The origin of this correlation must have important information about mantle sources and Martian evolution. In order to understand this correlation, it is necessary to know accurate value of oxidation state of other Martian meteorite groups. Nakhlites, cumulate clinopyroxenites, are another major group of Martian meteorites and have distinctly different trace element and isotopic characteristics from shergottites. Thus, estimates of oxidation state of nakhlites will give us important insight into the mantle source in general. Several workers have estimated oxidation state of nakhlites by using Fe-Ti oxide equilibrium. However, Fe-Ti oxides may not record the oxidation state of the parent melt of the nakhlite because it is a late-stage mineral. Furthermore, there is no comprehensive study which analyzed all nakhlite samples at the same time. Therefore, in this study (1) we reduced the uncertainty of the estimate using the same electron microprobe and the same standards under the same condition for Fe-Ti oxide in 6 nakhlites and (2) we also performed crystallization experiments to measure partition coefficients of Eu into pyroxene in the nakhlite system in order to estimate fO2 when the pyroxene core formed (i.e. Eu oxybarometer [e.g. 2,6]).

Makishima, J.↗

Excess Ar-40 in the Zagami Shergottite: Does It Reveal Crystallization History?

The Zagami basaltic shergottite has fine- and coarse-grained (FG & CG) areas, which may reflect partial crystallization in a deep, slowly cooled magma chamber to form Mg-rich pyroxene cores, followed by entrainment of these crystals into a magma that rose and crystallized near the surface. Late-stage melt pockets formed mesostasis and feldspar (maskelynite) having a range of compositions, but low water abundance. Higher I(sub Sr) in the FG portion may result from the second stage having incorporated old crustal rocks that failed to reach isotopic equilibrium. Zagami, like other shergottites, contains excess Ar-40(sub xs) beyond that expected from internal decay of K-40 during its Sm-Nd age of 177 Myr. We suggest that at least a portion of this Ar-40(sub xs) in Zagami and some other shergottites was inherited from the magma, much as is the case of MORBs on Earth. We made Ar-39-Ar-40 age determinations on feldspar and pyroxene separates from both the FG and CG portions of Zagami. If Zagami experienced an evolving fractional crystallization history, including possible crustal contamination of the magma, that might be indicated in differing amounts of Ar-40(sub xs) between mineral phases and between FG and CG portions.

Bogard, Donald D.↗

Experimental Constraints on Ureilite Petrogenesis

This experimental study explores the petrogenesis of ureilites by a partial melting/smelting process. Experiments have been performed over temperature (1150-1280 C), pressure (5-12.5 MPa), and low oxygen fugacity (graphite-CO gas) conditions appropriate for a hypothetical ureilite parent body approximately 200 km in size. Experimental and modeling results indicate that a partial melting/smelting model of ureilite petrogenesis can explain many of the unique characteristics displayed by this meteorite group. Compositional information preserved in the pigeonite-olivine ureilites was used to estimate the composition of melts in equilibrium with the ureilites. The results of 20 experiments saturated with olivine, pyroxene, metal, and liquid with appropriate ureilite compositions are used to calibrate the phase coefficients and pressure-temperature dependence of the smelting reaction. The calibrated coefficients are used to model the behavior of a hypothetical residue that is experiencing fractional smelting. The residue is initially olivine-rich and smelting progressively depletes the olivine content and enriches the pyroxene and metal contents of the residues. The modeled residue composition at 1260 C best reproduces the trend of ureilite bulk compositions. The model results also indicate that as a ureilite residue undergoes isothermal decompression smelting over a range of temperatures, Ca/Al values and Cr203 contents are enriched at lower temperatures (below about 1240 C) and tend to decrease at higher temperatures. Therefore, fractional smelting can account for the high Ca/A1 and Cr203 wt% values observed in ureilites. We propose that ureilites were generated from an olivine-rich, cpx-bearing residue. Smelting began when the residue was partially melted and contained liquid, olivine, and carbon. These residues experienced varying degrees of fractional smelting to produce the compositional variability observed within the pigeonite-bearing ureilites. Variations in mineral composition, modal proportions, and isotopic signatures are best described by heterogeneous accretion of the ureilite parent body followed by minimal and variable degrees of igneous processing.

