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At least 415 records · Page 23

Bursting Bubbles from Combustion of Thermoplastic Materials in Microgravity

Many thermoplastic materials in common use for a wide range of applications, including spacecraft, develop bubbles internally as they burn due to chemical reactions taking place within the bulk. These bubbles grow and migrate until they burst at the surface, forceably ejecting volatile gases and, occasionally, molten fuel. In experiments in normal gravity, Kashiwagi and Ohlemiller observed vapor jets extending a few centimeters from the surface of a radiatively heated polymethylmethacrylate (PMMA) sample, with some molten material ejected into the gas phase. These physical phenomena complicated the combustion process considerably. In addition to the non-steady release of volatiles, the depth of the surface layer affected by oxygen was increased, attributed to the roughening of the surface by bursting events. The ejection of burning droplets in random directions presents a potential fire hazard unique to microgravity. In microgravity combustion experiments on nylon Velcro fasteners and on polyethylene wire insulation, the presence of bursting fuel vapor bubbles was associated with the ejection of small particles of molten fuel as well as pulsations of the flame. For the nylon fasteners, particle velocities were higher than 30 cm/sec. The droplets burned robustly until all fuel was consumed, demonstrating the potential for the spread of fire in random directions over an extended distance. The sequence of events for a bursting bubble has been photographed by Newitt et al.. As the bubble reaches the fluid surface, the outer surface forms a dome while the internal bubble pressure maintains a depression at the inner interface. Liquid drains from the dome until it breaks into a cloud of droplets on the order of a few microns in size. The bubble gases are released rapidly, generating vortices in the quiescent surroundings and transporting the tiny droplets. The depression left by the escaping gases collapses into a central jet, which rises with a high velocity and may break up, releasing one or more relatively large drops (on the order of a millimeter in these experiments). A better understanding of bubble development and bursting processes, the effects of bursting behavior on burning rate of the bulk material, and the circumstances under which large droplets are expelled, as well as their trajectories, sizes, and burning rates, is sought through computer modeling compared with experiment.

Butler, K. B.↗

Flightweight Carbon Nanotube Magnet Technology

Virtually all plasma-based systems for advanced airborne/spaceborne propulsion and power depend upon the future availability of flightweight magnet technology. Unfortunately, current technology for resistive and superconducting magnets yields system weights that tend to counteract the performance advantages normally associated with advanced plasma-based concepts. The ongoing nanotechnology revolution and the continuing development of carbon nanotubes (CNT), however, may ultimately relieve this limitation in the near future. Projections based on recent research indicate that CNTs may achieve current densities at least three orders of magnitude larger than known superconductors and mechanical strength two orders of magnitude larger than steel. In fact, some published work suggests that CNTs are superconductors. Such attributes imply a dramatic increase in magnet performance-to-weight ratio and offer real hope for the construction of true flightweight magnets. This Technical Publication reviews the technology status of CNTs with respect to potential magnet applications and discusses potential techniques for using CNT wires and ropes as a winding material and as an integral component of the containment structure. The technology shortfalls are identified and a research and technology strategy is described that addresses the following major issues: (1) Investigation and verification of mechanical and electrical properties, (2) development of tools for manipulation and fabrication on the nanoscale, (3) continuum/molecular dynamics analysis of nanotube behavior when exposed to practical bending and twisting loads, and (4) exploration of innovative magnet fabrication techniques that exploit the natural attributes of CNTs.

Chapman, J. N.↗

Effects of Thermal and Mechanical Processing on Microstructures and Desired Properties of Particle-Strengthened Cu-Cr-Nb Alloys

