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At least 415 records · Page 23

Preliminary statistical survey of plasmaspheric ion properties from observations by DE 1/RIMS

The paper presents mean temperatures and densities of plasmaspheric H(+) ions obtained from observations by the retarding ion mass spectrometer on Dynamics Explorer 1. Composition is shown in terms of ratios of densities of the various ion species to those of H(+). The spatial variations are indicated in terms of L shell profiles, with separate profiles for local morning and evening sides.

Comfort, R. H.↗

Superthermal ions detected in Venus' dayside ionosheath, ionopause, and magnetic barrier regions

Results of a comprehensive morphological analysis of the dayside superthermal ion presence in the dayside ionopause region of Venus made using the Orbiter Ion Mass Spectrometer measurements are presented. There is a strong inbound-outbound difference in both the number and intensity of the superthermal ions with most events detected on the inbound crossing of the ionopause. The ambient energy of the detected ions is comparable to the ram energy of cold ions relative to the moving spacecraft. A comparison of the locations of the superthermal O(+) ion occurrences with respect to other parameters shows that the superthermals are a characteristic of the ionopause transition separating the essentially stationary ionosphere plasma from the flowing ionosheath plasma as deduced by Taylor et al. (1980) from individual examples.

Grebowsky, J. M.↗

Investigation of evolution-related aspects of bacterial rhodopsins

We have investigated evolution-related aspects of bacterial rhodopsins, the unique retinal-based energy transducing systems of halophilic archae. The approach was to describe both structural and functional aspects: the structure by sequencing genes to explore which regions are conserved, and the function by comparing proton and chloride transport in the closely related systems, bacteriorhodopsin and halorhodopsin, respectively. In the latter, we have made a good start toward the ultimate goal of separating the attributes of the general principles of retinal-based ionic pumps from those of the specific ion specificities, by determining the thermodynamics of the internal steps of the protein-mediated active transport process, as well as some of the intraprotein ion-transfer steps. Our present emphasis is on continuing to acquire the tools for studying what distinguishes proton transport from chloride transport. We consider it important, therefore, that we have been able to provide firm mathematical grounds for the kinetics analyses which underlies these studies. Our molecular biological studies have received a great boost from the expression vector for the bop gene based on a halobacterial plasmid, that we recently developed.

Source record↗

Compositional Impact of Io Volcanic Emissions on Jupiter's Magnetosphere and the Icy Galilean Moons

The magnetospheric ion population of Jupiter is dominated by the 1000 kg/s of iogenic material constantly ejected by IO volcanism as neutral gas (approx. 1 kg/s goes out as high speed dust grains), subsequent atmospheric losses to the IO torus, and radial transport of torus ions throughout the magnetosphere. As that magnetosphere is greatly distended in radial size by the iogenic plasma loading, so are surfaces of the other Galilean moons also significantly, and perhaps even dominantly, affected by iogenic plasma bombardment, e.g. at the level up to 0.2 kg/s heavy ions (mostly O and S) onto Europa as per local plasma ion measurements. In comparison, cometary impacts onto IO deliver about 0.02 kg/s of impact ejecta to Europa via ballistic transfer through the Jupiter system. The magnetosphere of this system operates as a powerful engine to produce and transport ions from the IO source to the surfaces of these other moons, and any future orbiter missions to these moons must account for surface distributions of the iogenic material and its chemical effects before real assessments can be made of sensible chemical materials otherwise arising from primordial formation and subsequent evolution of these moons. This is a fundamental problem of space weathering that must be addressed for all planetary bodies with thin atmospheres and direct surface exposure to their space plasma environments. Long-standing debates from Galileo Orbiter measurements about the origins of hydrate sulfates at Europa present examples of this problem, as to whether the sulfates arise from oceanic minerals or from iogenic sulfur chemistry. Any orbiter or landed mission to Europa for astrobiological investigations would further need to separate the potential chemical biosignatures of life or its precursors from the highly abundant background of iogenic material. Although no single ion carries a tag identifying it as of iogenic or other origin, the elemental abundance distributions of ions to be measured throughout the jovian magnetosphere and in the local moon environments can act as tracers if we know from direct measurements and models the distributions at the mostly likely sources, i.e. at IO. However, our knowledge of these abundances are very limited from earlier in-situ and remote measurements, mainly confined to major (S, O) and some minor (Na, K, Cl) species with abundances at or above a few percent relative to O. Future in-situ plasma measurements by the planned Jupiter Europa Orbiter and Jupiter Ganymede Orbiter missions should extend the abundance coverage to minor and even trace elemental species. For Europa astrobiological investigations it is also important to specify iogenic inputs and surface processing of isotopic species. We discuss the range of abundance distributions arising from models for IO hot volcanic emissions, and from the subsequent dynamics of ion injection, magnetospheric transport, and icy moon surface bombardment.