Singletary, Steven↗

Oxygen Isotope Systematics of Chondrules from the Least Equilibrated H Chondrite

Oxygen isotope compositions of bulk chondrules and their mineral separates in type 3 ordinary chondrites (UOC) show several % variability in the oxygen three isotope diagram with slope of approx.0.7 [1]. In contrast, ion microprobe analyses of olivine and pyroxene phenocrysts in ferromagnesian chondrules from LL 3.0-3.1 chondrites show mass dependent isotopic fractionation as large as 5% among type I (FeO-poor) chondrules, while type II (FeO-rich) chondrules show a narrow range (less than or equal to 1%) of compositions [2]. The .Delta(exp 17)O (=delta(exp 17)O-0.52xdelta(exp 18)O) values of olivine and pyroxene in these chondrules show a peak at approx.0.7% that are systematically lower than those of bulk chondrule analyses as well as the bulk LL chondrites [2]. Further analyses of glass in Semarkona chondrules show .17O values as high as +5% with highly fractionated d18O (max +18%), implying O-16-poor glass in chondrules were altered as a result of hydration in the parent body at low temperature [3]. Thus, chondrules in LL3.0-3.1 chondrites do not provide any direct evidence of oxygen isotope exchange between solid precursor and O-16-depleted gas during chondrule melting events. To compare the difference and/or similarity between chondrules from LL and H chondrites, we initiated systematic investigations of oxygen isotopes in chondrules from Yamato 793408 (H3.2), one of the least equilibrated H chondrite [4]. In our preliminary study of 4 chondrules, we reported distinct oxygen isotope ratios from dusty olivine and refractory forsterite (RF) grains compared to their host chondrules and confirmed their relict origins [5].

Kita, N. T.↗

What We Might Know About Gusev Crater if the Mars Exploration Rover Spirit Mission were Coupled with a Mars Sample Return Mission

The science instruments on the Mars Exploration Rover (MER) Spirit have provided an enormous amount of chemical and mineralogical data during more than 1450 sols of exploration at Gusev crater. The Moessbauer (MB) instrument identified 10 Fe-bearing phases at Gusev Crater: olivine, pyroxene, ilmenite, chromite, and magnetite as primary igneous phases and nanophase ferric oxide (npOx), goethite, hematite, a ferric sulfate, and pyrite/marcusite as secondary phases. The Miniature Thermal Emission Spectrometer (Mini-TES) identified some of these Fe-bearing phases (olivine and pyroxene), non- Fe-bearing phases (e.g., feldspar), and an amorphous high-SiO2 phase near Home Plate. Chemical data from the Alpha Particle X-Ray Spectrometer (APXS) provided the framework for rock classification, chemical weathering/alteration, and mineralogical constraints. APXS-based mineralogical constraints include normative calculations (with Fe(3+)/FeT from MB), elemental associations, and stoichiometry (e.g., 90% SiO2 implicates opalline silica). If Spirit had cached a set of representative samples and if those samples were returned to the Earth for laboratory analysis, what value is added by Mars Sample return (MSR) over and above the mineralogical and chemical data provided by MER?

Morris, Richard V.↗

Sm-Nd and Rb-Sr Ages for Northwest Africa 2977, A Young Lunar Gabbro from the PKT

Northwest Africa (NWA) 2977 is an olivine gabbro cumulate equivalent to one of the lithologies in lunar mare breccia NWA 773 [1,2,3]. The Ar-39-Ar-40 age is 2.77+/-0.04 Ga based on the last approx.57% of the gas release [4], similar to results for NWA 773 [5]. A Sm-Nd age (T) of 2.865+/-0.031 Ga and Epsilon(sub Nd) = -7.84+/-0.22 for the NWA 773 gabbro reported by [6] has been revised to T = 2.993+/-=0.032 Ga, Epsilon(sub Nd) -4.5+/-0.3 [7]. Sm-147-Nd-143 isochron for NWA 2977: Whole rock, pyroxene, olivine, plagioclase, whole rock leachate (approx.phosphate) and the combined leachates from the mineral separates yield a well defined Sm-Nd isochron for an age T = 3.10+/-0.05 Ga and Epsilon(sub Nd-CHUR) = -3.74+/-0.26 [8], or Epsilon(sub Nd-HEDR) = -4.61+/-0.26 [9]. Rb-87-Sr-87 isochron: NWA 2977 contains only a modest amount of Rb and/or Sr contamination. The Sr-isotopic composition of the contaminant closely resembles that of seawater. The whole rock residue after leaching combined with leach residues for plagioclase and pyroxene define an isochron age of 3.29+/-0.11 Ga for initial Sr-87/Sr-86 = 0.70287+/-18. The olivine residue, with lower Sr abundance of approx 1.5 ppm, is only slightly displaced from the isochron. The relatively small uncertainties of the Rb-Sr isochron parameters and near-concordancy with the Sm-Nd age indicate that both the Rb-Sr and the Sm-Nd ages are reliable.

