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At least 415 records · Page 23

Product distributions for some thermal energy charge transfer reactions of rare gas ions

Ion cyclotron resonance methods were used to measure the product distributions for thermal-energy charge-transfer reactions of He(+), Ne(+), and Ar(+) ions with N2, O2, CO, NO, CO2, and N2O. Except for the He(+)-N2 reaction, no molecular ions were formed by thermal-energy charge transfer from He(+) and Ne(+) with these target molecules. The propensity for dissociative ionization channels in these highly exothermic charge-transfer reactions at thermal energies contrasts with the propensity for formation of parent molecular ions observed in photoionization experiments and in high-energy charge-transfer processes. This difference is explained in terms of more stringent requirements for energy resonance and favorable Franck-Condon factors at thermal ion velocities.

Anicich, V. G.↗

Discovery of polarized light scattered by dust around Alpha Orionis

Following the suggestion by Jura and Jacoby (1976), linearly polarized blue continuum starlight scattered by the dust shell around the M2 Iab star Alpha Orionis (Betelgeuse) has been discovered. The polarization has been traced in the NE, NW, SE, and SW directions and has positive (tangential) orientation. Some asymmetry of the optical depth in the shell exists 15 and 30 arcsec from the star. In the NE direction the polarization was measured as far as 90 arcsec (17,000 AU) from the star. The dependence of the average intensity of the scattered light from the nebula on angular distance from the star is more consistent with an inverse-square density law than with inverse 1.5 or inverse-cube laws. Assuming that the density is proportional to the inverse square of distance from the star, the scattering optical depth in blue light along a radius of 0.03 arcsec is no more than 0.15 + or - 0.05. Future observations of the wavelength dependence of polarization will allow a determination of grain size.

Mcmillan, R. S.↗

Classification and generation of terrestrial rare gases

A Kr-84/Xe-130 versus Ne-20/Ar-36 diagram is a very useful format with which to study the elemental ratios of rare gases from terrestrial materials. It can separate not only the three types of rare gases which Ozima and Alexander (1976) classified but also the 'planetary' type rare gases from the other three types of rare gases. When all the available terrestrial rare gas data are plotted in a Kr-84/Xe-130 versus Ne-20/Ar-36 diagram, several observations can be made. First, most of the analyses of rare gases from shales yield Kr-84/Xe-130 ratios between the 'planetary' and atmospheric values. If, however, the atmosphere's high Kr-84/Xe-130 ratio was produced by the selective adsorption of xenon onto shales from an initially 'planetary' atmosphere, as is widely accepted, then the Kr-84/Xe-130 ratio in shales should be even lower than the 'planetary' value. Second, the rare gas pattern in the quenched rims of submarine basalts may be explained as fractionated samples of the rare gases in sea water.

Saito, K.↗

Thermal metamorphism of primitive meteorites. VIII - Noble gases, carbon and sulfur in Allende /C3/ meteorite heated at 400-1000 C

Noble gases, C and S, are lost from Allende samples heated for 1 week at temperatures of 400-1000 C in a low pressure environment. In the extreme, losses of He-3 and He-4 are about 100 x while for C, S and Ne, Ar and Kr isotopes and Xe-132 these are less than or equal to 10 x. Except for He, these losses are less severe than those of Bi or Tl from samples heated in the same runs. Significant He, Ne and Ar isotopic fractionation during heating indicates preferential outgassing of specific reservoirs. Next to He, Ar-40 is the most labile of those species considered here but still less so than Bi or Tl. L-group (but not H- or LL-group) chondrites may have lost mobile elements like Tl while being outgassed after late impact-associated heating. A less likely alternative involving a collateral relation between condensation conditions and depth in a parent object may also explain the L-group trend.

Herzog, G. F.↗

The isotopic composition of solar flare accelerated neon

The individual isotopes of neon in energetic solar-flare particles have been clearly resolved with a rms mass resolution of 0.20 amu. The ratios found are Ne-20/Ne-22 = 7.6 (+2.0, -1.8) and Ne-21/Ne-22 of no more than about 0.11 in the 11-26 MeV per nucleon interval. This isotopic composition is essentially the same as that of meteoritic planetary neon-A and is significantly different from that of the solar wind.

Mewaldt, R. A.↗

Fine-structure lines and elemental abundances in the Orion Nebula

Infrared observations of the forbidden fine-structure lines of Ne II at 12.81 microns, S IV at 10.51 microns, and Ar III at 8.99 microns in the Orion Nebula are presented. These measurements are combined with optical observations of forbidden Ne III, S II, S III, O II, and O III to derive total elemental abundances of neon, sulfur, and oxygen, Ne/H = 7.91, S/H = 7.34, and O/H = 8.60, which are very similar to solar abundances. While the commonly employed ionization correction formula scheme is found to work satisfactorily for neon, the method overcompensates for the abundance of S(3+) and leads to a higher sulfur abundance than is actually present, though the net discrepancy in the elemental abundance of sulfur in Orion is small.