Cooper, John↗

Modifying Silicates for Better Dispersion in Nanocomposites

An improved chemical modification has been developed to enhance the dispersion of layered silicate particles in the formulation of a polymer/silicate nanocomposite material. The modification involves, among other things, the co-exchange of an alkyl ammonium ion and a monoprotonated diamine with interlayer cations of the silicate. The net overall effects of the improved chemical modification are to improve processability of the nanocomposite and maximize the benefits of dispersing the silicate particles into the polymer. Some background discussion is necessary to give meaning to a description of this development. Polymer/silicate nanocomposites are also denoted polymer/clay composites because the silicate particles in them are typically derived from clay particles. Particles of clay comprise layers of silicate platelets separated by gaps called "galleries." The platelet thickness is 1 nm. The length varies from 30 nm to 1 m, depending on the silicate. In order to fully realize the benefits of polymer/silicate nanocomposites, it is necessary to ensure that the platelets become dispersed in the polymer matrices. Proper dispersion can impart physical and chemical properties that make nanocomposites attractive for a variety of applications. In order to achieve nanometer-level dispersion of a layered silicate into a polymer matrix, it is typically necessary to modify the interlayer silicate surfaces by attaching organic functional groups. This modification can be achieved easily by ion exchange between the interlayer metal cations found naturally in the silicate and protonated organic cations - typically protonated amines. Long-chain alkyl ammonium ions are commonly chosen as the ion-exchange materials because they effectively lower the surface energies of the silicates and ease the incorporation of organic monomers or polymers into the silicate galleries. This completes the background discussion. In the present improved modification of the interlayer silicate surfaces, the co-ion exchange strengthens the polymer/silicate interface and ensures irreversible separation of the silicate layers. One way in which it does this is to essentially tether one amine of each diamine molecule to a silicate surface, leaving the second amine free for reaction with monomers during the synthesis of a polymer. In addition, the incorporation of alkyl ammonium ions into the galleries at low concentration helps to keep low the melt viscosity of the oligomer formed during synthesis of the polymer and associated processing - a consideration that is particularly important in the case of a highly cross-linked, thermosetting polymer. Because of the chemical bonding between the surface-modifying amines and the monomers, even when the alkyl ammonium ions become degraded at high processing temperature, the silicate layers do not aggregate and, hence, nanometer-level dispersion is maintained.

Campbell, Sandi↗

Ion microprobe analyses of aluminous lunar glasses - A test of the 'rock type' hypothesis

Previous soil survey investigations found that there are natural groupings of glass compositions in lunar soils and that the average major element composition of some of these groupings is the same at widely separated lunar landing sites. This led soil survey enthusiasts to promote the hypothesis that the average composition of glass groupings represents the composition of primary lunar 'rock types'. In this investigation the trace element composition of numerous aluminous glass particles was determined by the ion microprobe method as a test of the above mentioned 'rock type' hypothesis. It was found that within any grouping of aluminous lunar glasses by major element content, there is considerable scatter in the refractory trace element content. In addition, aluminous glasses grouped by major elements were found to have different average trace element contents at different sites (Apollo 15, 16 and Luna 20). This evidence argues that natural groupings in glass compositions are determined by regolith processes and may not represent the composition of primary lunar 'rock types'.

Meyer, C., Jr.↗

Formulated plastic separators for soluble electrode cells

The fabrication and milling of membranes comprising a hydrochloric acid-insoluble sheet of a mixture of a rubber and a powdered ion transport material are described. The sheet can be present as a coating upon a flexible and porous substrate. These membranes can be used in oxidation-reduction electrical accumulator cells wherein the reduction of one member of a couple is accompanied by the by the oxidation of the other member of the couple on the other side of the cell and this must be accompanied by a change in chloride ion concentration in both sides.

Sheibley, D. W.↗

Method of making formulated plastic separators for soluble electrode cells

A method making a membrane comprised of a hydrochloric acid-insoluble sheet of a mixture of a rubber and a powdered ion transport material is disclosed. The sheet can be present as a coating upon a flexible and porous substrate. These membranes can be used in oxidation-reduction electrical accumulator cells wherein the reduction of one member of a couple is accompained by the oxidation of the other member of the couple on the other side of the cell and this must be accompained by a change in chloride ion concentration in both sides. The method comprises preparing a mixture of fine rubber particles, a solvent for the rubber and a powdered ion transport material. The mixture is formed into a sheet and dried to produce a microporous sheet. The ion transport material includes particles ranging from about 0.01 to 10 microns in size and comprises from 20 to 50 volume percent of the microporous sheet.