Nyquist, L. E.↗

Progress of the NASA/USGS Lunar Regolith Simulant Project

Beginning in 2004 personnel at MSFC began serious efforts to develop a new generation of lunar simulants. The first two products were a replication of the previous JSC-1 simulant under a contract to Orbitec and a major workshop in 2005 on future simulant development. Beginning in 2006 the project refocused its efforts and approached simulant development in a new and more comprehensive manner, examining new approaches in simulant development and ways to more accurately compare simulants to actual lunar materials. This led to a multi-year effort with five major tasks running in parallel. The five tasks are Requirements, Lunar Analysis, Process Development, Feed Stocks, and Standards. Major progress has been made in all five areas. A substantial draft of a formal requirements document now exists and has been largely stable since 2007. It does evolve as specific details of the standards and Lunar Analysis efforts proceed. Lunar Analysis has turned out to be vastly more difficult than anticipated. After great effort to mine existing published and gray literature, the team has realized the necessity of making new measurements of the Apollo samples, an effort that is currently in progress. Process development is substantially ahead of expectations in 2006. It is now practical to synthesize glasses of appropriate composition and purity. It is also possible to make agglutinate particles in significant quantities. A series of minerals commonly found on the Moon has been synthesized. Separation of mineral constituents from starting rock material is also proceeding. Customized grinding and mixing processes have been developed and tested are now being documented. Identification and development of appropriate feedstocks has been both easier and more difficult than anticipated. The Stillwater Mining Company, operating in the Stillwater layered mafic intrusive complex of Montana, has been an amazing resource for the project, but finding adequate sources for some of the components remains a difficult problem. For example the ratio of clino- to ortho-pyroxenes in the Stillwater is not an exact match for lunar materials. One of the sources being examined as an alternative pyroxene source is the Bushveld Complex in South Africa. Standards have been a major success for the project. The Figure of Merit algorithms have been created, tested, and are being considered for an ISO standard. Agreement has been reached in the community about how to make many of the critical measurements. There remains much work to do: (1) driving down the cost of simulants remains a major obstacle; (2) documentation and cost data analysis have not kept up with progress; (3) educating users in the complexity of the lunar regolith and the use of simulants remains a major task. In summary the project has made enormous progress and is successfully placing simulant development and use on a rigorous, scientifically defensible, engineering basis.

Rickman, Doug↗

Late Reduction Textures in Almahata Sitta Ureilite

The Almahata Sitta ureilite, derived from asteroid 2008 TC3, consists of many individual fragments recovered from the Nubian dessert strewn field [1]. Like most ureilites, it contains abundant carbon and exhibits examples of disequilibrium textures that record a late reduction event accompanied by rapid cooling (tens of degC/h) from high temperatures (1150-1300 C). Variations in Fe/Mg of silicate minerals are accompanied by variations in Fe/Mn, indicating loss of Fe into metal [2]. In coarser-grained fragments of Almahata Sitta, olivine exhibits irregular high mg# rims in contact with networks of interstitial metal 5- 20 microns in typical thickness. This is a common ureilite texture thought to be driven by the reaction of graphite to a CO gas phase and the concurrent reduction of FeO in olivine to Fe metal, with excess silica going primarily into pyroxene (2MgFeSiO4 + C approaches MgSiO4 + MgSiO3 + 2Fe + CO) [3, see also 4,5,6]. Other fragments of Almahata Sitta exhibit anomalous textures such as fine grain size, high porosity, and abundant graphite. Within these fragments pyroxene locally exhibits high-mg# rims in contact with metal and a discreet silica phase, suggesting that the reduction mechanism MgFeSi2O6 + C approaches MgSiO3 + Fe + SiO2 + CO. Metals in Almahata Sitta are particularly unaltered in comparison to ureilite finds. Variations in minor and trace element composition of this metal might partly result from localized dilution as iron is supplied by reduction of silicates.

