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At least 415 records · Page 23

Quenching of the B /super 2/Sigma-plus state of the CN radical.

The quenching of the B (super 2)Sigma-plus fluorescence from the CN radical has been studied as a function of the relative velocity of the quenching collision and the total pressure in the fluorescence cell. The rate constant for the quenching of the CN fragment by ICN vapor was found to be directly proportional to the relative velocity of the quenching collision. Electronic quenching was also observed for methane, diatomic hydrogen, Kr, and Ar.

Jackson, W. M.↗

Rare gas record in the largest Apollo 15 rock.

The results obtained from mass-spectrometry analyses of the noble gases He, Ne, Ar, Kr, and Xe in a 182-mg chip of the largest Apollo 15 rock 15555 are presented. The spallation krypton data indicate a well-shielded location through most of the time during which the rock was exposed to cosmic rays. Gas retention ages are estimated. No evidence for the presence of products from plutonium-244 or iodine-129 was found.

Marti, K.↗

Systematics in auroral energy spectra.

Observation of a systematic increase in the mean energy of auroral electrons as the total precipitated energy increases. The change in 4278-A N2(+) intensity from about 50 R to about 10 kR correlates better with the change in mean energy of the precipitating electrons than with the change in number flux. Nightside aurora that exhibit this property superimpose on a wide region of soft (less than or about equal to 1 keV) precipitation that extends from the equatorial boundary of aurora to well poleward of normal visible aurora. On the dayside, the soft 'cusp' precipitation generates the statistical oval, although there may be larger energy inputs equatorward of the oval.

Eather, R. H.↗

Rare gas studies in Luna 16-G-7 fines by stepwise heating technique - A low fission solar wind Xe.

Examination of He, Ne, Kr, and Xe in a dust sample (equal to or less than 125 micrometer) of Luna 16 in 12 temperature steps with especially small intervals in the low temperature range (80 C steps). The gas concentrations, as well as their relative abundances, are in general agreement with values reported by Vinogradov (1971) for Luna 16 and values found in Apollo 11 fines except for Ne. Comparison is made with various other experimental results. The solar wind Xe was lower in the fission-affected isotopes than was found in Apollo 11 fines and in the 1000 C fraction of the Pesyanoe meteorite as measured by Marti (1969). Air-Xe is interpreted as a fractional solar wind Xe with the composition found in this study.

Kaiser, W. A.↗

Foreign-gas broadening of nitrous oxide absorption lines.

We have measured the foreign-gas broadening coefficients for collisional broadening of lines in the nu-3 fundamental of N2O by He, Ne, Ar, Kr, Xe, H2, D2, and CH4. These coefficients, which give the ratio of the line-broadening ability of these gases to the line-broadening ability of N2, can be used with recent measurements and calculations of N2 broadening to obtain optical collision cross sections.

Tubbs, L. D.↗

Hydrogen formation in the photolysis of propyne at 1236 A.

A Kr resonance lamp was used in the investigations. All experiments were performed at 25 C and 0.2 torr of propyne. Between 5% and 25% of the propyne was decomposed in any one experiment. It was found that the addition of 25% C2D4 had no effect on the quantum yield of molecular hydrogen. This suggests that hydrogen formation in the photolysis of propyne at 1236 A occurs exclusively via a molecular process. Pressure effects on the distribution of isotopic hydrogen formed in the photolysis were also investigated.

Payne, W. A.↗

Brightness of forbidden O I lines and properties of shadow bands during the eclipse of 7 March 1970.

Results of two types of measurements made at a site in the center of the eclipse track during the total eclipse of Mar. 7, 1970. The O I forbidden 5577-A and 6300-A lines were measured looking vertically through the eclipse shadow. The intensities were approximately 1 kR, essentially the values obtained in recent rocket measurements of normal day airglow at altitudes above 100 km. This is consistent with the hypothesis that these lines originate primarily at altitudes well above the shadow from mechanisms which are not appreciably perturbed by the approaching shadow. Measurements were also made of the time variation of intensity of incident light during the shadow-band period before second contact. There are saw-tooth fluctuations with steep leading edges, as well as many high-frequency components of smaller amplitude. This time variation does not appear to be obviously related in a simple way to current theories of their production mechanisms, or to the visual appearance of shadow bands.

