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At least 415 records · Page 23
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

Kinetics of the gas-phase reaction between hydroxyl and carbonyl sulfide over the temperature range 300-517 K

By use of a discharge-flow resonance-fluorescence method the rate constant for the title reaction has been measured at five temperatures in the range 300-520 K. The Arrhenius expression is k(OH + OCS) = (1.3 + or - 0.3) x 10 to the -12th exp/-(2300 + or - 100)/T/ cu cm/s. Mass spectrometry has been used to detect the product HS and to collect some information about its reactivity. This study has carefully avoided the pitfalls associated with possible photolysis of reactants and complications due to H2S impurity in carbonyl sulfide that may have marred previous studies. This study has confirmed that the rate constant for this reaction is so much lower than the value originally used in computer modeling of the upper and lower atmosphere that conclusions about the relative importance of photolysis of OCS and of the reaction OH + OCS in the stratosphere must now be reassessed. The reaction OH + OCS has little significance for atmospheric chemistry.

Leu, M.-T.↗
NASA NTRS1981

Temperature dependence of the NO + O3 reaction rate from 195 to 369 K

The temperature dependence of the NO + O3 reaction rate was examined by means of the fast flow technique. Several different experimental conditions and detection schemes were employed. With excess NO or excess O3, NO2 chemiluminescence was monitored. In addition, with excess O3, NO was followed by fluorescence induced by an NO microwave discharge lamp. The results of the three independent sets of data are compared and found to agree within experimental error, indicating the absence of secondary chemistry which might complicate the kinetics. The data exhibit curvature on an Arrhenius plot; however, the simple Arrhenius expression k = (2.6 + or - 0.8) x 10 to the -12th exp(-1435 + or - 64/T) cu cm/molecule s is an adequate description for T between 195 and 369 K. This result is compared to earlier determinations.

Michael, J. V.↗
NASA NTRS1980

Classification, experimental petrology and possible volcanic histories of the Apollo 11 high-K basalts

The Apollo 11 high-K basalt samples are classified into three textural categories: vitrophyric, anti-insertal, and antiophitic. Low-pressure phase equilibrium experiments and cooling rate studies were performed on a synthetic analog of 10085, 832. The dynamic crystallization experiments were designed to study textural development with: (1) a variable cooling rate from a constant initial temperature above the liquidus, and (2) cooling at a constant rate from variable initial temperatures below the liquidus. These experiments show that a variety of cooling rates initiated from temperatures both below and above the liquidus can produce all the observed textures. The results are consistent with the interpretation that all of the high-K basalt samples were derived from a single lava flow or lava lake.

Grove, T. L.↗
NASA NTRS1982

Stellar luminosity functions in the R, I, J, and K bands obtained by transformation from the visual band

The stellar luminosity function that has been measured in the visual band into the R, I, J, and K bands, where it has not yet been obtained directly, is transformed. The transformation is effected by subdividing the total visual function, which includes all stars, into subluminosity functions for each luminosity class (supergiants through white dwarfs), applying the known (V - D) color, D = R, I, J, K for each spectral type, and then summing the resultant transformed subluminosity functions into a total luminosity function for the band D. Simple analytic forms that accurately fit the transformed luminosity functions are given. Consideration is also given to the possibility of a systematic error resulting from the existence of a very red stellar population not accounted for in the visual band luminosity function

Mamon, G. A.↗
NASA NTRS1982

Rate constant for the reaction between OH and CS2 at 298 and 520 K

In an attempt to resolve discrepancies between published values of the rate constant for the reaction between the hydroxyl radical and carbon disulfide, the reaction has been studied in a discharge flow system by using resonance fluorescence for kinetic measurements and mass spectrometry for product analysis. On the basis of the measured rate constant for disappearance of OH, and measurements of the amount of carbonyl sulfide formed, it was estimated that for the reaction HO + CS2 yields HS + OCS, rate constant values are not greater than 3 x 10 to the -15th/cu cm per sec at 520 K and not greater than 7 x 10 to the -15th/cu cm per sec at 298 K, upper limits are specified because of the inability to isolate exclusively this reaction channel, and because of possible involvement of wall reactions. These results confirm the low values found for this rate constant in two very recent studies.

Leu, M.-T.↗
NASA NTRS1982

K sub A-band weather-dependent system performance estimates for Goldstone

A K sub A band atmospheric noise temperature and attenuation statistical model is developed for Goldstone, based on water vapor radiometer measurements at 31.4 GHz made during winter and spring 1981. An equivalent X-band model is derived from these measurements, and the two sets of data are compared to determine the possible advantages of developing DSN telecommunications links at 32 GHz. For a nominal elevation angle of 30 degrees and identical antennas, it is found that a K sub A band system at Goldstone will show a 5 to 1 dB signal-to-noise ratio advantage oer an X-band system more than 99 percent of the time.