Ternary Cu-Cr-Nb alloys, particularly Cu-8 Cr-4 Nb (in at.%), have demonstrated good thermal stability as well as high strength and conductivity at elevated temperatures. The initial powder material has a bimodal size distribution of Cr2Nb precipitates. Primary Cr2Nb precipitates are approx. 1 micron, and secondary Cr2Nb particles are 30-200 nm. The particle coarsening was analyzed and found to follow LSW-type behavior, This study provides a detailed examination of the stability and strengthening effects of Cr2Nb particles. This investigation also revealed that the primary particles provide direct grain boundary pinning and indirect grain boundary strengthening but virtually no Orowan strengthening. The secondary particles found within grains do provide Orowan strengthening. For extruded material, grain bound-ary strengthening (Hall-Petch effect) accounts for two-thirds of the strength with Orowan effects contributing the remainder. The proven advantages of Cu-Cr-Nb were the motivation to improve these attributes via microstructural refinement. Mechanical milling (MM) of Cu- 4 Cr-2 Nb and Cu-8 Cr-2 Nb produced an increase in hot pressed Vickers hardness of 122% and 96%, respectively. The increase in hardness was more due to Cu grain-size refinement than to Cr,,Nb refinement. This study also demonstrated enhanced stability of MM Cu-4 Cr-2 Nb. Hot pressed 4 h milled Cu-4 Cr-2 Nb experienced only a 22% drop in hardness when annealed at 1273 K for 50 h versus a 30% drop for extruded Cu-8 Cr-4 Nb. The goal of improving the strength and stability of Cu-4 Cr-2 Nb to better than such properties for as- extruded Cu-8 Cr-4 Nb has been met. In addition, a figure-of-merit (FOM) coupling hardness and thermal conductivity was maximized for the case of 4 h milled Cu-4 Cr-2 Nb material. Overall, Cu-Cr-Nb alloys not only possess high strength, conductivity and thermal stability but also can be further developed to improve strength and stability.

Anderson, Kenneth Reed↗

The influence of man in space observations

The paper evaluates the Skylab missions from the viewpoint of to what extent the presence of men may have been a detriment to scientific observations, either through their movements or through contamination of the spacecraft and instruments. The stability of the instrument canister within the Apollo Telescope Mount was secured by the Experiment Pointing Control System. Angular stability was specified to be within plus or minus 2.5 arc seconds, and was found to be less than 2 arc seconds during normal crew activity. No astronomical observations were reported as being degraded by crew movements. Instrumentation was installed to measure rates of contaminant particle deposition on optical surfaces. Clouds were formed from particles originating in outgassing from vehicle surface materials and from vent apertures. The Coronograph Contamination Measurement Instrument was used to measure the brightness of the induced cloud surrounding Skylab. Preliminary analysis shows no significant degradation of photographic data attributable to contamination.

Hanes, T. E.↗

Evolution of non-condensable gas in ammonia heat pipes

Accumulation of noncondensible gas (NCG) has been observed in ammonia heat pipes. NCG has been found to be detrimental to the performance of heat pipes and can result in complete operational failure. A kinetic and thermodynamic analysis has been performed that evaluates the dissociation of ammonia under various conditions and predicts the amount of NCG present in heat pipes. The analysis indicates that the observed NCG in ammonia heat pipes can be attributed to the dissociation of ammonia into its constituents, hydrogen and nitrogen. It shows time and temperature to be the important parameters, in conjunction with the catalytic characteristic of the container material.

Richter, Robert↗

Thermal stress analysis of a silicon carbide/aluminum composite

Thermal deformations and stresses were studied in a silicon-carbide/aluminum filamentary composite at temperatures up to 370 C (700 F). Longitudinal and transverse thermal strains were measured with strain gages and a dilatometer. An elastoplastic micromechanical analysis based on a one-dimensional rule-of-mixtures model and an axisymmetric two-material composite cylinder model was performed. It was established that beyond a critical temperature thermal strains become nonlinear with decreasing longitudinal and increasing transverse thermal-expansion coefficients. This behavior was attributed to the plastic stresses in the aluminum matrix above the critical temperature. An elastoplastic analysis of both micromechanical models was performed to determine the stress distributions and thermal deformation in the fiber and matrix of the composite. While only axial stresses can be determined by the rule-of-mixtures model, the complete triaxial state of stress is established by the composite cylinder model. Theoretical predictions for the two thermal-expansion coefficients were in satisfactory agreement with experimental results.