Kerr, D. E.↗

The Gas Exchange Experiment for life detection - The Viking Mars Lander.

The Gas Exchange Experiment of the Viking mission accepts a sample of Martian soil, incubates this soil with nutrient medium, and periodically samples the enclosed atmosphere over this soil for the gases H2, N2, O2, Kr, and CO2. These gases are analyzed by an automated gas chromatograph, and the data are transmitted to earth. The design of the experiment and the qualitative and quantitative changes, if any, of gas composition should allow conclusions to be made on the presence of life on Mars. Data and theory substantiating this approach are presented.

Oyama, V. I.↗

Noble gas studies on regolith materials from Apollo 14 and 15.

Abundances and isotopic compositions of the five stable noble gases, He, Ne, Ar, Kr, and Xe in soils and breccia were determined. The samples investigated included material from a range of depths in a trench and a core tube. Noble gas determinations were performed in a 6-inch all-metal mass spectrometer of high sensitivity. The grain size separates and stepwise heating experimental methods used give results that supplement each other. Calculated concentrations of spallation Xe-126 in many of the fines and gas-rich breccia are presented in a table. Bulk soil samples obtained by Apollo 14 show an inverse correlation of spallation Xe-126 with grain size.

Bogard, D. D.↗

Observations of the Helium II 304-A and Helium I 584-A atmospheric dayglow radiation.

Two photometers with bandpasses of 170 to 500 and 170 to 800 A were employed to observe dayglow emissions in the extreme ultraviolet (EUV) over an altitude range of 90 to 186 km. The emissions observed with these photometers are identified as resonantly scattered He I 584-A and He II 304-A radiations. At 186 km, 209 plus or minus 70 rayleighs of 584-A and 9.3 plus or minus 3.1 rayleighs of 304-A radiation were measured. These observations are compared with theoretical calculations of resonance scattering of solar emissions from geocoronal He and He(+). Using the Jacchia (1971) atmospheric model for He, it is found that the observed brightness of the 584-A emission requires that the solar 584-A line width be 0.014 plus or minus 0.004 A. In this model the maximum overhead brightness of 584-A dayglow would occur at 900 km, and its magnitude would be 1.9 plus or minus 0.6 kR. The authors' observation of 304-A brightness requires that the overhead column density of the He(+) ions be 4.2 x 10 to the 11th ions/sq cm column. This value is consistent with a constant-density plasmasphere model with a He(+) ion density of 320 ions/cu cm in the plasmasphere.

Kumar, S.↗

Daytime ion chemistry of N2+.

Rocket measurements of the emission of the (0, 0) first negative band of N2+ at 3914 A in the day airglow have been made between 120 and 300 km. The solar zenith angle at the time of the flight was 60 deg, and the zenith intensity above 120 km was 1.6 kR averaged over both legs of the flight. The data are compared with a model in which charge exchange of N2 with metastable O+(2D) ions is included as an additional source of N2 ionization. Above 240 km this mechanism is dominant over the photoionization of N2 by solar extreme ultraviolet radiation. The derived N2+ density is consistent with the results of rocket-borne mass spectrometric observations.

Feldman, P. D.↗

Characteristics of tracks of ions of 14 less than or equal to Z less than or equal to 36 in common rock silicates.