Clauss, R. C.↗
NASA NTRS1982

Kinetics of the reaction O + HO2 yields OH + O2 from 229 to 372 K

The discharge-flow resonance fluorescence technique has been used to obtain absolute rate data for the O + HO2 reaction from 229 to 372 K at a total pressure of 1 torr. Pseudo-first-order conditions were used with HO2 concentrations in large excess over initial atomic oxygen in order to minimize interference from secondary reactions. The results are independent of the method used to generate HO2 and atomic oxygen. At 299 K, the result is (6.1 + or - 0.4) x 10 to the -11th cu cm/molecule s. The temperature dependence expressed in Arrhenius form is (3.1 + or - 0.3) x 10 to the -11th exp/(+200 + or - 28)/T/. The error limits given are twice the standard deviation; overall experimental error is estimated to be + or - 25%.

Keyser, L. F.↗
NASA NTRS1983

The application of near-nadir Delta-k radar techniques to geodetic altimetry and oceanographic remote sensing

This paper first examines the extension of two-frequency, or Delta-k near-nadir remote sensing techniques to off-nadir radar altimetry. A different approach to sea state sensing is investigated which appears to offer much higher accuracy. The second section examines the Delta-k method of sensing rough surface area correlation or ocean wavenumber spectrum. The technique shows promise of directly sensing this parameter, in contrast with synthetic-aperture radar methods which are based on complex wave interaction mechanisms and mathematical transformations requiring the acquisition of voluminous data.

Miller, L. S.↗
NASA NTRS1983

High-performance K-band GaAs power field-effect transistors prepared by molecular beam epitaxy

The maturity of the molecular beam epitaxy (MBE) technique for preparing device quality GaAs material for microwave applications is demonstrated by the excellent performance characteristics of K-band GaAs power field-effect transistors (FETs) fabricated on the MBE wafers. An output power of 710 mW with 4.5-dB gain and 17.7 percent power-added efficiency was achieved at 21 GHz with a 1.26-mm gate width pi-gate device. A similar device with a 0.56-mm gate width produced an output power of 320 mW with 5.0-dB gain and 26.6 percent power-added efficiency at 21 GHz. These are the best results yet reported to date for GaAs power FETs operated in the K-band frequency range.

Saunier, P.↗
NASA NTRS1984

K-Band Latching Switches

Design, development, and tests are described for two single-pole-double-throw latching waveguide ferrite switches: a K-band switch in WR-42 waveguide and a Ka-band switch in WR-28 waveguide. Both switches have structurally simple junctions, mechanically interlocked without the use of bonding materials; they are impervious to the effects of thermal, shock, and vibration stresses. Ferrite material for the Ka-band switch with a proper combination of magnetic and dielectric properties was available and resulted in excellent low loss, wideband performance. The high power handling requirement of the K-band switch limited the choice of ferrite to nickel-zinc compositions with adequate magnetic properties, but with too low relative dielectric constant. The relative dielectric constant determines the junction dimensions for given frequency responses. In this case the too low value unavoidably leads to a larger than optimum junction volume, increasing the insertion loss and restricting the operating bandwidth. Efforts to overcome the materials-related difficulties through the design of a composite junction with increased effective dielectric properties efforts to modify the relative dielectric constant of nickel-zinc ferrite are examined.

Piotrowski, W. S.↗
NASA NTRS1983

Differences in the temporal variations of solar UV flux, 10.7-cm solar radio flux, sunspot number, and Ca-K plage data caused by solar rotation and active region evolution

Attention is given to two types of temporal variations in the solar UV spectral irradiance caused by solar rotation and active region evolution. It is noted that the first type of dissimilar temporal behavior occurs when concentrations of solar active regions evolve at solar longitudes nearly 180 deg apart. Both the UV observations and modeled UV fluxes based on Ca-K plage data then exhibit pronounced 13-day periodicity, whereas the 10.7-cm solar radio flux and sunspot number exhibit quite dissimilar temporal variations. This type of dissimilarity is related to the modeled UV flux and has a dependence on the solar central meridian distance that is narrower than that for the 10.7-cm radio flux or for sunspot numbers. A second case of marked dissimilarity is seen when major new solar active regions arise and dominate the full-disk fluxes for several rotations. It is found that the strongest peaks in 10.7 cm and sunspot numbers tend to occur on their first rotation, for example, during major dips in the total solar irradiance, whereas the Ca-K plages and UV enhancements peak on the next rotation and then decay more slowly on subsequent rotations.

Donnelly, R. F.↗
NASA NTRS1984

Limitations and empirical extensions of the k-epsilon model as applied to turbulent confined swirling flows

Shortcomings and recommended corrections to the standard two-equation k-epsilon turbulence model suggested by previous investigators are presented. They are assessed regarding their applicability to turbulent swirling recirculating flow. Recent experimental data on swirling confined flows, obtained with a five-hole pitot probe and a six-orientation hot-wire probe, are used to obtain optimum values of the turbulence parameters C-mu, C2, and sigma-epsilon for swirling flows. General predictions of moderately and strongly swirling flows with these values are more accurate than predictions with the standard or previous simple extensions of the k-epsilon turbulence model.