Herrin, J. S.↗

39Ar - 40Ar Studies of Lherzolitic Shergottites Yamato 000097 and 984028

Yamato 984028 (Y984028) was discovered by the Japanese Antarctic Research Expedition (JARE) in 1998 and recently classified as a lherzolitic shergottite with large pyroxene oikocrysts enclosing rounded olivine and chromites. It also contains shock veining and maskelynite. Y984028 is paired with the more recent lherzolitic shergottite finds Y000027/47/97 based on similarities in mineralogy and chemistry, as well as isotopic composition. We present here the studied Ar-39-Ar-40 of Y-984028 whole rock (WR) and pyroxene (Px), in order to gain better understanding of trapped Ar components with a comparison of the possibly-paired Y000097 Ar release.

Park, J.↗

Ar-Ar Studies of Lherzolitic Shergottites Yamato 000097 and 984028

The approx.170 Ma age of the rock(s) is (likely) preserved in minor phases of high K content. Terrestrial Ar appears to have a nearly ubiquitous presence in the gas release, and mixes with Martian Ar in variable proportions. The intermediate temperature release of the plag separate shows an apparently higher approx.270 Ma age, and suggests the presence of terrestrial Ar that "torques" the correlation to a steeper slope than for 170 Ma. The intermediate temperature data of the pyroxene is consistent with a "young" age (either approx.170 to approx.270 Ma) and mostly Martian trapped Ar. The low temperature (needs checking) data also are essentially consistent with the approx.170 Ma age, but an intercept near the terrestrial value is suspicious. Would not have had terrestrial Ar on Mars, so this is more likely a mixing line. Admixtures of terrestrial Ar in the pyroxene extractions seems pervasive, but can t explain the variation in 39/36 along the intermediate temp. "isochron".

Park, J.↗

Water in the Oceanic Lithosphere: Salt Lake Crater Xenoliths, Oahu, Hawaii

Water can be present in nominally anhydrous minerals of peridotites in the form of hydrogen bonded to structural oxygen. Such water in the oceanic upper mantle could have a significant effect on its physical and chemical properties. However, the water content of the MORB source has been inferred indirectly from the compositions of basalts. Direct determinations on abyssal peridotites are scarce because they have been heavily hydrothermally altered. Here we present the first water analyses of minerals from spinel peridotite xenoliths of Salt Lake Crater, Oahu, Hawaii, which are exceptionally fresh. These peridotites are thought to represent fragments of the Pacific oceanic lithosphere that was refertilized by alkalic Hawaiian melts. A few have unradiogenic Os and radiogenic Hf isotopes and may be fragments of an ancient (~2 Ga) depleted and recycled lithosphere. Water contents in olivine (Ol), orthopyroxene (Opx), and clinopyroxene (Cpx) were determined by FTIR spectrometry. Preliminary H_{2}O contents show ranges of 8-10 ppm for Ol, 151-277 ppm for Opx, and 337-603 ppm for Cpx. Reconstructed bulk rock H_{2}O contents range from 88-131 ppm overlapping estimates for the MORB source. Water contents between Ol minerals of the same xenolith are heterogeneous and individual OH infrared bands vary within a mineral with lower 3230 cm^{-1} and higher 3650-3400 cm^{-1} band heights from core to edge. This observation suggests disturbance of the hydrogen in Ol likely occurring during xenolith entrainment to the surface. Pyroxene water contents are higher than most water contents in pyroxenes from continental peridotite xenoliths and higher than those of abyssal peridotites. Cpx water contents decrease with increasing degree of depletion (e.g. increasing Fo in Ol and Cr# in spinel) consistent with an incompatible behavior of water. However Cpx water contents also show a positive correlation with LREE/HREE ratios and LREE concentrations consistent with refertilization. Opx water contents increase with increasing degree of depletion and decrease with LREE/HREE ratios which is inconsistent with the incompatible behavior of H. Calculated water contents of melts in equilibrium with Cpx or Opx range from 1.4 to 3.8 wt % which is higher than that of all Hawaiian lavas. Calculated melts in equilibrium with Cpx and Opx have variable but mostly high H_{2}O/Ce ratios (194 to 1146) consistent with those of rejuvenated stage lavas from Niihau and the South Arch volcanic field, but unlike the drier shield building stage tholeiites. Whether the high water contents recorded in Salt Lake Crater xenoliths were acquired before and/or during interaction of the oceanic lithosphere with the Hawaiian plume will be discussed.

