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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 415 records · Page 23
All sourcesNASA NTRSDOE OSTI
DOE OSTI2012

Synthesis and characterization of a PbO{sub 2}-clay nanocomposite: Removal of lead from water using montmorillonite

Graphical abstract: The replacement of Na by Pb in the interlayer space of the smectite leads to a decrease in the intensity of the the (0 0 1) reflection as the concentration of lead nitrate increases. A significant restructuring at the particle scale is observed leading probably to the exfoliation of the caly. In addition, the thermal behaviour of the montmorillonite samples with regard to their dehydration and dehydroxilation capacities is significantly influenced. This leads to a lowering of the water content and a decrease in the ionic conductivity of the clay. Highlights: Black-Right-Pointing-Pointer In the clay, Pb replaces Na ions and a significant restructuring at the particle scale is observed. Black-Right-Pointing-Pointer Pb influenced significantly the thermal behaviour of the clay with regard to its dehydration. Black-Right-Pointing-Pointer In the interlayer space, the exchange of Na by Pb leads to a decrease in the protonic conductivity. Black-Right-Pointing-Pointer A PbO{sub 2}-clay nanocomposite material with good conductivity is synthesized. -- Abstract: The aim of this paper is to present the results obtained with Pb(II) sorption on an Algerian Clay. The experiments were carried out using a batch process. Powder X-rays diffraction patterns (PXRD) prove that in the montmorillonite Pb replaces Na ions. A significant restructuring at the particle scale is observed leading to the disappearance of the d{sub 001} reflection of the clay at high concentrations of lead. The replacement of hydrated Na with Pb ions influenced significantly the thermal behaviour of the montmorillonite samples with regard to their dehydration and dehydroxilation capacities with a lowering of the water content. A PbO{sub 2}-clay composite material with good electrical conductivity is synthesized.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2017

Use of multiple tools including lead isotopes to decipher sources of ozone and reactive mercury to urban and rural locations in Nevada, USA

Ambient air particulate matter (< 2.5 μm in diameter) samples were collected on two different filter types in 2014 and 2015 over 24 h periods and analyzed for reactive mercury (gaseous oxidized mercury + particulate bound mercury) concentrations and lead isotopes to determine sources of pollution to three sites in Nevada, USA. Two sites were located on the western edge of Nevada (Reno, urban, 1370 m and Peavine Peak, rural, high elevation, 2515 m); the third location was ~ 485 km east in rural Great Basin National Park, NV (2061 m). Reactive mercury samples were collected on cation exchange membranes simultaneously with lead samples, collected on Teflon membranes. Lead isotopic ratios have previously identified trans-Pacific lead sources based on the 206/207 and 208/207 lead ratios. Influence from trans-Pacific air masses was higher from March to June associated with long-range transport of pollutants. Spring months are well known for increased transport across the Pacific; however, fall months were also influenced by trans-Pacific air masses in this study. Western North American background ozone concentrations have been measured and modeled at 50 to 55 ppbv. Median ozone concentrations at both rural sites in Nevada were within this range. Sources leading to enhancements in ozone of 2 to 18 ppbv above monthly medians in Nevada included emissions from Eurasia, regional urban centers, and global and regional wildfires, resulting in concentrations close to the USA air quality standard. At the high elevation locations, ozone was derived from pollutants being transported in the free troposphere that originate around the globe; however, Eurasia and Asia were dominant sources to the Western USA. Negative correlations between reactive mercury and percent Asian lead, Northern Eurasia and East Asia trajectories indicated reactive mercury concentrations at the two high elevation sites were produced by oxidants from local, regional, and marine boundary layer sources.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2014

Non-equilibrium Green's functions method: Non-trivial and disordered leads

The non-equilibrium Green's function algorithm requires contact self-energies to model charge injection and extraction. All existing approaches assume infinitely periodic leads attached to a possibly quite complex device. This contradicts today's realistic devices in which contacts are spatially inhomogeneous, chemically disordered, and impacting the overall device characteristics. This work extends the complex absorbing potentials method for arbitrary, ideal, or non-ideal leads in atomistic tight binding representation. The algorithm is demonstrated on a Si nanowire with periodic leads, a graphene nanoribbon with trumpet shape leads, and devices with leads of randomly alloyed Si{sub 0.5}Ge{sub 0.5}. It is found that alloy randomness in the leads can reduce the predicted ON-state current of Si{sub 0.5}Ge{sub 0.5} transistors by 45% compared to conventional lead methods.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2020

