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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 415 records · Page 23
All sourcesNASA NTRSDOE OSTI
NASA NTRS2014

James Webb Space Telescope: The First Light Machine

NASA James Webb Space Telescope (JWST) will search for the first luminous objects of the Universe to help answer fundamental questions about how the Universe came to look like it does today. At 6.5 meters in diameter, JWST will be the world's largest space telescope. Its architecture, e.g. aperture, wavelength range and operating temperature, is driven by JWST's science objectives. Introduction: Scheduled to start its 5 year mission after 2018, JWST will study the origin and evolution of galaxies, stars and planetary systems. Its science mission is to: Identify the first bright objects that formed in the early Universe, and follow the ionization history. Determine how galaxies form. Determine how galaxies and dark matter, including gas, stars, metals, overall morphology and active nuclei evolved to the present day. Observe the birth and early development of stars and the formation of planets. And, study the physical and chemical properties of solar systems for the building blocks of Life. Principle: To accomplish the JWST science objectives requires a larger aperture infrared cryogenic space telescope. A large aperture is required because the objects are very faint. The infrared spectral range is required because the objects are so far away that their ultraviolet and visible wavelength spectral lines are red-shifted into the infrared. Because the telescope is infrared, it needs to be cryogenic. And, because of the telescope is infrared, it must operate above the Earth's atmosphere, i.e. in space. JWST is probably the single most complicated mission that humanity has attempted. It is certainly the most difficult optical fabrication and testing challenge of our generation. The JWST 6.5 m diameter primary mirror is nearly a parabola with a conic constant of -0.9967 and radius of curvature at 30K of 15.880 m. The primary mirror is divided into 18 segments with 3 different prescriptions; each with its own off-axis distance and aspheric departure. The radius of curvature for all 18 segments must match to +/- 0.150 mm at 30K. JWST is diffraction limited at 2 micrometers which translates into a transmitted wavefront specification of 156 nm rms. Of that amount, 50 nm rms is allocated to the primary mirror. Each segment is allocated 22 nm rms surface error. At the start of the JWST program, the capability to make such a mirror did not exist. In 1996, NASA began a systematic and comprehensive mirror technology development effort which resulted in JWST. This program resulted in a qualified mirror fabrication process being approved in 2006. Today, all JWST primary mirror segments meet their requirements and are on schedule for a 2018 launch. The next step is system level assembly, integration and test. Ambient tests will be conducted at Goddard Space Flight Center and cryogenic system level testing will be performed in Chamber A at the Johnson Space Center.

Stahl, H. Philip↗
NASA NTRSDate not supplied

A Low-Cost Innovative Observatory for the Reionization Explorer Mission (REX)

The early universe, from 400 to 800 million years after the Big Bang, or “Cosmic Dawn,” is characterized by large scale distributions of neutral and ionized intergalactic gas undergoing reionization on a cosmic scale at redshifts effectively unobservable through Earth’s atmosphere. Characterizing this active period of cosmological history requires wide-field, narrow passband surveys of galactic Lyman-alpha light red-shifted to the near infrared. REX combines low noise Near Infrared detectors and wide field optics to rapidly map large areas of space during the crucial Cosmic Dawn epoch of 400-800 million years after the Big Bang (Red Shift z=7 to z=10+).

T Casey↗
NASA NTRS1995

Dosimetry on STS-42 with the RME APD

Beginning with the STS-42 mission, this laboratory began participating in instrument comparison studies in which space radiation was measured contiguously by passive and active methods. The active instrument was the RME-3 microdosimeter. This instrument measures four-channel LET spectra and employs a tissue-equivalent proportional counter. It is sensitive to the full LET range of ionizing radiation present. Our area passive dosimeter, the RME APD, contained arrays of plastic nuclear track detectors (PNTD's) and thermoluminescent detectors (TLD's). The PNTD's measure LET spectra, while the TLD's measure total absorbed dose. The object of this experiment is to compare the active and passive measurements on the basis of LET spectra, total absorbed dose, and dose equivalent. The STS-42 mission was launched on January 22, 1992, with a flight duration of 8.052 days. The orbit had an inclination of 57 deg and an altitude of 302 km. The shuttle in this orbit is expected to encounter radiation levels dominated by galactic cosmic rays (GCR's) with a lesser contribution from trapped protons in the lower region of the South Atlantic Anomaly (SAA).