Peslier, Anne H.↗

Sm-Nd Isotopic Studies of Ureilite Novo Urei

Ureilites are ultramafic (harzburgitic) achondrites composed predominantly of olivine and pyroxenes, abundant carbon (graphites and shock-produced diamonds), some metal and sulfides. These rocks probably represent ultramafic mantles of differentiated parent asteroidal bodies. Age determinations of these rocks by Rb-Sr and Sm-Nd methods have been difficult because of their extremely low abundances of these parent-daughter elements. Nevertheless, Sm-Nd isochron ages were reported for Kenna, Goalpara, MET 78008 and PCA 82506 yielding ages of 3.74+/-0.02 Ga, approx.3.7 Ga, 4.09+/-0.08 Ga, 4.23+/-0.06 Ga, respectively [1-4]. These "young" Sm-Nd ages may represent secondary metasomatism events [1] related to impacts [5], as indicated by the similarly young Ar-39-Ar-40 degassing ages of 3.3-4.1 Ga for ureilites Kenna, Novo Urei and Havero [6]. Alternatively, it has been suggested that these rocks may have been contaminated with terrestrial crustal materials and the isochrons do not have any age significance [2,7]. Indications of old approx.4.56 Ga ages for ureilites were reported from the U-Pb and Sm-Nd model ages for MET 78008 [8]. More reliable evidences for old formation ages of ureilites were reported recently using the short-lived chronometers Hf-182-W-182, Al-26-Mg-26 and Mn-53-Cr-53. The deficits of 182W in ureilites suggest the metal-silicate segregation occurred very early, approx.1-2 Ma after CAI [9]. The Al-26-Mg-26 and Mn-53-Cr-53 studies for a feldspathic lithology [10] and the Mn-53-Cr-53 for olivine- and pyroxene-dominant lithologies [11] in ureilites revealed that they crystallized approx.5.4 Ma after CAI, i.e., at 4563.8+/-0.5 Ma relative to D.Orbigny. In this report, we present Sm-Nd isotopic data for a relatively fresh ureilite, Novo Urei, a rare ureilite fall (1886). We compare these data to Sm-Nd data for other ureilites, and discuss Novo Urei's petrogenesis

Shih, C.-Y.↗

Preliminary Examination of Particles Recovered from the Surface of the Asteroid Itokawa by the Hayabusa Mission

The Hayabusa spacecraft arrived at S-type Asteroid 25143 Itokawa in November 2006, and reveal astounding features of the small asteroid (535 x 294 x 209 m). Near-infrared spectral shape indicates that the surface of this body has an olivinerich mineral assemblage potentially similar to that of LL5 or LL6 chondrites with different degrees of space weathering. Based on the surface morphological features observed in high-resolution images of Itokawa s surface, two major types of boulders were distinguished: rounded and angular boulders. Rounded boulders seem to be breccias, while angular boulders seem to have severe impact origin. Although the sample collection did not be made by normal operations, it was considered that some amount of samples, probably small particles of regolith, was collected from MUSES-C regio on the Itokawa s surface. The sample capsule was successfully recovered on the earth on June 13, 2010, and was opened at curation facility of JAXA (Japan Aerospace Exploration Agency), Sagamihara, Japan. A large number of small particles were found in the sample container. Preliminary analysis with SEM/EDX at the curation facility showed that at least more than 1500 grains were identified as rocky particles, and most of them were judged to be of extraterrestrial origin, and definitely from Asteroid Itokawa. Minerals (olivine, low-Ca pyroxene, high-Ca pyroxene, plagioclase, Fe sulfide, Fe-Ni metal, chromite, Ca phosphate), roughly estimated mode the minerals and rough measurement of the chemical compositions of the silicates show that these particles are roughly similar to LL chondrites. Although their size are mostly less than 10 m, some larger particles of about 100 m or larger were also identified. A part of the sample (probably several tens particles) will be selected by Hayabusa sample curation team and examined preliminary in Japan within one year after the sample recovery in prior to detailed analysis phase. Hayabusa Asteroidal Sample Preliminary Examination Team (HASPET) has been preparing for the preliminary examination with close cooperation with the curation team.