Measurements of the Flow in the Vicinity of an Additively Manufactured Turbine Leading-Edge Using X-Ray Particle Tracking Velocimetry

X-ray particle tracking velocimetry (PTV) is performed, for the first time, to measure the velocity field inside a leading-edge of a turbine blade made by laser-additive-manufacturing (LAM) process. The traditional showerhead holes were replaced by a porous matrix in the leading-edge. The flow through such a leading-edge piece cannot be faithfully recreated by traditional prototype testing methods due to the surface roughness and imperfections caused by LAM process. Hence, direct measurement is the only option. However, it is difficult to measure flow inside such pieces with traditional velocimetry measurements due to the existence of metallic walls. Moreover, small internal size and high flow speeds call for a measurement technique with high spatial and temporal resolutions. To address these issues, we performed time-resolved X-ray PTV using the Advanced Photon Source (APS) synchrotron facility at the Argonne National Laboratory (ANL). A hydraulic system was constructed to run water, mixed with seeding particles, through the leading-edge piece. A high-speed camera captured the images of the seeding particles, which were later processed to create particle tracks. The time-averaged velocity field showed distinct pairs of vortices located in front of the porous outlet inside the leading-edge piece. The inlet channel showed reversed flow due to partial obstruction by the porous inlet of the test piece. Such knowledge of the flow field inside a leading-edge of a turbine blade will help us to design better cooling paths leading to higher cooling efficiency and increased life-span of a turbine blade.

42 ENGINEERING↗
NASA NTRS1973

Integrated circuit package with lead structure and method of preparing the same

A beam-lead integrated circuit package assembly including a beam-lead integrated circuit chip, a lead frame array bonded to projecting fingers of the chip, a rubber potting compound disposed around the chip, and an encapsulating molded plastic is described. The lead frame array is prepared by photographically printing a lead pattern on a base metal sheet, selectively etching to remove metal between leads, and plating with gold. Joining of the chip to the lead frame array is carried out by thermocompression bonding of mating goldplated surfaces. A small amount of silicone rubber is then applied to cover the chip and bonded joints, and the package is encapsulated with epoxy resin, applied by molding.

Kennedy, B. W.↗
NASA NTRS1973

Lead: Aspects of its ecology and environmental toxicity

An analysis of lead toxicity in the Hawaiian environment was conducted. It was determined that lead enters the environment as an industrial contaminant resulting from the combustion of leaded gasoline. The amount of lead absorbed by the plants in various parts of the Hawaiian Islands is reported. The disposition of lead in the sediments of canals and yacht basins was investigated. The methods for conducting the surveys of lead content are described. Possible consequences of continued environmental pollution by burning leaded gasoline are discussed.

Siegel, S. M.↗
NASA NTRS1975

Flow visualization of leading-edge vortex enhancement by spanwise blowing

Flow visualization studies were conducted in a small pilot wind tunnel to determine qualitative effects of blowing a discrete jet essentially parallel to the leading edge of a 45 deg-swept trapezoidal wing featuring leading- and trailing-edge flaps. Test parameters included wing angle-of-attack, jet momentum coefficient, leading- and trailing-edge flap deflections, and nozzle chordwise displacement. Results of this study indicate that blowing from a reflection plane over the wing enhances the leading-edge vortex and delays vortex bursting to higher angles-of-attack and greater span distances. Increased blowing rates decrease vortex size, growth rate, and vertical displacement above the wing surface at a given span station and also extend the spanwise effectiveness of lateral blowing. Deflection of a leading-edge flap delays the beneficial effects of spanwise blowing to higher angles-of-attack. Nozzle chordwise locations investigated for the wing with and without leading-edge flap deflection appear equally effective in enhancing the separated leading-edge flow.