Source record↗
DOE OSTI2020

High efficiency continuous-flow production of radioisotopes

Methods and systems are provided for continuous-flow production of radioisotopes with high specific activity. Radioisotopes with high specific activity produced according to the methods described are also provided. The methods can include causing a liquid capture matrix to contact a target containing a target nuclide; irradiating the target with radiation, ionizing radiation, particles, or a combination thereof to produce the radionuclides that are ejected from the target and into the capture matrix; and causing the liquid capture matrix containing the radionuclides to flow from the target to recover the capture matrix containing the radionuclides with high specific activity. The methods are suitable for the production of a variety of radionuclides. For example, in some aspects the target nuclide is 237Np, and the radionuclide is 238Np that decays to produce 238Pu. In other aspects, the target nuclide is 98Mo, and the radionuclide is Mo that decays to produce 99mTc.

07 ISOTOPE AND RADIATION SOURCES↗
DOE OSTI2025

Cu-, Co-, and Zn-Based Metal–Organic Framework-Derived Nanoporous Ion Emitters for Picogram Level Analysis of Actinides

Thermal ionization mass spectrometry (TIMS) is often regarded as the preferred technique for trace-level isotopic analysis of actinides owing to its high sensitivity and absence of carry-over effects. However, actinide sample utilization efficiency (SUE) is typically low (<0.05%) without the use of activators or specialized loading approaches which can yield SUEs of >5%. To this effect, we investigate a series of metal–organic framework (MOF)-based nanoporous ion emitters (nano-PIEs) that show enhanced ionization of actinides when used in TIMS loading. We study the impact of physical and chemical properties of MOFs on TIMS SUEs using two families of MOFs that can be synthesized under similar reaction conditions. The structural and chemical properties of these MOFs can be systematically modified one at a time while keeping other features the same. This allows us to strategically investigate their impact on SUEs. The first family of MOFs considered in this study is Zeolitic Imidazole Frameworks (ZIFs) which are made using 2 methyl-imidazole as an organic linker with zinc (ZIF-8) and cobalt (ZIF-67) as metal centers. Additionally, the effect of morphology was also studied using Zn-based ZIF-L with a 2-dimensional structure. The second family of MOFs was synthesized using benzene-1,3,5-tricarboxylate (BTC) with copper (Cu-BTC) and zinc (Zn-BTC) as the metal center. Among the MOFs tested, Cu-BTC showed the highest SUE with an average SUE of 0.27 ± 0.15%, followed closely by Zn-BTC (0.24 ± 0.10%), ZIF-8 (0.17 ± 0.10%), and trailed by the other MOFs. When the MOFs were pyrolyzed in N 2 before loading, an apparent increase in the SUE was observed with ZIF-8 and Cu-BTC showing average SUEs of 0.25 ± 0.08% and 0.34 ± 0.13%, respectively, with the highest measured SUE of 0.53% for pyrolyzed Cu-BTC. In conclusion, this observed increase in SUE by up to an order of magnitude compared to bare filaments demonstrates the efficacy and potential of MOF-derived nano-PIEs for TIMS application.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1998

Theoretical Studies of Starburst Infrared Emission: Luminosity Indicators in Dusty Photoionized Environments

The luminosity of the central source in ionizing radiation is an essential parameter in a photoionized environment and is one of the most fundamental physical quantities one can measure. We outline a method of determining the luminosity for any emission-line region using only infrared data. In dusty environments, grains compete with hydrogen in absorbing continuum radiation. Grains produce infrared emission, and hydrogen produces recombination lines. We have computed a very large variety of photoionization models, using ranges of abundances, grain mixtures, ionizing continua, densities, and ionization parameters. The conditions were appropriate for such diverse objects as H(II) regions, planetary nebulae, starburst galaxies, and the narrow- and broad-line regions of active nuclei. The ratio of the total thermal grain emission relative to H-Beta (IR/H-Beta) is the primary indicator of whether the cloud behaves as a classical Stroemgren sphere (a hydrogen-bounded nebula) or whether grains absorb most of the incident continuum (a dust-bounded nebula). We find two global limits: when IR/H-Beta < 100, infrared recombination lines determine the source luminosity in ionizing photons; when IR/H-Beta >> 100, the grains act as a bolometer to measure the luminosity.