Gdoutos, E. E.↗

Magnetized Target Fusion Driven by Plasma Liners

Magnetized target fusion is an emerging, relatively unexplored approach to fusion for electrical power and propulsion application. The physical principles of the concept are founded upon both inertial confinement fusion (ICF) and magnetic confinement fusion (MCF). It attempts to combine the favorable attributes of both these orthogonal approaches to fusion, but at the same time, avoiding the extreme technical challenges of both by exploiting a fusion regime intermediate between them. It uses a material liner to compress, heat and contain the fusion reacting plasma (the target plasma) mentally. By doing so, the fusion burn could be made to occur at plasma densities as high as six orders of magnitude higher than conventional MCF such as tokamak, thus leading to an approximately three orders of magnitude reduction in the plasma energy required for ignition. It also uses a transient magnetic field, compressed to extremely high intensity (100's T to 1000T) in the target plasma, to slow down the heat transport to the liner and to increase the energy deposition of charged-particle fusion products. This has several compounding beneficial effects. It leads to longer energy confinement time compared with conventional ICF without magnetized target, and thus permits the use of much lower plasma density to produce reasonable burn-up fraction. The compounding effects of lower plasma density and the magneto-insulation of the target lead to greatly reduced compressional heating power on the target. The increased energy deposition rate of charged-particle fusion products also helps to lower the energy threshold required for ignition and increasing the burn-up fraction. The reduction in ignition energy and the compressional power compound to lead to reduced system size, mass and R&D cost. It is a fusion approach that has an affordable R&D pathway, and appears attractive for propulsion application in the nearer term.

Thio, Y. C. Francis↗

Visible–near infrared spectral indices for mapping mineralogy and chemistry with OSIRIS-REx

The primary objective of the Origins, Spectral Interpretation, Resource Identification, and Security–Regolith Explorer (OSIRIS-REx) mission is to return to Earth a pristine sample of carbonaceous material from the primitive asteroid (101955) Bennu. To support compositional mapping of Bennu as part of sample site selection and characterization, we tested 95 spectral indices on visible to near infrared laboratory reflectance data from minerals and carbonaceous meteorites. Our aim was to determine which indices reliably identify spectral features of interest. Most spectral indices had high positive detection rates when applied to spectra of pure, single-component materials. The meteorite spectra have fewer and weaker absorption features and, as a result, fewer detections with the spectral indices. Indices targeting absorptions at 0.7 and 2.7–3 µm, which are attributable to hydrated minerals, were most successful for the meteorites. Based on these results, we identified a set of 17 indices that are most likely to be useful at Bennu. These indices detect olivines, pyroxenes, carbonates, water/OH-bearing minerals, serpentines, ferric minerals, and organics. Particle size and albedo are known to affect band depth but had a negligible impact on interpretive success with spectral indices. Preliminary analysis of the disk-integrated Bennu spectrum with these indices is consistent with expectations given the observed absorption near 3 lm. Our study prioritizes spectral indices to be used for OSIRIS-REx spectral analysis and mapping and informs the reliability of all index-derived data products, including a science value map for sample site selection.

Hannah H. Kaplan↗

Constraints on the Composition of Trojan Asteroid 624 Hektor

We present a composite spectrum of Trojan asteroid 624 Hektor, 0.3-3.6 microns, which shows that there is no discernible 3-micron absorption band. Such a band would indicate the presence of OH or H2O- bearing silicate minerals, or macromolecular carbon-rich organic material of the kind seen on the low-albedo hemisphere of Saturn's satellite Iapetus (Owen et al. 2000). The absence of spectral structure is itself indicative of the absence of the nitrogen-rich tholins (which show a distinctive absorption band attributed to N-H). The successful models in this study all incorporate the mineral pyroxene (Mg, Fe SiO3, the composition of hypersthene), which matches the red color of Hektor. Pyroxene is a mafic mineral common in terrestrial and lunar lavas, and is also seen in Main Belt asteroid spectra. An upper limit to the amount of crystalline H20 ice (30-micron grains) in the surface layer of Hektor is 3 weight percent. The upper limit for serpentine, as a representative of hydrous silicates, is much less stringent, at 40 percent, based on the shape of the spectral region around 3 gm. Thus, the spectrum at 3 gm does not preclude the presence of a few weight percent of volatile material in the surface layer of Hektor. All of the models we calculated require elemental carbon to achieve the low geometric albedo that matches Hektor. This carbon could be of organic or inorganic origin. By analogy, other D-type asteroids could achieve their red color, low albedo, and apparent absence of phyllosilicates, from compositions similar to the models presented here.