Sheibley, D. W.↗

Electron and ion density depletions measured in the STS-3 orbiter wake

The third Space Shuttle flight on Columbia carried instrumentation to measure thermal plasma density and temperature. Two separate investigations, the Plasma Diagnostics Package (PDP) and the Vehicle Charging and Potential Experiment (VCAP), carried a Langmuir Probe, and the VCAP also included a Spherical Retarding Potential Analyzer (SRPA). Only those measurements made while the PDP is in the payload bay are discussed here since the VCAP instrumentation remains in the payload bay at all times and the two measurements are compared. The wake behind a large structure (in this case the Space Shuttle Orbiter) flying through the ionospheric plasma is discussed. Much theoretical work was done regarding plasma wakes. The instrumentation on this mission gives the first data taken with a large vehicle in the ionospheric laboratory. First, the PDP Langmuir Probe and its data set will be presented, then the VCAP Langmuir Probe and SRPA with associated data. The agreement between the two data sets is discussed and then followed by some other PDP data which infers an even lower wake density.

Murphy, G. B.↗

Thermal proton flow in the plasmasphere - The morning sector

Vertical profiles of electron density obtained in the vicinity of the plasmapause using the Alouette-2 topside sounder have been analyzed to assess the presence of H(+) flow in the topside ionosphere. The observations in the midnight sector show clearly the presence of the plasmapause - i.e., there is a sharp boundary separating the poleward regions of polar wind H(+) flow and the more gentle conditions of the plasmasphere where light ions are present in abundance. In contrast, in the sunlit morning sector upward H(+) flow is deduced to be present to invariant latitudes as low as 48 deg (L = 2.2) in the regions normally known to be well inside the plasmasphere. The upward H(+) flux is so large 300,000,00 ions per sq cm per sec that the plasmapause cannot be seen in the latitudinal electron density contours of the topside ionosphere.

Banks, P. M.↗

Lunar surface solar wind observations at the Apollo 12 and Apollo 15 sites

The solar wind-lunar magnetic field interaction is examined by comparing Apollo 12 and Apollo 15 solar wind spectrometric data. The instrumentation and data analysis methods are described along with the observations at the Apollo 15 site, and the data from the two sites are compared. The results show no noticeable differences between the properties of the upstream solar wind and the plasma observed at the Apollo 15 site (where the local magnetic field is relatively weak) and strong perturbations in the solar wind at the Apollo 12 site (where the field is relatively strong), which include deceleration, deflection, and heating of solar wind protons, focusing or defocusing of the ion flux, and an increased level of plasma parameter fluctuations. These effects are shown to require a charge-separated electric field above the lunar surface and a scale size of about 5 km for the local magnetic field at the Apollo 12 site and to suggest that local lunar magnetic field regions cause lunar limb compression waves which should be more noticeable for low solar wind dynamic pressures.

Clay, D. R.↗

Numerically simulated two-dimensional auroral double layers

A magnetized 2 1/2-dimensional particle-in-cell system which is periodic in one direction and bounded by reservoirs of Maxwellian plasma in the other is used to numerically simulate electrostatic plasma double layers. For the cases of both oblique and two-dimensional double layers, the present results indicate periodic instability, Debye length rather than gyroradii scaling, and low frequency electrostatic turbulence together with electron beam-excited electrostatatic electron-cyclotron waves. Estimates are given for the thickness of auroral doule layers, as well as the separations within multiple auroral arcs. Attention is given to the temporal modulation of accelerated beams, and the possibilities for ion precipitation and ion conic production by the double layer are hypothesized. Simulations which include the atmospheric backscattering of electrons imply the action of an ionospheric sheath which accelerates ionospheric ions upward.

Borovsky, J. E.↗

Interferometric phase velocity measurements

Phase velocities of plasma waves near the lower hybrid frequency were measured with an interferometer composed of two spatially separated electron-density probes. The plasma waves were produced in the F-region ionosphere by an argon ion beam. By calculating the normalized cross spectrum of the plasma waves a coherency of .98 was estimated along with a maximum phase difference of pi/3 radians between the two probes. This implies that the wavelength was 6 meters compared to an O(+) gyroradius of 3.8 meters, and that the phase velocity was 45 km/sec compared to an ion-beam velocity of 12.4 km/sec. These numbers compare favorably with recent predictions of a nonresonant mode produced by a dense ion beam.