Bottorff, Mark↗
NASA NTRS1971

X-ray spectroscopy of solar active regions and flares.

Review of some recent contributions of X-ray spectroscopy to knowledge about solar active regions and flares. As an example of the importance of X-ray spectroscopy, it is pointed out that, while there are no emission lines from highly ionized silicon in the visible spectrum, the XUV spectrum has emission lines from SiIX through SiXIV. Jordan's (1969) calculations of ionization equilibria for silicon and iron are illustrated by diagrams and discussed. The observation of SiXIV gives evidence for regions having electron temperatures from 5 to 20 million deg. The ability to record the corona against the disk of the sun has enabled Van Speybroeck et al. (1970) to identify many bright diffuse X-ray emitting regions with remnants of old active regions of the type giving rise to unipolar magnetic regions. The physical characteristics of the hot coronal plasma associated with chromospheric flares are outlined on the basis of current observations.

Neupert, W. M.↗
NASA NTRS2012

Mass Spectrometric Studies of Oxides

Current studies at NASA Glenn on oxide thermodynamics are discussed. Previous studies on the vaporization of B2O3 in reducing atmospheres led to inconsistent studies when B was used as a reductant. It is shown that liquid B2O3 does not wet B and a clear phase separation was noted in the Knudsen cell. This problem was solved by using FeB and Fe2B to supply a different and constant activity of B. The thermodynamic data thus derived are compared to quantum chemical composite calculations. A major problem in high temperature mass spectrometry is the determination of accurate ionization cross sections, particularly for molecules. The method of Deutsch and Mark shows promise and some sample calculations are discussed. Finally current studies on the thermodynamics of rare earth silicates are discussed. Here the problems are obtaining a measurable signal from SiO2 vaporization and non-equilibrium vaporization. The use of a Ta reducing agent provides a stronger signal, which is related to silica activity. The Whitman-Motzfeld relation adapted to KEMS measurements is applied to obtain equilibrium pressures.

Jacobson, Nathan S.↗
NASA NTRS1975

Electron density profiles from ionograms - Underlying ionization corrections and their comparison with rocket results

Electron density profiles from nine daytime rocket flights at Wallops Island, Va., conducted at high and low levels of solar activity are compared with profiles calculated by inversion of ionograms obtained at the same times and location. Sources of error and uncertainty in the ionogram inversion are discussed, as are means for their amelioration. In most cases, agreement between the two kinds of measurement within a few percent in electron density and within a few percent of a scale height can be achieved.

Wright, J. W.↗
NASA NTRS2010

The Chandra X-Ray Observatory and its Role for the Study of Ionized Plasmas

NASA's Chandra X-Ray Observatory was launched in July of 1999. Featuring a 1000cm2-class X-ray telescope with sub-arcsecond angular resolution, the Observatory has observed targets from the solar system including the earth s moon, comets, and planets to the most distant galaxy clusters and active galactic nuclei. Capable of performing moderate energy resolution image-resolved spectroscopy using its CCD detectors, and high-resolution grating spectroscopy, the Observatory has produced, and continues to produce, valuable data and insights into the emission mechanisms of the ionized plasmas in which the X-rays originate. We present a brief overview of the Observatory to provide insight as to how to use it for your investigations. We also present an, admittedly brief and biased, overview of some of the results of investigations performed with Chandra that may be of interest to this audience.