Erickson, G. E.↗
NASA NTRS1975

Low-heat-leak current leads for intermittent use

The paper reports on the development of current leads for an orbiting superconducting magnetic spectrometer that were required to achieve a zero-current heat leak of 0.03 W with a total coolant flow rate as low as 0.011 g/sec cooling only the coldest third of the length of a lead. Analysis of heat flow phenomena in an insulated current lead in thermal contact with cryogenic gas flow is given for prediction of lead performance. A basic lead design was then tested and modified by such techniques as tapering, adding superconducting sections, and operating above the optimum current, until a lead satisfying the low-leak requirements was obtained. Operating the insulated leads at well above their optimum current for short periods at high mass flow is possible, and instability behavior is predictable.

Smoot, G. F.↗
NASA NTRS1982

Shaping Transistor Leads for Better Solder Joints

Special lead-forming tool puts step in leads of microwave power transistors without damaging braze joints that fasten leads to package. Stepped leads are soldered to circuit boards more reliably than straight leads, and stress on brazes is relieved. Lead-forming hand-tool has two parts: a forming die and an actuator. Spring-loaded saddle is adjusted so that when transistor package is placed on it, leads rest on forming rails.

Mandel, H.↗
NASA NTRS1984

A method for computing the leading-edge suction in a higher-order panel method

Experimental data show that the phenomenon of a separation induced leading edge vortex is influenced by the wing thickness and the shape of the leading edge. Both thickness and leading edge shape (rounded rather than point) delay the formation of a vortex. Existing computer programs used to predict the effect of a leading edge vortex do not include a procedure for determining whether or not a vortex actually exists. Studies under NASA Contract NAS1-15678 have shown that the vortex development can be predicted by using the relationship between the leading edge suction coefficient and the parabolic nose drag. The linear theory FLEXSTAB was used to calculate the leading edge suction coefficient. This report describes the development of a method for calculating leading edge suction using the capabilities of the higher order panel methods (exact boundary conditions). For a two dimensional case, numerical methods were developed using the double strength and downwash distribution along the chord. A Gaussian quadrature formula that directly incorporates the logarithmic singularity in the downwash distribution, at all panel edges, was found to be the best method.

Ehlers, F. E.↗
NASA NTRS1984

The influence of leading-edge load alleviation on supersonic wing design

A theoretical and experimental program to assess the effect of leading-edge load constraints on wing design and performance was conducted. For a planform characterized by a highly swept leading edge on the inboard region, linear theory was used to design camber surfaces which produced minimum drag-due-to-lift at the design lift coefficient of 0.08 and a design Mach number of 2.4. In an effort to delay the formation of leading edge vortices which often occur on highly swept wings, two approaches were used in the design criteria to limit the loadings on the leading edge. One wing was constrained to have the normal Mach number less than one everywhere along the leading edge and the second wing was constrained to have a pressure coefficient of zero on the leading edge. Force tests were run on the two constrained wings, on a flat reference wing and on an optimized wing with no leading edge constraints. All wings had identical planforms and thicknesses and were tested over a range of Mach numbers from 1.8 to 2.8 and a range in angles of attack from -5 deg to 8 deg. A comparison of the experimental performance of these four models is shown. Correlations of these results with theoretical predictions and flow visualization photographs are also included.