Cruikshank, Dale P.↗

High temperature condensates among meteors

It is noted that two meteors which exhibited no lines of iron or sodium in their spectra have been tentatively attributed to aubrites in order to explain their lack of iron. It is shown, however, that no meteorites, including aubrites, have simultaneously low abundances of iron and sodium and that possible parent materials other than aubrites must be considered for the observed meteors. Other possible parent materials considered in this letter include melilite and diopside, two minerals containing both Ca and Mg but neither Fe nor Na. It is suggested that meteoroids rich in Ca and Mg but lacking Fe and Na might form a reservoir for the so-called 'lost' elements (Ca, Mg, Al, Ti, the lanthanides, and other refractory elements) which are depleted in ordinary and enstatite chondrites relative to cosmic abundances.

Wilkening, L. L.↗

Changes in geometrical and biomechanical properties of immature male and female rat tibia

The differences in the geometry and mechanical properties of immature male and female rat tibiae were detailed in order to provide comparative data for spaceflight, exercise, or disease experiments that use immature rats as an animal model. The experiment focuses on the particularly rapid period of growth that occurs in the Sprague-Dawley rat between 40 and 60 d of age. Tibial length and middiaphysical cross-sectional data were analyzed for eight different groups of rats according to age and sex, and tibial mechanical properties were obtained via three-point bending tests to failure. Results indicate that, during the 15 d period of rapid growth, changes in rat tibial geometry are more important than changes in bone material properties for influencing the mechanical properties of the tibia. Male tibiae changed primarily in structural properties, while in the female rats major changes in mechanical properties of the tibia were only attributable to changes in the structural properties of the bone.

Zernicke, Ronald F.↗

The role of rifting in the generation of melt: Implications for the origin and evolution of the Lada Terra-Lavinia Planitia region of Venus

A rift over 6000 km in total length runs along the border of Lada Terra, a highland in the southern hemisphere of Venus, and Lavinia Planitia, a basin that has been interpreted as a site of early-stage mantle downwelling. Along the length of the rift are a number of volcanic centers of widely varying morphology and volcanic output. These include coronae, radially fractured domes, and large flow fields similar in scale to terrestrial flood basalts. We develop a model for the origin of extension related to passive rifting in response to stresses created by the adjacent downwelling. Volcanism and extension at other rifts on Venus, such as Devana Chasma, have been attributed to deep-seated mantle plume activity. In contrast, we interpret the origin of extension and volcanism along the Lada rift to be linked to upwelling and decompression melting of mantle material due to rifting and, possibly, to counterflow associated with downwelling. Extension occurred generally prior to the formation of volcanic centers and the eruption of large-scale flow fields, although most of the volcanic centers have been fractured by continued extension along the rift. Current debate over the formation of terrestrial flood basalts centers on the necessity of preexisting extension and stretched and thinned lithosphere to produce enhanced decompression melting within a large plume head or mantle thermal anomaly. Our studies of large-scale flow fields associated with the Lada rift and coronae on Venus indicate that extension is a prerequisite for the formation of the majority of large-scale flow units on Venus.