Weisskopf, Martin C.↗
NASA NTRS2007

A Relation between the Mid-Infrared [Ne v] 14.3 Micrometers and [Ne III] 15.6 Micrometer Lines in Active Galactic Nuclei

We present a strong correlation between the [Ne v] 14.3 mm and [Ne III] 15.6 mm emission lines arising from the narrow-line regions (NLRs) of active galactic nuclei (AGNs), spanning 4 orders of magnitude in luminosity. The data are compiled primarily from Spitzer Space Telescope observations of nearby Seyfert galaxies (median z p 0.01) and 3C radio sources (median z p 0.52). This correlation is consistent with earlier studies in the optical/UV bands showing that line ratios arising in the NLRs are remarkably constant across AGNs. We also show that the correlation allows only a very narrow range in ionization parameter for simple photoionization models. The observed correlation will place tight constraints on alternative models, which predict constant line ratios over a broader range in ionization parameter.

emission lines↗
NASA NTRS1995

Detection of compact ultraviolet nuclear emission in liner galaxies

Low-ionization nuclear emission-line regions (LINERs), which exist in a large fraction of galaxies, may be the least luminous manifestation of quasar activity. As such, they may make possible the study of the active galactic nucleus (AGN) phenomenon in the nearest galaxies. The nature of LINERs has, however, remained controversial because an AGN-like nonstellar continuum source has not been directly observed in them. We report the detection of bright (greater than or approximately = 2 x 10(exp -16) ergs/s/sq cm/A), unresolved (full width at half maximum (FWHM) less than or approximately = 0.1 sec) point sources of UV (approximately 2300 A) emission in the nuclei of nine nearby galaxies. The galaxies were imaged using the Faint Object Camera (FOC) on the Hubble Space Telescope (HST), and seven of them are from a complete sample of 110 nearby galaxies that was observed with HST. Ground-based optical spectroscopy reveals that five of the nuclei are LINERs, three are starburst nuclei, and one is a Seyfert nucleus. The observed UV flux in each of the five LINERs implies an ionizing flux that is sufficient to account to the observed emission lines through photoionization. The detection of a strong UV continuum in the LINERs argues against shock excitation as the source of the observed emission lines, and supports the idea that photoionization excites the lines in at least some objects of this class. We have analyzed ground-based spectra for most of the northern-hemisphere galaxies in the HST sample and find that 26 of them are LINERs, among which only the above five LINERs have a detected nuclear UV source.

Maoz, Dan↗
DOE OSTI2024

Revealing the role of redox reaction selectivity and mass transfer in current–voltage predictions for ensembles of photocatalysts

Photocatalysts are conceptually simple reaction units where nanoscale semiconductors integrated with catalysts drive a pair of redox reactions on illumination. However, the proximity of reaction sites performing cathodic and anodic reactions poses dire challenges to realize large light-to-fuel conversion efficiencies. In this study, a powerful, yet straightforward, equivalent-circuit detail-balance modeling framework is developed and applied to evaluate the performance of photocatalytic systems featuring multiple light absorbers. Specifically, low bandgap iridium-doped strontium titanate is modeled as a Z-scheme photocatalyst to achieve desirable hydrogen evolution and iron-based redox shuttle oxidation reactions. Our model has unique capabilities to simulate competing redox reactions and address mass-transfer limitations. In a significant departure from state-of-the-art circuit models, our study develops tools to perform load-line analyses by incorporating a net electrochemical load curve that includes both desired and competing redox reactions. Consequently, reaction selectivity is predicted from equivalent circuit models for photocatalytic and photoelectrochemical systems. Our investigation into ensembles comprised of multiple, semi-transparent light absorbers reveals their potential to outperform a single, optically thick light absorber, particularly when operated under mass-transfer-limited conditions. However, this outcome hinges on minimizing mass-transfer rates of select redox species to prevent undesired reactions of hydrogen oxidation and/or redox shuttle reduction. Our findings demonstrate that reaction selectivity can be achieved by tuning asymmetry in redox species mass-transfer even with perfectly symmetric electrocatalytic charge-transfer coefficients. The influences of various kinetic, mass-transfer, and thermodynamic parameters are explored to offer crucial insights for synthesis of the next-generation of photocatalysts and selective coatings, and reactor designs.