Darden, C. M.↗
NASA NTRS1986

Computation of leading-edge vortex flows

The simulation of the leading edge vortex flow about a series of conical delta wings through solution of the Navier-Stokes and Euler equations is studied. The occurrence, the validity, and the usefulness of separated flow solutions to the Euler equations of particular interest. Central and upwind difference solutions to the governing equations are compared for a series of cross sectional shapes, including both rounded and sharp tip geometries. For the rounded leading edge and the flight condition considered, viscous solutions obtained with either central or upwind difference methods predict the classic structure of vortical flow over a highly swept delta wing. Predicted features include the primary vortex due to leading edge separation and the secondary vortex due to crossflow separation. Central difference solutions to the Euler equations show a marked sensitivity to grid refinement. On a coarse grid, the flow separates due to numerical error and a primary vortex which resembles that of the viscous solution is predicted. In contrast, the upwind difference solutions to the Euler equations predict attached flow even for first-order solutions on coarse grids. On a sufficiently fine grid, both methods agree closely and correctly predict a shock-curvature-induced inviscid separation near the leeward plane of symmetry. Upwind difference solutions to the Navier-Stokes and Euler equations are presented for two sharp leading edge geometries. The viscous solutions are quite similar to the rounded leading edge results with vortices of similar shape and size. The upwind Euler solutions predict attached flow with no separation for both geometries. However, with sufficient grid refinement near the tip or through the use of more accurate spatial differencing, leading edge separation results. Once the leading edge separation is established, the upwind solution agrees with recently published central difference solutions to the Euler equations.

Newsome, R. W.↗
NASA NTRS1990

Mapping sea ice leads with a coupled numeric/symbolic system

A method is presented which facilitates the detection and delineation of leads with single-channel Landsat data by coupling numeric and symbolic procedures. The procedure consists of three steps: (1) using the dynamic threshold method, an image is mapped to a lead/no lead binary image; (2) the likelihood of fragments to be real leads is examined with a set of numeric rules; and (3) pairs of objects are examined geometrically and merged where possible. The processing ends when all fragments are merged and statistical characteristics are determined, and a map of valid lead objects are left which summarizes useful physical in the lead complexes. Direct implementation of domain knowledge and rapid prototyping are two benefits of the rule-based system. The approach is found to be more successfully applied to mid- and high-level processing, and the system can retrieve statistics about sea-ice leads as well as detect the leads.

Key, J.↗
NASA NTRS1995

Arctic sea ice leads from advanced very high resolution radiometer images

A large number of advanced very high resolution radiometer (AVHRR) images from throughout 1989 are analyzed to determine lead characteristics. The units of analysis are square 200-km cells, and there are 270 such cells in the data set. Clouds are masked manually. Leads determine from images of the potential open water delta, a scaled version of the surface temperature or albedo that weights thin ice by its thermal or brightness impact. The lead fraction is determined as the mean delta, the monthly mean lead fraction ranges from 0.02 in winter to 0.06 in summer in the central Arctic and is near 0.08 in the winter in the peripheral seas. A method of accounting for lead width sampling errors due to the finite sample areas is introduced. In the central Arctic the observed mean lead width for a threshold of delta = 0.1 ranges from 2 or 3 km (near the resolution of the instrument) in the winter to 6 km in the summer. In the peripheral seas it is about 5 km in the winter. Width distributions are often more heavily weighted in the tail than exponential distributions and are well approximated by a power law. The along-track, number density power law N = aw(exp -6) has a mean exponent of b = 1.60 (standard deviation 0.18) and shows some seasonal variability. Mean floe widths in the central Arctic are 40 to 50 km in the winter, dropping to about 10 km in the summer. For floes the power law has a mean exponent of 0.93 and exhibits a clearer annual cycle. Lead orientation is determined with a method based on the direction of maximum extent.

Lindsay, R. W.↗
NASA NTRS1995

Lead-induced atmospheric circulations

Leads provide a significant source of heat and moisture to the Arctic winter atmosphere, and plumes from wide leads have been observed to penetrate the Arctic inversion. We have developed a two-dimensional, high-resolution, deep anelastic numerical model to investigate the atmospheric convection from leads with widths ranging from 100 m to 10 km. A second-order turbulence closure scheme is used to parameterize the atmospheric turbulence in the horizontally inhomogeneous system. This study describes how the lead-induced circulations can enhance the vertical transport of heat into the atmospheric boundary layer. This model is compared with large-eddy simulation results and with lidar observations of a lead-induced ice crystal plume. The model is used to study the effect of varying lead widths and ambient atmospheric conditions on the resultant convection from leads, and some preliminary results are described.