Tsuchiyama, A.↗

Towards a Regolith Maturity Index for Howardites

The Dawn spacecraft has just arrived at asteroid 4 Vesta, parent of the howardite, eucrite and diogenite (HED) meteorites [1], to begin a yearlong surface study from orbit [2]. As Dawn will view a debris-covered surface, understanding the formation and mixing processes for the debris layer will strongly aid surface data interpretations. Howardites are polymict breccias mainly composed of clasts derived from basaltic (eucritic) and orthopy-roxenitic (diogenitic) parent materials [3]. Some howardites are poorly reworked (fragmental howardites) whilst others have been extensively gardened in an active regolith (regolithic howardites) [4]. The latter may represent an ancient, well-mixed regolith, whilst the former may be from more recent ejecta deposits [4]. Due to environmental differences, regolith development on Vesta differs in detail from that on the Moon [4-6]. We have been developing petrological criteria to apply to howardite thin sections to determine their relative regolithic maturity, which we are fine-tuning with comparison to noble gas data [7, 8]. Whilst we previously emphasized the abundance of reworked clasts (fragmental and impact-melt breccia clasts), this is an imperfect criterion: one howardite with abundant re-worked clasts (EET 99408) shows no evidence of solar wind Ne (SW-Ne), yet, two of our alleged fragmental howardites have clear SW-Ne signatures (LEW 85313, MET 00423) [7, 8]. We are now investigating the diversity in minor and trace element contents of low-Ca pyroxene clasts in howardites as a measure of regolith grade, and will begin analyses of such grains within reworked clasts. Our hypothesis is that regolithic howardites (and the breccia clasts they contain) will show greater diversity because they sampled more diverse diogenitic plutons than fragmental howardites, which formed from ejecta from only a few impacts [e.g. 4]. Our initial LA-ICP-MS work showed ranges in trace element diversity in low-Ca pyroxenes (estimated from the standard error of the mean of analyses), where those howardites considered of medium to high regolithic grade showed greater diversity [9]. Our EMPA results (from a larger howardite suite) show an overall greater diversity in our putative medium to high regolithic grade howardites, though there are exceptions. The greatest diversity is found for paired howardites GRO 95574 and GRO 95581, which were not considered regolithic in our initial study. We will continue investigating avenues to determine regolith maturity in thin section, factoring in bulk rock compositional data, and will coordinate these studies with noble gas results.

Mittlefehldt, David W.↗

Allan Hills 76005 Polymict Eucrite Pairing Group: Curatorial and Scientific Update on a Jointly Curated Meteorite

Allan Hills 76005 (or 765) was collected by the joint US-Japan field search for meteorites in 1976-77. It was described in detail as "pale gray in color and consists of finely divided macrocrystalline pyroxene-rich matrix that contains abundant clastic fragments: (1) Clasts of white, plagioclase-rich rocks. (2) Medium-gray, partly devitrified, cryptocrystalline. (3) Monomineralic fragments and grains of pyroxene, plagioclases, oxide minerals, sulfides, and metal. In overall appearance it is very similar to some lunar breccias." Subsequent studies found a great diversity of basaltic clast textures and compositions, and therefore it is best classified as a polymict eucrite. Samples from the 1976-77, 77-78, and 78-79 field seasons (76, 77, and 78 prefixes) were split between US and Japan (NIPR). The US specimens are currently at NASA-JSC, Smithsonian Institution, or the Field Museum in Chicago. After this initial finding of ALH 76005, the next year s team recovered one additional mass ALH 77302, and then four additional masses were found during the third season ALH 78040 and ALH 78132, 78158 and 78165. The joint US-Japan collection effort ended after three years and the US began collecting in the Trans-Antarctic Mountains with the 1979-80 and subsequent field seasons. ALH 79017 and ALH 80102 were recovered in these first two years, and then in 1981-82 field season, 6 additional masses were recovered from the Allan Hills. Of course it took some time to establish pairing of all of these specimens, but altogether the samples comprise 4292.4 g of material. Here will be summarized the scientific findings as well as some curatorial details of how specimens have been subdivided and allocated for study. A detailed summary is also presented on the NASA-JSC curation webpage for the HED meteorite compendium.

Righter, K.↗