Lester, D. F.↗

University of Florida nuclear pumped laser program

The mechanism of excitation of laser gases by fast ions (triton, proton, or fission fragments) and especially any role UF6 might play in radiative deexcitation of these gases were investigated. Population densities of excited important for laser action were obtained. Nuclear pumped CW-laser systems, especially He-Ne and CO2, were studied using steady state reactors. It was demonstrated that He-Ne lases in a CW-mode with nuclear pumping at both the red and the infrared transition. The infrared transition was observed to be superradiant.

Richard T. Schneider↗

Satellite measurements of the isotopic composition of galactic cosmic rays

The individual isotopes of galactic cosmic ray Ne, Mg, and Si at 100 MeV/nucleon were clearly resolved with an rms mass resolution of 0.20 amu. The results suggest the cosmic ray source is enriched in Ne-22, Mg-25, and Mg-26 when compared to the solar system. The ratio of (Mg-25)+(Mg-26) to Mg-24, which is approximately 0.49 compared to the solar system value of 0.27, suggest that the cosmic ray source and solar system material were synthesized under different conditions.

Mewaldt, R. A.↗

A process of stellar nucleosynthesis which mimicks mass fractionation in P-xenon

The combination of the O-shell theory of Heymann and Dziczkaniec and the supernova theory of Woosley and Howard clearly identifies the astrophysical sites for the formation of the anomalous light Xe component in carbonaceous chondrites. These sites are the O- and Ne-shells, and possibly C-shell of a massive star. Most of the Xe-124 and Xe-126 are formed in the O-shell during hydrostatic core silicon-burning, when a seed of heavy nuclei is exposed to an effective temperature near T9 = 2.0. Xe-128 is formed via Ba-128 in the O-shell, but the amounts appear too small to satisfy the deduced Xe-128/Xe-124 and Xe-128/Xe-126 yield ratios from the chondrites. However, substantial amounts of Xe-128 can be formed in the adjacent Ne- and C-shells during the explosion. The formation of Ba-128 in the O-shell would increase if the (gamma, alpha) photodisintegration rate in Ba-128 is actually smaller than calculated by Woosley and Howard. Lewis et al. have proposed that the anomalous light Xe component is mass-fractionated normal Xe. It is in this sense that the process of stellar nucleosynthesis of the present paper mimicks mass-fractionation.

Heymann, D.↗

CNO isotope production in nova outbursts

A current model of novae is presented which explains their outbursts assuming that the progenitor of a common nova is a carbon-oxygen dwarf. This white dwarf accretes H-rich material from its companion which produces strong shock waves at its surface; as the amount of accreted material increases later, its bottom ignites. The nova outburst is then triggered by CNO-Ne reactions which favor the formation of rare isotopes with proton-rich radioactive parents such as C-13, N-15, O-17, and Ne-21. The production of such nuclear species is examined in different nova models, and conclusions are drawn concerning the importance of novae in models of chemical evolution of the galaxy.

Audouze, J.↗

The carbon abundance in two h 2 regions of the small Megallanic Cloud

Observations of the ultraviolet spectra of two locations in the H II region NGC 346 and of the entire H II region IC 1644 in the Small Magellanic Cloud (SMC) were made using the International Ultraviolet Explorer (IUE) satellite. The abundance of carbon in the nebulae was derived using theoretical model analysis combined with ground-based spectrophotometry of other emission lines. The abundance of C relative to H in the SMC was found to be lower by -0.9 dex compared with the Sun and lower by -0.8 dex compared with the Orion Nebula. This C deficiency is similar to that of O, Ne, S, and Ar in the SMC, but not as great as found for N. The sites and history of C nucleosynthesis in galaxies is similar to that of O, Ne, S, and Ar, in contrast to that of N, which appears to be more complex, perhaps because of a mixture of secondary primary sources or a significant contribution from intermediate-mass long-lived stars.

Dufour, R. J.↗

Satellite measurements of the isotopic composition of galactic cosmic rays

The individual isotopes of galactic cosmic ray Ne, Mg, and Si at about 100 MeV/nucleon have been resolved with an rms mass resolution of about 0.20 amu. The results suggest that the cosmic ray source is enriched in Ne-22, Mg-25, and Mg-26 when compared to the solar system. It is suggested that the cosmic ray source and solar system material were synthesized under different conditions.