Alam, Afshan↗
NASA NTRS1959

Effects of Outboard Thickened and Blunted Leading Edges on the Wave Drag of a 45 Degree Swept-Wing and Body Combination

An investigation to evaluate the effects of thickened and blunted leading-edge modifications on the wave drag of a swept wing has been made at Mach numbers from 0.65 to 2.20 and at a Reynolds number of 2,580,000 based on the mean aerodynamic chord of the basic wing. Two leading-edge designs were investigated and they are referred to as the thickened and the blunted modifications although both sections had equally large leading-edge radii. The thickened leading edge was formed by increasing the thickness over the forward 40 percent of the basic wing section. The blunted modification was formed by reducing the wing chords about 1 percent and by increasing the section thickness slightly over the forward 6 percent of the basic section in a manner to keep the wing sweep and volume essentially equal to the respective values for the basic wing. The basic wing had an aspect ratio of 3, a leading-edge sweep of 45 deg., a taper ratio of 0.4, and NACA 64AO06 sections perpendicular to a line swept back 39.45 deg., the quarter-chord line of these sections. Test results indicated that the thickened modification resulted in an increase in zero-lift drag coefficient of from 0.0040 to 0.0060 over values for the basic model at Mach numbers at which the wing leading edge was sonic or supersonic. Although drag coefficients of both the basic and thickened models were reduced at all test Mach numbers by body indentations designed for the range of Mach numbers from 1.00 to 2.00, the greater drag of the thickened model relative to that of the basic model was not reduced. The blunted model, however, had less than one quarter of the drag penalty of the thickened model relative to the basic model at supersonic leading-edge conditions (M greater or equal to root-2).

Holdaway, George H.↗
NASA NTRS1960

Heat Transfer to 36.75 and 45 degree Swept Blunt Leading Edges in Free Flight at Mach Numbers from 1.70 to 2.99 and From 2.50 to 4.05

A flight investigation has been conducted to study the heat transfer to swept-wing leading edges. A rocket-powered model was used for the investigation and provided data for Mach number ranges of 1.78 to 2.99 and 2.50 to 4.05 with corresponding free-stream Reynolds number per foot ranges of 13.32 x 10(exp 6) to 19.90 x 10(exp 6) and 2.85 x 10(exp 6) to 4.55 x 10(exp 6). The leading edges employed were cylindrically blunted wedges ', three of which were swept 450 with leading-edge diameters of 1/4, 1/2, and 3/4 inch and one swept 36-750 with a leading-edge diameter of 1/2 inch. In the high Reynolds number range, measured values of heat transfer were found to be much higher than those predicted by laminar theory and at the larger values of leading-edge diameter were approaching the values predicted by turbulent theory. For the low Reynolds number range a comparison between measured and theoretical heat transfer showed that increasing the leading-edge diameter resulted in turbulent flow on the cylindrical portion of the leading edge.

ONeal, Robert L.↗
NASA NTRS1959

Low-Speed Wind-Tunnel Investigation of Blowing Boundary-Layer Control on Leading- and Trailing-Edge Flaps of a Large-Scale, Low-Aspect-Ratio, 45 Swept-wing Airplane Configuration

Blowing boundary-layer control was applied to the leading- and trailing-edge flaps of a 45 deg sweptback-wing complete model in a full-scale low-speed wind-tunnel study. The principal purpose of the study was to determine the effects of leading-edge flap deflection and boundary-layer control on maximum lift and longitudinal stability. Leading-edge flap deflection alone was sufficient to maintain static longitudinal stability without trailing-edge flaps. However, leading-edge flap blowing was required to maintain longitudinal stability by delaying leading-edge flow separation when trailing-edge flaps were deflected either with or without blowing. Partial-span leading-edge flaps deflected 60 deg with moderate blowing gave the major increase in maximum lift, although higher deflection and additional blowing gave some further increase. Inboard of 0.4 semispan leading-edge flap deflection could be reduced to 40 deg and/or blowing could be omitted with only small loss in maximum lift. Trailing-edge flap lift increments were increased by boundary-layer control for deflections greater than 45 deg. Maximum lift was not increased with deflected trailing-edge flaps with blowing.

Maki, Ralph L.↗