Identification of heavy ion tracks in minerals by measurements of track etch rates and total etchable track lengths were irradiated with beams of Si, Cl, Ti, Fe, Zn, and Kr at energies up to 10.35 MeV/nucleon. Nine minerals commonly used to study fossil cosmic ray tracks in meteorites and lunar samples. From measurements of etched track length as a function of residual range, response curves for various minerals were determined as a function of ionization rate, using the expression previously derived by Price et al. (1968). These curves increase smoothly with ionization rate instead of rising abruptly at some critical value as was previously thought. It is shown that the track etch rate concept accounts qualitatively for total etchable track length distributions, but that the positions of the peaks of different elements in these histograms occur at shorter lengths for fossil tracks than for fresh tracks. Annealing data indicate that, at maximum lunar surface temperatures, tracks in olivine, orthopyroxenes, and feldspars may be significantly shortened, whereas tracks in clinopyroxenes will not be affected.

Price, P. B.↗

The far-ultraviolet spectrum of Jupiter.

A far-ultraviolet spectrum of Jupiter, observed from a sounding rocket, is presented. The H I 1216-A disk brightness was 4.4 kR. Other characteristics of the 1180- to 1900-A spectrum were Rayleigh scattering of solar radiation longward of 1600 A and emission between 1250 and 1500 A and near 1600 A.

Rottman, G. J.↗

Trapped solar and cosmogenic noble gas abundances in Apollo 15 and 16 deep drill samples

Abundances and isotopic compositions of all the stable noble gases (He, Ne, Ar, Kr, Xe) were measured at different depths of the Apollo 15 and Apollo 16 deep drill cores, and in several surface fines and breccias. All samples analyzed from both drill cores were found to contain large concentrations of solar wind implanted gases. This means that even the deepest layers of both cores have experienced a lunar surface history. The Apollo 15 core data are consistent with a combined accretion plus static time of a few hundred million years, and also indicate variable pre-accretion irradiation of core material. Depth profiles of cosmogenic gases in the Apollo 16 core show considerably larger concentrations of cosmic gases below 65 cm depth than above. This pattern may be interpreted either as an accretionary process, or by a more recent deposition of regolith to the upper 70 cm of the core.

Bogard, D. D.↗

Surface properties of the Orgueil meteorite - Implications for the early history of solar system volatiles

The Kr and H2O adsorption properties of Orgueil were studied. Dehydration by stepwise calcination produced a tenfold change in its B.E.T. surface area, which increased to 120 and then fell to 40 square meters per gram. Water exchangeability was measured by water regain from lab air between calcination cycles. Dehydration at room temperature showed that Orgueil contained 6 per cent by weight of water adsorbed on free surfaces. These results are consistent with an identification of Orgueil as montmorillonite, although chemical data conflict with this. High D/H ratios in CI carbonaceous chondrites may result from D enrichment in OH- groups during equilibration of dispersed phyllosilicate dust with preplanetary nebula gas at temperatures much less than 0 C.

Fanale, F. P.↗

Inert gases in Sea of Fertility regolith

The content and isotopic composition were studied of inert gases -- He, Ne, Ar, Kr, and Xe -- in samples of lunar regolith returned by the Luna 16 automatic station. The samples were taken from depths of about 12 and 30 cm. The high concentrations of inert gases exceed by several orders their concentrations observed in ordinary stony meteorites. The gases in lunar regolith were a complex mixture of gases of different origins: Solar, cosmogenic, radiogenic, and so on. Solar wind gases predominated, distributed in the thin surficial layer of the regolith grains. The concentrations of these gases in the surficial layer is several cubic centimeters per gram. The isotopic composition of the inert gases of solar origin approaches their composition measured in gas-rich meteorites.

Vinogradov, A. P.↗

Decomposition of NO studied by infrared emission and CO laser absorption

A diagnostic technique for monitoring the concentration of NO using absorption of CO laser radiation was developed and applied in a study of the decomposition kinetics of NO. Simultaneous measurements of infrared emission by NO at 5.3 microns were also made to validate the laser absorption technique. The data were obtained behind incident shocks in NO-N2O-Ar (or Kr) mixtures, with temperatures in the range 2400-4100 K. Rate constants for dominant reactions were inferred from comparisons with computer simulations of the reactive flow.

Hanson, R. K.↗