Mewaldt, R. A.↗

Cosmic ray exposure ages of chondrites, pre-irradiation and constancy of cosmic ray flux in the past

Calibration of the production rate of the Ne-21 nuclide was accomplished by 4 methods based on (Al-26)-age, (Mn-53)-age, Kr-81/Kr-83, and Na-22/Ne-22. These production rates are normalized to a shielding parameter ratio Ne-22/Ne-21 = 1.11 and to the chemical composition of L chondrites; a value of P(21)(1.11) = 0.31 is suggested, and a production rate equation derived in terms of the 'F' parameters for L, LL, and H chondrites. The Al-26 half-life measurements are considered to evaluate the effects resulting from preirradiation of meteorites and to examine the data on the constancy of the cosmic ray flux in the light of current astronomical observations.

Nishizumi, K.↗

Isotopic anomalies in the galactic cosmic-ray source

Observations of the isotopic compositions of oxygen, neon and magnesium nuclei in galactic cosmic rays are presented and discussed in terms of nucleosynthesis at the galactic cosmic ray source. The observations, made with a charged-particle telescope carried aboard ISEE-3, show enhancements in the Ne-22/Ne-20, Mg-25/Mg-24 and Mg-26/Mg-24 ratios with respect to solar system abundances by factors of 4.1, 1.6 and 1.6, respectively. The data thus demonstrate that the galactic cosmic ray source is compositionally distinct from the solar system, and also rule out the models of Woolsey and Weaver (in press) for the synthesis of excess Ne-22 and a model of normal star formation, evolution and mass loss in a region enriched in metals.

Wiedenbeck, M. E.↗

Analysis of solar X-ray emission line profiles

The high spatial and spectral resolution solar X-ray observations of an active region in which an X-ray and radio gradual rise and fall was in progress are reported. The correlations of highly collimated X-ray scans with the magnetic data indicate the presence of a hot localized region of X-ray emission near the end of the magnetic neutral line. A thermal interpretation of the continuum observed from this region is consistent with an emission temperature of 3 x 10 to the 48th/cu cm and an electron temperature of 10 to the 7th K. A model of the temperature distribution of the X-ray emitting material within the collimator field of view is derived using the resonance lines of Ne X, Ne IX, and Fe XVII. Most of the emission measure is at temperatures less than 2,000,000 K, but some high-temperature material with an electron temperature between 5,000,000 K and 7,000,000 K is required.

Burek, A. J.↗

Development of critical molecular weight-property specifications for high performance polymers used as adhesives and composites

The polyimide resin, LARC-160, was prepared from diethyl-3, 3', 4,4'-benzophenone tetracarboxylate, ethyl-5-norbornene-2,3-dicarboxylate and Jeffamine AP-22. The imidization reactions of NE and BTDE were studied by HPLC, C-13-NMR and IR. NE imidizes slowly at 12 C; BTDE imidizes when the resin is heated above 100 C. Both imidization reactions proceed directly to the imide. Neither amic acid is present in significant quantities at any stage of the imidization reactions. The monomer mixture was stored at 12 C for periods up to 14 months. The effects of resin aging at this temperature on the chemical composition of the resin monomer mixture and the imidized polymer formed on curing were investigated. Aging the resin monomer mixture has the effect of partially advancing the imidization reaction. The average size of the cured polymer increases slightly with resin age.

Kranbuehl, D. E.↗

IUE observations of the 1981 outburst of nova Cr A

Low dispersion spectrum observations are analyzed. The light curve of nova Cr A, indicating a moderately fast nova, is presented. Flux calibrated, merged spectrum graphs of April 21, 1981 and September 13, 1981 are presented, demonstrating very strong lines of Al and Si. Additional strong C, Ni, O, and Ne emission lines were identified. Emission lines due to highly ionized species such as Mg VII and Al Vl were observed for short times in May and June 1981. Preliminary analysis of spectra obtained 200 days after maximum indicate that the nebula is still in transition and has not yet reached the nebula state. An over abundance of N and Ne are suggested.

Sparks, W. M.↗

The abundances of neon, sulfur, and argon in planetary nebulae

New infrared observations of Ne II, Ar III, and S IV are used in optical observations of other ionization states of the considered elements to evaluate the abundances of neon, argon, and sulfur in 18 planetary nebulae. Attention is also given to one or more of the infrared lines in 18 other nebulae. It is pointed out that S IV was detected in approximately 90% of the observed objects, while Ar III was found in about 80%, and Ne II in roughly one-third. It is noted that optical observations typically include only a limited region of the nebula, while the infrared measurements frequently involve integration over the entire nebular image.

Beck, S. C.↗