25 ENERGY STORAGE↗
DOE OSTI2022

The EXO-200 detector, part II: auxiliary systems

The EXO-200 experiment searched for neutrinoless double-beta decay of 136 Xe with a single-phase liquid xenon detector. It used an active mass of 110 kg of 80.6%-enriched liquid xenon in an ultra-low background time projection chamber with ionization and scintillation detection and readout. Here, this paper describes the design and performance of the various support systems necessary for detector operation, including cryogenics, xenon handling, and controls. Novel features of the system were driven by the need to protect the thin-walled detector chamber containing the liquid xenon, to achieve high chemical purity of the Xe, and to maintain thermal uniformity across the detector.

47 OTHER INSTRUMENTATION↗
NASA NTRS1990

Scoping estimates of the LDEF satellite induced radioactivity

The Long Duration Exposure Facility (LDEF) satellite was recovered after almost six years in space. It was well-instrumented with ionizing radiation dosimeters, including thermoluminescent dosimeters, plastic nuclear track detectors, and a variety of metal foil samples for measuring nuclear activation products. The extensive LDEF radiation measurements provide the type of radiation environments and effects data needed to evaluate and help resolve uncertainties in present radiation models and calculational methods. A calculational program was established to aid in LDEF data interpretation and to utilize LDEF data for assessing the accuracy of current models. A summary of the calculational approach is presented. The purpose of the reported calculations is to obtain a general indication of: (1) the importance of different space radiation sources (trapped, galactic, and albedo protons, and albedo neutrons); (2) the importance of secondary particles; and (3) the spatial dependence of the radiation environments and effects expected within the spacecraft. The calculational method uses the High Energy Transport Code (HETC) to estimate the importance of different sources and secondary particles in terms of fluence, absorbed dose in tissue and silicon, and induced radioactivity as a function of depth in aluminum.

Armstrong, Tony W.↗
NASA NTRS1992

The Venus ionosphere from in situ measurements

The present characterization of the Venus ionosphere gives attention to features observed by the Pioneer Venus orbiter in situ ionospheric particle measuring instrument over an entire cycle of solar activity. A striking change is noted in the typical ionospheric morphology from solar maximum to minimum. The principal source of ionization in the dayside ionosphere during both solar maximum and minimum is solar EUV radiation, while that in the nightside is a downward flux of O(+) ions that originate in the dayside ionosphere and are transported across the nightside hemisphere by a supersonic ion wind. The dayside ionosphere contains fluxes of suprathermal electrons whose energy spectra are consistent with fluxes originating in EUV photo production.

Knudsen, William C.↗
NASA NTRS1996

Role of the micro/macro structure of welds in crack nucleation and propagation in aerospace aluminum-lithium alloy

Al-Li alloys offer the benefits of increased strength, elastic modulus and lower densities as compared to conventional aluminum alloys. Martin Marietta Laboratories has developed an Al-Li alloy designated 2195 which is designated for use in the cryogenic tanks of the space shuttle. The Variable Polarity Plasma Arc (VPPA) welding process is currently being used to produce these welds [1]. VPPA welding utilizes high temperature ionized gas (plasma) to transfer heat to the workpiece. An inert gas, such as Helium, is used to shield the active welding zone to prevent contamination of the molten base metal with surrounding reactive atmospheric gases. [1] In the Space Shuttle application, two passes of the arc are used to complete a butt-type weld. The pressure of the plasma stream is increased during the first pass to force the arc entirely through the material, a practice commonly referred to as keyholing. Molten metal forms on either side of the arc and surface tension draws this liquid together as the arc passes. 2319 Al alloy filler material may also be fed into the weld zone during this pass. During the second pass, the plasma stream pressure is reduced such that only partial penetration of the base material is obtained. Al 2319 filler material is added during this pass to yield a uniform, fully filled welded joint. This additional pass also acts to alter the grain structure of the weld zone to yield a higher strength joint.

Talia, George E.↗