Magee, Kari P.↗

Striations, Polish, and Related Features from Clasts in Impact-Ejecta Deposits and the "Tillite Problem"

Proximal ejecta deposits related to three large terrestrial impacts, the 14.8-Ma Ries impact structure in Germany (the Bunte Breccia), the 65-Ma Chicxulub impact structure in the Yucatan (the Albion and Pook's Hill Diamictites in Belize) and the mid-Tertiary Azuara impact structure in Spain (the Pelarda Fm.) occur in the form of widespread debris-flow deposits most likely originating from ballistic processes. These impact-related diamictites typically are poorly sorted, containing grain sizes from clay to large boulders and blocks, and commonly display evidence of mass flow, including preferred orientation of long axes of clasts, class imbrication, flow noses, plugs and pods of coarse debris, and internal shear planes. Clasts of various lithologies show faceting, various degrees of rounding, striations (including nailhead striae), crescentic chattermarks, mirror-like polish, percussion marks, pitting, and penetration features. Considering the impact history of the Earth, it is surprising that so few ballistic ejecta, deposits have been discovered, unless the preservation potential is extremely low, or such materials exist but have been overlooked or misidentified as other types of geologic deposits . Debris-flow diamictites of various kinds have been reported in the geologic record, but these are commonly attributed to glaciation based on the coarse and poorly sorted nature of the deposits and, in many cases, on the presence of clasts showing features considered diagnostic of glacial action, including striations of various kinds, polish, and pitting. These diamictites are the primary evidence for ancient ice ages. We present evidence of the surface features on clasts from known proximal ejecta debris-flow deposits and compare these features with those reported in diamictites. interpreted as ancient glacial deposits (tillites). Our purpose is to document the types of features seen on clasts in diamictites of ejecta origin in order to help in the interpretation of the origin of ancient diamictites. The recognition of characteristic features in clast populations in ancient diamictites may allow identification and discrimination of debris-flow deposits of various origins (e.g., impact glacial, tectonic) and may shed light on some climatic paradoxes, such as inferred Proterozoic glaciations at low paleolatitudes.

Rampino, M. R.↗

Negative Searches for Evidence of Aqueous Alteration on Asteroid Surfaces

Small bodies in the Solar System preserve evidence of the processes occurring during early Solar System formation, unlike the larger planets that undergo continuous churning of their surfaces. We study these bodies to understand what processes affected different stages of Solar System formation. The action of aqueous alteration (the alteration of material by the interaction of that material with liquid formed by the melting of incorporated ice) of near-subsurface material has been inferred to occur on many asteroids based on the spectrophotometric evidence of phyllosilicates and iron alteration minerals. The definitive indication of aqueous alteration is the 3.0- micron absorption feature attributed to structural hydroxyl (OH) and interlayer and adsorbed water (H2O) in phyllosilicates (clays) (hereafter water of hydration). A weak absorption feature centered near 0.7 microns attributed to an Fe (2+) right arrow Fe (3+) charge transfer transition in oxidized iron in phyllosilicates has been observed in the reflectance spectra and photometry of approximately 50% of the main-belt C-class asteroids. An approximately 85% correlation between this 0.7- micron feature and the 3.0- micron water of hydration absorption feature was found among the low-albedo asteroids. The feature is usually centered near 0.68 microns in asteroid spectra, and ranges in wavelength from approximately 0.57 to 0.83 microns. Serendipitously, three of the Eight Color Asteroid Survey filters the v (0.550 microns), w (0.701 microns), and x (0.853 microns)-bracket this feature well, and can be used to determine the presence of this feature in the reflectance properties of an asteroid, and probe the aqueous alteration history of larger samples of asteroid data. Two efforts to search for evidence of aqueous alteration based on the presence of this 0.7- micron absorption feature are presented here.