Kintner, P. M.↗

The origin of complex organic ions in the coma of Comet Halley

The Giotto-PICCA instrument has obtained heavy-ion mass spectra in the inner coma of Comet Halley; the spectra exhibit a series of distinct mass groups separated by a constant about 15 amu, and extending to at least 120 amu, whose pattern is typical of CHON molecules. It is found that neither coma gas-phase chemistry nor UV photon, solar wind particle, or cosmic irradiation of the nucleus in its current orbit can generate enough heavy molecules to account for the PICCA abundances. It is suggested that these abundances may be supplied by UV and cosmic irradiation of the icy, precometary grains within interstellar molecular clouds and/or the protosolar nebula.

Mitchell, D. L.↗

Clusters of DNA damage induced by ionizing radiation: formation of short DNA fragments. II. Experimental detection

The basic 30-nm chromatin fiber in the mammalian cell consists of an unknown (possibly helical) arrangement of nucleosomes, with about 1.2 kb of DNA per 10-nm length of fiber. Track-structure considerations suggest that interactions of single delta rays or high-LET particles with the chromatin fiber might result in the formation of multiple lesions spread over a few kilobases of DNA (see the accompanying paper: W.R. Holley and A. Chatterjee, Radiat. Res. 145, 188-199, 1996). In particular, multiple DNA double-strand breaks and single-strand breaks may form. To test this experimentally, primary human fibroblasts were labeled with [3H]thymidine and exposed at 0 degrees C to X rays or accelerated nitrogen or iron ions in the LET range of 97-440 keV/microns. DNA was isolated inside agarose plugs and subjected to agarose gel electrophoresis under conditions that allowed good separation of 0.1-2 kb size DNA. The bulk of DNA remained in the well or migrated only a small distance into the gel. It was found that DNA fragments in the expected size range were formed linearly with dose with an efficiency that increased with LET. A comparison of the yield of such fragments with the yield of total DNA double-strand breaks suggests that for the high-LET ions a substantial proportion (20-90%) of DNA double-strand breaks are accompanied within 0.1-2 kb by at least one additional DNA double-strand break. It is shown that these results are in good agreement with theoretical calculations based on treating the 30-nm chromatin fiber as the target for ionizing particles. Theoretical considerations also predict that the clusters will contain numerous single-strand breaks and base damages. It is proposed that such clusters be designated "regionally multiply damaged sites." Postirradiation incubation at 37 degrees C resulted in a decline in the number of short DNA fragments, suggesting a repair activity. The biological significance of regionally multiply damaged sites is presently unknown.

Non-NASA Center↗

Polyimide-Clay Composite Materials for Space Application

The introduction of nanometer-sized clay particles into a polyimide matrix has been shown to enhance the physical properties of specific polymer systems. The clay comprises large stacked platelets of the oxides of aluminum and silicon. These sheets have long dimensions on the order of tenths of a micrometer and thicknesses of several nanometers. Homogeneous dispersion of the clay platelets in the polymer matrix is necessary to achieve those enhancements in polymer properties. Natural montmorillonite with the empirical formula Na0.33Mg0.33Al1.67(OH)2(Si4O10) contains exchangeable inorganic cations. The clay lamellae stack together with the positive sodium ions situated between the surfaces of the individual sheets to balance negatively charged oxygen atoms that are on the surfaces of the sheets. These surface charges contribute to strong electrostatic forces which hold the sheets together tightly. Exfoliation can be accomplished only with unusual measures. In preparing clay nanocomposites, we have taken two steps to try to reduce these interlamellar forces in order to promote the separation (exfoliation) of the sheets and the dispersion of the individual clay particles throughout the organic polymer matrix. In the first step, some of the surface Na(+) ions are replaced with Li(+) ions. Unlike sodium cations, the lithium cations migrate into the interior of the lamellae when the system is heated. Their departure from the surface reduces the surface charge and therefore the attractive forces between the sheets. The loss of alkali metal cations from the surface can be measured as the cation exchange capacity (CEC) of the clay. For example, we found that the CEC of montmorillonite clay was reduced by almost two thirds by treating it with lithium ions and heating to 250 C for 24 hr. Lesser heating has a smaller effect on the CEC. X-ray diffraction measurements show that the d-spacing decreased from ca. 1.34 to 0.97 nm, apparently a consequence of a collapse of the clay layers. We observed that the d-spacing can be varied by altering the heat treatment. In the second part of our effort to reduce the interlamellar forces, the remaining inorganic surface cations were replaced by the trimethylphenylammonium ion (TMPA), the biphenyltrimethylammonium ion (BTMA), or the tetraphenylphosphonium ion (TPP).

Orwoll, Robert A.↗