Lilley, D. G.↗
NASA NTRS1984

GaAs dual-gate FET for operation up to K-band

A high-frequency equivalent-circuit model of a GaAs dual-gate FET and analytical expressions for the input/output impedances, transconductance, unilateral gain, and stability factor are presented. It is found that the gain of a dual-gate FET is higher than of a single-gate FET at low frequency but decreases faster as frequency increases because of the capacitive shunting effect of the second gate. A dual-gate power FET suitable for variable-gain-amplifier applications up to K-band has been developed. At 10 GHz, a 1.2-mm-gatewidth device has achieved an output power of 1.1 W with 10.5-dB gain and 31-percent power-added efficiency. At 20 GHz, the same device delivered an output power of 340 mW with 5.3-dB gain. At K-band, a dynamic-gain control range of up to 45 dB was obtained with an insertion phase change of no more than + or 2 degrees for the first 10 dB of gain control.

Kim, B.↗
NASA NTRS1984

K-coronameter observations and potential field model comparison in 1976 and 1977

Results of determining the shape and location of the heliospheric current sheet from a potential field model and from K-coronameter observations are compared. Interplanetary magnetic field polarities as observed by IMP 8, Helios 1 and 2, and Voyager 2 spacecraft were used to test the two methods over the period May 1976 to August 1977 throughout 18 Carrington rotations. The computed heliospheric current sheets from both methods had a quasi-stationary four-sector structure and very similar shapes. Agreement between interplanetary magnetic field polarity and the results from the potential field model was found on 79 percent of the days, while agreement between the interplanetary field polarity and the polarities derived from the K-coronameter data was found on 87 percent of the days.

Bruno, R.↗
NASA NTRS1985

Evidence for Non-radiative Activity in Stars with T Sub Eff 10000 K

Major advances in the acquisition of evidence for and the understanding of nonradiative heating and other activity in stars cooler than T sub eff = 10,000 K has occurred in the last few years primarily as a result of the IUE and Einstein spececraft. This evidence is critically reviewed and trends that are now becoming apparent are noted. The existence for nonradiatively heated outer atmospheric layers (chromospheres, transition regions, and coronae) in dwarf stars cooler than spectral type A7, in F ang G giants, pre-main sequence stars, and close binary systems in unambiguous, and chromospheres exist in the K and M giants and supergiants. The existence of nonradiative heating in the outer layers of the A stars remains undetermined despite repeated searches at all wavelengths. Some important trends in these data are the decrease in plasma emission measure with age on the main sequence and decreasing rotational velocity. Variability and atmospheric inhomogeneity is commonly seen, and there is considerable evidence that magnetic fields define the geometry and control the energy balance in the outer atmospheric layers.

Linsky, J. L.↗
NASA NTRS1985

Quantitation of Na+, K+-atpase Enzymatic Activity in Tissues of the Mammalian Vestibular System

In order to quantify vestibular Na(+), K(+)-ATPase, a microassay technique was developed which is sufficiently sensitive to measure the enzymatic activity in tissue from a single animal. The assay was used to characterize ATPase in he vestibular apparatus of the Mongolian gerbil. The quantitative procedure employs NPP (5 mM) as synthetic enzyme substrate. The assay relies upon spectrophotometric measurement (410 nm) of nitrophenol (NP) released by enzymatic hydrolysis of the substrate. Product formation in the absence of ouabain reflects both specific (Na(+), K(+)-ATPase) and non-specific (Mg(++)-ATPase) enzymatic activity. By measuring the accumulation of reaction product (NP) at three-minute intervals during the course of incubation, it is found that the overall enzymatic reaction proceeds linearly for at least 45 minutes. It is therefore possible to determine two separate reaction rates from a single set of tissues. Initial results indicate that total activity amounts to 53.3 + or - 11.2 (S.E.M.) nmol/hr/mg dry tissue, of which approximately 20% is ouabain-sensitive.

Kerr, T. P.↗
NASA NTRS1985

Nitrogen-broadened lines of ethane at 150 K

Spectral transmittance has been measured in the nu9 fundamental band of C2H6 at 150 K using a Fourier transform spectrometer with apodized spectral resolution of 0.06/cm. Comparison of observed spectral transmittance with a line-by-line computation using the spectral catalog of Atakan et al. (1983) has yielded N2-broadened half-widths at 150 K.

Chudamani, S.↗
NASA NTRS1986

Shell correction for the stopping power of K electrons

In view of the inapplicability of the asymptotic expressions for the stopping number available in the literature at high energies, an alternative approach is taken to compute the shell correction to the stopping number of K electrons. Anholt's formula for the K-shell ionization has been used to calculate the excitation function for longitudinal interaction and numerical integration over energy has been carried out to evaluate the shell correction. Comparison with other theoretical calculations is made. It is proposed that, with the inclusion of relativistic effects, an asymptotic expansion of the stopping number with a leading-term logarithmic in the energy of the incident particle would be more meaningful and might enable one to extract the relativistic contribution to the shell correction from it.

Leung, P. T.↗