Vilas, F.↗

Flywheels Upgraded for Systems Research

With the advent of high-strength composite materials and microelectronics, flywheels are becoming attractive as a means of storing electrical energy. In addition to the high energy density that flywheels provide, other advantages over conventional electrochemical batteries include long life, high reliability, high efficiency, greater operational flexibility, and higher depths of discharge. High pulse energy is another capability that flywheels can provide. These attributes are favorable for satellites as well as terrestrial energy storage applications. In addition to energy storage for satellites, the several flywheels operating concurrently can provide attitude control, thus combine two functions into one system. This translates into significant weight savings. The NASA Glenn Research Center is involved in the development of this technology for space and terrestrial applications. Glenn is well suited for this research because of its world-class expertise in power electronics design, rotor dynamics, composite material research, magnetic bearings, and motor design and control. Several Glenn organizations are working together on this program. The Structural Mechanics and Dynamics Branch is providing magnetic bearing, controls, and mechanical engineering skills. It is working with the Electrical Systems Development Branch, which has expertise in motors and generators, controls, and avionics systems. Facility support is being provided by the Space Electronic Test Engineering Branch, and the program is being managed by the Space Flight Project Branch. NASA is funding an Aerospace Flywheel Technology Development Program to design, fabricate, and test the Attitude Control/Energy Storage Experiment (ACESE). Two flywheels will be integrated onto a single power bus and run simultaneously to demonstrate a combined energy storage and 1-degree-of-freedom momentum control system. An algorithm that independently regulates direct-current bus voltage and net torque output will be experimentally demonstrated.

Jansen, Ralph H.↗

A sensitive time-resolved radiation pyrometer for shock-temperature measurements above 1500 K

The general design, calibration, and performance of a new high-sensitivity radiation pyrometer are described. The pyrometer can determine time-resolved temperatures (as low as 1500 K) in shocked materials by measuring the spectral radiance of light emitted from shocked solid samples in the visible and near-infrared wavelength range (0.5-1.0 micron). The high sensitivity of the radiation pyrometer is attributed to the large angular aperture (0.06 sr), the large bandwidth per channel (up to 0.1 micron), the large photodiode detection areas (1.0 sq cm), and the small number of calibrated channels (4) among which light is divided.

Boslough, Mark B.↗

Organic Combustion in the Presence of Ca-Carbonate and Mg-Perchlorate: A Possible Source for the Low Temperature CO2 Release Seen in Mars Phoenix Thermal and Evolved Gas Analyzer Data

Two of the most important discoveries of the Phoenix Lander were the detection of approx.0.6% perchlorate [1] and 3-5% carbonate [2] in landing site soils. The Thermal and Evolved Gas Analyzer (TEGA) instrument on the Phoenix lander could heat samples up to approx.1000 C and monitor evolved gases with a mass spectrometer. TEGA detected a low (approx.350 C) and high (approx.750 C) temperature CO2 release. The high temp release was attributed to the thermal decomposition of Ca-carbonate (calcite). The low temperature CO2 release could be due to desorption of CO2, decomposition of a different carbonate mineral, or the combustion of organic material. A new hypothesis has also been proposed that the low temperature CO2 release could be due to the early breakdown of calcite in the presence of the decomposition products of certain perchlorate salts [3]. We have investigated whether or not this new hypothesis is also compatible with organic combustion. Magnesium perchlorate is stable as Mg(ClO4)2-6H2O on the martian surface [4]. During thermal decomposition, this perchlorate salt releases H2O, Cl2, and O2 gases. The Cl2 can react with water to form HCl which then reacts with calcite, releasing CO2 below the standard thermal decomposition temperature of calcite. However, when using concentrations of perchlorate and calcite similar to what was detected by Phoenix, the ratio of high:low temperature CO2 evolved is much larger in the lab, indicating that although this process might contribute to the low temp CO2 release, it cannot account for all of it. While H2O and Cl2 cause calcite decomposition, the O2 evolved during perchlorate decomposition can lead to the combustion of any reduced carbon present in the sample [5]. We investigate the possible contribution of organic molecules to the low temperature CO2 release seen on Mars.

Archer, Douglas↗

Multifunctional Structures for High-Energy Lightweight Load-Bearing Storage

The Multifunctional Structures for High Energy Lightweight Load-bearing Storage (M-SHELLS) subproject is evaluating the feasibility of a structural hybrid super-capacitor concept, drawn from recent nano-technology advances in both electrochemistry and microstructures to create a transformative multi-functional airframe material which carries structural load and stores energy to save weight and enable electric aero propulsion. Multi-disciplinary engineering approach assures high energy storage and power levels, as well as good mechanical attributes.

Loyselle, Patricia↗